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公开号/公开日
US2016214930 A1 2016-07-28 [US20160214930] / 2016-07-28
申请号/申请日
2014US-15023424 / 2014-09-29
发明人
KILAAS LARS;NORDGARD ERLAND;DALAGER DYRLI ANNE;
申请人
RESMAN;
主分类号
IPC分类号
C07C-043/205C07C-069/42C07C-069/76C07C-309/10E21B-047/10
摘要
(US20160214930) The present invention relates to novel compounds of polyfunctionalized polyethylene and polypropylene glycols, their synthesis and their use, in particular as tracers in applications related to oil and gas production, and especially as specific markers of various target fluids.
机翻摘要
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地址
代理人
代理机构
;
优先权号
2013NO-0001305 2013-09-30 2014WO-NO50179 2014-09-29
主权利要求
(US20160214930) 15. A compound wherein the following generic structure    R1R2R3 -- (OCHR4 -- CH2 -- )n -- R5 -- [( -- CH2 -- CHR6O)m -- R7R8R9]p     wherein the core unit R5 are aryl or aralkyl units with 3-15 carbon atoms, or branched or linear alkyl units with from 3 to 12 carbon atoms, containing two or more ether functions and/or ester functions, connected to 2-4 groups by carbon, ether or ester bonds, optionally containing halogen atoms, sulfonic acids, phosphonic acids or salts thereof, with the exception of R5 being a group consisting of linear units of ethylene glycol or propylene glycol;   R4 and R6 is H or  -- CH3 to give PEG or PPG chains;   n and m are integers between 2 and 12 in which n is the same or different from m;   p is an integer between 1 and 3 depending on R5;   R3 and R7 are alkylic or alkenylic or aromatic hydrocarbon moieties with 2-40 carbon coupled to the PEG units or the PPG units by an ester or ether bond;   R2 and R8 are H;   R1 and R9 are sulfonic or phosphonic acid groups; or salts, hydrates and solvates thereof; or   a compound selected from the group consisting of:     Ex.Schemem/z.  asChemical nameNo.no.NH4 adduct21,2-bis(2-(2-(2-(benzyloxy)ethoxy)ethoxy)ethoxy)benzene1.2572.331,2-bis((1-phenyl-2,5,8,11-tetraoxatridecan-13-yl)oxy)benzene11.2660.441,2-bis((1-phenyl-2,5,8,11,14-pentaoxahexadecan-16-1.2748.5yl)oxy)benzene51,2-bis((1-phenyl-2,5,8,11,14,17-hexaoxanonadecan-19-1.2836.5yl)oxy)benzene61,2-bis((1-phenyl-2,5,8,11,14,17,20,23-octaoxapentacosan-1.21012.6/25-yl)oxy)benzene515.471,2-bis(2-(2-((4-methylbenzyl)oxy)ethoxy)ethoxy)benzene1.2512.481,2-bis(2-(2-(2-((4-1.2600.4methylbenzyl)oxy)ethoxy)ethoxy)ethoxy)benzene91,2-bis((1-(p-tolyl)-2,5,8,11-tetraoxatridecan-13-1.2688.5yl)oxy)benzene101,2-bis((1-(p-tolyl)-2,5,8,11,14-pentaoxahexadecan-16-1.2776.4yl)oxy)benzene111,2-bis((1-(p-tolyl)-2,5,8,11,14,17-hexaoxanonadecan-19-1.2864.5yl)oxy)benzene121,2-bis((1-(4-(tert-butyl)phenyl)-2,5,8,11-tetraoxatridecan-13-1.2772.5yl)oxy)benzene131,2-bis((1-(4-(tert-butyl)phenyl)-2,5,8,11,14,17,20,23-1.21124.7/octaoxapentacosan-25-yl)oxy)benzene571.5141,2-bis(2-(2-(naphthalen-2-ylmethoxy)ethoxy)ethoxy)benzene1.2584.4151,2-bis((1-(naphthalen-2-yl)-2,5,8,11,14,17-1.2936.4hexaoxanonadecan-19-yl)oxy)benzene161,3-bis((1-phenyl-2,5,8,11-tetraoxatridecan-13-yl)oxy)benzene1.3660.418(((((((4-methyl-1,2-phenylene)bis(oxy))bis(ethane-2,1-1.2498.4diyl))bis(oxy))bis(ethane-2,1-diyl))bis(oxy))bis(methylene))dibenzene19(((((((((4-methyl-1,2-phenylene)bis(oxy))bis(ethane-2,1-1.2586.3diyl))bis(oxy))bis(ethane-2,1-diyl))bis(oxy))bis(ethane-2,1-diyl))bis(oxy))bis(methylene))dibenzene2013,13'-((4-methyl-1,2-phenylene)bis(oxy))bis(1-phenyl-1.2674.52,5,8,11-tetraoxatridecane)2116,16'-((4-methyl-1,2-phenylene)bis(oxy))bis(1-phenyl-1.2762.52,5,8,11,14-pentaoxahexadecane)2219,19'-((4-methyl-1,2-phenylene)bis(oxy))bis(1-phenyl-1.2850.62,5,8,11,14,17-hexaoxanonadecane)2325,25'-((4-methyl-1,2-phenylene)bis(oxy))bis(1-phenyl-1.21026.5/2,5,8,11,14,17,20,23-octaoxapentacosane)522.4244,4'-(((((((4-methyl-1,2-phenylene)bis(oxy))bis(ethane-2,1-1.2526.4diyl))bis(oxy))bis(ethane-2,1-diyl))bis(oxy))bis(methylene))bis(methylbenzene)254,4'-(((((((((4-methyl-1,2-phenylene)bis(oxy))bis(ethane-2,1-1.2614.4diyl))bis(oxy))bis(ethane-2,1-diyl))bis(oxy))bis(ethane-2,1-diyl))bis(oxy))bis(methylene))bis(methylbenzene)2613,13'-((4-methyl-1,2-phenylene)bis(oxy))bis(1-(p-tolyl)-1.2702.52,5,8,11-tetraoxatridecane)2716,16'-((4-methyl-1,2-phenylene)bis(oxy))bis(1-(p-tolyl)-1.2790.52,5,8,11,14-pentaoxahexadecane)2819,19'-((4-methyl-1,2-phenylene)bis(oxy))bis(1-(p-tolyl)-1.2878.62,5,8,11,14,17-hexaoxanonadecane)294,4'-(((((((4-ethyl-1,3-phenylene)bis(oxy))bis(ethane-2,1-111.3540.5diyl))bis(oxy))bis(ethane-2,1-diyl))bis(oxy))bis(methylene))bis(methylbenzene)3013,13'-((4-ethyl-1,3-phenylene)bis(oxy))bis(1-(p-tolyl)-2,5,8,11-121.3716.4tetraoxatridecane)3119,19'-((4-ethyl-1,3-phenylene)bis(oxy))bis(1-(p-tolyl)-131.3892.5/2,5,8,11,14,17-hexaoxanonadecane)455.432(((((((4-(tert-butyl)-1,2-phenylene)bis(oxy))bis(ethane-2,1-1.2540.3diyl))bis(oxy))bis(ethane-2,1-diyl))bis(oxy))bis(methylene))dibenzene33(((((((((4-(tert-butyl)-1,2-phenylene)bis(oxy))bis(ethane-2,1-1.2628.5diyl))bis(oxy))bis(ethane-2,1-diyl))bis(oxy))bis(ethane-2,1-diyl))bis(oxy))bis(methylene))dibenzene3413,13'-((4-(tert-butyl)-1,2-phenylene)bis(oxy))bis(1-phenyl-1.2416.52,5,8,11-tetraoxatridecane)3516,16'-((4-(tert-butyl)-1,2-phenylene)bis(oxy))bis(1-phenyl-1.2804.52,5,8,11,14-pentaoxahexadecane)3619,19'-((4-(tert-butyl)-1,2-phenylene)bis(oxy))bis(1-phenyl-1.2892.62,5,8,11,14,17-hexaoxanonadecane)3725,25'-((4-(tert-butyl)-1,2-phenylene)bis(oxy))bis(1-phenyl-1.21068.5/2,5,8,11,14,17,20,23-octaoxapentacosane)543.5384,4'-(((((((4-(tert-butyl)-1,2-phenylene)bis(oxy))bis(ethane-2,1-1.2568.4diyl))bis(oxy))bis(ethane-2,1-diyl))bis(oxy))bis(methylene))bis(methylbenzene)394,4'-(((((((((4-(tert-butyl)-1,2-phenylene)bis(oxy))bis(ethane-1.2656.62,1-diyl))bis(oxy))bis(ethane-2,1-diyl))bis(oxy))bis(ethane-2,1-diyl))bis(oxy))bis(methylene))bis(methylbenzene)4013,13'-((4-(tert-butyl)-1,2-phenylene)bis(oxy))bis(1-(p-tolyl)-1.2744.52,5,8,11-tetraoxatridecane)4116,16'-((4-(tert-butyl)-1,2-phenylene)bis(oxy))bis(1-(p-tolyl)-1.2832.52,5,8,11,14-pentaoxahexadecane)4219,19'-((4-(tert-butyl)-1,2-phenylene)bis(oxy))bis(1-(p-tolyl)-1.2920.62,5,8,11,14,17-hexaoxanonadecane)4325,25'-((4-(tert-butyl)-1,2-phenylene)bis(oxy))bis(1-(4-(tert-1.21180.8/butyl)phenyl)-2,5,8,11,14,17,20,23-octaoxapentacosane)599.54419,19'-((4-(tert-butyl)-1,2-phenylene)bis(oxy))bis(1-1.2992.5(naphthalen-2-yl)-2,5,8,11,14,17-hexaoxanonadecane)45(((((((3,5-di-tert-butyl-1,2-phenylene)bis(oxy))bis(ethane-2,1-1.2596.5diyl))bis(oxy))bis(ethane-2,1-diyl))bis(oxy))bis(methylene))dibenzene4613,13'-((3,5-di-tert-butyl-1,2-phenylene)bis(oxy))bis(1-phenyl-1.2772.62,5,8,11-tetraoxatridecane)4719,19'-((3,5-di-tert-butyl-1,2-phenylene)bis(oxy))bis(1-phenyl-1.2948.62,5,8,11,14,17-hexaoxanonadecane)4825,25'-((3,5-di-tert-butyl-1,2-phenylene)bis(oxy))bis(1-phenyl-1.21124.7/2,5,8,11,14,17,20,23-octaoxapentacosane)571.54913,13'-((3,5-di-tert-butyl-1,2-phenylene)bis(oxy))bis(1-(4-(tert-1.2884.6butyl)phenyl)-2,5,8,11-tetraoxatridecane)5025,25'-((3,5-di-tert-butyl-1,2-phenylene)bis(oxy))bis(1-(4-(tert-1.21236.8/butyl)phenyl)-2,5,8,11,14,17,20,23-octaoxapentacosane)627.5511,2-bis(15-phenyl-2,5,8,11,14-pentaoxapentadecyl)benzene1.7688.2521,2-bis(27-phenyl-2,5,8,11,14,17,20,23,26-1.71040.6en space (1/2-em)nonaoxaheptacosyl)benzene531,2-bis(15-(4-(tert-butyl)phenyl)-2,5,8,11,14-181.7800.5pentaoxapentadecyl)benzene544,4'-(((((((4-chloro-1,3-phenylene)bis(oxy))bis(ethane-2,1-1.3546.2diyl))bis(oxy))bis(ethane-2,1-diyl))bis(oxy))bis(methylene))bis(methylbenzene)5513,13'-((4-chloro-1,3-phenylene)bis(oxy))bis(1-(p-tolyl)-151.3722.42,5,8,11-tetraoxatridecane)561,5-bis((1-phenyl-2,5,8,11-tetraoxatridecan-13-1.2710.4yl)oxy)naphthalene572,3-bis(2-(2-(benzyloxy)ethoxy)ethoxy)naphthalene1.2534.3582,3-bis(2-(2-(2-(benzyloxy)ethoxy)ethoxy)ethoxy)naphthalene1.2622.5592,3-bis((1-phenyl-2,5,8,11-tetraoxatridecan-13-61.2710.4yl)oxy)naphthalene602,3-bis((1-phenyl-2,5,8,11,14-pentaoxahexadecan-16-1.2798.4yl)oxy)naphthalene612,3-bis((1-phenyl-2,5,8,11,14,17-hexaoxanonadecan-19-1.2886.4yl)oxy)naphthalene622,3-bis((1-phenyl-2,5,8,11,14,17,20,23-octaoxapentacosan-1.21062.5/25-yl)oxy)naphthalene540.4632,3-bis(2-(2-((4-methylbenzyl)oxy)ethoxy)ethoxy)naphthalene1.2562.4642,3-bis(2-(2-(2-((4-1.2650.4methylbenzyl)oxy)ethoxy)ethoxy)ethoxy)naphthalene652,3-bis((1-(p-tolyl)-2,5,8,11-tetraoxatridecan-13-1.2738.4yl)oxy)naphthalene662,3-bis((1-(p-tolyl)-2,5,8,11,14-pentaoxahexadecan-16-1.2826.4yl)oxy)naphthalene672,3-bis((1-(p-tolyl)-2,5,8,11,14,17-hexaoxanonadecan-19-1.2914.6yl)oxy)naphthalene6813,13'-((propane-2,2-diylbis(4,1-phenylene))bis(oxy))bis(1-(p-1.2806.4tolyl)-2,5,8,11-tetraoxatridecane)6919,19'-((propane-2,2-diylbis(4,1-phenylene))bis(oxy))bis(1-(p-1.2982.5/tolyl)-2,5,8,11,14,17-hexaoxanonadecane)500.5701,33-bis(4-(tert-butyl)phenyl)-15,19-dimethyl-211.6796.62,5,8,11,14,17,20,23,26,29,32-undecaoxatritriacontane721,56-diphenyl-1.8992.62,5,8,11,14,17,20,23,26,31,34,37,40,43,46,49,52,55-octadecaoxahexapentacontane73bis(1-phenyl-2,5,8,11-tetraoxatridecan-13-yl) succinate5668.474bis(1-(4-(tert-butyl)phenyl)-2,5,8,11-tetraoxatridecan-13-yl)5780.5succinate75bis(1-(4-(tert-butyl)phenyl)-2,5,8,11,14,17,20,23-51132.6/octaoxapentacosan-25-yl) succinate575.576bis(1-phenyl-2,5,8,11-tetraoxatridecan-13-yl) glutarate25682.477bis(1-phenyl-2,5,8,11,14,17,20,23-octaoxapentacosan-25-yl)51034.5/glutarate526.478bis(1-(4-(tert-butyl)phenyl)-2,5,8,11-tetraoxatridecan-13-yl)5794.5glutarate79bis(1-phenyl-2,5,8,11-tetraoxatridecan-13-yl) adipate5696.4801,3,5-tris((1-(4-(tert-butyl)phenyl)-2,5,8,11-tetraoxatridecan-13-1.21110.7en space (1/2-em)yl)oxy)benzene811,3,5-tris(15-phenyl-2,5,8,11,14-pentaoxapentadecyl)benzene241.9984.5821,3,5-tris(27-phenyl-2,5,8,11,14,17,20,23,26-251.9765.6nonaoxaheptacosyl)benzene83tris(1-phenyl-2,5,8,11-tetraoxatridecan-13-yl) benzene-1,3,5-351026.4en space  (1/2-em)tricarboxylate13625,25'-((4-ethyl-1,3-phenylene)bis(oxy))bis(1-phenyl-141.21104.4/2,5,8,11,14,17,20,23-octaoxapentacosane)561.41381,2-bis((1-(naphthalen-2-yl)-2,5,8,11-tetraoxatridecan-13-1.2760.4yl)oxy)benzene1392,2'-(((((((4-(tert-butyl)-1,2-phenylene)bis(oxy))bis(ethane-2,1-1.2640.4diyl))bis(oxy))bis(ethane-2,1-diyl))bis(oxy))bis(methylene))dinaphthalene14013,13'-((4-(tert-butyl)-1,2-phenylene)bis(oxy))bis(1-1.2816.4(naphthalen-2-yl)-2,5,8,11-tetraoxatridecane) 1-14. (canceled) 16. A compound according to claim 15, wherein n and m are integers between 3 and 12. 17. A compound according to claim 15, wherein the core R5 unit is selected from the group consisting of:   18. A compound according to claim 15 selected from:    Ex.Schemem/z. asChemical nameNo.no.NH4 adduct84potassium 3,3'-(((((1,2-phenylenebis(oxy))bis(ethane-2,1-71.2.4548.2diyl))bis(oxy))bis(ethane-2,1-diyl))bis(oxy))bis(propane-1-sulfonate)85potassium 3,3'-(((((((1,2-phenylenebis(oxy))bis(ethane-2,1-1.2.4636.3diyl))bis(oxy))bis(ethane-2,1-diyl))bis(oxy))bis(ethane-2,1-diyl))bis(oxy))bis(propane-1-sulfonate)86potassium 1,1'-(1,2-phenylenebis(oxy))bis(3,6,9,12-81.2.4724.3tetraoxapentadecane-15-sulfonate)87potassium 1,1'-(1,2-phenylenebis(oxy))bis(3,6,9,12,15,18-1.2.4900.3/hexaoxahenicosane-21-sulfonate)459.288potassium 1,1'-(1,2-1.2.41076.8/phenylenebis(oxy))bis(3,6,9,12,15,18,21,24-547.4octaoxaheptacosane-27-sulfonate)89potassium 4,4'-(((((1,2-phenylenebis(oxy))bis(ethane-2,1-1.2.4567.0diyl))bis(oxy))bis(ethane-2,1-diyl))bis(oxy))bis(butane-1-sulfonate)90potassium 1,1'-(1,2-phenylenebis(oxy))bis(3,6,9,12-1.2.4752.3tetraoxahexadecane-16-sulfonate)91potassium 1,1'-(1,2-phenylenebis(oxy))bis(3,6,9,12,15,18-1.2.4928.3/hexaoxadocosane-22-sulfonate)473.392potassium 1,1'-(1,2-1.2.41104.4/phenylenebis(oxy))bis(3,6,9,12,15,18,21,24-561.2octaoxaoctacosane-28-sulfonate)93potassium 3,3'-((((((4-methyl-1,2-1.2.4562.3phenylene)bis(oxy))bis(ethane-2,1-diyl))bis(oxy))bis(ethane-2,1-diyl))bis(oxy))bis(propane-1-sulfonate)94potassium 1,1'-((4-methyl-1,2-91.2.4738.1/phenylene)bis(oxy))bis(3,6,9,12-tetraoxapentadecane-15-378.3sulfonate)95potassium 1,1'-((4-methyl-1,2-1.2.4914.3/phenylene)bis(oxy))bis(3,6,9,12,15,18-hexaoxahenicosane-466.321-sulfonate)96potassium 1,1'-((4-methyl-1,2-1.2.41090.8/phenylene)bis(oxy))bis(3,6,9,12,15,18,21,24-554.4octaoxaheptacosane-27-sulfonate)97potassium 4,4'-((((((4-methyl-1,2-1.2.4590.0phenylene)bis(oxy))bis(ethane-2,1-diyl))bis(oxy))bis(ethane-2,1-diyl))bis(oxy))bis(butane-1-sulfonate)98potassium 1,1'-((4-methyl-1,2-101.2.4766.4phenylene)bis(oxy))bis(3,6,9,12-tetraoxahexadecane-16-sulfonate)99potassium 1,1'-((4-methyl-1,2-1.2.4942.0/phenylene)bis(oxy))bis(3,6,9,12,15,18-hexaoxadocosane-22-480.3sulfonate)100potassium 1,1'-((4-methyl-1,2-1.2.41118/phenylene)bis(oxy))bis(3,6,9,12,15,18,21,24-568octaoxaoctacosane-28-sulfonate)101potassium 1,1'-((((((4-methyl-1,2-171.2.4618.3phenylene)bis(oxy))bis(ethane-2,1-diyl))bis(oxy))bis(ethane-2,1-diyl))bis(oxy))bis(pentane-3-sulfonate)102potassium 4,4'-((((((4-methyl-1,2-161.2.4742.3phenylene)bis(oxy))bis(ethane-2,1-diyl))bis(oxy))bis(ethane-2,1-diyl))bis(oxy))bis(1-phenylbutane-2-sulfonate)103potassium 1,1'-((4-methyl-1,2-phenylene)bis(oxy))bis(28-1.2.4644.5phenyl-3,6,9,12,15,18,21,24-octaoxaoctacosane-27-sulfonate)104potassium 3,3'-((((((4-ethyl-1,3-1.2.4576.3phenylene)bis(oxy))bis(ethane-2,1-diyl))bis(oxy))bis(ethane-2,1-diyl))bis(oxy))bis(propane-1-sulfonate)105potassium 1,1'-((4-ethyl-1,3-phenylene)bis(oxy))bis(3,6,9,12-1.2.4752.3tetraoxapentadecane-15-sulfonate)106potassium 1,1'-((4-ethyl-1,3-1.2.4928.3/phenylene)bis(oxy))bis(3,6,9,12,15,18-hexaoxahenicosane-473.321-sulfonate)107potassium 1,1'-((4-ethyl-1,3-1.2.41104.4/phenylene)bis(oxy))bis(3,6,9,12,15,18,21,24-561.2octaoxaheptacosane-27-sulfonate)108potassium 4,4'-((((((4-ethyl-1,3-1.2.4604.3phenylene)bis(oxy))bis(ethane-2,1-diyl))bis(oxy))bis(ethane-2,1-diyl))bis(oxy))bis(butane-1-sulfonate)109potassium 1,1'-((4-ethyl-1,3-phenylene)bis(oxy))bis(3,6,9,12-1.2.4780.3tetraoxahexadecane-16-sulfonate)110potassium 1,1'-((4-ethyl-1,3-1.2.4956.4/phenylene)bis(oxy))bis(3,6,9,12,15,18-hexaoxadocosane-22-487.3sulfonate)111potassium 1,1'-((4-ethyl-1,3-1.2.41132.2/phenylene)bis(oxy))bis(3,6,9,12,15,18,21,24-575.1octaoxaoctacosane-28-sulfonate)112potassium 3,3'-((((((4-(tert-butyl)-1,2-1.2.4604.3phenylene)bis(oxy))bis(ethane-2,1-diyl))bis(oxy))bis(ethane-2,1-diyl))bis(oxy))bis(propane-1-sulfonate)113potassium 1,1'-((4-(tert-butyl)-1,2-1.2.4780.4/phenylene)bis(oxy))bis(3,6,9,12-tetraoxapentadecane-15-399.4sulfonate)114potassium 1,1'-((4-(tert-butyl)-1,2-1.2.4956.5/phenylene)bis(oxy))bis(3,6,9,12,15,18-hexaoxahenicosane-487.421-sulfonate)115potassium 1,1'-((4-(tert-butyl)-1,2-1.2.41132.8/phenylene)bis(oxy))bis(3,6,9,12,15,18,21,24-575.4octaoxaheptacosane-27-sulfonate)116potassium 4,4'-((((((4-(tert-butyl)-1,2-1.2.4632.3phenylene)bis(oxy))bis(ethane-2,1-diyl))bis(oxy))bis(ethane-2,1-diyl))bis(oxy))bis(butane-1-sulfonate)117potassium 1,1'-((4-(tert-butyl)-1,2-1.2.4808.5/phenylene)bis(oxy))bis(3,6,9,12-tetraoxahexadecane-16-413.4sulfonate)118potassium 1,1'-((4-(tert-butyl)-1,2-1.2.4984.5/phenylene)bis(oxy))bis(3,6,9,12,15,18-hexaoxadocosane-22-501.4sulfonate)119potassium 1,1'-((4-(tert-butyl)-1,2-1.2.41160/phenylene)bis(oxy))bis(3,6,9,12,15,18,21,24-589.4octaoxaoctacosane-28-sulfonate)120potassium 1,1'-((3,5-di-tert-butyl-1,2-1.2.4836.4/phenylene)bis(oxy))bis(3,6,9,12-tetraoxapentadecane-15-427.4sulfonate)121potassium 1,1'-((3,5-di-tert-butyl-1,2-1.2.41012.5/phenylene)bis(oxy))bis(3,6,9,12,15,18-hexaoxahenicosane-515.421-sulfonate)122potassium 1,1'-((3,5-di-tert-butyl-1,2-1.2.4864.5/phenylene)bis(oxy))bis(3,6,9,12-tetraoxahexadecane-16-441.4sulfonate)123potassium 3,3'-((((((4-chloro-1,3-1.2.4582.2phenylene)bis(oxy))bis(ethane-2,1-diyl))bis(oxy))bis(ethane-2,1-diyl))bis(oxy))bis(propane-1-sulfonate)124potassium 1,1'-((4-chloro-1,3-phenylene)bis(oxy))bis(3,6,9,12-1.2.4758.2tetraoxapentadecane-15-sulfonate)125potassium 4,4'-((((((4-chloro-1,3-1.2.4610.2phenylene)bis(oxy))bis(ethane-2,1-diyl))bis(oxy))bis(ethane-2,1-diyl))bis(oxy))bis(butane-1-sulfonate)126potassium 1,1'-((4-chloro-1,3-phenylene)bis(oxy))bis(3,6,9,12-1.2.4786.3tetraoxahexadecane-16-sulfonate)127potassium 3,3'-(((((naphthalene-2,3-diylbis(oxy))bis(ethane-1.2.4598.32,1-diyl))bis(oxy))bis(ethane-2,1-diyl))bis(oxy))bis(propane-1-sulfonate)128potassium 1,1'-(naphthalene-2,3-diylbis(oxy))bis(3,6,9,12-1.2.4774.3/tetraoxapentadecane-15-sulfonate)396.3129potassium 1,1'-(naphthalene-2,3-1.2.4950.3/diylbis(oxy))bis(3,6,9,12,15,18-hexaoxahenicosane-21-484.3sulfonate)130potassium 1,1'-(naphthalene-2,3-1.2.41126.8/diylbis(oxy))bis(3,6,9,12,15,18,21,24-octaoxaheptacosane-27-572.4sulfonate)131potassium 4,4'-(((((naphthalene-2,3-diylbis(oxy))bis(ethane-1.2.4626.32,1-diyl))bis(oxy))bis(ethane-2,1-diyl))bis(oxy))bis(butane-1-sulfonate)132potassium 1,1'-(naphthalene-2,3-diylbis(oxy))bis(3,6,9,12-1.2.4802en space (1/2-em)tetraoxahexadecane-16-sulfonate)133potassium 1,1'-(naphthalene-2,3-1.2.4978.3/diylbis(oxy))bis(3,6,9,12,15,18-hexaoxadocosane-22-498.4sulfonate)134potassium 1,1'-(naphthalene-2,3-1.2.41154.6/diylbis(oxy))bis(3,6,9,12,15,18,21,24-octaoxaoctacosane-28-586.3sulfonate)1351,1'-(1,2-phenylenebis(oxy))bis(3,6,9,12,15,18,21,24-41.2.41104.4/octaoxaoctacosane-28-sulfonic acid)561.213625,25'-((4-ethyl-1,3-phenylene)bis(oxy))bis(1-phenyl-141.21104.4/2,5,8,11,14,17,20,23-octaoxapentacosane)561.4137potassium 1,1'-((4-methyl-1,2-1.2.4794.4/phenylene)bis(oxy))bis(3,6,9,12-tetraoxaheptadecane-15-406.3sulfonate) 19. A compound according to claim 15, as tracers by LC-MS. 20. A composition comprising at least one compound according to claim 15 and at least one additional constituent like solvents, diluents, surfactants, adsorbents, stabilizers and/or formulated into tablets or capsules or other matrix forms and geometrical shapes. 21. The use of a compound wherein the following generic structure R1R2R3 -- (OCHR4 -- CH2 -- )n -- R5 -- [( -- CH2 -- CHR6O)m -- R7R9R9]p, wherein the core unit R5 are aryl or aralkyl units with 3-24 carbon atoms, or branched or linear alkyl units with from 3 to 12 carbon atoms, containing two or more ether functions and/or ester functions and connected to 2-4 groups by carbon, ether or ester bonds, with the exception of R5 being a group consisting of linear units of ethylene glycol or propylene glycol; R4 and R6 is H or  -- CH3 to give PEG or PPG chains;   n and m are integers between 2 and 12 in which n is the same or different from m;   p is an integer between 1 and 3 depending on R5;   R3 and R7 are alkylic or alkenylic or aromatic hydrocarbon moieties with 2-40 carbon coupled to the PEG units or the PPG units by an ester or ether bond;   R1, R2, R8 and R9 are all H or identical or different hydrophilic functional groups selected from the group consisting of carboxylic, sulfonic or phosphonic acid groups; or salts, hydrates and solvates thereof;   or a composition according to claim 20, as a tracer. 22. The use according to claim 21, as tracers in fluid systems. 23. The use according to claim 21, as tracers for inflow monitoring during oil and gas production. 24. The use according to claim 21, where components are detected topside after release from oil and gas wells. 25. The use according to claim 21, where the components are detected topside after release from oil and gas wells by LCMS, GCMS or a combination thereof.
法律状态
(US20160214930) LEGAL DETAILS FOR US2016214930  Actual or expected expiration date=2034-09-29    Legal state=ALIVE    Status=PENDING     Event publication date=2014-09-29  Event code=US/APP  Event indicator=Pos  Event type=Examination events  Application details  Application country=US US15023424  Application date=2014-09-29  Standardized application number=2014US-15023424     Event publication date=2016-07-28  Event code=US/A1  Event type=Examination events  Application published  Publication country=US  Publication number=US2016214930  Publication stage Code=A1  Publication date=2016-07-28  Standardized publication number=US20160214930
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A1
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