来源

Dyes and Pigments

年/卷/期

2019 / 166 /

页码

340-349

ISSN号

0143-7208

作者单位

Heilongjiang Univ, Sch Chem Chem Engn & Mat, Dept Macromol Sci & Engn, Minist Educ,Key Lab Funct Inorgan Mat Chem, Harbin 150086, Heilongjiang, Peoples R China;Heilongjiang Univ, Sch Chem Chem Engn & Mat, Dept Macromol Sci & Engn, Minist Educ,Key Lab Funct Inorgan Mat Chem, Harbin 150086, Heilongjiang, Peoples R China;Heilongjiang Univ, Sch Chem Chem Engn & Mat, Dept Macromol Sci & Engn, Minist Educ,Key Lab Funct Inorgan Mat Chem, Harbin 150086, Heilongjiang, Peoples R China;Heilongjiang Univ, Sch Chem Chem Engn & Mat, Dept Macromol Sci & Engn, Minist Educ,Key Lab Funct Inorgan Mat Chem, Harbin 150086, Heilongjiang, Peoples R China;Heilongjiang Univ, Sch Chem Chem Engn & Mat, Dept Macromol Sci & Engn, Minist Educ,Key Lab Funct Inorgan Mat Chem, Harbin 150086, Heilongjiang, Peoples R China;Heilongjiang Univ, Sch Chem Chem Engn & Mat, Dept Macromol Sci & Engn, Minist Educ,Key Lab Funct Inorgan Mat Chem, Harbin 150086, Heilongjiang, Peoples R China;Heilongjiang Univ, Sch Chem Chem Engn & Mat, Dept Macromol Sci & Engn, Minist Educ,Key Lab Funct Inorgan Mat Chem, Harbin 150086, Heilongjiang, Peoples R China;Heilongjiang Univ, Sch Chem Chem Engn & Mat, Dept Macromol Sci & Engn, Minist Educ,Key Lab Funct Inorgan Mat Chem, Harbin 150086, Heilongjiang, Peoples R China;Heilongjiang Univ, Sch Chem Chem Engn & Mat, Dept Macromol Sci & Engn, Minist Educ,Key Lab Funct Inorgan Mat Chem, Harbin 150086, Heilongjiang, Peoples R China;Heilongjiang Univ, Sch Chem Chem Engn & Mat, Dept Macromol Sci & Engn, Minist Educ,Key Lab Funct Inorgan Mat Chem, Harbin 150086, Heilongjiang, Peoples R China;Harbin Inst Technol, Sch Mat Sci & Engn, Harbin 150080, Heilongjiang, Peoples R China;

作者

Lu, Qingyi;Yang, Caiyu;Qiao, Xin;Zhang, Xu;Cai, Wanan;Chen, Ye;Wang, Yan;Zhang, Wei;Lin, Xiaoxue;Niu, Haijun;Wang, Wen;

摘要

Four novel multifunctional electrochromic materials (PTT, PDTT, PNT and PDNT) based on tetraphenylethylene (TPE) and triphenylamine (TPA) units by Stille coupling reaction were prepared. Electrochemical impedance spectroscopy (EIS) measurements found that four polymers had low resistance values which improved their electrochemical and electrochromic properties. In addition, the maximum coloration efficiency (CE; eta) value is 126 cm(2)/C at 1246 nm of PDTT, bleaching and coloring response times are 2.6 s and 1.6 s, respectively. There is no significant change of performance after a 100 cycle scanning. In addition to their excellent electrochromic properties, they also exhibit a strong aggregation-induced emission (ME) effect. Furthermore, the fluorescence color of PDNT changed from bright green to black when voltage was applied from 0.0 to 1.6 V. Four polymers responded rapidly to light and they maintained stability over a 1000 s cycle.

机翻摘要

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关键词/主题词

Aggregation-induced emission;Triphenylamine;Electrochromic;Electrofluorochromic;Photodetector;

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