(EP2432762) The invention relates to novel arylpyrroline compounds of formula (I) which have excellent insecticidal activity and which can thus be used as an insecticide.
(EP2432762) 1. Arylpyrroline compounds of formula (I) (see diagramm) wherein Q stands for a 2-pyridyl group, a 3-pyridyl group, or a 4-pyridyl group which may be substituted by at least one substituent X or X **1; X and X **1 each independently stand for fluorine, chlorine, bromine, iodine, C 1-12haloalkyl, nitro, C 1-12alkyl, or C 1-12alkoxyl, cyano, C 1-12haloalkoxyl, C 1-12alkylsulfenyl, C 1-12alkylsulfinyl, C 1-12alkylsulfonyl, C 1-12haloalkylsulfenyl, C 1-12haloalkylsulfinyl, or C 1-12haloalkylsulfonyl, hydroxyl, thiol, amino, C 1-12acylamino, C 1-12alkoxy-carbonylamino, C 1-12haloalkoxycarbonylamino, C 1-12alkoxyimino, C 1-12haloalkoxyimino, or C 1-12alkylsulfonylamino, or sulfur pentafluoride; A **1, A **2, A **3 and A **4 each independently stand for a carbon atom which may be substituted by a substituent Y, and whereas two adjacent substituents Y together with the carbon atoms to which they are attached may form a 5- or 6-membered aromatic ring, or A **1, A **2, A **3 and A **4 each independently stand for a nitrogen atom, under the proviso that only 2 of the chemical groups A **1, A **2, A **3 and A **4 stand at the same time for nitrogen; Y stands for fluorine, chlorine, bromine, iodine, C 1-12haloalkyl, nitro, C 1-12alkyl, C 3-8cycloalkyl, C 3-8cyclohaloalkyl, C 1-12alkoxyl, cyano, C 1-12haloalkoxyl, C 1-12alkylsulfenyl, C 1-12alkylsulfinyl, C 1-12alkylsulfonyl, C 1-12haloalkylsulfenyl, C 1-12haloalkylsulfinyl, C 1-12haloalkylsulfonyl, C 1-12alkylsulfonyloxy, C 1-12haloalkylsulfonyloxy, C 1-12alkylaminosulfonyl, C 1-12haloalkylaminosulfonyl, di(C 1-12)alkylaminosulfonyl, or di((C 1-12haloalkyl)aminosulfonyl, hydroxyl, thiol, amino, C 1-12alkylamino, di(C 1-12)alkylamino, C 1-12acylamino, C 1-12alkoxycarbonylamino, C 1-12haloalkoxycarbonylamino, C 1-12alkylsulfonylamino, C 1-12haloalkylsulfonylamino, C 1-12trialkylsilyl, C 1-12alkoxyimino, C 1-12 haloalkoxyimino, C 1-12alkoxyiminoalkyl, C 1-12haloalkoxyimino(C 1-12)alkyl, C 1-12alkylsulfinylimino, C 1-12alkylsulfinylimino(C 1-12)alkyl, C 1-12alkylsulfinylimino(C 1-12)alkylcarbonyl, C 1-12alkylsulfoxyimino, C 1-12alkylsulfoxyimino(C 1-12)alkyl, C 1-12alkoxycarbonyl, C 1-12alkylcarbonyl, aminocarbonyl, C 1-12alkylaminocarbonyl, aminothiocarbonyl, C 1-12alkylaminothiocarbonyl, di(C 1-12)alkylaminocarbonyl, or di(C 1-12)alkylaminothiocarbonyl; G stands for a heterocyclic group G1 to G9 having the following formula (see diagramm) which may be substituted by a substituent Z which is selected among fluorine, chlorine, bromine, iodine, C 1-6 haloalkyl, nitro, C 1-6alkoxy, cyano, C 1-6haloalkoxy, C 1-6alkylsulfenyl, C 1-6alkylsulfinyl, C 1-6alkylsulfonyl, C 1-6haloalkylsulfenyl, C 1-6haloalkylsulfinyl, C 1-6haloalkylsulfonyl, hydroxyl and thiol, or represents a chemical group G10 characterized by the following formula: (see diagramm) wherein R **1 and R **2 each independently stand for hydrogen, C 1-12alkyl, C 3-8cycloalkyl, C 1-12haloalkyl, C 3-8cyclohaloalkyl, C 2-12alkenyl, C 2-12alkynyl, C 2-12haloalkenyl, C 2-12haloalkynyl, cyano, C 1-12alkoxycarbonyl, or C 1-12 alkoxythiocarbonyl, or R **1 and R **2, together with the carbon atom to which they are attached, form a 3 to 6-membered carbocyclic ring; R **3 represents hydrogen, amino, hydroxyl, C 1-12alkoxy, C 1-12alkylcarbonylamino, C 1-12alkylimino, C 1-12alkyl, C 3-8cycloalkyl, or C 1-12haloalkyl, cyano, or C 2-12alkenyl, C 2-12alkynyl, or C 1-12alkylcarbonyl, or is selected from the following groups CH 2-R **5,C(=O)R **5, C(=S)R **5, R **4 represents a chemical group selected among hydrogen, cyano, C 1-12alkylcarbonyl, C 1-12alkylthiocarbonyl, C 1-12haloalkylcarbonyl, C 1-12haloalkylthiocarbonyl, C 1-12 alkylaminocarbonyl, C 1-12alkylaminothiocarbonyl, di(C 1-12)alkylaminocarbonyl, di(C 1-12)alkyl-aminothiocarbonyl, C 1-12alkoxyaminocarbonyl, C 1-12alkoxyaminothiocarbonyl, C 1-12alkoxycarbonyl, C 1-12alkoxythiocarbonyl, C 1-12thioalkoxycarbonyl, C 1-12thioalkoxythiocarbonyl, C 1-12alkylsulfonyl, C 1-12haloalkylsulfonyl, C 3-8cycloalkylcarbonyl, C 2-12alkenylcarbonyl, C 2-12alkynylcarbonyl, C 3-8cycloalkyl-(C 1-12)alkylcarbonyl, C 1-12alkylsulfonyl(C 1-12)alkylcarbonyl, C 1-12alkylsulfinyl(C 1-12)alkylcarbonyl, C 1-12alkylsulfonyl(C 1-12)alkylcarbonyl, C 1-12alkylcarbonyl(C 1-12)alkylcarbonyl, C 3-8cycloalkylaminocarbonyl, C 2-12 alkenylaminocarbonyl, C 2-12alkynylaminocarbonyl, C 1-12alkoxy(C 1-12)alkyl, or is selected from the groups C(=O)R **5 and C(=S)R **5, or R **3 and R **4, together with the nitrogen atom to which they are bound, form a 3- to 6-membered heterocyclic ring which may be substituted with a substituent X or X **1, or may be substituted with a keto, thioketo or nitroimino group; and R **5 represents optionally substituted phenyl, or an optionally substituted heterocyclic ring. 2. Arylpyrroline compounds according to claim 1, wherein in formula (I) the grouping (see diagramm) stands for a grouping selected among P1 to P4 (see diagramm) wherein Y is as defined herein, and k stands for 0, 1, 2, 3 or 4. 3. Composition, comprising at least one compound according to any one of claims 1 or 2 for controlling animal pests. 4. Use of at least one compound according to any one of claims 1 or 2 for preparing compositions for controlling arthropods. 5. Use of compounds according to any one of claims 1 or 2 for treating seed of conventional or transgenic plants. 6. Compounds according to any one of claims 1 or 2 for use against animal parasitic pests 7. Compounds according to any one of claims 1 or 2 for use for controlling arthropods which attack animals.
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indicator=Neg Event type=Event indicating Not In Force Event type=Payment or non-payment notifications Lapsed in a contracting state announced via postgrant inform. from nat. office to EPO LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Corresponding cc: Designated or member state=PL MEMBER STATE LEGAL DETAILS FOR RO Actual or expected expiration date=2015-10-30 Legal state=DEAD Status=LAPSED Corresponding cc: Designated or member state=RO Event publication date=2015-10-30 Event code=EP/PG25 Event indicator=Neg Event type=Event indicating Not In Force Event type=Payment or non-payment notifications Lapsed in a contracting state announced via postgrant inform. from nat. office to EPO LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Corresponding cc: Designated or member state=RO MEMBER STATE LEGAL DETAILS FOR SE Actual or expected expiration date=2015-07-31 Legal state=DEAD Status=LAPSED Corresponding cc: Designated or member state=SE Event publication date=2015-07-31 Event code=EP/PG25 Event indicator=Neg Event type=Event indicating Not In Force Event type=Payment or non-payment notifications Lapsed in a contracting state announced via postgrant inform. from nat. office to EPO LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Corresponding cc: Designated or member state=SE MEMBER STATE LEGAL DETAILS FOR SI Actual or expected expiration date=2016-02-29 Legal state=DEAD Status=LAPSED Corresponding cc: Designated or member state=SI Event publication date=2016-02-29 Event code=EP/PG25 Event indicator=Neg Event type=Event indicating Not In Force Event type=Payment or non-payment notifications Lapsed in a contracting state announced via postgrant inform. from nat. office to EPO LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Corresponding cc: Designated or member state=SI MEMBER STATE LEGAL DETAILS FOR SK Actual or expected expiration date=2015-10-30 Legal state=DEAD Status=LAPSED Corresponding cc: Designated or member state=SK Event publication date=2015-10-30 Event code=EP/PG25 Event indicator=Neg Event type=Event indicating Not In Force Event type=Payment or non-payment notifications Lapsed in a contracting state announced via postgrant inform. from nat. office to EPO LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Corresponding cc: Designated or member state=SK MEMBER STATE LEGAL DETAILS FOR SM Actual or expected expiration date=2017-05-31 Legal state=DEAD Status=LAPSED Corresponding cc: Designated or member state=SM Event publication date=2017-05-31 Event code=EP/PG25 Event indicator=Neg Event type=Event indicating Not In Force Event type=Payment or non-payment notifications Lapsed in a contracting state announced via postgrant inform. from nat. office to EPO LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Corresponding cc: Designated or member sta(...)
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