Synthesis, structural and Raman spectroscopic in organic-inorganic halide perovskites based on beta-Alanine 机翻标题: 暂无翻译,请尝试点击翻译按钮。

2020-02-10

The amino acid copper chlorides [NH3C2H4CO2H](2) CuCl4 is a new member of the family of organicinorganic hybrid like perovskite system. This compound crystallizes in the monoclinic space group C2/c with unit cell parameters a = 25.1209 (3) angstrom, b = 7.7432 (2) angstrom, c = 7.4130 (2) angstrom, beta = 105.293 (2)degrees and Z = 4. The molecule formula consists of a combination of [CuCl4](2-) anions and two twisted organic [NH3(CH2)(2)CO2H](+) cations to form a two-dimensional perovskite system. Three dimensional hydrogen - bonding network is assuring the cohesion between these layers to stabilize the crystal. The micro-Raman spectroscopy measurement technique is used to probe organic-inorganic halide perovskite vibration modes and to study the effect of laser beam power on the intensity of Raman lines. (C) 2019 Elsevier B.V. All rights reserved.

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