Non-aqueous active ingredient concentrates having an herbicidal effect 机翻标题: 暂无翻译,请尝试点击翻译按钮。

公开号/公开日
WO2008015279 A2 2008-02-07 [WO200815279]WO2008015279 A3 2008-08-07 [WO200815279] / 2008-02-072008-08-07
申请号/申请日
2007WO-EP58091 / 2007-08-03
发明人
KRAPP MICHAEL;BERGHAUS RAINER;BRATZ MATTHIAS;KIBLER ELMAR;VANTIEGHEM HERVE R;
申请人
BASF;
主分类号
IPC分类号
A01N-025/32A01N-043/10A01N-043/78A01N-043/80
摘要
(WO200815279) The present invention relates to active ingredient concentrates having an herbicidal effect, comprising: a) 10 to 100 g/L of at least one 4-benzoyl-substituted pyrazol compound of the formula (I), wherein R<SUP>1</SUP>, R<SUP>3</SUP> independently of each other stand for hydrogen, halogen, hethyl, halogen methyl, methoxy, halogen methoxy, methylthio, methyl sulfinyl, or methyl sulfonyl; R<SUP>2</SUP> stands for a 5-membered heterocyclic residue, which is unsubstituted, or carries 1, 2, 3, or 4 substituents, which are selected from halogen, C<SUB>1</SUB>-C<SUB>6</SUB>-alkyl, C<SUB>1</SUB>-C<SUB>4</SUB>-akoxy, C<SUB>1</SUB>-C<SUB>4</SUB>-halogen alkyl, C<SUB>1</SUB>-C<SUB>4</SUB>-halogen alkoxy, and C<SUB>1</SUB>-C<SUB>4</SUB>-alkylthio; R<SUP>4</SUP> stands for hydrogen, halogen, or methyl; R<SUP>5</SUP> stands for C<SUB>1</SUB>-C<SUB>6</SUB>-alkyl, C<SUB>3</SUB>-C<SUB>6</SUB>-cycloalkyl, or C<SUB>3</SUB>-C<SUB>6</SUB>-cycloalkylmethyl; and R<SUP>6</SUP> stands for hydrogen, or C<SUB>1</SUB>-C<SUB>4</SUB>-Alkyl; or one of its salts used in agriculture, b) 200 to 700 g/L 2-chlorine-N-(2,4-dimethyl-3-thienyl)-N-(2-methoxy-1-methylethyl)-acetamide, and 25 c) 10 to 200 g/L of at least a surface-active substance S, which is selected from a mixture of at least one anionic surface-active compound, and at least one non-ionic surface-active compound, wherein the components a), b), and c) are dissolved in an organic solvent mixture, which comprises at least 95 wt.-%, based on the solvent mixture, of d1) at least one aprotic polar organic solvent, which has a miscibility with water at 25°C and 1 bar of at least 50 g/l, and d2) at least one organic solvent, which has a solubility in water at 25°C and 1 bar of less than 5 g/l.
机翻摘要
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地址
代理人
代理机构
;
优先权号
2006EP-0118445 2006-08-04
主权利要求
(WO200815279) Claims 1. Non-aqueous active compound concentrate, comprising A) 10 to 100 g/L of at least one connector formation - 4-Benzoyl-substituted pyrazole of the formula I wherein R1, R3are independently hydrogen, halogen, methyl, halomethyl, methoxy, halomethoxy, Methylthio, methylsulphinyl or methylsulphonyl are; R25-membered heterocyclic radical is a, - or 1 group is the unsubstitu, 2, 3 or 4 substituent, the substituent selected from halo, d-ce-alkyl, ci-C4- alkoxy, ci-C4- haloalkyl, d-C4- halo - alkoxy and ci-C4- Alkylthio are; R4hydrogen, halogen or methyl; R5d-ce-alkyl, C3- C6- cycloalkyl or C3- C6- cycloalkylmethyl; and R6is hydrogen or ci - C4- Al is allcyl; or one of its agriculturally useful salts, b) 200 to 700 g/L - 2-chloro-N(2.4-dimethyl-3-thienyl) - N - (- methyl - ethyl 2-methoxy-1) acetamide, and C) 10 to 200 g/L at least one surfactant S, is selected from a mixture of at least one anionic surfactant and at least one nonionic surface-active substance, wherein components a), b) and c) are dissolved in an organic solvent mixture, at least 95 -% by weight to, based on the solvent mixture, from α " l) at least one aprotic polar organic solvent, at 25 a miscibility with water01 bar of at least 50 g/liter and C has, and d2) at least one organic solvent, at 25 in water01 C and a solubility of less than 5 gms/l bar having, is. 2. Active substance concentrate according to claim 1, wherein the organic solvent constitutes 200 to 800 gms/L of the formulation. 3. Active substance concentrate according to claim 1 or 2, wherein the aprotic polar, organic solvent is selected from dimethyl sulfoxide, sulfolane, the amides, N-ci-C4 alkylamides and N, N-Di - (ci-C4-alkyl) amides of aliphatic monocarboxylic acids having 1 to 12 C atoms -, N-ci - C4 kyllactamen- Al and mixtures thereof. 4. Active substance concentrate according to claim 3, wherein the aprotic polar, organic solvent is selected from dimethylsulfoxide, N-methylpyrrolidone, N-ethylpyrrolidone and mixtures thereof. 5. Active substance concentrate according to one of the preceding claims, wherein the weight ratio of aprotic polar solvent and hydrocarbon - Ge - 5 solvent in the range of: 1 to 1:5 is. 6. Active substance concentrate according to one of the preceding claims, wherein the anionic surfactant is selected from compounds, - a SC runs at least the we " 3 group or a Pcu group and at least one of which the resulting hydrocarbon radical having 8 to 22 - aliphatiC atoms or an araliphatic hydrocarbon radical having 10 to 24 C-atoms. 7. Active substance concentrate according to one of the preceding claims, wherein the non - ionic surfactant as a main component at least one poly - C2 - C3 - glycol ethers-compound. 8. An aqueous active compound concentrate, comprising A) 10 to 100 gms/L of at least one compound of formula I 4-Benzoyl-substituted pyrazole as defined in claim 1, b) 200 to 700 g/L - 2-chloro-N(2.4-dimethyl-3-thienyl) - N - (ethyl - 2-methoxy-1-methyl) acetamide, and C) 10 to 200 g/L at least one surfactant S, is selected out of the non-ionic surfactants and mixtures thereof with - at least one anionic surface-active substance, wherein components a) and b) are present in dispersed form in an aqueous diluent. 9. Active substance concentrate according to claim 8, wherein the non-ionic surfactant as a main component containing a compound of the formula III R-O-I(A-O)x; (E-OJy]R1 wherein Cio-C22-alkyl for R, C8 - C22 - Alkylphenyl, Mono -, Di - or Tristyryl is, R′ is hydrogen, Ci- Cio-alkyl, benzyl, Formyl or Ci- Cio-Alkylcarbonyl, A is CH (CH3) CH2is, CH E2CH2is, x is a number in the range of from 1 to 30 and y is a number in the range of 2 to 50 are. 10. Active substance concentrate according to claim 9, wherein the non-ionic surfactant further comprises at least one ethylene oxide-propylene oxide block copolymer. 1 1st Active substance concentrate according to one of the preceding claims, wherein the weight ratio of compound I to - Ge 2-chloro-N - (2.4-dimethyl-3-thienyl) - N - (2 - methoxy-1-methyl) acetamide is in the range of 1:5 to 1: is 50. 12. Active substance concentrate according to one of the preceding claims, containing 2-chloro-N - (2.4-dimethyl-3-thienyl) - N - (2-methoxy-1-methyl ethyl) acetamide in the form of itS- enantiomer or in the form of a non-racemic mixture of the two Enantiomers with an enantiomeric excess of the S-enantiomer of at least 80%. 13. Active substance concentrate according to one of the preceding claims, wherein in formula I R1and R5are each methyl, R2for 4.5- Dihydroisoxazol-3-yl is, R4methvlsulfonvl means and R6is hydrogen. 14. Use of an active compound concentrate according to any one of claims 1 to 13 for controlling undesired plant growth. 15. Method for controlling undesirable plant growth, characterized in, that an aqueous spray liquor by diluting a concentrate of active ingredient - producing plant according to any one of claims 1 to 13 and, their seeds and/or their habitat. 16. Method according to claim 15, characterized in, that the leaves of the undesired plants are treated with the aqueous spray liquor.
法律状态
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