Pyrandiones, thiopyrandiones and cyclohexantriones having herbicidal properties 机翻标题: 暂无翻译,请尝试点击翻译按钮。

公开号/公开日
EP2222657 A1 2010-09-01 [EP2222657]EP2222657 B1 2012-09-12 [EP2222657] / 2010-09-012012-09-12
申请号/申请日
2008EP-0859463 / 2008-12-11
发明人
MUEHLEBACH MICHEL;MATHEWS CHRISTOPHER JOHN;SCUTT JAMES NICHOLAS;JEANMART STEPHANE ANDRE MARIE;GOVENKAR MANGALA;
申请人
SYNGENTA;SYNGENTA PARTICIPATIONS;
主分类号
IPC分类号
A01N-035/06A01N-043/16A01N-043/18C07C-049/603C07D-309/28C07D-335/02C07D-405/10C07D-409/10C07D-409/14C07D-493/10
摘要
(EP2222657) Pyrandione, thiopyrandione and cyclohexanetrione compounds, which are suitable for use as herbicides.
机翻摘要
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地址
代理人
代理机构
;
优先权号
2007IN-DE02616 2007-12-13 2008WO-EP10513 2008-12-11
主权利要求
(EP2222657) 1. A compound of formula I (see diagramm) wherein R **1 is halogen, C 1-C 4alkyl, C 1-C 4haloalkyl, C 3-C 6cycloalkyl, C 2-C 4alkenyl, C 2-C 4haloalkenyl, C 2-C 4alkynyl, C 1-C 4alkoxy, C 1-C 4haloalkoxy, C 1-C 4alkylthio, C 1-C 4alkylsulfinyl, C 1-C 4alkylsulfonyl, nitro or cyano; R **2 is aryl or heteroaryl; or aryl or heteroaryl both substituted by halogen, C 1-C 4alkyl, C 1-C 4haloalkyl, phenoxy, C 2-C 4alkenyl, C 2-C 4haloalkenyl, C 2-C 4alkynyl, C 1-C 4alkoxy, C 1-C 4haloalkoxy, C 1-C 4alkylthio, C 1-C 4alkylsulfinyl, C 1-C 4alkylsulfonyl, C 1-C 4haloalkylthio, C 1-C 4haloalkylsulfinyl, C 1-C 4haloalkylsulfonyl, nitro or cyano; r is 0, 1, 2 or 3; R **3, if r is 1, is halogen, C 1-C 6alkyl, C 1-C 6haloalkyl, C 1-C 6alkoxy, C 1-C 6haloalkoxy, C 2-C 6alkenyl, C 2-C 6alkynyl, C 1-C 6alkylthio, C 1-C 6alkylsulfinyl, C 1-C 6alkylsulfonyl, cyano or nitro; or the substituents R **3, if r is 2 or 3, independently of each other, are halogen, C 1-C 6alkyl, C 1-C 6haloalkyl, C 1-C 6alkoxy, C 1-C 6haloalkoxy, C 2-C 6alkenyl, C 2-C 6alkynyl, C 1-C 6alkylthio, C 1-C 6alkylsulfinyl, C 1-C 6alkylsulfonyl, cyano or nitro; R **4, R **5, R **6 and R **7, independently of each other, are hydrogen, C 1-C 4alkyl, C 1-C 4haloelkyl, C 1-C 4alkoxyC 1-C 4alkyl, C 1-C 4alkylthioC 1-C 4alkyl, C 1-C 4alkylsulfinylC 1-C 4alkyl, C 1-C 4alkylsulfonylC 1-C 4alkyl, cyclopropyl or cyclopropyl substituted by C 1- or C 2alkyl, C 1- or C 2haloalkyl or halogen; cyclobutyl or cyclobutyl substituted by C 1- or C 2alkyl; oxetanyl or oxetanyl substituted by C 1- or C 2alkyl; C 6-C 7cycloalkyl or C 5-C 7cycloalkyl substituted by C 1- or C 2alkyl or C 1- or C 2haloalkyl, where a methylene group of the cycloalkyl moiety is optionally replaced by an oxygen or sulfur atom or a sulfinyl or sulfonyl group; C 4-C 7cycloalkenyl or C 4-C 7cycloalkenyl substituted by C 1- or C 2alkyl or C 1- or C 2haloalkyl, where a methylene group of the cycloalkenyl moiety is optionally replaced by an oxygen or sulfur atom or a sulfinyl or sulfonyl group; cyclopropylC 1-C 5alkyl or cyclopropylC 1-C 5alkyl substituted by C 1- or C 2alkyl, C 1- or C 2haloalkyl or halogen; cyclobutylC 1-C 5alkyl or cyclobutylC 1-C 5alkyl substituted by C 1-C 2alkyl; oxetanylC 1-C 5alkyl or oxetanylC 1-C 5alkyl substituted by C 1- or C 2alkyl; C 5-C 7 cycloalkylC 1-C 5alkyl or C 5-C 7cycloalkylC 1-C 5alkyl substituted by C 1-or C 2alkyl or C 1- or C 2haloalkyl, where a methylene group of the cycloalkyl moiety is optionally replaced by an oxygen or sulfur atom or a sulfinyl or sulfonyl group; C 4-C 7cycloalkenylC 1-C 5 alkyl or C 4-C 7cycloalkenylC 1-C 5alkyl which is substituted by C 1- or C 2alkyl or C 1- or C 2haloalkyl, where a methylene group of the cycloalkenyl moiety is optionally replaced by an oxygen or sulfur atom or a sulfinyl or sulfonyl group; phenyl or phenyl substituted by C 1-C 4alkyl, C 1-C 4alkoxy, C 1-C 4haloalkyl, halogen, nitro, cyano, C 1-C 4alkylthio, C 1-C 4alkylsulfinyl, C 1-C 4alkylsulfonyl or C 1-C 4alkylcarbonyl; benzyl or benzyl substituted by C 1-C 4alkyl, C 1-C 4alkoxy, C 1-C 4haloalkyl, halogen, nitro, cyano, C 1-C 4alkylthio, C 1-C 4alkylsulfinyl, C 1-C 4alkylsulfonyl or C 1-C 4alkylcarbonyl; heteroaryl or heteroaryl substituted by C 1-C 4alkyl, C 1-C 4alkoxy, C 1-C 4haloalkyl, halogen, nitro, cyano, C 1-C 4alkylthio, C 1-C 4alkylsulfinyl, C 1-C 4alkylsulfonyl or C 1-C 4alkylcarbonyl; or R **4 and R **5, or R **6 and R **7, are joined to form a 5-7 membered saturated or unsaturated ring in which a methylene group is optionally replaced by an oxygen or sulfur atom, or a 5-7 membered saturated or unsaturated ring substituted by C 1- or C 2alkyl, where a methylene group of the ring is optionally replaced by an oxygen or sulfur atom; or R **4 and R **7 are joined to form a 4-8membered saturated or unsaturated ring which is unsubstituted or substituted by C 1-C 2alkyl, C 1-C 2alkoxy, C 1-C 2alkoxyC 1-C 2alkyl, hydroxy, halogen, phenyl or phenyl substituted by C 1-C 4alkyl, C 1-C 4alkoxy, C 1-C 4haloalkyl, halogen, nitro, cyano, C 1-C 4alkylthio, C 1-C 4alkylsulfinyl, C 1-C 4alkylsulfonyl or C 1-C 4alkylcarbonyl; heteroaryl or heteroaryl substituted by C 1-C 4alkyl, C 1-C 4alkoxy, C 1-C 4haloalkyl, halogen, nitro, cyano, C 1-C 4alkylthio, C 1-C 4alkylsulfinyl, C 1-C 4alkylsulfonyl or C 1-C 4alkylcarbonyl; Y is O, C=O, S(O) m or S(O) nNR **8; provided that when Y is C=O, R **6 and R **7 are different from hydrogen when either R **4 or R **5 is hydrogen, and R **4 and R **5 are different from hydrogen when either R **6 or R **7 is hydrogen; m is 0 or 1 or 2 and n is 0 or 1; R **8 is hydrogen, C 1-C 6alkyl, C 3-C 6cycloalkyl, C 1-C 6alkoxycarbonyl, tri(C 1-C 6alkyl)silylethyloxycarbonyl, C 1-C 6haloalkoxycarbonyl, cyano, C 1-C 6haloalkyl, C 1-C 6hydroxyalkyl, C 2-C 6alkenyl, C 2-C 6alkynyl, C 2-C 6haloalkenyl, C 1-C 6alkylcarbonyl, C 1-C 6haloalkylcarbonyl, C 1-C 6cycloalkylcarbonyl, phenylcarbonyl or phenylcarbonyl substituted by R **9; benzylcarbonyl or benzylcarbonyl substituted by R **9; pyridylcarbonyl or pyridylcarbonyl substituted by R **9; phenoxycarbonyl or phenoxycarbonyl substituted by R **9; benzyloxycarbonyl or benzyloxycarbonyl substituted by R **9; R **9 is C 1-C 6haloalkyl, C 1-C 6alkoxycarbonyl, nitro, cyano, formyl, carboxyl or halogen; and G is hydrogen, an agriculturally acceptable cation or a latentiating group; wherein, in G, the latentiating group is selected from the groups C 1-C 8alkyl, C 2-C 8haloalkyl, phenylC 1-C 8alkyl (wherein the phenyl is optionally substituted by C 1-C 3alkyl, C 1-C 3haloalkyl, C 1-C 3alkoxy, C 1-C 3haloalkoxy, C 1-C 3alkylthio, C 1-C 3alkylsulfinyl, C 1-C 3 alkylsulfonyl, halogen, cyano or by nitro), heteroarylC 1-C 8alkyl (wherein the heteroaryl is optionally substituted by C 1-C 3alkyl, C 1-C 3haloalkyl, C 1-C 3alkoxy, C 1-C 3haloalkoxy, C 1-C 3alkylthio, C 1-C 3alkylsulfinyl, C 1-C 3 alkylsulfonyl, halogen, cyano or by nitro), C 3-C 8 alkenyl, C 3-C 8 haloalkenyl, C 3-C 8 alkynyl, C(X **a)-R **a, C(X **b)-X **c-R **b, C(X **d)-N(R **c)-R **d, -SO 2-R **e, -P(X **e)(R **f)-R **9 and CH 2-X **f-R **h; wherein X **a, X **b, X **c, X **d, X **e and X **f are independently of each other oxygen or sulfur: and wherein R **a is H, C 1-C 16alkyl, C 2-C 18alkenyl, C 2-C 18alkynyl, C 1-C 10haloalkyl, C 1-C 10cyanoalkyl, C 1-C 10nitroalkyl, C 1-C 10aminoalkyl, C 1-C 5alkylaminoC 1-C 5alkyl, di(C 2-C 8alkyl)aminoC 1-C 5alkyl, C 3-C 7cycloalkylC 1-C 5alkyl, C 1-C 5alkoxyC 1-C 5alkyl, C 3-C 5alkenyloxyC 1-C 5alkyl, C 3-C 5alkynyloxyC 1-C 5alkyl, C 1-C 5alkylthioC 1-C 5alkyl, C 1-C 5alkylsulfinylC 1-C 5alkyl, C 1-C 5alkylsulfonylC 1-C 5alkyl, C 2-C 6alkylideneaminoxyC 1-C 5alkyl, C 1-C 5alkylcarbonylC 1-C 5alkyl, C 1-C 5alkoxycarbonylC 1-C 5alkyl, aminocarbonylC 1-C 5alkyl, C 1-C 5alkylaminocarbonylC 1-C 5alkyl, di(C 2-C 8alkyl)aminocarbonylC 1-C 5alkyl, C 1-C 5alkylcarbonylaminoC 1-C 5alkyl, N-C 1-C 5alkylcarbonyl-N-C 1-C 6alkylaminoC 1-C 5alkyl, tri(C 3-C 6alkyl)silylC 1-C 5alkyl, phenylC 1-C 5alkyl (wherein the phenyl is optionally substituted by C 1-C 3alkyl, C 1-C 3haloalkyl, C 1-C 3alkoxy, C 1-C 3haloalkoxy, C 1-C 3alkylthio, C 1-C 3alkylsulfinyl, C 1-C 3alkylsulfonyl, halogen, cyano, or by nitro), heteroarylC 1-C 5alkyl (wherein the heteroaryl is optionally substituted by C 1-C 3alkyl, C 1-C 3haloalkyl, C 1-C 3alkoxy, C 1-C 3haloalkoxy, C 1-C 3alkylthio, C 1-C 3alkylsulfinyl, C 1-C 3alkylsulfonyl, halogen, cyano, or by nitro), C 2-C 5haloalkenyl, C 3-C 8cycloalkyl, phenyl or phenyl substituted by C 1-C 3alkyl, C 1-C 3haloalkyl, C 1-C 3alkoxy, C 1-C 3haloalkoxy, halogen, cyano or nitro, or heteroaryl or heteroaryl substituted by C 1-C 3alkyl, C 1-C 3haloalkyl, C 1-C 3alkoxy, C 1-C 3haloalkoxy, halogen, cyano or nitro;  R **b is C 1-C 18alkyl, C 3-C 18alkenyl, C 3-C 18alkynyl, C 2-C 10haloalkyl, C 1-C 10cyanoalkyl, C 1-C 10nitroalkyl, C 2-C 10aminoalkyl, C 1-C 5alkylaminoC 1-C 5alkyl, di(C 2-C 8alkyl)aminoC 1-C 5alkyl, C 3-C 7cycloalkylC 1-C 5alkyl, C 1-C 6alkoxyC 1-C 5alkyl, C 3-C 5alkenyloxyC 1-C 5alkyl, C 3-C 5alkynyloxyC 1-C 6alkyl, C 1-C 5alkylthioC 1-C 5alkyl, C 1-C 5alkylsulfinylC 1-C 5alkyl, C 1-C 5alkylsulfonylC 1-C 5alkyl, C 2-C 8alkylideneaminoxyC 1-C 5alkyl, C 1-C 6alkylcarbonylC 1-C 5alkyl, C 1-C 5alkoxycarbonylC 1-C 5alkyl, aminocarbonylC 1-C 5alkyl, C 1-C 5alkylaminocarbonylC 1-C 5alkyl, di(C 2-C 5alkyl)aminocarbonylC 1-C 5alkyl, C 1-C 5alkylcarbonylaminoC 1-C 5alkyl, N-C 1-C 5alkylcarbonyl-N-C 1-C 6alkylaminoC 1-C 5alkyl, tri(C 3-C 6alkyl)silylC 1-C 5alkyl, phenylC 1-C 5alkyl (wherein the phenyl is optionally substituted by C 1-C 3alkyl, C 1-C 3haloalkyl, C 1-C 3alkoxy, C 1-C 3haloalkoxy, C 1-C 3alkylthio, C 1-C 3alkylsulfinyl, C 1-C 3alkylsulfonyl, halogen, cyano, or by nitro), heteroarylC 1-C 5alkyl (wherein the heteroaryl is optionally substituted by C 1-C 3alkyl, C 1-C 3haloalkyl, C 1-C 3alkoxy, C 1-C 3haloalkoxy, C 1-C 3alkylthio, C 1-C 3alkylsulfinyl, C 1-C 3alkylsulfonyl, halogen, cyano, or by nitro), C 3-C 6haloalkenyl, C 3-C 8cycloalkyl, phenyl or phenyl substituted by C 1-C 3alkyl, C 1-C 3haloalkyl, C 1-C 3alkoxy, C 1-C 3haloalkoxy, halogen, cyano or nitro, or heteroaryl or heteroaryl substituted by C 1-C 3alkyl, C 1-C 3haloalkyl, C 1-C 3alkoxy, C 1-C 3haloalkoxy, halogen, cyano or nitro; R **c and R **d are each independently of each other hydrogen, C 1-C 10alkyl, C 3-C 10alkenyl, C 3-C 10alkynyl, C 2-C 10haloalkyl, C 1-C 10cyanoalkyl, C 1-C 10nitroalkyl, C 1-C 10aminoalkyl, C 1-C 5alkylaminoC 1-C 5alkyl, di(C 2-C 8alkyl)aminoC 1-C 5alkyl, C 3-C 7cycloalkylC 1-C 5alkyl, C 1-C 5alkoxyC 1-C 5alkyl, C 3-C 5alkenyloxyC 1-C 5alkyl, C 3-C 5alkynyloxyC 1-C 5alkyl, C 1-C 5alkylthioC 1-C 5alkyl, C 1-C 5alkylsulfinylC 1-C 5alkyl, C 1-C 5alkylsulfonylC 1-C 5alkyl, C 2-C 8alkylideneaminoxyC 1-C 5alkyl, C 1-C 5alkylcarbonylC 1-C 5alkyl, C 1-C 5alkoxycarbonylC 1-C 5alkyl, aminocarbonylC 1-C 5alkyl, C 1-C 5alkylaminocarbonylC 1-C 5alkyl, di(C 2-C 8alkyl)aminocarbonylC 1-C 5alkyl, C 1-C 5alkylcarbonylaminoC 1-C 5alkyl, N-C 1-C 5alkylcarbonyl-N-C 2-C 5alkylaminoalkyl, C 3-C 6trialkylsilylC 1-C 5alkyl, phenylC 1-C 5alkyl (wherein the phenyl is optionally substituted by C 1-C 3alkyl, C 1-C 3haloalkyl, C 1-C 3alkoxy, C 1-C 3haloalkoxy, C 1-C 3alkylthio, C 1-C 3alkylsulfinyl, C 1-C 3alkylsulfonyl, halogen, cyano, or by nitro), heteroarylC 1-C 5alkyl (wherein the heteroaryl is optionally substituted by C 1-C 3alkyl, C 1-C 3haloalkyl, C 1-C 3alkoxy, C 1-C 3haloalkoxy, C 1-C 3alkylthio, C 1-C 3alkylsulfinyl, C 1-C 3alkylsulfonyl, halogen, cyano, or by nitro), C 2-C 5haloalkenyl, C 3-C 8cycloalkyl, phenyl or phenyl substituted by C 1-C 3alkyl, C 1-C 3haloalkyl, C 1-C 3alkoxy, C 1-C 3haloalkoxy, halogen, cyano or nitro, heteroaryl or heteroaryl substituted by C 1-C 3 alkyl, C 1-C 3haloalkyl, C 1-C 3alkoxy, C 1-C 3haloalkoxy, halogen, cyano or nitro, heteroarylamino or heteroarylamino substituted by C 1-C 3 alkyl, C 1-C 3haloalkyl, C 1-C 3alkoxy, C 1-C 3haloalkoxy, halogen, cyano or nitro, diheteroarylamino or diheteroarylamino substituted by C 1-C 3alkyl, C 1-C 3haloalkyl, C 1-C 3alkoxy, C 1-C 3haloalkoxy, halogen, cyano or nitro, phenylamino or phenylamino substituted by C 1-C 3alkyl, C 1-C 3haloalkyl, C 1-C 3alkoxy, C 1-C 3haloalkoxy, halogen, cyano or by nitro, diphenylamino or diphenylamino substituted by C 1-C 3alkyl, C 1-C 3haloalkyl, C 1-C 3alkoxy, C 1-C 3haloalkoxy, halogen, cyano or by nitro, amino, C 1-C 3alkylamino, di(C 1-C 3alkyl)amino, C 1-C 3alkoxy or C 3-C 7cycloalkylamino, di(C 3-C 7cycloalkyl)amino or C 3-C 7cycloalkoxy; or R **c and R **d join together to form a 3-7 membered ring, optionally containing one heteroatom selected from O or S and optionally substituted by 1 or 2 C 1-C 3alkyl groups; R **e is C 1-C 10alkyl, C 2-C 10alkenyl, C 2-C 10alkynyl, C 1-C 10haloalkyl, C 1-C 10cyanoalkyl, C 1-C 10nitroalkyl, C 1-C 10aminoalkyl, C 1-C 5alkylaminoC 1-C 5alkyl, di(C 2-C 8alkyl)aminoC 1-C 5alkyl, C 3-C 7cycloalkylC 1-C 5alkyl, C 1-C 5alkoxyC 1-C 5alkyl, C 3-C 5alkenyloxyC 1-C 5alkyl, C 3-C 5alkynyloxyC 1-C 5alkyl, C 1-C 5alkylthioC 1-C 5alkyl, C 1-C 5alkylsulfinylC 1-C 5alkyl, C 1-C 5alkylsulfonylC 1-C 5alkyl, C 2-C 8alkylideneaminoxyC 1-C 5alkyl, C 1-C 5alkylcarbonylC 1-C 5alkyl, C 1-C 5alkoxycarbonylC 1-C 5alkyl, aminocarbonylC 1-C 5alkyl, C 1-C 5alkylaminocarbonylC 1-C 5alkyl, di(C 2-C 8alkyl)aminocarbonylC 1-C 5alkyl, C 1-C 5alkylcarbonylaminoC 1-C 5alkyl, N-C 1-C 5alkylcarbonyl-N-C 1-C 5alkylaminoC 1-C 5alkyl, tri(C 3-C 6alkyl)silylC 1-C 5alkyl, phenylC 1-C 5alkyl (wherein the phenyl is optionally substituted by C 1-C 3alkyl, C 1-C 3haloalkyl, C 1-C 3alkoxy, C 1-C 3haloalkoxy, C 1-C 3alkylthio, C 1-C 3alkylsulfinyl, C 1-C 3alkylsulfonyl, halogen, cyano, or by nitro), heteroarylC 1-C 5alkyl (wherein the heteroaryl is optionally substituted by C 1-C 3alkyl, C 1-C 3haloalkyl, C 1-C 3alkoxy, C 1-C 3haloalkoxy, C 1-C 3alkylthio, C 1-C 3alkylsulfinyl, C 1-C 3alkylsulfonyl, halogen, cyano, or by nitro), C 2-C 5haloalkenyl, C 3-C 6cycloalkyl, phenyl or phenyl substituted by C 1-C 3alkyl, C 1-C 3haloalkyl, C 1-C 3alkoxy, C 1-C 3haloalkoxy, halogen, cyano or nitro, heteroaryl or heteroaryl substituted by C 1-C 3alkyl, C 1-C 3haloalkyl, C 1-C 3alkoxy, C 1-C 3haloalkoxy, halogen, cyano, amino or by nitro, heteroarylamino or heteroarylamino substituted by C 1-C 3alkyl, C 1-C 3haloalkyl, C 1-C 3alkoxy, C 1-C 3haloalkoxy, halogen, cyano or by nitro, diheteroarylamino or diheteroarylamino substituted by C 1-C 3alkyl, C 1-C 3haloalkyl, C 1-C 3alkoxy, C 1-C 3haloalkoxy, halogen, cyano or nitro, phenylamino or phenylamino substituted by C 1-C 3alkyl, C 1-C 3haloalkyl, C 1-C 3alkoxy, C 1-C 3haloalkoxy, halogen, cyano or nitro, amino, diphenylamino, or diphenylamino substituted by C 1-C 3alkyl, C 1-C 3haloalkyl, C 1-C 3alkoxy, C 1-C 3haloalkoxy, halogen, cyano or nitro, or C 3-C 7cycloalkylamino, di(C 3-C 7cycloalkyl)amino or C 3-C 7cycloalkoxy, C 1-C 10alkoxy, C 1-C 10haloalkoxy, C 1-C 5alkylamino or di(C 2-C 8alkyl)amino;  R **f and R **9 are each independently of each other C 1-C 10alkyl, C 2-C 10alkenyl, C 2-C 10alkynyl, C 1-C 10alkoxy, C 1-C 10haloalkyl, C 1-C 10cyanoalkyl, C 1-C 10nitroalkyl, C 1-C 10aminoalkyl, C 1-C 5alkylaminoC 1-C 5alkyl, di(C 2-C 8alkyl)aminoC 1-C 5alkyl, C 3-C 7cycloalkylC 1-C 5alkyl, C 1-C 6alkoxyC 1-C 6alkyl, C 3-C 5alkenyloxyC 1-C 5alkyl, C 3-C 5alkynyloxyC 1-C 5alkyl, C 1-C 5alkylthioC 1-C 5alkyl, C 1-C 5alkylsulfinylC 1-C 5alkyl, C 1-C 5alkylsulfonylC 1-C 5alkyl, C 2-C 8alkylideneaminoxyC 1-C 5alkyl, C 1-C 5alkylcarbonylC 1-C 5alkyl, C 1-C 5alkoxycarbonylC 1-C 5alkyl, aminocarbonylC 1-C 5alkyl, C 1-C 5alkylaminocarbonylC 1-C 5alkyl, di(C 2-C 8alkyl)aminocarbonylC 1-C 5alkyl, C 1-C 5alkylcarbonylaminoC 1-C 5alkyl, N-C 1-C 5alkylcarbonyl-N-C 2-C 5alkylaminoalkyl, tri(C 3-C 6alkyl)silylC 1-C 5alkyl, phenylC 1-C 5alkyl (wherein the phenyl is optionally substituted by C 1-C 3alkyl, C 1-C 3haloalkyl, C 1-C 3alkoxy, C 1-C 3haloalkoxy, C 1-C 3alkylthio, C 1-C 3alkylsulfinyl, C 1-C 3alkylsulfonyl, halogen, cyano, or by nitro), heteroarylC 1-C 5alkyl (wherein the heteroaryl is optionally substituted by C 1-C 3alkyl, C 1-C 3haloalkyl, C 1-C 3alkoxy, C 1-C 3haloalkoxy, C 1-C 3alkylthio, C 1-C 3alkylsulfinyl, C 1-C 3alkylsulfonyl, halogen, cyano, or by nitro), C 2-C 5haloalkenyl, C 3-C 8cycloalkyl, phenyl or phenyl substituted by C 1-C 3alkyl, C 1-C 3haloalkyl, C 1-C 3alkoxy, C 1-C 3haloalkoxy, halogen, cyano or nitro, heteroaryl or heteroaryl substituted by C 1-C 3alkyl, C 1-C 3haloalkyl, C 1-C 3alkoxy, C 1-C 3haloalkoxy, halogen, cyano or by nitro, heteroarylamino or heteroarylamino substituted by C 1-C 3 alkyl, C 1-C 3haloalkyl, C 1-C 3alkoxy, C 1-C 3haloalkoxy, halogen, cyano or by nitro, diheteroarylamino or diheteroarylamino substituted by C 1-C 3alkyl, C 1-C 3haloalkyl, C 1-C 3alkoxy, C 1-C 3haloalkoxy, halogen, cyano or nitro, phenylamino or phenylamino substituted by C 1-C 3alkyl, C 1-C 3haloalkyl, C 1-C 3alkoxy, C 1-C 3haloalkoxy, halogen, cyano or nitro, amino, hydroxyl, diphenylamino, or diphenylamino substituted by C 1-C 3alkyl, C 1-C 3haloalkyl, C 1-C 3alkoxy, C 1-C 3haloalkoxy, halogen, cyano or nitro, or C 3-C 7cycloalkylamino, di(C 3-C 7cycloalkyl)amino or C 3-C 7cycloalkoxy, C 1-C 10haloalkoxy, C 1-C 5alkylamino or di(C 2-C 8alkyl)amino, or benzyloxy or phenoxy, wherein the benzyl and phenyl groups may in tum be substituted by C 1-C 3alkyl, C 1-C 3haloalkyl, C 1-C 3alkoxy, C 1-C 3haloalkoxy, halogen, cyano or nitro; and R **h is C 1-C 10alkyl, C 3-C 10alkenyl, C 3-C 10alkynyl, C 1-C 10haloalkyl, C 1-C 10cyanoalkyl, C 1-C 10nitroalkyl, C 2-C 10aminoalkyl, C 1-C 5alkylaminoC 1-C 5alkyl, di(C 2-C 8alkyl)aminoC 1-C 5alkyl, C 3-C 7cycloalkylC 1-C 5alkyl, C 1-C 5alkoxyC 1-C 5alkyl, C 3-C 5alkenyloxyC 1-C 5alkyl, C 3-C 5alkynyloxyC 1-C 5alkyl, C 1-C 5alkylthioC 1-C 5alkyl, C 1-C 5alkylsulfinylC 1-C 5alkyl, C 1-C 5alkylsulfonylC 1-C 5alkyl, C 2-C 8alkylideneaminoxyC 1-C 5alkyl, C 1-C 5alkylcarbonylC 1-C 5alkyl, C 1-C 5alkoxycarbonylC 1-C 5alkyl, aminocarbonylC 1-C 5alkyl, C 1-C 5alkylaminocarbonylC 1-C 5alkyl, di(C 2-C 8alkyl)aminocarbonylC 1-C 5alkyl, C 1-C 5alkylcarbonylaminoC 1-C 5alkyl, N-C 1-C 5alkylcarbonyl-N-C 1-C 5alkylaminoC 1-C 5alkyl, tri(C 3-C 6alkyl)silylC 1-C 6alkyl, phenylC 1-C 5alkyl (wherein wherein the phenyl is optionally substituted by C 1-C 3alkyl, C 1-C 3haloalkyl, C 1-C 3alkoxy, C 1-C 3haloalkoxy, C 1-C 3alkylthio, C 1-C 3alkylsulfinyl, C 1-C 3 alkylsulfonyl, halogen, cyano or by nitro), heteroarylC 1-C 5alkyl (wherein the heteroaryl is optionally substituted by C 1-C 3alkyl, C 1-C 3haloalkyl, C 1-C 3alkoxy, C 1-C 3haloalkoxy, C 1-C 3alkylthio, C 1-C 3alkylsulfinyl, C 1-C 3 alkylsulfonyl, halogen, cyano or by nitro), phenoxyC 1-C 5alkyl (wherein the phenyl is optionally substituted by C 1-C 3alkyl, C 1-C 3haloalkyl, C 1-C 3alkoxy, C 1-C 3haloalkoxy, C 1-C 3alkylthio, C 1-C 3alkylsulfinyl, C 1-C 3 alkylsulfonyl, halogen, cyano or by nitro), heteroaryloxyC 1-C 5alkyl (wherein the heteroaryl is optionally substituted by C 1-C 3alkyl, C 1-C 3haloalkyl, C 1-C 3alkoxy, C 1-C 3haloalkoxy, C 1-C 3alkylthio, C 1-C 3alkylsulfinyl, C 1-C 3 alkylsulfonyl, halogen, cyano or by nitro), C 3-C 5haloalkenyl, C 3-C 8cycloalkyl, phenyl or phenyl substituted by C 1-C 3alkyl, C 1-C 3haloalkyl, C 1-C 3alkoxy, C 1-C 3haloalkoxy, halogen or by nitro, or heteroaryl, or heteroaryl substituted by C 1-C 3alkyl, C 1-C 3haloalkyl, C 1-C 3alkoxy, C 1-C 3haloalkoxy, halogen, cyano or by nitro; and wherein, in the compound of formula I, "aryl" means phenyl or naphthyl; and wherein, in the compound of formula I, "heteroaryl" means thienyl, furyl, pyrrolyl, isoxazolyl, oxazolyl, isothiazolyl, thiazolyl, pyrazolyl, imidazolyl, triazolyl, tetrazolyl, pyridyl, pyrimidinyl, pyrazinyl, triazinyl, oxadiazolyl, thiadiazolyl or pyridazinyl, or, where appropriate, a N-oxide or a salt thereof. 2. A compound according to claim 1, wherein R **1 is halogen, C 1-C 4alkyl, C 1-C 4haloalkyl, C 2-C 4alkenyl or C 2-C 4 alkynyl. 3. A compound according to claim 1 or 2, wherein R **2 is phenyl, thienyl, furyl, pyrrolyl, isoxazolyl, oxazolyl, isothiazolyl, thiazolyl, pyrazolyl, imidazolyl, triazolyl, tetrazolyl, pyridyl, pyrimidinyl, pyrazinyl, triazinyl, pyridazinyl, oxadiazolyl or thiadiazolyl, or an N-oxide or salt thereof, where these rings are unsubstituted or substituted by halogen, C 1-C 4alkyl, C 1-C 4haloalkyl, C 2-C 4alkenyl, C 2-C 4haloalkenyl, C 2-C 4alkynyl, C 1-C 4alkoxy, C 1-C 4haloalkoxy, Ci-C 4alkylthio, C 1-C 4alkylsulfinyl, C 1-C 4alkylsulfonyl, C 1-C 4haloalkylthio, C 1-C 4haloalkylsulfinyl, C 1-C 4haloalkylsulfonyl, nitro or cyano. 4. A compound according to claim 1 or 2, wherein R **2 is phenyl or pyridyl; or phenyl or pyridyl both substituted by halogen, nitro, cyano, C 1-C 2alkyl, C 1-C 2haloalkyl, C 1-C 2alkoxy or C 1-C 2haloalkoxy. 5. A compound according to claim 1 or 2, wherein R **2 is phenyl substituted at the para-position by halogen and is optionally further substituted by halogen, nitro, C 1-C 2alkyl, C 1-C 2haloalkyl, C 1-C 2alkoxy or C 1-C 2haloalkoxy. 6. A compound according to any one of claims 1 to 5, wherein R **3 is hydrogen (i.e. r is 0), or R **3 is halogen or C 1-C 6alkyl. 7. A compound according to claim 6, wherein R **3 is hydrogen (r is 0). 8. A compound according to claim 6, wherein r is 1, and R **3 is halogen or C 1-C 3alkyl. 9. A compound according to any one of claims 1 to 8, wherein: R **4, R **5, R **6 and R **7, independently of each other, are hydrogen, C 1-C 4alkyl, C 1-C 4haloalkyl, C 1-C 4alkoxyC 1-C 4 alkyl, C 1-C 4alkylthioC 1-C 4alkyl, C 1-C 4alkylsulfinylC 1-C 4alkyl, C 1-C 4alkylsulfonylC 1-C 4alkyl; C 6-C 7cycloalkyl or C 5-C 7cycloalkyl substituted by C 1- or C 2alkyl or C 1- or C 2haloalkyl and in which a methylene group is optionally replaced by an oxygen or sulfur atom or a sulfinyl or sulfonyl group; or C 5-C 7cycloalkylC 1-C 5alkyl or C 5-C 7cycloalkylC 1-C 5alkyl substituted by C 1-C 2alkyl or C 1- or C 2haloalkyl and in which a methylene group is optionally replaced by an oxygen or sulfur atom or a sulfinyl or sulfonyl group; or R **4 and R **7 are joined to form a 4-8 membered saturated or unsaturated ring which is unsubstituted or substituted by C 1-C 2alkyl, C 1-C 2alkoxy or C 1-C 2alkoxyC 1-C 2alkyl, while R **5 and R **6 independently of each other are hydrogen or C 1-C 2alkyl. 10. A compound according to any one of claims 1 to 8, wherein R **4, R **6, R **6 and R **7, independently of each other, are hydrogen, C 1-C 2alkyl, C 1-C 2haloalkyl or C 1-C 2alkoxy-C 1-C 2alkyl. 11. A compound according to any one of claims 1 to 10, wherein Y is O, S or C=O. 12. A compound according to claim 11, wherein Y is O. 13. A compound according to any one of claims 1 to 12, wherein G denotes C(X **a)-R **a or C(X **b)-X **c-R **b, and the meanings of X **a, R **a, X **b, X **c and R **b are as defined in claim 1. 14. A compound according to any one of claims 1 to 12, wherein, in G, the latentiating group is selected from the groups C(X **a)-R **a and C(X **b)-X **c-R **b, wherein X **a, X **b and X **c are oxygen, R **a is C 1-C 6alkyl, C 2-C 6alkenyl, C 2-C 6alkynyl, C 3-C 6cycloalkyl or C 1-C 4alkoxyC 1-C 4alkyl, and R **b is C 1-C 6alkyl, C 3-C 6alkenyl, C 3-C 6alkynyl, C 3-C 6cycloalkyl or C 1-C 4alkoxyC 1-C 4alkyl. 15. A compound according to any one of claims 1 to 12, wherein G is hydrogen. 16. A compound according to claim 1, wherein: R **1 is C 1-C 4alkyl, R **2 is phenyl or phenyl substituted by halogen or C 1-C 2alkyl, R **3 is hydrogen (i.e. r is 0), R **4, R **5, R **6 and R **7, independently of each other, are C 1-C 2alkyl, Y is O and G is hydrogen; or R **1 is C 1-C 4alkyl, R **2 is phenyl or phenyl substituted by halogen or C 1-C 2alkyl, R **3 is hydrogen (i.e. r is 0), R **5 and R **6, independently of each other, are hydrogen or C 1-C 2alkyl, R **4 and R **7 are joined to form a 4-8 membered saturated or unsaturated ring which is unsubstituted or substituted by C 1-C 2alkyl, C 1-C 2alkoxy or C 1-C 2alkoxyC 1-C 2alkyl, Y is O and G is hydrogen. 17. A process for the preparation of a compound of formula I according to claim 1, which comprises reacting a compound of the formula (H) (see diagramm) wherein R **1, R **3, R **4, R **5, R **6, R **7, Y and r have the meanings assigned to them in claim 1 and Hal is chlorine, bromine, iodine or trifluoromethanesulfonyloxy, with an aryl- or heteroaryl boronic acid of formula R **2B(OH) 2, wherein R **2 has the meaning assigned to it in claim 1, or a salt or ester thereof, in the presence of a suitable palladium catalyst, a ligand and a base, and in a suitable solvent. 18. A process for the preparation of a compound of formula I according to claim 1, which is a compound of the formula (A) (see diagramm) which comprises reacting a compound of the formula (AA) (see diagramm) with a Lewis or Brönsted acid, optionally in the presence of a solvent, where the substituents In the compounds of the formulae (A) and (AA) are as defined in claim 1, and wherein Y is O. 19. A compound of the formula (H) (see diagramm)wherein R **1, R **4, R **5, R **6, R **7 and Y have the meanings assigned to them in claim 1; Hal is chlorine, bromine, iodine or trifluoromethanesulfonyloxy; r is 0, 1, 2 or 3; R **3 is hydrogen (i.e. r is 0), or R **3 is halogen or C 1-C 6alkyl; and wherein R **3, if r is 1, is halogen or C 1-C 3alkyl. 20. A compound of the formula (AA) (see diagramm) wherein the substituents are as defined in claim 1. 21. A method of controlling grasses and weeds in crops of useful plants, which comprises applying a herbicidally effective amount of a compound of formula I as defined in any one of claims 1 to 16, or of a composition comprising such a compound, to the plants or to the locus thereof. 22. A herbicidal composition, which, in addition to comprising formulation adjuvants, comprises a herbicidally effective amount of a compound of formula I as defined in any one of claims 1 to 16. 23. A composition according to claim 22, which, in addition to comprising the compound of formula I, comprises a further herbicide as mixing partner and optionally a safener.
法律状态
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