Thermodynamic properties of binary mixtures formed by cyclic ethers and chloroalkanes 机翻标题: 暂无翻译,请尝试点击翻译按钮。

来源
Journal of thermal analysis and calorimetry
年/卷/期
2007 / 90 / 2
页码
587-595
ISSN号
1388-6150
作者单位
Univ Zaragoza, Fac Ciencias, Dept Quim Organ, Quim Fis, Zaragoza 50009, Spain;Escuela Politecn Super, Quim Fis, Dept Quim Organ, Huesca 22071, Spain;
作者
Giner I;Villares A;Haro M;Gascon I;Lafuente C;
摘要
Densities, speeds of sound and refractive indices of the binary mixtures 1,3-dioxolane or 1,4-dioxane+1-chloropentane or 1-chlorohexane have been measured at the temperatures of 298.15 and 313.15 K. Excess molar volumes, isentropic compressibilities, isentropic compressibility deviations and refractive index deviations have been obtained from experimental data. Excess molar volumes, isentropic compressibility and refractive index deviations have been fitted to a Redlich-Kister equation. Excess molar volumes, speeds of sound and isentropic compressibilities have been estimated at 298.15 K using the Prigogine-Flory-Patterson theory.
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关键词/主题词
chloroalkane;cyclic ether;density;PFP theory;refractive index;speed of sound;VAPOR-LIQUID-EQUILIBRIUM;ISOMERIC CHLOROBUTANES;STATISTICAL THERMODYNAMICS;VOLUMETRIC MEASUREMENTS;1;3-DIOXOLANE;1;4-DIOXANE;ALKANES;
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