(WO9841094) The invention relates to a fungicide mixture with synergistic effect, containing a) a fungicide active compound of formula IA or IB wherein <u>- - -</u> represents a single or double bond and the index and substituents have the following meanings: R' -C[CO2CH3] =CHOCH3, -C[CO2CH3] =NOCH3, -C[CONHCH3] =NOCH3, -C[CO2CH3] =CHCH3, -C[CO2CH3] =CHCH2CH3, -C[COCH3] =NOCH3, -C[COCH2CH3] =NOCH3, -N(OCH3) -CO2CH3, -N(CH3) -CO2CH3, -N(CH2CH3) -CO2CH3; R'' a C-organic radical which is bonded directly or via an oxy-, mercapto-, amino- or alkylamino group; together with a group X and the ring Q or T to which they are bonded, an optionally substituted bicyclic, partially or completely unsaturated system; R<x> -OC[CO2CH3] =CHOCH3, -OC[CO2CH3] =CHCH3, -OC[CO2CH3] =CHCH2CH3, -SC[CO2CH3] =CHOCH3, -SC[CO2CH3] =CHCH3, -SC[CO2CH3] =CHCH2CH3, -N(CH3)C[CO2CH3] =CHOCH3, -N(CH3)C[CO2CH3] =NOCH3, -CH2C[CO2CH3] =CHOCH3, -CH2C[CO2CH3] =NOCH3, -CH2C[CONHCH3] =NOCH3; R<y> oxygen, sulfur, =CH- or =N-; n 0, 1, 2 or 3; X cyano, nitro, halogen, alkyl, halogenalkyl, alkoxy, halogenalkoxy, alkylthio; if n>1, an optionally substituted alkylene, alkenylene, oxyalkylene, oxyalkylenoxy, oxyalkenylene, oxyalkenylenoxy or butadiendiyl group bonded to two adjoining C-atoms of the phenyl ring; Y C- or -N-; Q cyclopentenyl, cyclohexenyl, phenyl, pyrrolyl, thienyl, furyl, pyrazolyl, imidazolyl, oxazolyl, isoxazolyl, thiazolyl, thiadiazolyl, triazolyl, pyridinyl, 2-pyridonyl, pyrimidinyl and triazinyl; T phenyl, oxazolyl, thiazolyl, thiadiazolyl, oxadiazolyl, pyridinyl, pyrimidinyl and triazinyl, and b) the herbicide active agent II and/or b2) the herbicide active agent III. The invention also relates to methods for producing mixtures of that type and the use of such mixtures for combatting harmful fungi in the area of plant and material protection.
(WO9841094) Claims 1. Fungicidal mixture, comprising A) a fungicidally active compound of the formula IA or IB ^ - ^ is a single - or in which double bond and the index and the substituents have the following meaning: R′ - C [C0CH3]=CHOCH3, - C [C02CH3]=N0CH3, - C [CONHCH3]=NOR3, - C [C02CH3]=CHCH3, - C [C02CH3]=CHCH2CH3, - C [COCH3]=NOR3, - C [COCH2CH3]=NOR3, - N (OCH3) - C02CH3, - N (CH3) - C02CH3, - N (CH2CH3) - C02CH3; R " a C-organic radical, which is directly or indirectly or via an Oxy -, Mercapto -, amino -, or alkyl amino group is bonded; together with a group X and the ring Q or T, to which they are attached, an optionally substituted - bicyclithen an, - Sy stem partially or fully unsaturated, which in addition to carbon ring members of the group consisting of oxygen atoms, sulfur and nitrogen can; Rx- OC [C02CH3]=CH0CH3, - OC [C02CH3]=CHCH3, - OC [C02CH3]=CHCH2CH3, - SC [C02CH3]=CH0CH3, - SC [C02CH3]=CHCH3, - SC [C0 CH3]=CHCH2CH3, - N (CH3) C [C0 CH3]=CHOCH3, - N (CH3) C [C02CH3]=NOR3, - CH2C [CO2CH3]=CHOCH3, - CH2C [C02CH3]=NOR3, - CH2C [CONHCH3]=NOR3; Ryoxygen, sulfur, or - N - CH==; n is 0, 1, 2 or 3, wherein the radicals X may be different, when n is greater than 1; X cyano, Nitro, halogen, Cι-C4- alkyl, Cι-C4halogen - alkyl -, ~C C ι4- alkoxy, Cι-C4- haloalkoxy, Cχ-C4- Alkylthio; in the case, that n&gt; is 1, two adjacent C atoms of the phenyl ring at a C-bonded3- C5- alkylene -, C3- C5- alkenylene -, - C-Oxy-C4- alkylene -, - Oxy-Cχ-C - alkylenoxy, Oxy-C2- C4alkynyleneeachc - -, Oxy-C2- C4- alkenylenoxy - diyl group or butadiene, where - in this chain may carry one to three of the following radicals in turn: halogen, C ι.- C4- alkyl, Cι-C4- haloalkyl, Cι-C4- alkoxy, Cι-C4Cι-C - - haloalkoxy or Alkylthio, Y=C - or - N -; Q Cyclopentenyl, Cyclohexenyl, phenyl, Pyrrolyl, Thienyl, Furyl, Pyrazolyl, Imidazolyl, Oxazolyl, Isoxazolyl, Thiazolyl, Thiadiazolyl, Triazolyl, Pyridinyl, 2- Pyridonyl, Pyrimidinyl and Triazinyl; T is phenyl, Oxazolyl, thiazolyl, thiadiazolyl, Oxa¬diazolyl, Pyridinyl, Pyrimidinyl and triazinyl, as well as bl) the herbicidally active compound II and/or b2) the herbicidally active compound III in a synergistically effective amount. 2. Fungicidal mixture according to claim 1, characterized in, that the weight ratio of the compounds IA or IB to the compound II or 10:1 to 0.1: 1 and the weight ratio of the compounds IA or IB to the compound II and compound iii 10:1:0, 4 to 0.1: 1: 0.4 is. 3. Method for controlling harmful fungi, characterized in characterized -, in that the harmful fungi, their habitat or the plants to be kept free from them, seeds, soils, areas, materials or spaces with a compound of formula IA or IB according to claim 1 and the compound of formula II according to claim 1 and/or the compound iii according to claim 1 treated. 4. Method according to claim 3, characterized in, that the compound IA or IB according to claim 1 and the compound II according to claim 1 and/or the compound iii - dimensional claim 1 n_ge simultaneously, or in common n_ge¬separates, or sequentially dispenses. 5. Method for protecting crop plants from fungi according to claim 3, characterized in, that - the harmful fungi, their habitat or the plants to be kept free from them, seed or soils with 0.01 to 1 kg/ha of a compound IA or IB according to claim 1 treated. 6. Method according to claim 5, characterized in, that the compound II according to claim 1 in an amount of from 0.01 to 1 kg/ha applies. 7. Method according to claim 5, characterized in, that the compound III according to claim 1 in an amount of from 0.001 to 0.3 kg/ha applies. 8. Method for the protection of materials or spaces in front of fungi according to claim 3, characterized in, that the materials or spaces to be kept free from fungi with 0.01 to 20 gms/m3of a compound IA or IB according to claim 1 treated. 9. Method according to claim 8, characterized in, that the compound II according to claim 1 in an amount of from 0.01 to 20 gms/m3applies. 10. Method according to claim 8, characterized in, that the compound III according to claim 1 in an amount of from 0.01 to 20 gms/m3applies. 11. Use of a compound IA or IB according to claim 1 for the production of a fungicidally active synergistic mixture according to claim 1. 12. Use of the compound II according to claim 1 for the production of a fungicidally effective synergistic mixture according to claim 1. 13. Use of the compound III according to claim 1 reconverter a fungicidally effective synergistic mixture for manufacturing - according to claim 1.
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