(KR20180132845) a building containing Perfluoro (Polor) and Amidsilan compounds 机翻标题: 暂无翻译,请尝试点击翻译按钮。

源语言标题
(KR20180132845) a building containing Perfluoro (Polor) and Amidsilan compounds
公开号/公开日
KR10-2159595KR10-2018-0132845 / 2020-09-252018-12-12
申请号/申请日
KR10-2018-7032414 / 2017-08-30
发明人
MITSUHASHI HisashiNOMURA TAKASHINOSE MasatoshiNAITOU MASATO;
申请人
DAIKIN INDUSTRIES;
主分类号
IPC分类号
C07C-069/63 C07F-007/18 C09K-003/18
摘要
(KR10-2159595) The present invention provides a surface treatment agent which contains at least one type of perfluoro(poly)ether-modified amide silane compound represented by formula (1) (In the formula, each symbol has the same meaning as stated in the description), and at least one type of carboxylic acid ester compound represented by formula (2) (In the formula, each symbol has the same meaning as stated in the description), wherein the content of the carboxylic acid ester compound represented by formula (2) constitutes 4.1-35 mol%, inclusive, of the total content of the perfluoro(poly)ether-modified amide silane compound represented by formula (1) and the carboxylic acid ester compound represented by formula (2).  (From WO2018047686 A1)
机翻摘要
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地址
代理人
(KR102159595) JANG, SU GIL SEONG, JAE DONG
代理机构
;
优先权号
2016JP-0175842 2017WO-JP31086
主权利要求
(KR10-2159595) 1. At least one perfluoro (poly) ether modified amidesilane compound represented by the following formula (1):  Where: Rf1Represents an alkyl group having 1 to 16 carbon atoms which may be substituted by one or more fluorine atoms; PFPE1Are each independently-(OC6F12)a-(OC5F10)b-(OC4F8)c-(OC3F6)d-(OC2F4)e-(OCF2)f- Wherein a, b, c, d, e and f are each independently an integer of 0 or more and 200 or less, the sum of a, b, c, d, e and f is at least 1, the occurrence order of the respective repeating units in parentheses with the subscript a, b, c, d, e or f is not limited in the formula; and X1Is a single bond or-(Cr82)k1-(O)k2-(NR9)k3- , wherein: R8Are each independently a hydrogen atom or a fluorine atom; R9Are each independently a hydrogen atom, a phenyl group or a C1-6An alkyl group; k1 is an integer of 1 to 20; k2 is an integer of 0 to 10; k3 is an integer of 0 to 10; and wherein the occurrence order of the respective repeating units in parentheses with the subscript k1, k2 or k3 is not limited in the formula); and R1Are each independently a substituted or unsubstituted monovalent group selected from -X2-SiRa1l1Rb1m1Rc1n1X2Is-(Cr102)k4-(O)k5-(NR11)k6- , wherein: R10Are each independently a hydrogen atom or a fluorine atom; R11Are each independently a hydrogen atom, a phenyl group or a C1-6An alkyl group; k4 is an integer of 1 to 20; k5 is an integer of 0 to 10; k6 is an integer of 0 to 10; and wherein the occurrence order of the respective repeating units in parentheses with the subscript k4, k5 or k6 is not limited in the formula); and Ra1Are each independently at each occurrence -Z1-SiRa2l2Rb2m2Rc2n2Z1Are each independently at each occurrence an oxygen atom or a C1-6An alkylene group,-(CH2)g-O-(CH2)h- Wherein g is an integer from 1 to 6 and h is an integer from 1 to 6, or -phenylene-(CH2)i- Wherein i is an integer from 0 to 6; and Ra2Is each and independently at each occurrence Ra1'; Ra1'Is Ra1; and Ra1 Where Z1Si connected straight chain through a group is up to 5; Rb2Each occurrence independently represents a hydroxyl group or a hydrolyzable group; Rc2Each independently at each occurrence represents a hydrogen atom or an alkyl group having 1-20 carbons; l2 at each occurrence is each independently an integer of 0-3; m2 at each occurrence is each independently an integer of 0-3; n2 at each occurrence is each independently an integer of 0-3; and Rb1Each occurrence independently represents a hydroxyl group or a hydrolyzable group; Rc1Each independently at each occurrence represents a hydrogen atom or an alkyl group having 1-20 carbons; l1 at each occurrence is each independently an integer from 0-3; m1 at each occurrence is each independently an integer from 0-3; n1 at each occurrence is each independently an integer from 0-3; and R2Are each independently a hydrogen atom, a C1-6An alkyl group or a phenyl group; and p is 1 or 2; with the proviso that at least one Rb1 Or Rb2Are present] and at least one carboxylic acid ester compound represented by the following formula (2):  Wherein: R3Represents a hydrocarbon group; R4Is Rf2-PFPE2-X3- RF2Each independently represents an alkyl group having 1 to 16 carbon atoms which may be substituted by one or more fluorine atoms; PFPE2Each independently is-(OC6F12)a-(OC5F10)b-(OC4F8)c-(OC3F6)d-(OC2F4)e-(OCF2)f- Wherein a, b, c, d, e and f are each independently an integer of 0 or more and 200 or less, the sum of a, b, c, d, e and f is at least 1, the occurrence order of the respective repeating units in parentheses with the subscript a, b, c, d, e or f is not limited in the formula; and X3Is a single bond or-(Cr152)k7-(O)k8-(NR16)k9- , wherein: R15Are each independently a hydrogen atom or a fluorine atom; R16Are each independently a hydrogen atom, a phenyl group or a C1-6An alkyl group; k7 is an integer of 1 to 20; k8 is an integer of 0 to 10; k9 is an integer of 0 to 10; and wherein the occurrence order of the respective repeating units in parentheses with the subscript k7, k8 or k9 is not limited in the formula, Wherein the content of the carboxylic acid ester compound of the formula (2) is 4.5 mol% or more and 30 mol% or less relative to the total content of the perfluoro (poly) ether-modified amide silane compound of the formula (1) and the carboxylic acid ester compound of the formula (2). 2. The composite particle of claim 1 wherein Rf1Is a perfluoroalkyl group having 1 to 16 carbons. 3. The composition of claim 1 or 2, wherein the PFPE1A compound of formula (a), (b) or (c):-(OC3F6)d- [In the formula, d is an integer of 1 or more and 200 or less.]-(OC4F8)c-(OC3F6)d-(OC2F4)e-(OCF2)f- Wherein c and d are each independently an integer of 0 or more and 30 or less; e and f are each independently an integer of 1 or more and 200 or less; the sum of c, d, e and f is an integer of 10 or more and 200 or less; and the occurrence order of each repeating unit in parentheses with the subscript c, d, e or f is not limited in the formula. -(R6-R7)q-(c) Wherein R6Is OCF2 Or OC2F4; R7Silver OC3F6, OC4F8, OC5F10 And OC6F12Or a combination of two or three groups selected from these groups; and q is an integer of 2 to 100. 4. The compound of any one of Claims 1 to 2, wherein X1This,-(CF2)k1'- Or-(CF2)k1'-(O)k2'- Wherein: k1'is an integer of 1 to 6; k2' is an integer of 1 to 3; and wherein the occurrence order of the respective repeating units in parentheses with the subscript k1'or k2' is not limited in the formula, and X2Is-(CH2)k4'- Or-(CH2)k4'-Ok5'- Wherein: k4'is an integer of 1 to 6; k5' is an integer of 1 to 3; and wherein the occurrence order of the respective repeating units in parentheses with the subscript k4'or k5' is not limited in the formula. 5. The compound of claim 1 or 2, wherein R2Is an alkyl group having 1 to 3 carbons or a phenyl group. 6. The compound of claim 1 or 2, wherein Rb1 And Rb2Is OCH3 Or OC2H5Based on the total weight of the surface-treating agent. 7. The surface treatment agent according to claim 1 or 2, wherein p is 1. 8. The composite particle of claim 1 or 2 wherein Rf2Is a perfluoroalkyl group having 1 to 16 carbon atoms. 9. The composition of claim 1 or 2, wherein the PFPE2Is represented by the following formula (a), (b) or (c):-(OC3F6)d- [In the formula, d is an integer of 1 or more and 200 or less.]-(OC4F8)c-(OC3F6)d-(OC2F4)e-(OCF2)f- Wherein c and d are each independently an integer of 0 or more and 30 or less; e and f are each independently an integer of 1 or more and 200 or less; the sum of c, d, e and f is an integer of 10 or more and 200 or less; and the occurrence order of each repeating unit in parentheses with the subscript c, d, e or f is not limited in the formula. -(R6-R7)q-(c) Wherein R6Is OCF2 Or OC2F4; R7Silver OC3F6, OC4F8, OC5F10 And OC6F12Or a combination of two or three groups independently selected from these groups; and q is an integer of 2 to 100. 10. The compound of any one of Claims 1 to 2, wherein X3This,-(CF2)k7'- Or-(CF2)k7'-(O)k8'- Wherein: k7'is an integer of 1 to 6; k8' is an integer of 1 to 3; and wherein the occurrence order of the respective repeating units in parentheses with the subscript k7'or k8' is not limited in the formula. 11. The compound of claim 1 or 2, wherein R3Is an alkyl group having 1 to 3 carbons. 12. The surface treatment agent according to claim 1 or 2, further containing one or more other components selected from fluorine-containing oils, silicone oils and catalysts. 13. The method according to claim 12, wherein the fluorine-containing oil is a fluorine-containing oil represented by the formula (3):  Where: Rf5Represents an alkyl group having 1 to 16 carbon atoms which may be substituted by one or more fluorine atoms; Rf6Represents an alkyl group having 1 to 16 carbon atoms which may be substituted by one or more fluorine atoms, a fluorine atom or a hydrogen atom; a', b', c'and d' each represent the number of four repeating units of perfluoro (poly) ether constituting the main backbone of the polymer, Independently from each other, an integer of 0 or more and 300 or less, the sum of a', b', c'and d' is at least 1, and the occurrence order of the respective repeating units in parentheses with the subscript a', b', c'or d' is not limited in the formula. 14. The surface treatment agent according to claim 1 or 2, further comprising a solvent. 15. The surface treatment agent according to claim 1 or 2, which is used as an antifouling coating agent or a waterproof coating agent. 16. Pellets containing the surface treatment agent described in claim 1 or 2. 17. An article comprising a substrate and a layer formed on the surface of the substrate from the surface treatment agent described in claim 1 or 2. 18. The article of claim 17, wherein the substrate is glass or sapphire glass. 19. The article of claim 17, wherein the substrate is a glass selected from the group consisting of soda-lime glass, alkali aluminosilicate glass, borosilicate glass, alkali-free glass, crystal glass and quartz glass. 20. The article of claim 17 wherein the article is an optical member. 21. The article of claim 17 wherein the article is a display. 22. AMEND STATUS: Delete 23. AMEND STATUS: Delete 24. AMEND STATUS: Delete 25. AMEND STATUS: Delete 26. AMEND STATUS: Delete
法律状态
GRANTED
专利类型码
B1A
国别省市代码
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