MXene/Co3O4 composite material: stable synthesis and its enhanced broadband microwave absorption 机翻标题: 暂无翻译,请尝试点击翻译按钮。


Microwave absorbers serve the purpose to ensure the transmission efficiency and accuracy in 5G telecommunications. Twodimensional MXene has great potential in absorbing microwave. In this study, MXene(Ti3C2Tx)Co3O4 composites are successfully fabricated by a facile and stable hydrothermal treatment in concentrated strong base and Argon environment, followed by a onestep annealing process. Phase composition, chemical state of elements, morphology and structure of the new composite materials are studied by systematical characterization. It is revealed that adsorbed Na ions and terminations, which are generated at the interface during hydrothermal treatment in concentrated NaOH solution, can protect the Ti3C2Tx from being decomposed. The synthesis mechanism is also proposed for stable fabrication of other MXenebased composite materials. The MXeneCo3O4 composite is able to perform singleband absorption, multiband absorption and even broadband absorption in 218 GHz band by tuning its composition and thickness. Particularly, better than 90% absorption in a wide range of 10.817 GHz can be achieved with a thickness of just 2 mm. Enhanced wideband absorption originates from the multilayer structure, the surface defects, the conductivity of Ti3C2Tx and the capacitance structure of Co3O4. Ultrathin and broadband high absorption features make the material a promising candidate for future application.ReferencesJ. G. Andrews, S. Buzzi, W. Choi, S. V. Hanly, A. Lozano, A. C. K. Soong, J. C. Zhang, What will 5G be IEEE Journal on Selected Areas in Communications. 32 (2014)T. S. Rappaport, S. Sun, R. Mayzus, H. Zhao, Y. Azar, K. Wang, G. N. Wong, J. K. Schulz, M. Samimi, F. Gutierrez, Millimeter wave mobile communications for 5G cellular: it will work IEEE Access : Practical Innovations, Open Solutions. 1 (2013)W. Roh, J. Y. Seol, J. Park, B. Lee, J. Lee, Y. Kim, J. Cho, K. Cheun, F. Aryanfar, Millimeterwave beamforming as an enabling technology for 5G cellular communications: theoretical feasibility and prototype results. IEEE Communications Magazine. 52 (2014)J. Riihijarvi, P. Mahonen, M. Petrova, What will interference be like in 5G HetNets Phys. Commun.Amst. 18 (2016)N. Seyhan, Electromagnetic pollution and our health. Noropsikiyatri Ars. 47 (2010)J. S. Li, Y. Duan, W. B. Lu, T. W. Chou, Polyanilinestabilized electromagnetic wave absorption composites of reduced graphene oxide on magnetic carbon nanotube film. Nanotechnology. 29 (2018)S. Dong, J. T. Song, X. H. Zhang, P. Hu, B. Q. Sun, S. T. Zhou, X. G. Luo, Strong contribution of in situ grown nanowires to enhance the thermostabilities and microwave absorption properties of porous graphene foams under different atmospheres. Journal of Materials Chemistry. C, Materials for Optical and Electronic Devices. 5 (2017)M. K. Han, X. W. Yin, Z. X. Hou, C. Q. Song, X. L. Li, L. T. Zhang, L. F. Cheng, Flexible and thermostable grapheneSiC nanowire foam composites with tunable electromagnetic wave absorption properties. ACS Appl. Mater. Int. 9 (2017)J. Z. He, X. X. Wang, Y. L. Zhang, M. S. Cao, Small magnetic nanoparticles decorating reduced graphene oxides to tune the electromagnetic attenuation capacity. Journal of Materials Chemistry. C, Materials for Optical and Electronic Devices. 4 (2016)Z. X. Li, X. H. Li, Y. Zong, G. G. Tan, Y. Sun, Y. Y. Lan, M. He, Z. Y. Ren, X. L. Zheng, Solvothermal synthesis of nitrogendoped graphene decorated by superparamagnetic Fe3O4 nanoparticles and their applications as enhanced synergistic microwave absorbers. Carbon. 115 (2017)P. J. Liu, Z. J. Yao, J. T. Zhou, Z. H. Yang, L. B. Kong, Small magnetic Codoped NiZn ferritegraphene nanocomposites and their dualregion microwave absorption performance. Journal of Materials Chemistry. C, Materials for Optical and Electronic Devices. 4 (2016)D. D. Min, W. C. Zhou, Y. C. Qing, F. Luo, D. M. Zhu, Singlelayer and doublelayer microwave absorbers based on graphene nanosheetsepoxy resin composite. Nano. 12 (2017)J. H. Peng, Z. W. Peng, Z. P. Zhu, R. Augustine, M. M. Mahmoud, H. M. Tang, M. J. Rao, Y. B. Zhang, G. H. Li, T. Jiang, Achieving ultrahigh electromagnetic wave absorption by anchoring Co0.33Ni0.33Mn0.33Fe2O4 nanoparticles on graphene sheets using microwaveassisted polyol method. Ceramics International. 44 (2018)L. Wang, H. L. Xing, S. T. Gao, X. L. Ji, Z. Y. Shen, Porous flowerlike NiO@graphene composites with superior microwave absorption properties. Journal of Materials Chemistry. C, Materials for Optical and Electronic Devices. 5 (2017)W. Shen, B. Y. Ren, S. Z. Wu, W. Wang, X. F. Zhou, Facile synthesis of rGOSmFe5O12CoFe2O4 ternary nanocomposites: composition control for superior broadband microwave absorption performance. Applied Surface Science. 453 (2018)H. L. Xu, X. W. Yin, M. Zhu, M. H. Li, H. Zhang, H. J. Wei, L. T. Zhang, L. F. Cheng, Constructing hollow graphene nanospheres confined in porous amorphous carbon particles for achieving full X band microwave absorption. Carbon. 142 (2019)J. R. Ma, X. X. Wang, W. Q. Cao, C. Han, H. J. Yang, J. Yuan, M. S. Cao, A facile fabrication and highly tunable microwave absorption of 3D flowerlike Co3O4rGO hybridarchitectures. Chemical Engineering Journal. 339 (2018)H. L. Lv, Z. H. Yang, P. L. Wang, G. B. Ji, J. Z. Song, L. R. Zheng, H. B. Zeng, Z. C. J. Xu, A voltageboosting strategy enabling a lowfrequency, flexible electromagnetic wave absorption device. Advanced Materials. 30 (2018)D. Q. Zhang, J. X. Chai, J. Y. Cheng, Y. X. Jia, X. Y. Yang, H. Wang, Z. L. Zhao, C. Han, G. C. Shan, W. J. Zhang, G. P. Zheng, M. S. Cao, Highly efficient microwave absorption properties and broadened absorption bandwidth of MoS2iron oxide hybrids and MoS2based reduced graphene oxide hybrids with heterostructures. Applied Surface Science. 462 (2018)J. S. Li, W. B. Lu, J. Suhr, H. Chen, J. Q. Xiao, T. W. Chou, Superb electromagnetic waveabsorbing composites based on largescale graphene and carbon nanotube films. Scientific Reports. 7 (2017)M. Naguib, V. N. Mochalin, M. W. Barsoum, Y. Gogotsi, 25th anniversary article: MXenes: a new family of twodimensional materials. Advanced Materials. 26 (2014)Y. C. Qing, W. C. Zhou, F. Luo, D. M. Zhu, Titanium carbide (MXene) nanosheets as promising microwave absorbers. Ceramics International. 42 (2016)X. L. Li, X. W. Yin, M. K. Han, C. Q. Song, H. L. Xu, Z. X. Hou, L. T. Zhang, L. F. Cheng, Ti3C2 MXenes modified with in situ grown carbon nanotubes for enhanced electromagnetic wave absorption properties. Journal of Materials Chemistry. C, Materials for Optical and Electronic Devices. 5 (2017)G. L. Zhao, H. P. Lv, Y. Zhou, X. T. Zheng, C. Wu, C. Xu, Selfassembled sandwichlike MXenederived nanocomposites for enhanced electromagnetic wave absorption. ACS Appl. Mater. Int. 10 (2018)P. J. Liu, Z. J. Yao, V. M. H. Ng, J. T. Zhou, L. B. Kong, K. Yue, Facile synthesis of ultrasmall Fe3O4 nanoparticles on MXenes for high microwave absorption performance. Compos. Part AAppl. S. 115 (2018)Y. Qian, H. W. Wei, J. D. Dong, Y. Z. Du, X. J. Fang, W. H. Zheng, Y. T. Sun, Z. X. Jiang, Fabrication of urchinlike ZnOMXene nanocomposites for highperformance electromagnetic absorption. Ceramics International. 43 (2017)H. B. Yang, J. J. Dai, X. Liu, Y. Lin, J. J. Wang, L. Wang, F. Wang, Layered PVBBa3Co2Fe24O41Ti3C2 Mxene composite: enhanced electromagnetic wave absorption properties with high impedance match in a wide frequency range. Materials Chemistry and Physics. 200 (2017)M. K. Han, X. W. Yin, X. L. Li, B. Anasori, L. T. Zhang, L. F. Cheng, Y. Gogotsi, Laminated and twodimensional carbonsupported microwave absorbers derived from MXenes. ACS Appl. Mater. Int. 9 (2017)D. D. Min, W. C. Zhou, F. Luo, D. M. Zhu, Facile preparation and enhanced microwave absorption properties of flake carbonyl ironFe3O4 composite. Journal of Magnetism and Magnetic Materials. 435 (2017)T. Wang, P. Wang, Y. Wang, L. Qiao, A broadband farfield microwave absorber with a sandwich structure. Materials & Design. 95 (2016)X. D. Sun, G. Y. Ma, X. L. Lv, M. X. Sui, H. B. Li, F. Wu, J. J. Wang, Controllable fabrication of Fe3O4ZnO coreshell nanocomposites and their electromagnetic wave absorption performance in the 218 GHz frequency range. Materials (Basel). 11 (2018)X. H. Gao, X. Y. Wu, J. Qiu, High electromagnetic waves absorbing performance of a multilayerlike structure absorber containing activated carbon hollow porous fiberscarbon nanotubes and Fe3O4 nanoparticles. Advanced Electronic Materials. 4 (2018)Y. Ding, Z. Zhang, B. H. Luo, Q. L. Liao, S. Liu, Y. C. Liu, Y. Zhang, Investigation on the broadband electromagnetic wave absorption properties and mechanism of Co3O4nanosheetsreducedgrapheneoxide composite. Nano Research. 10 (2017)F. S. Wen, H. Hou, J. Y. Xiang, X. Y. Zhang, Z. B. Su, S. J. Yuan, Z. Y. Liu, Fabrication of carbon encapsulated Co3O4 nanoparticles embedded in porous graphitic carbon nanosheets for microwave absorber. Carbon. 89 (2015)L. Kong, X. W. Yin, M. K. Han, L. T. Zhang, L. F. Cheng, Carbon nanotubes modified with ZnO nanoparticles: highefficiency electromagnetic wave absorption at hightemperatures. Ceramics International. 41 (2015)B. Quan, X. H. Liang, X. Zhang, G. Y. Xu, G. B. Ji, Y. W. Du, Functionalized carbon nanofibers enabling stable and flexible absorbers with effective microwave response at low thickness. ACS Appl. Mater. Int. 10 (2018)L. Liu, Z. D. He, Y. T. Zhao, J. C. Sun, G. X. Tong, Modulation of the composition and surface morphology of expanded graphiteFeFe3O4 composites for plasmon resonanceenhanced microwave absorption. Journal of Alloys and Compounds. 765 (2018)C. F. J. Zhang, S. Pinilla, N. McEyoy, C. P. Cullen, B. Anasori, E. Long, S. H. Park, A. SeralAscaso, A. Shmeliov, D. Krishnan, C. Morant, X. H. Liu, G. S. Duesberg, Y. Gogotsi, V. Nicolosi, Oxidation stability of colloidal twodimensional titanium carbides (MXenes). Chemistry of Materials. 29 (2017)A. H. Feng, Y. Yu, F. Jiang, Y. Wang, L. Mi, Y. Yu, L. X. Song, Fabrication and thermal stability of NH4HF2etched Ti3C2 MXene. Ceramics International. 43 (2017)M. Naguib, M. Kurtoglu, V. Presser, J. Lu, J. J. Niu, M. Heon, L. Hultman, Y. Gogotsi, M. W. Barsoum, Twodimensional nanocrystals produced by exfoliation of Ti3AlC2. Advanced Materials. 23 (2011)A. H. Feng, Y. Yu, Y. Wang, F. Jiang, Y. Yu, L. Mi, L. X. Song, Twodimensional MXene Ti3C2 produced by exfoliation of Ti3AlC2. Materials & Design. 114 (2017)J. Yang, H. W. Liu, W. N. Martens, R. L. Frost, Synthesis and characterization of cobalt hydroxide, cobalt oxyhydroxide, and cobalt oxide nanodiscs. The Journal of Physical Chemistry C. 114 (2010)L. Zhao, B. L. Dong, S. Z. Li, L. J. Zhou, L. F. Lai, Z. W. Wang, S. L. Zhao, M. Han, K. Gao, M. Lu, X. J. Xie, B. Chen, Z. D. Liu, X. J. Wang, H. Zhang, H. Li, J. Q. Liu, H. Zhang, X. Huang, W. Huang, Interdiffusion reactionassisted hybridization of twodimensional metalorganic frameworks and Ti3C2Tx nanosheets for electrocatalytic oxygen evolution. ACS Nano. 11 (2017)Y. Xie, M. Naguib, V. N. Mochalin, M. W. Barsoum, Y. Gogotsi, X. Q. Yu, K. W. Nam, X. Q. Yang, A. I. Kolesnikov, P. R. C. Kent, Role of surface structure on Liion energy storage capacity of twodimensional transitionmetal carbides. Journal of the American Chemical Society. 136 (2014)M. Naguib, J. Halim, J. Lu, K. M. Cook, L. Hultman, Y. Gogotsi, M. W. Barsoum, New twodimensional niobium and vanadium carbides as promising materials for Liion batteries. Journal of the American Chemical Society. 135 (2013)A. N. Enyashin, A. L. Ivanovskii, Atomic structure, comparative stability and electronic properties of hydroxylated Ti2C and Ti3C2 nanotubes. Computational & Theoretical Chemistry. 989 (2012)Q. Tang, Z. Zhou, P. W. Shen, Are MXenes promising anode materials for Li ion batteries Computational studies on electronic properties and Li storage capability of Ti3C2 and Ti3C2X2 (X F, OH) monolayer. Journal of the American Chemical Society. 134 (2012)S. Kajiyama, L. Szabova, K. Sodeyama, H. Iinuma, R. Morita, K. Gotoh, Y. Tateyama, M. Okubo, A. Yamada, Sodiumion intercalation mechanism in MXene nanosheets. ACS Nano. 10 (2016)X. H. Liu, R. Yi, N. Zhang, R. R. Shi, X. G. Li, G. Z. Qiu, Cobalt hydroxide nanosheets and their thermal decomposition to cobalt oxide nanorings. Chemistry, an Asian Journal. 3 (2008)E. N. Konyushenko, N. E. Kazantseva, J. Stejskal, M. Trchova, J. Kovarova, I. Sapurina, M. M. Tomishko, O. V. Demicheva, J. Prokes, Ferromagnetic behaviour of polyanilinecoated multiwall carbon nanotubes containing nickel nanoparticles. Journal of Magnetism and Magnetic Materials. 320 (2008)R. X. Deng, K. Zhang, M. L. Li, L. X. Song, T. Zhang, Targeted design, analysis and experimental characterization of flexible microwave absorber for window application. Materials & Design. 162 (2019)


点击如下链接查看来源站点的原文: 原文链接