Composition for the impregnation of fibers, fabrics and nettings imparting a protective activity against pests 机翻标题: 暂无翻译,请尝试点击翻译按钮。

公开号/公开日
EP1697578 A2 2006-09-06 [EP1697578]EP1697578 B1 2011-08-31 [EP1697578] / 2006-09-062011-08-31
申请号/申请日
2004EP-0804134 / 2004-12-21
发明人
KARL ULRICH;HEISSLER HEINZ;THOMAS JOHN H;SCHOEPKE HOLGER;BURGER JOACHIM;
申请人
BASF;
主分类号
IPC分类号
A01N-025/10A01N-053/00D06M-015/19D06M-015/263D06M-015/273D06M-015/29D06M-015/564D06M-015/568
摘要
(EP1697578) Summary Insecticide composition for application to a textile material or plastics material selected from the group consisting of yarn, fibers, fabric, knitgoods, nonwovens, netting material, foils, tarpaulins and coating compositions, which insecticide composition comprises a mixture including at least one insecticide and/or at least one repellent, and at least one binder; an impregnated textile material or plastics material comprising at least one insecticide and/or at least one repellent, and at least one binder; processes for impregnation of a textile material or plastics material and a process for coating of a textile material or plastics material.
机翻摘要
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地址
代理人
代理机构
;
优先权号
2003US-10740428 2003-12-22 2004WO-EP14536 2004-12-21
主权利要求
(EP1697578) 1. An insecticide or repellent or rodenticide, fungicide, molluscicide, larvicide or ovicide composition for application to a textile material or plastics material which composition comprises a mixture including a) at least one insecticide and/or at least one repellent and/or at least one rodenticide, fungicide, molluscicide, larvicide and/or ovicide as component A, and b1) at least one acrylic binder as component B1 obtainable by emulsion polymerisation of the following components: b1a) n-butyl acrylate as component 81A, b1b) at least one monomer of formula I as component B1B (see diagramm) wherein  R **1, R **2 and R **3 are independently selected from C 1- to C 10-alkyl which may be linear or branched; substituted or unsubstituted aryl;  R **1 and R **2 may further be H;  except of R **3 = n-butyl, when R **1 and R **2 are H; b1c) at least one monomer of formula II as component B1C (see diagramm) wherein  R **4, R **5, R **6 and R **7 are independently selected from the group consisting of H, C 1- to C 10-alkyl which may be linear or branched; substituted or unsubstituted aryl; b1d) optionally at least one momomer of formula III as component B1D (see diagramm) wherein  R **8 and R **9 are independently selected from the group consisting of H, C 1- to C 10-alkyl which may be linear or branched; substituted or unsubstituted aryl;  X is selected from the group consisting of H, OH, NH 2, OR **11OH, glycidyl, hydroxypropyl, (see diagramm) groups of the formula (see diagramm) wherein  R **10 is selected from the group consisting of C 1- to C 10-alkyl which may be branched or linear; substituted or unsubstituted aryl;  R **11 is selected from the group consisting of C 1- to C 10-alkylene; substituted or unsubstituted arylenes; b1e) optionally further monomers which are copolymerizable with the monomers mentioned above selected from b1e1) polar monomers as component B1E1; and/or b1e2) non polar monomers as component B1E2. 2. The insecticide or repellent or rodenticide, fungicide, molluscicide, larvicide or ovicide composition as claimed in claim 1, wherein the acrylic binder is obtainable by emulsion polymerization of the following components: b1a) 10 to 90% by weight of component B1A; b1 b) 10 to 90% by of component B1B; b1 c) 1 to 5 % by weight of component B1 C; b1d) 0 to 5 % by weight of component B1D; b1e) further monomers which are copolymerizable with the monomers menti oned above selected from b1e1) 0 to 30 % by weight of component B1E1; and/or b1 e2) 0 to 40 % by weight of component B1 E2; wherein the sum of the components B1A, B1B, B1C and optionally B1D and B1E is 100 % by weight. 3. The insecticide or repellent or rodenticide, fungicide, molluscicide, larvicide or ovicide composition as claimed in claim 1, wherein the acrylic binder is obtainable by emulsion polymerization of the following components: b1a) 30 to 85% by weight of component B1A; b1b) 10 to 90% by weight of component B 1 B; b1c) 1 to 5 % by weight of component B1C; b1d) 0 to 5 % by weight of component B1D; b1e) further monomers which are copolymerizable with the monomers menti oned above selected from b1e1) 0 to 30 % by weight of component B1E1; and/or b1e2) 0 to 40 % by weight of component B1 E2; wherein the sum of the components B1A, B1B, B1C and optionally B1D and B1E is 100 % by weight. 4. The insecticide or repellent or rodenticide, fungicide, molluscicide, larvicide or ovicide composition as claimed in any of claims 1 to 3, wherein the insecticide is selected from  pyrethroid compounds,  carbamate compounds,  organophosphorous compounds,  insecticides with a sterilising effect on adult mosquitoes,  the repellent is selected from N,N-diethyl-meta-toluamide (DEET), N,N-diethylphenylacetamide (DEPA), 1-(3-cyclohexan-1-yl-carbonyl)-2-methyl-piperine, (2-hydroxymethylcyclohexyl) acetic acid lactone, 2-ethyl-1,3-hexandiol, indalone, methylneodecanamide (MNDA), a pyrethroid not used for insect control, a repellent derived from or identical with plant extracts or crude plant extracts, IR3535 (ethyl butylacetylaminopropionate) and icaridin (1-piperidinecarboxylic acid 2-(2-hydroxyethyl)-1-methylpropylester),  niclosamide is selected as molluscicide;  suitable rodenticides of first generation anticoagulant rodenticides and second generation anticoagulant rodenticides are selected from the group consisting of warfarin, chlorphacinone, coumatetralyl as first generation anticoagulant rodenticides, and flocoumafen, brodifacoum, difenacoum, bromadialone, difethialone, and bromethalin as second generation anticoagulant rodenticides;  antifungal agents as fungicides used in the case of athlete's foot are selected from the group consisting of clotrimazole: 1-(2-chlorotrityl)imidazole, miconazole: 1-[2-(2,4-dichlorophenyl)-2-[(2,4-dichlorophenyl)methoxy]ethyl]-1H-imidazole, econazole 4-[2-[(4-chlorophenyl)memoxy]-2-(2,4-dichlorophenyl)-ethyl]-4H-imidazole, tioconazole: 1-[2-[(2-chloro-3-thienyl)methoxy]-2-(2,4-dichlorophenyl)-ethyl]-1H-imidazole, undecylenic acid, terbinafine hydrochloride: N,6,6-trimethyl-N-(naphthalen-4-ylmethyl)hept-2-en-4-yn-1-amine hydrochloride (lamisil topical), and tolnaftate: N-methyl-N-(m-tolyl)-1-naphthalen-3-yloxy-thioformamide;  further fungicides are selected from  azoles,  strobilurines,  acylalanines,  amine derivatives, selected from Aldimorph, Dodine, Dodemorph, Fenpropimorph, Fenpropidin, Guazatine, Iminoctadine, Spiroxamine, and  Tridemorph;  anilinopyrimidines,  dicarboximides,  cinnamic acid amide and analogs, selected from Dimethomorph, Flumetover, and  Flumorph;  antibiotics,  dithiocarbamates,  heterocyclic compounds,  nitrophenyl derivatives, selected from Binapacryl, Dinocap, Dinobuton, Nitrophthal-isopropyl;  sulfonic acid derivatives, selected from Captafol, Captan, Dichlofluanid, Folpet,  and Tolylfluanid,  further fungicides are selected from Acibenzolar-S-methyl, Benthiavalicarb, Carpropamid, Chlorothalonil, Cyflufenamid, Cymoxanil, Dazomet, Diclomezin, Diclocymet, Diclofluanid, Diethofencarb, Edifenphos, Ethaboxam, Fenhexamid, Fentin-Acetate, Fenoxanil, Ferimzone, Fluazinam, Fosetyl, Fosetyl-Aluminium, phosphorous acid, Iprovalicarb, hexachlorobenzene, Metrafenone, Pencycuron, Propamocarb, Phthalid, Toloclofos-methyl,  Quintozene and Zoxamide. 5. The insecticide or repellent or rodenticide, fungicide, molluscicide, larvicide or ovicide composition as claimed in claim 4, wherein the insecticide is selected from  pyrethroid compounds selected from the group consisting of  Etofenprox: 2-(4-ethoxyphenyl)-2-methylpropyl-3-phenoxybenzyl ether, Chlorfenapyr: 4-bromo-2-(4-chlorophenyl)-1-ethoxymethyl-5-(trifluoromethyl)-pyrrole-3-carbonitrile,  Fenvalerate: (RS)-alpha-cyano-3-phenoxybenzyl (RS)-2-(4-chlorophenyl)-3 methylbutyrate,  Esfenvalerate: (S)-alpha-cyano-3-phenoxybenzyl (S)-2-(4-chlorophenyl)-3-methylbuty-rate,  Fenpropathrin: (RS)-alpha-cyano-3-phenoxybenzyl 2,2,3,3-tetramethylcyclopropane-carboxylate,  Cypermethrin: (RS)-alpha-cyano-3-phenoxybenzyl (1RS)-cis, trans-3-(2,2-dichlorovinyl)-2,2-dimethylcyclopropanecarboxylate,  alpha-Cypermethrin: racemate comprising the (S)-alpha -(1R) and (R)-alpha -(1S) diastereomers,  Permethrin: 3-phenoxybenzyl (1RS)-cis, trans-3-(2,2-dichlorovinyl)-2,2-dimethylcyclopropanecarboxylate,  Cyhalothrin: (RS)-alpha-cyano-3-phenoxybenzyl (Z)-(1RS)-cis-3-(2-chloro-3,3,3-trifluoroprop-1-enyl)-2,2-dimethylcyclopro panecarboxylate, lambda-cyhalothrin, Deltamethrin: (S)-alpha-cyano-3-phenoxybenzyl (1R)-cis-3-(2,2-dibromovinyl)-2,2-dimethylcyclopropanecarboxylate,  Cycloprothrin: (RS)-alpha-cyano-3-phenoxybenzyl (RS)-2,2-dichloro-1-(4-ethoxyphenyl)cyclopropanecarboxylate,  Fluvalinate: alpha-cyano-3-phenoxybenzyl N-(2-chloro-alpha, alpha, alpha, alpha-trifluoro-p-tolyl)-D-valinate,  Bifenthrin: (2-methylbiphenyl-3-ylmethyl)0(Z)-(1RS)-cis-3-(2-chloro-3,3,3-trifluoro-1-propenyl)-2,2-dimethylcyclopropanecarboxylate, 2-methyl-2-(4-bromodifluoromethoxyphenyl)propyl (3-phenoxybenzyl)ether, Tralomethrin: (S)-alpha-cyano-3-phenoxybenzyl (1R-cis)3((1'RS)(1',2',2',2'-tetrabromoethyl))-2,2-dimethylcyclopropanecarboxylate,  Silafluofen: 4-ethoxyphenyl(3-(4-fluoro-3-phenoxyphenyl)propyl}dimethylsilane, D-fenothrin: 3-phenoxybenzyl (1R)-cis, trans)-chrysanthemate,  Cyphenothrin: (RS)-alpha-cyano-3-phenoxybenzyl (1R-cis, trans)-chrysanthemate, D-resmethrin: 5-benzyl-3-furylmethyl (1R-cis, trans)-chrysanthemate,  Acrinathrin: (S)-alpha-cyano-3-phenoxybenzyl (1R-cis(Z))-(2,2-dimethyl-3-(oxo-3-(1,1,1,3,3,3-hexafluoropropyloxy)propenyl(cyclopropanecarboxylate,  Cyfluthrin: (RS)-alpha-cyano-4-fluoro-3-phenoxybenzyl 3-(2,2-dichlorovinyl)-2,2-dimethylcyclopropanecarboxylate,  Tefluthrin: 2,3,5,6-tetrafluoro-4-methylbenzyl (1RS-cis (Z))-3-(2-chloro-3,3,3-trifluoro-prop-1-enyl)-2,2-dimethylcyclopropanecarboxylate,  Transfluthrin: 2,3,5,6-tetrafluorobenzyl (1R-trans)-3-(2,2-dichlorovinyl)-2,2-dimethyl-cyclopropanecarboxylate,  Tetramethrin: 3,4,5,6-tetrahydrophthalimidomethyl (1RS)-cis, trans-chrysanthemate,  Allethrin: (RS)-3-allyl-2-methyl-4-oxocyclopent-2-enyl (1RS)-cis, trans-chrysanthemate,  Prallethrin: (S)-2-methyl-4-oxo-3-(2-propynyl)cyclopent-2-enyl (1R)-cis, trans-chrysanthemate,  Empenthrin: (RS)-1-ethynyl-2-methyl-2-pentenyl (1R)-cis,trans-chrysanthemate, Imiprothrin: 2,5-dioxo-3-(prop-2-ynyl)imidazolidin-1-ylmethyl (1R)-cis, trans-2,2-dimethyl-3-(2-methyl-l-propenyl)-cyclopropanecarboxylate,  D-flamethrin: 5-(2-propynyl)-furfuryl (1R)-cis, trans-chrysanthemate, and 5-(2-propynyl)furfuryl 2,2,3,3-tetramethylcyclopropanecarboxylate;  Pyriproxyfen: 4-phenoxyphenyl (RS)-2-(2-pyridyloxy)propyl ether;  pyrethrum;  d-d, trans-cyphenothrin: (RS)-alpha -cyano-3-phenoxybenzyl (1RS,3RS;1RS,3SR)-2,2-dimethyl-3-(2-methylprop-1-enyl)cyclopropanecarboxylate;  DDT;  carbamate compounds selected from the group consisting of  Alanycarb: S-methyl-N[[N-methyl-N-[N-benzyl-N(2-ethoxy-carbonylethyl)amino-thio]carbamoyl]thioacetimidate,  Bendiocarb: 2,2-dimethyl-1,3-benzodioxol-4-yl-methylcarbamate), Carbaryl(1-naphthyl N-methylcarbamate,  Isoprocarb: 2-(1-methylethyl)phenyl methylcarbamate,  Carbosulfan: 2,3 dihydro-2,2-dimethyl-7-benzofuranyl[(dibutylamino)thio]methylcarbamate,  Fenoxycarb: Ethyl[2-(4-phenoxyphenoxy)ethyl]carbamate,  Indoxacarb: Methyl-7-chloro-22,3,4 deg.,5-tetrahydro-2-[methoxycarbonyl (-4-trifluoromethoxyphenyl)]  Propoxur: 2-isopropyloxyphenal methylcarbamate,  Pirimicarb: 2-dimethylamino-5,6-dimethyl-4-pyrimidinyl-dimethylcarbamate, Thiodiocarb: dimethyl N,N'(thiobis((methylimino)carbonoyloxy)bisethanimidiothioate);  Methomyl: S-methyl N-((methylcarbamoyl)oxy)thioacetamidate,  Ethiofencarb: 2-((ethylthio)methy)phenyl methylcarbamate,  Fenothiocarb: S-(4-phenoxybutyl)-N,N-dimethyl thiocarbamate,  Cartap: S,S'-(2-5 dimethylamino)trimethylene)bis (thiocarbamate)hydrochloride, Fenobucarb: 2-sec-butylphenylmethyl carbamate,  XMC: 3,5-dimethylphenyl-methyl carbamate,  Xylylcarb: 3,4-dimethylphenylmethylcarbamate;  organophosphorous compounds selected from the group consisting of  Trichlorfon: phosphoric acid, (2,2,2-trichloro-1-hydroxyethyl)-, dimethyl ester Fenitrothion: O,O-dimethyl O-(4-nitro-m-tolyl)phosphorothioate,  Diazinon: O,O-diethyl-O-(2-Isopropyl-6-methyl-4-pyrimidinyl)phosphorothioate, Pyridaphenthion: O-(1,6-dihydro-6-oxo-1-phenylpyrazidin-3-yl) O,O-diethyl phosphorothioate,  Pirimiphos-Etyl: O,O-diethyl O-(2-(diethylamino)6-methyl-pyrimidinyl)phosphorothioate, Pirimiphos-Methyl: O-[2-(diethylamino)-6-methyl-4 pyrimidinyl] O,O-dimethyl phosphorothioate,  Etrimphos: O-6-ethoxy-2-ethyl-pyrimidin-4-yl-O,O-dimethyl-phosphorothioate, Fenthion: 0,O-dimethyl-O-[-3-methyl-4-(methylthio)phenyl phosphorothioate,  Phoxim: 2-(diethoxyphosphinothoyloxyimino)-2-phenylacetonitrile,  Chlorpyrifos: O,O-diethyl-O-(3,5,6-trichloro-2-pyrinyl)phosphorothioate, Chlorpyriphosmethyl: O,O-dimethyl O-(3,5,6-trichloro-2-pyridinyl)phosphorothioate,  Cyanophos: O,O-dimethyl O-(4 cyanophenyl)phosphorothioate,  Pyraclofos: (R,S)[4-chlorophenyl)-pyrazol-4-yl]-O-ethyl-S-n-propyl phosphorothioate,  Acephate: O, S-dimethyl acetylphosphoroamidothioate,  Azamethiphos: S-(6-chloro-2,3-dihydro-oxo-1,3-oxazolo[4,5-b]pyridine-3-ylmethyl phosphorothioate,  Malathion: O,O-dimethyl phosphorodithioate ester of diethyl mercaptosuccinate, Temephos: (O,O'(thiodi-4-1-phenylene) O,O,O,O-tetramethyl phosphorodithioate, Dimethoate: ((O,O-dimethyl S-(n-methylcarbamoylethyl)phosphorodithioate, Formothion: S[2-formylmethylamino]-2-oxoethyl]-O,O-dimethyl phosphorodithioate,  Phenthoate: O,O-dimethyl S-(alpha-ethoxycarbonylbenzal)-phosphorodithioate; lodofenphos: O-(2,5-dichloro-4-iodophenyl)-O,O-dimethyl-phosphorthioate;  insecticides with a sterilising effect on adult mosquitoes selected from the group consisting of  1-(alfa-(chloro-alpha-cyclopropylbenzylidenamino-oxy)-p-tolyl)-3-(2,6-difluorobenzoyl)urea,  Diflubenzuron: N-(((3,5-dichloro-4-(1,1,2,2-tetraflouroethoxy)phenylamino)carbonyl)2,6 difluoro benzamide,  Triflumuron: 2-chloro-N-(((4-(trifluoromethoxy)phenyl)-amino-)carbonyl)benzamide, or a triazine, which is N-cyclopropyl-1,3,5-triazine-2,4,6-triamine;  and  Lambda-cyhalothrine:  alpha -cyano-3-phenoxybenzyl-3-(2-chloro-3,3,3-trifluoroprop-1-enyl)-2,2-dimethylcyclopropane carboxylate, as a 1:1 mixture of (Z)-(1R,3R), R-ester and (Z)-(1S,3S), S-ester,  the repellent is selected from the group consisting of  N,N-diethyl-meta-toluamide (DEET), N,N-diethylphenylacetamide (DEPA), 1-(3-cyclohexan-1-yl-carbonyl)-2-methylpiperine, (2-hydroxymethylcyclohexyl) acetic acid lactone, 2-ethyl-1,3-hexandiol, indalone, methylneodecanamide (MNDA), {(+/-)-3-allyl-2-methyl-4-oxocyclopent-2-(+)-enyl-(+)-trans-chrysantemate (Esbiothrin), limonene, eugenol, (+)-eucamalol (1), (-)-1-epi-eucamalol, crude plant extracts from Eucalyptus maculata, Vitex rotundifolia, Cymbopogan martinii, Cymbopogan citratus (lemon grass), Cymopogan nartdus (citronella), IR3535 (ethyl butylacetylaminopropionate), and icaridin (1-piperidinecarboxylic acid 2-(2-hydroxyethyl)-1-methylpropylester).  the further fungicides are selected from  azoles selected from Bitertanol, Bromoconazole, Cyproconazole, Difenoconazole, Dinitroconazole, Epoxiconazole, Fenbuconazole, Fluquiconazole, Flusilazol, Flutriafol, Hexaconazole, Imazalil, Ipconazole, Metconazole, Myclobutanil, Penconazole, Propiconazole, Prochloraz, Prothioconazole, Simeconazole, Tebuconazole, Tetraconazole, Triadimefon, Triadimenol, Triflumizol, and Triticonazole;  strobilurines, selected from Azoxystrobin, Dimoxystrobin, Fluoxastrobin, Kresoxim-methyl, Metominostrobin, Orysastrobin, Picoxystrobin, Pyraclostrobin, and Trifloxystrobin;  acylalanines selected from Benalaxyl, Metalaxyl, Mefenoxam, Ofurace, and Oxadixyl;  amine derivatives selected from Aldimorph, Dodine, Dodemorph, Fenpropimorph, Fenpropidin, Guazatine, Iminoctadine, Spiroxamine, and Tridemorph;  anilinopyrimidines selected from Pyrimethanil, Mepanipyrim, and Cyprodinil;  dicarboximides selected from Iprodione, Myclozolin, Procymidon, and Vinclozolin;  cinnamic acid amide and analogues selected from Dimethomorph, Flumetover, and Flumorph;  antibiotics selected from Cycloheximid, Griseofulvin, Kasugamycin, Natamycin, Polyoxin, and Streptomycin;  dithiocarbamates selected from Ferbam, Nabam, Maneb, Mancozeb, Metam, Metiram, Propineb, Polycarbamat, Thiram, Ziram and Zineb;  heterocyclic compounds selected from Anilazin, Benomyl, Boscalid, Carbendazim, Carboxin, Oxycarboxin, Cyazofamid, Dazomet, Dithianon, Famoxadon, Fenamidon, Fenarimol, Fuberidazol, Flutolanil, Furametpyr, Isoprothiolan, Mepronil, Nuarimol, Picobenzamid, Probenazol, Proquinazid, Pyrifenox, Pyroquilon, Quinoxyfen, Silthiofam, Thiabendazol, Thifluzamid, Thiophanat-methyl, Tiadinil, Tricyciazol, and Triforine M inorganics;  nitrophenyl derivatives selected from Binapacryl, Dinocap, Dinobuton, Nitrophthal-isopropyl;  Phenylpyrrole, Fenpiclonil and Fludioxonil, and  sulfonic acid derivatives selected from Captafol, Captan, Dichlofluanid, Folpet, and Tolylfluanid. 6. The insecticide or rodenticide, fungicide, molluscicide, larvicide or ovicide composition as claimed in any of claims 1 to 5, wherein the particle size of the insecticide and/or repellent and/or rodenticide, fungicide, molluscicide, larvicide and/or ovicide is from 50 nm to 20 micron m. 7. The insecticide or repellent or rodenticide, fungicide, molluscicide, larvicide or ovicide composition as claimed in any of claims 1 to 6, further comprising one or more component selected from water, preservatives, detergents, stabilizers, agents having UV-protecting properties, optical brighteners, spreading agents, anti-migrating agents, foam-forming agents, wetting agents, anti-soiling agents, thickeners, further biocides, plasticizers, adhesive agents, fragrance, pigments and dyestuffs. 8. The insecticide or repellent or rodenticide, fungicide, molluscicide, larvicide or ovicide composition as claimed in any of claims 1 to 7, comprising from 0.001 to 95 % by weight of the insecticide and/or repellent and/or at least one rodenticide, fungicide, molluscicide, larvicide and/or ovicide. 9. The insecticide or repellent or rodenticide, fungicide, molluscicide, larvicide or ovicide composition as claimed in any of claims 1 to 8, which is provided as a kit for impregnation by the end-user or in a local factory. 10. The insecticide or repellent or rodenticide, fungicide, molluscicide, larvicide or ovicide composition as claimed in claim 9 wherein the composition in the kit is adapted for preparing a solution or emulsion by adding water. 11. The insecticide or repellent or rodenticide, fungicide, molluscicide, larvicide or ovicide composition as claimed in any of claims 1 to 10, additionally comprising a fixative agent. 12. The insecticide or repellent or rodenticide, fungicide, molluscicide, larvicide or ovidde composition as claimed in claim 11, wherein the fixative agent is an isocyanurate comprising free isocyanate groups. 13. The insecticide or repellent or rodenticide, fungicide, molluscicide, larvicide or ovicide composition as claimed in claim 12, wherein the fixative agent is an isocyanurate based on HMDI which is hydrophilized with a polyethylene oxide and which is dissolved in propylene carbonate (70 % by weight of HMDI in 30 % by weight of propylene carbonate), wherein the amount of free isocyanate groups is 11 to 12 % by weight, based on the amount of isocyanate used as staring material for the preparation of the isocyanurate. 14. The insecticide or repellent or rodenticide, fungicide, molluscicide, larvicide or ovicide composition as claimed in any of claims 11 to 13 comprising the following components, based on the solids content of the composition: a) 20 to 70 % by weight, of at least one insecticide and/or at least one repellent and/or at least one rodenticide, fungicide, molluscicide, larvicide and/or ovicide (component A), and b1) 29 to 72 % by weight, of at least one acrylic binder (component B1) as defined above, comprising; b1a) 10 to 90% by weight based on the acrylic binder of n-butyl acrylate (component B1A); b1 b) 10 to 90% by weight based on the acrylic binder of at least one monomer of formula I (component B1 B); b1c) 1 to 5 % by weight based on the acrylic binder of at least one monomer of formula II (component B1C); b1d) 0 to 5 % by weight based on the acrylic binder of at least one monomer of formula III (component B1D); b1e) further monomers which are copolymerizable with the monomers mentioned (component B1E) above selected from b1e1) 0 to 30 % by weight based on the acrylic binder of at least one polar momomer (component B1E1); and/or b1e2) 0 to 40 % by weight based on the acrylic binder of at least one non polar momomer (component B1E1);c) 1 to 8 % by weight of at least one fixative agent (component C); wherein the sum of the components is 100 % by weight of solids content of the insecticide or repellent or rodenticide, fungicide, molluscicide, larvicide or ovicide composition. 15. An impregnated textile material or plastics material for insect killing and/or repellence of an insect comprising a) at least one insecticide and/or at least one repellent, and b1) at least one acrylic binder as claimed in any of claims 1 to 3. 16. The impregnated textile material, or plastics material as claimed in claim 15 comprising an insecticide and/or repellent as defined in claim 4. 17. The impregnated textile material or plastics material as claimed in claim 15 or 16 further comprising one or more components selected from preservatives, detergents, stabilizers, agents having UV-protecting properties, optical brighteners, spreading agents, anti-migrating agents, foam-forming agents, wetting agents, anti-soiling agents, thickeners, further biocides, plasticizers, adhesive agents, fragrance, pigments and dyestuffs. 18. The impregnated textile material or plastics material as claimed in any of claims 15 to 17 comprising from 0.001 to 10 % by weight of the weight of the textile material or plastics material of at least one insecticide and/or at least one repellent. 19. The impregnated textile material or plastics material as claimed in claim 18, comprising a) 0.01 to 10 % by weight of the textile material or plastics material of at least one insecticide and/or at least one repellent, and b1) 0.001 to 10 % by weight of the weight of the textile material or plastics material of at least one acrylic binder as claimed in any of claims 1 to 3. 20. The impregnated textile material or plastics material as claimed in any of claims 15 to 19, wherein the textile material or plastics material is a netting made from polyester. 21. A process for impregnation of a textile material or plastics material comprising the steps i) forming an aqueous formulation or a melt, comprising at least one insecticide and/or at least one repellent and/or at least one rodenticide, fungicide, molluscicide, larvicide and/or ovicide as defined in claim 4 and at least one acrylic binder as defined in any of claim 1 to 3 and optionally further ingredients; ii) applying the aqueous formulation to the textile material or plastics material by iia) passing the textile material or plastics material through the aqueous formulation;  or iib) bringing the textile material or plastics material in contact with a roller that is partly or fully dipped into the aqueous formulation and drawing the aqueous formulation to the side of the textile material or plastics material in contact with the roller;  or iic) double-side coating of the textile material or plastics material;  or iid) spraying the aqueous formulation onto the textile material or plastics material; wherein the spraying is carried out with any suitable device for spraying by hand or automatically, for example with an aerosol can or devices usually used in a factory;  or iie) applying the aqueous formulation in form of a foam;  or iif) submerging the textile material or plastics material into the aqueous formulation;  or iig) brushing the aqueous formulation onto or into the textile material or plastics material;  or iih) pouring the aqueous formulation onto the textile material or plastics material; or  applying the melt by calandering or with a doctor-blade; iii) optionally removing surplus aqueous formulation or surplus melt; and iv) drying and/or curing the textile material or plastics material. 22. The process as claimed in claim 21, wherein step iia) is carried out by completely submerging the textile material or plastics material in the aqueous formulation either in a trough containing the aqueous formulation or passing the textile material or plastics material through the aqueous formulation which is held between two horizontally oriented rollers. 23. The process as claimed in claim 21 or 22, wherein the insecticide and/or repellent and/or rodenticide, fungicide, molluscicide, larvicide and/or ovicide is an insecticide and/or repellent and/or rodenticide, fungicide, molluscicide, larvicide and/or ovicide as defined in claim 4. 24. The process as claimed in any of claims 21 to 23, wherein the aqueous formulation further comprises one or more ingredients selected from the group consisting of detergents, stabilizers, agents having UV-protecting properties, optical brighteners, spreading agents, anti-migrating agents, preservatives, foam-forming agents, wetting agents, thickeners, further biocides, plasticizers, adhesive agents, anti-soiling agents, fragrance, pigments and dyestuffs. 25. The process as claimed in any of claims 21 to 24, wherein the dying of the textile material or plastics material is carried out simultaneously with the impregnation of the textile material or plastics material, wherein an aqueous formulation is formed further comprising at least one dyestuff and/or at least one pigment. 26. The process as claimed in any of claims 21 to 25, wherein the curing in step iv) is carried out at 60 to 170  deg.C. 27. A process for coating a textile material or plastics material by applying a composition comprising at least one insecticide and/or at least one repellent and/or at least one rodenticide, fungicide, molluscicide, larvicide and/or ovicide and at least one acrylic binder as defined in any of claims 1 to 3 to the textile material or plastics material. 28. The process as claimed in claim 27, wherein the composition further comprises one or more ingredients selected from the group consisting of detergents, stabilizers, agents having UV-protecting properties, optical brighteners, spreading agents, anti-migrating agents, preservatives, foam-forming agents, anti-soiling agents, wetting agents, thickeners, further biocides, plasticizers, adhesive agents, fragrance, pigments and dyestuffs. 29. Use of an insecticide or repellent or rodenticide, fungicide, molluscicide, larvicide or ovicide composition as claimed in any of claims 1 to 14 for impregnation of textile material or plastics material.
法律状态
(EP1697578) LEGAL DETAILS FOR EP1697578  Actual or expected expiration date=2024-12-21    Legal state=ALIVE    Status=GRANTED     Event publication date=2004-12-21  Event code=EP/APP  Event indicator=Pos  Event type=Examination events  Application details  Application country=EP EP04804134  Application date=2004-12-21  Standardized application number=2004EP-0804134     Event publication date=2006-09-06  Event code=EP/A2  Event type=Examination events  Application published without search report  Publication country=EP  Publication number=EP1697578  Publication stage Code=A2  Publication date=2006-09-06  Standardized publication number=EP1697578     Event publication date=2006-09-06  Event code=EP/17P  Event indicator=Pos  Event type=Examination events  Request for examination filed Pruefungsantrag gestellt  Effective date of the event=2006-06-02     Event publication date=2006-09-06  Event code=EP/AK  Event indicator=Pos  Event type=Designated states  Designated contracting states: Benannte vertragsstaaten AT BE BG CH CY CZ DE DK EE ES FI FR GB GR HU IE IS IT LI LT LU MC NL PL PT RO SE SI SK TR    Event publication date=2006-09-06  Event code=EP/AX  Event indicator=Pos  Event type=Designated states  Extension of the European patent to Request for extension of the european patent to AL BA HR LV MK YU    Event publication date=2007-03-28  Event code=EP/DAX  Event indicator=Neg  Event type=Designated states  Request for extension of the european patent (to any country) deleted    Event publication date=2008-03-05  Event code=EP/RAP1  Event type=Change of name or address  Event type=Reassignment  Transfer of rights of an application Anmelder uebertragung (korr.) 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