Mixtures comprising a superabsorbent polymer (sap) and a biopesticide 机翻标题: 暂无翻译,请尝试点击翻译按钮。

公开号/公开日
WO2015091967 A1 2015-06-25 [WO201591967] / 2015-06-25
申请号/申请日
2014WO-EP78774 / 2014-12-19
发明人
ANGEL RODRIGUEZ-TELLO;BOUGOURE JEREMY;FLAVEL RICHARD;GLASER ALBAN;KÖHLE HARALD;MAINWARNING DAVID;MARK TINA;MATHES FALKO;MURPHY DANIEL;MURUGARAJ PANDIYAN;PEARCE JEREMY DAVID;PERERA GEETHA;PUENTE PILAR;RYAN PETER;SANZ-GOMEZ JORGE;
申请人
BASF;CRC FOR POLYMERS;
主分类号
IPC分类号
A01N-025/10A01N-063/00A01N-063/02A01N-063/04A01N-065/00A01P-007/04A01P-021/00
摘要
(WO201591967) A mixture or kit-of-parts comprising a superabsorbent polymer (hereinafter referred to as "SAP" or "SAPs") and a biopesticide, their application in agriculture, or the method for conducting the combined application of SAP and biopesticide in agriculture.
机翻摘要
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地址
代理人
代理机构
;
优先权号
2013EP-0198612 2013-12-19
主权利要求
(WO201591967) Claims 1 . A mixture or a kit-of-parts comprising: 1 ) at least one superabsorbent polymer (S) selected from the groups (S10), (S20), (S30), (S40), (S50), (S60), (S70), (S80), and (S90): (S10) Peptide/protein-based SAP selected from the groups (S1 1 ), (S12), and (S13): (S1 1 ) Naturally occurring peptide/protein-based SAP: elastin, collagen, Gelatin A, Gelatin B, silk fibroin, globular proteins, beta-lactoglobulin, bovine serum albumin, ovalbumin; (512) Semi-synthetic or fully-synthetic peptide/protein-based SAP: collagen-based synthetic hydrogels, elastin-like polypeptides, silk— elastin-iike polypeptides, hydrogels based on a coiled coil motif, triblock polypeptides, polyaspartic acid, polyaspartates, polyglutamic acid, polyglutamates; (513) Peptide/protein-based SAP other than those listed in (S1 1 ) or (S12); (S20) Polysaccharide selected from the groups (S21 ), (S22), (S23), (S24), and (S25): (521 ) Naturally occurring polysaccharide: agar, alginate, beta-glucan, carrageenan, cellulose, micro-/nanofibrillar cellulose, chitin, d extra n, galactomannan, glucomannan, guar gum, gum arabic, hyaluronan, pectin starch, starch, starch derivatives, xanthan; (522) Semi-synthetic or fully-synthetic polysaccharide: carboxymethyl starch (CMS), sulfoethyl starch (SES), carboxymethyl cellulose (CMC), sulfoethyl cellulose (SEC), hydroxypropyl cellulose, hydroxyethyl cellulose, methylcellulose, chitosan; (S23) Cross-linked polysaccharide: CMS cross-linked with multi-functional carboxylic acids (MFC) or multi-functional epoxides (MFE), SES cross-linked with MFC or MFE, CMC cross-linked with MFC or MFE, SEC cross-linked with MFC or MFE, hydroxypropyl cellulose cross-linked with MFC or MFE, hydroxyethyl cellulose cross-linked with MFC or MFE, methylcellulose cross-linked with MFC or MFE, chitosan cross-linked with MFC or MFE; (S24) Polysaccharide graft copolymer: Polysaccharides obtained by graft polymerizing a monomer onto a polysaccharide, wherein the monomer is selected from acrylonitrile, acrylic acid, methacrylic acid, acrylamide, methacrylamide, 2-acrylamido-2-methyl- propanesulfonic acid (AMPS), vinyl sulfonic acid, ethyl acrylate, and potassium acrylate; (S25) Polysaccharide other than those listed in (S21 ), (S22), (S23) or (S24); OD (S30) Polymer containing one or more unsaturated carboxylic acid, or its salts thereof, as monomeric units, selected from the groups (S31 ), (S32), (S33), (S34), and (S35): (S31 ) Polymer containing acrylic acid, or its salts thereof, as monomeric units; (S32) Polymer containing methacrylic acid, or its salts thereof, as monomeric units; (S33) Polymer containing as monomeric units at least one of the unsaturated carboxylic acids - or salts thereof - selected from: crotonic acid, isocrotonic acid, 2'- methylisocrotonic acid, maleic acid, fumaric acid, vinyl acetic acid, ethacrylic acid, alpha-chloroacrylic acid, alpha-cyanoacrylic acid, alpha-phenylacrylic acid, beta- acryloxypropionic acid, sorbinic acid, alpha-chlorosorbinic acid, cinnamic acid, p- chlorocinnamic acid, beta-stearic acid, itaconic acid, citraconic acid, mesaconic acid, glutaconic acid, aconitic acid, tricarboxy ethylene, and maleic acid anhydride; (S34) Polymer containing as monomeric units at least one of the unsaturated carboxylic acids - or salts thereof - selected from: terephthalic acid, dimethyl terephthalate, phthalic acid, isophthalic acid, naphthalene dicarboxylic acid, 4-hydroxybenzoic acid, 6-hydroxynaphthalene-2-carboxylic acid; (S35) Polymer containing as monomeric units one or more unsaturated carboxylic acid - or salts thereof - which are not listed in (S31 ), (S32), (S33), or (S34); (S40) Polymer containing one or more unsaturated sulfonic acid, or one or more unsaturated phosphonic acid, or its salts thereof, as monomeric units, selected from the groups (S41 ), (S42), and (S43): (541 ) Polymer containing as monomeric units at least one of the unsaturated sulfonic acids - or salts thereof - selected from: 2-acrylamido-2-methyl-1 -propanesulfonic acid (AMPS), methallyl sulfonic acid, allyl sulfonic acid, acrylic sulfonic acid, methacrylic sulfonic acid, vinyl sulfonic acid, 4-vinylbenzylsulfonic acid, vinyltoluenesulfonic acid, styrenesulfonic acid, sulfoethyl(meth)acrylate, sulfopropyl(meth)acrylate, and 2-hydroxy-3-methacryloxypropylsulfonic acid; (542) Polymer containing as monomeric units at least one of the unsaturated phosphonic acids - or salts thereof - selected from: vinylphosphonic acid, allylphosphonic acid, vinylbenzylphosphonic acid, (meth)acrylamidoalkylphosphonic acids, acrylamidoalkyldiphosphonic acids, phosphonomethylated vinylamines and (meth)acrylphosphonic acid derivatives; (S43) Polymer containing as monomeric units one or more unsaturated sulfonic acids not listed in (S41 ) or one or more unsaturated phosphonic acids not listed in (S42); (S50) Polymer containing one or more amines or amides as monomeric units, selected from the groups (S51 ), (S52), (S53), (S54) and (S55): O f (S51 ) Polymer containing acrylamide or methacrylamide as monomeric units; (552) Polymer containing as monomeric units at least one of the unsaturated amides selected from; N-methylol(meth)acrylamide, N, N-dimethylamino(meth)acrylamide, dimethyl(meth)acrylamide, diethyl(meth)acrylamide, N-vinylamides, N- vinylformamides, N-vinylacetamides, N-vinyl-N-methylacetamide, N-vinyl-N- methylformamides, vinylpyrrolidone; (553) Polymer containing as monomeric units one or more amides not listed in (S51 ) or (S52); (554) Polymer containing as monomeric units at least one primary amine, secondary amine, tertiary amine, or quarternary ammonium salt; (555) Polyamidoamines; (S60) Polymer containing optionally cross-linked polyethers or polyols, selected from the groups (S61 ), (S62), (S63), (S64), and (S65): (561 ) Polymer containing optionally cross-linked polyethylene glycol (PEG); (562) Polymer containing optionally cross-linked polypropylene glycol (PPG) or poly(oxyethylene-oxypropylene) copolymer; (563) Polymer containing at least one optionally cross-linked polyether selected from: polyoxymethylene, poly (tetra hyd rof ura n ) , polyphenyl ether (PPE), and poly(p- phenylene oxide) (PPO); (564) Polymer containing optionally cross-linked polyvinyl alcohol; (565) Polymer containing optionally cross-linked polyethers or polyols not listed in (S61 ), (S62), (S63) or (S64); (S70) Polymer selected from the groups (S71 ), (S72), (S73), and (S74): (S71 ) Polymer containing monoethylenically unsaturated acidic group-containing monomers S70A and monoethylenically unsaturated monomers S70B which are cross-linked with at least one cross-linker S71 C selected from: alkenyldi(meth)acrylates, ethyleneglycoldi(meth)acrylate, 1 ,3- propyleneglycoldi(meth) acrylate, 1 ,4-butyleneglycoldi(meth)acrylate, 1 ,3- butyleneglycoldi(meth)acrylate, 1 ,6-hexanedioldi(meth)acrylate, 1 ,10- decanedioldi(meth)acrylate, 1 ,12-dodecanedioldi(meth)acrylate, 1 ,18- octadecanedioldi(meth)acrylate, cyclopentanedioldi(meth)acrylate, neopentylglycoldi(meth)acrylate, methylenedi(meth)acrylate or pentaerythritoldi(meth)acrylate, alkenyldi(meth)acrylamides, N- methyldi(meth)acrylamide, N,N'-3-methylbutylidenebis(meth)acrylamide, N, N'-(1 ,2- dihydroxyethylene)bis(meth)acrylamide, N,N'-hexamethylenebis(meth)acrylamide or N,N'-methylenebis(meth)acrylamide, polyalkoxydi(meth)acrylates, diethyleneglycoldi(meth)acrylate, triethyleneglycoldi(meth) acrylate, tetraethyleneglycoldi(meth)acrylate, dipropyleneglycoldi(meth)acrylate, tripropyleneglycoldi(meth)acrylate or tetrapropyleneglycoldi(meth) acrylate, bisphenol-A-di(meth)acrylate, ethoxylated bisphenol-A-di(meth)acrylate, benzylidenedi(meth)acrylate, 1 ,3-di(meth)acryloyloxypropanol-2, hydroquinonedi(meth)acrylate, di(meth)acrylate esters of trimethyloipropane, ethoxylated di(meth)acrylate esters of trimethyloipropane, thioethyleneglycoldi(meth)acrylate, thiopropyleneglycoldi(meth)acrylate, thiopolyethyleneglycoldi(meth)acrylate, thiopolypropyleneglycoldi(meth)acrylate, divinyl ethers, 1 ,4-butanedioldivinylether, divinyl esters, divinyladipate, alkanedienes, butadiene or 1 ,6-hexadiene, divinylbenzene, di(meth)allyl compounds, di(meth)allylphthalate or di(meth)allylsuccinate, homo- and co-polymers of di(meth)allyldimethylammonium chloride and homo- and co-polymers of diethyl(meth)allylaminomethyl(meth)acrylateammonium chloride, vinyl(meth)acrylic compounds, vinyl(meth)acrylate, (meth)allyl(meth)acrylic compounds, (meth)allyl(meth)acrylate, (meth)allyl(meth)acrylate ethoxylated with 1 to 30 mol ethylene oxide per hydroxy I group, di(meth)allylesters of polycarbonic acids, di(meth)allylmaleate, di(meth)allylfumarate, di(meth)allylsuccinate or di(meth)allylterephthalate, compounds with 3 or more ethylenically unsaturated, glycerine tri(meth)acrylate, (meth)acrylate esters of glycerins which are ethoxylated, trimethylolpropanetri(meth)acrylate, tri(meth)acrylate esters of trimethyloipropane, ethoxylated tri(meth)acrylate esters of trimethyloipropane, trimethacrylamide, (meth)allylidenedi(meth)acrylate, 3-allyloxy-1 ,2-propanedioldi(meth)acrylate, tri(meth)allylcyanurate, tri(meth)allylisocyanurate, pentaerythritoltetra(meth)acrylate, pentaerythritoltri(meth)acrylate, (meth)acrylic acid esters of pentaerythritol which is ethoxylated, tris(2-hydroxyethyl)isocyanuratetri(meth)acrylate, trivinyltrimellitate, tri(meth)allylamine, di(meth)allylalkylamines, di(meth)allylmethylamine, tri(meth)allylphosphate, tetra(meth)allylethylenediamine, poly(meth)allyl ester, tetra(meth)allyloxyethane or tetra(meth)allylammonium halides; Polymer containing monoethylenically unsaturated acidic group-containing monomers S70A and monoethylenically unsaturated monomers S70B which are cross-linked with at least one cross-linker S72C selected from: polyols, ethyleneglycol, polyethyleneglycols, diethyleneglycol, triethyleneglycol, tetraethyleneglycol, propyleneglycol, polypropyleneglycols, dipropyleneglycol, tripropyleneglycol, tetrapropyleneglycol, 1 ,3-butanediol, 1 ,4-butanediol, 1 ,5- pentanediol, 2,4-pentanediol, 1 ,6-hexanediol, 2,5-hexanediol, glycerine, polyglycerin, trimethyloipropane, poiyoxypropylene, oxyethylene-oxypropylene-block copolymer, sorbitan fatty acid esters, polyoxyethylenesorbitan fatty acid esters, pentaerythritol, polyvinylalcohol and sorbitol, aminoalcohols, ethanolamine, diethanolamine, triethanolamine or propanolamine, polyamine compounds, ethylenediamine, diet ylenetriamine, triethylenetetraamine, tetraethylenepentaamine or pentaethylenehexaamine, polyglycidyl ether compounds, ethyleneglycoldiglycidyl ether, polyethyleneglycoldiglycidyl ether, glycerinediglycidyl ether, glycerinepolyglycidyl ether, pentaerithritolpolyglycidyl ether, propyleneglycoidiglycidyl ether, polypropyleneglycoldiglycidyl ether, neopentylglycoldiglycidyi ether, hexanediolglycidyl ether, trimethylo!propanepolyglycidyl ether, sorbitolpolyglycidyl ether, phthalic acid diglycidy! ester, adipinic acid diglycidyl ether, 1 ,4-phenylenebis(2-oxazoline), glycidol, polyisocyanates, diisocyanates, 2,4-toluenediioscyanate, hexamethyienediisocyanate, polyaziridine compounds, 2,2- bishydroxymethylbutanol-tris[3-(1 -aziridinyl-)propionate], 1 ,6- hexamethylenediethyleneurea, diphenyimethane-bis-4,4'-N , N'-diethyleneurea, halogen epoxides, epichlorohydrin, epibromohydrin and alpha- methylepichlorohydrin, alkylenecarbonates, 1 ,3-dioxolane-2-one (ethylene carbonate), 4-methyl-1 , 3-dioxolane-2-one(propylene carbonate), 4,5-dimethyl-1 ,3- dioxolane-2-one, 4,4-dimethyl-1 ,3-dioxolane-2-one, 4-ethyl-1 , 3-dioxolane-2-one, 4- hydroxymethyl-1 ,3-dioxolane-2-one, 1 , 3-dioxane-2-one, 4-methyl-1 ,3-dioxane-2- one, 4,6-dimethyl-1 ,3-dioxane-2-one, 1 ,3-dioxolane-2-one, poly-1 ,3-dioxolane-2- one, polyquaternary amines, condensation products from dimethylamines and epichlorohydrin, polyoxazolines, 1 , 2-ethylenebisoxazoline, crosslinkers with silane groups, 7-glycidooxypropyltrimethoxysilane, 7-aminopropyltrimethoxysilane, oxazolidinones, 2-oxazolidinone, bis- and poly-2-oxazolidinone and diglycolsilicates; (S73) Polymer containing monoethylenically unsaturated acidic group-containing monomers S70A and monoethylenically unsaturated monomers S70B which are cross-linked with at least one cross-linker S73C selected from: hydroxy I or amino group-containing esters of (meth)acrylic acid, 2- hydroxyethyl(meth)acrylate, as well as hydroxy I or amino group-containing (meth)acry!amides, or mono(meth)allylic compounds of diols; (S74) Polymer containing monoethylenically unsaturated acidic group-containing monomers S70A and monoethylenically unsaturated monomers S70B which are cross-linked with at least one polyvalent metal cross-linker S74C selected from: singly charged cations, doubly charged cations derived from zinc, beryllium, alkaline earth metals, magnesium, calcium, strontium, cations with higher charge selected from cations from aluminium, iron, chromium, manganese, titanium, zirconium and other transition metals as well as double salts of such cations or mixtures of said salts; Polymer selected from the groups (S81 ), (S82), (S83), (S84), (S85), (S86), and (S87): (S81 ) Polymer produced by the process disclosed in WO2013/060848; (S82) polymer produced by the process (S80P1 ); (S83) polymer produced by the process (S80P2); (S84) polymer mixed or grafted with lignocellulose material; (585) polymer mixed or grafted with lignocellulose material selected from list (S80L1 ); (586) polymer containing acrylic acid, or its salts thereof, as monomeric units, mixed or grafted with lignocellulose material selected from list (S80L1 ); (587) polymer selected from the groups (S1 1 ), (S12), (S13), (S21 ), (S22), (S23), (S24), (S25), (S32), (S33), (S34), (S35), (S41 ), (S42), (S43), (S51 ), (S52), (S53), (S54), (S55), (S61 ), (S62), (S63), (S64), (S65), (S71 ), (S72), (S73), and (S74), mixed or grafted with lignocellulose material selected from list (S80L1 ), wherein (S80P1 ) is a process for producing polymer composites suitable for absorbing and storing aqueous liquids, comprising: a free-radical polymerization of a monomer composition S80M which a) 50 to 100% by weight, based on the total amount of monomers S80A and S80B, of at least one monomer S80A having one ethylenic double bond and at least one neutralizable acid group group, b) 0 to 50% by weight of optionally one or more comonomers S80B which are different than the monomers S80A and have one ethylenic double bond, and c) 0 to 10% by weight, based on the total amount of monomers S80A and S80B, of at least one crosslinker S80C, in an aqueous suspension of a water-insoluble particulate substance S80S comprising cellulose or lignocellulose, the weight ratio of the monomer composition S80M to the substance S80S being in the range from 9:1 to 1 :9; wherein the monomers S80A used for polymerization are present in the aqueous suspension in anionic form to an extent of at least 10 mol%, wherein (S80P2) is the process according to (S80P1 ), wherein the particulate substance S80S comprises a lignocellulose material and the substance S80S is selected to an extent of at least 50% by weight, based on the total amount of substance S80S, from the list (S80L1 ), wherein the list (S80L1 ) is: hemp dust, flax dust, sawdust, bran, ground straw, ground olive stones, ground tree bark, reject material from pulp production, sugar beet peel, sugar cane waste, rice husks, cereal husks, ground hemp fibers, ground flax fibers, ground Chinese silvergrass fibers, ground coconut fibers, ground kenaf fibers or ground wood fibers, pulp or mechanical pulp from papermaking, and wastes from biogas production, (S90) Inorganic superabsorbent materials: phyllosilicates, phyllosilicates in form of exfoliated or semi-exfoliated clay, clay selected from the group consisting of smectites, hectorites, bentonites, montmorillonites, celites, illites and mixtures thereof; and 2) at least one biopesticide (L) selected from the groups (L1 ), (L3), (L5) and (L7): (L1 ) Microbial pesticides with fungicidal, bactericidal, viricidal and/or plant defense activator activity selected from: (L1 1 ) Ampelomyces quisqualis, (L12) Aspergillus flavus, (L13) Aureobasidium pullulans, (L14) Bacillus amyloliquefaciens, (L15) Bacillus mojavensis, (L16) Bacillus pumilus, (L17) Bacillus simplex, (L18) Bacillus solisalsi, (L19) Bacillus subtilis, (L20) Bacillus subtilis var. amyloliquefaciens, (L21 ) Candida oleophila, or C. saitoana, (L22) Clavibacter michiganensis (bacteriophages), (L23) Coniothyrium minitans, (L24) Cryphonectria parasitica, (L25) Cryptococcus albidus, (L26) Dilophosphora alopecuri, (L27) Fusarium oxysporum, (L28) Clonostachys rosea f. catenulate (also named Gliocladium catenulatum), (L29) Gliocladium roseum, (L30) Lysobacter antibioticus, or L. enzymogenes, (L31 ) Metschnikowia fructicola, (L32) Microdochium dimerum, (L33) Microsphaeropsis ochracea, (L34) Muscodor albus, (L35) Paenibacillus polymyxa, (L36) Pantoea vagans, (L37) Phlebiopsis gigantea, (L38) Pseudomonas sp., or Pseudomonas chloraphis, (L39) Pseudozyma flocculosa, (L40) Pichia anomala, (L41 ) Pythium oligandrum, (L42) Sphaerodes mycoparasitica, (L43) Streptomyces griseoviridis, S. lydicus, or S.violaceusniger, (L44) Talaromyces flavus, (L45) Trichoderma asperellum, T. atroviride, T. fertile, T. gamsii, T. harmatum, T. harzianum, T. stromaticum, T. virens (also named Gliocladium virens), T. viride, or mixture of T. harzianum and T. viride, or mixture of T. polysporum and T. harzianum, (L46) Typhula phacorrhiza, (L47) Ulocladium oudemansii, (L48) Verticillium dahlia, (L49) zucchini yellow mosaic virus (avirulent strain); (L3) Microbial pesticides with insecticidal, acaricidai, moliuscidal and/or nematicidal activity selected from: (L51 ) Agrobacterium radiobacter, (L52) Bacillus cereus, (L53) Bacillus firmus, (L54) Bacillus thuringiensis, B. t. ssp. aizawai, B. t. ssp. israelensis, B. t. ssp. galleriae, B. t. ssp. kurstaki, or B. t. ssp. tenebrionis, (L55) Beauveria bassiana, or B. brongniartii, (L56) Burkholderia sp., (L57) Chromobacterium subtsugae, (L58) Cydia pomonella granulosis virus, (L59) Cryptophlebia leucotreta granulovirus (CrleGV), (L60) Isaria fumosorosea, (L61 ) Heterorhabditis bacteriophora, (L62) Lecanicillium longisporum, or L. muscarium (formerly Verticillium lecanii), (L63) Metarhizium anisopliae, or M. anisopliae var. acridum, (L64) Nomuraea rileyi, (L65) Paecilomyces fumosoroseus, or P. lilacinus, (L66) Paenibacillus popilliae, (L67) Pasteuria spp., P. nishizawae, P. penetrans, P. ramose, P. reneformis, P. thornea, or P. usgae, (L68) Pseudomonas fluorescens, (L69) Steinernema carpocapsae, S. feltiae, or S. kraussei; (L5) Microbial pesticides with plant stress reducing, plant growth regulator, plant growth promoting and/or yield enhancing activity selected from: (L81 ) Azospirillum amazonense, A. brasilense, A. lipoferum, A. irakense, or A. halopraeferens, (L82) Bradyrhizobium sp., B. elkanii, B. japonicum, B. liaoningense, or B. lupini, (L83) Delftia acidovorans, (L84) VA mycorrhiza selected from the genera Glomus, Acaulospora, Entrophosphora, Gigaspora, Scutellospora and Sclerocytis, (L85) VA mycorrhiza selected from the group consisting of Glomus fasciculatum, G. caledonium, G. mosseae, G. versiforme, G. intraradices and G. etunicatum, (L86) Mesorhizobium sp., (L87) Paenibacillus alvei, (L88) Penicillium bilaiae, (L89) hizobium leguminosarum bv. phaseoli, R. I. trifolii, R. I. bv. viciae, or R. tropici, (L90) Sinorhizobium meliloti, (L91 ) Enterobacter spp., E. ludwigii, E. aerogenes, E. amnigenus, E. agglomerans, E. arachidis, E. asburiae, E. cancerogenous, E. cloacae, E. cowanii, E. dissolvens, E. gergoviae, E. helveticus, E. hormaechei, E. intermedius, E. kobei, E. mori, E. nimipressuralis, E. oryzae, E. pulveris, E. pyrinus, E. radicincitans, E. taylorae, E. turicensis, or E. sakazakii, (L92) Oxalobacteraceae spp., Herbaspirillum seropedicae (DSM No.: 6445) (free-living nitrogen fixing bacterium), Janthinobacterium lividum (DSM No.: 1522) (violacein- producing bacterium), or Pseudoduganella violaceinigra (DSM No.: 15887) (violacein- producing bacterium); (L7) Metabolites produced by the microbial pesticides selected from: (L93) siderophores, bacillibactin (L94) antibiotiics such as zwittermicin-A, kanosamine, polyoxine, bacilysin, violacein (L95) enzymes such as alpha-amylase, chitinases, pektinases, phosphatase (acid and alkaline) and phytase (L96) phytohormones and precursors thereof and volatile compounds, such as auxines, gibberellin-like substances, cytokinin-like compounds, acetoin, 2,3-butanediol, ethylene, indole acetic acid, (L97) lipopeptides such as iturins, plipastatins, surfactins, agrastatin, agrastatin A, bacillomycin, bacillomycin D, fengycin, (L98) antibacterial polyketides such as difficidin, macrolactin and bacilaene (L99) antifungal metabolites such as pyrones, cytosporone, 6-pentyl-2H-pyran-2-one (also termed 6-pentyl-a-pyrone), koninginins (complex pyranes), in particular those metabolites produced by Trichoderma species. 2. A mixture or a kit-of-parts according to claim 1 , wherein the at least one biopesticide (L) is (L14), (L15), (L16), (L17), (L18), (L19), (L20), (L45), (L51 ), (L65), (L81 ), (L82), (L84), (L85), (L87), (L89), or (L91 ). 3. The mixture or a kit-of-parts according to claim 1 , wherein the at least one biopesticide (L) is (L16), (L51 ), (L81 ), (L82), (L85), (L87), (L89) or (L91 ). 4. The mixture or a kit-of-parts according to claim 1 , wherein the at least one biopesticide (L) is Bacillus pumilus, Bacillus amyloliquefaciens, Bacillus subtilis, Bacillus subtilis var. amyloliquefaciens, Bacillus simplex, Trichoderma fertile, Agro bacterium radiobacter, Paecilomyces lilacinus, Azospirillum amazonense, A. brasilense, A. lipoferum, A. irakense, A. halopraeferens, Glomus intraradices, Bradyrhizobium sp., B. elkanii, B. japonicum, B. liaoningense, B. lupini, Paenibacillus alvei, Rhizobium leguminosarum bv. phaseoli, R. I. trifolii, R. I. bv. viciae, R. tropici or Enterobacter ludwigii. 5. The mixture or a kit-of-parts according to claim 1 , wherein the at least one superabsorbent polymer (S) is (S80) a polymer selected from the groups (S81 ), (S82), (S83), (S84), (S85), (S86) and (S87). 6. The mixture or a kit-of-parts according to claim 1 , wherein the at least one superabsorbent polymer (S) is (S86) polymer containing acrylic acid, or its salts thereof, as monomeric units, mixed or grafted with lignocellulose material selected from list (S80L1 ). The mixture or a kit-of-parts according to claim 1 , wherein the at least one superabsorbent polymer (S) is (S86) polymer containing acrylic acid, or its salts thereof, as monomeric units, mixed or grafted with lignocellulose material selected from list (S80L1 ), and the at least one biopesticide (L) is Bacillus pumilus, Bacillus amyloliquefaciens, Bacillus subtilis, Bacillus subtilis var. amyloliquefaciens, Bacillus simplex, Trichoderma fertile, Agro bacterium radiobacter, Paecilomyces lilacinus, Azospirillum amazonense, A. brasilense, A. lipoferum, A. irakense, A. halopraeferens, Glomus intraradices, Bradyrhizobium sp., B. elkanii, B. japonicum, B. liaoningense, B. lupini, Paenibacillus alvei, Rhizobium leguminosarum bv. phaseoli, R. I. trifolii, R. I. bv. viciae, R. tropici, or Enterobacter ludwigii. 8. The method for conducting the combined application of 1 ) at least one superabsorbent polymer (S) selected from the groups (S10), (S20), (S30), (S40), (S50), (S60), (S70), (S80), and (S90): (S10) Peptide/protein-based SAP selected from the groups (S1 1 ), (S12), and (S13): (S1 1 ) Naturally occurring peptide/protein-based SAP: elastin, collagen, Gelatin A, Gelatin B, silk fibroin, globular proteins, beta-lactoglobulin, bovine serum albumin, ovalbumin; (512) Semi-synthetic or fully-synthetic peptide/protein-based SAP: collagen-based synthetic hydrogels, elastin-like polypeptides, silk— elastin-iike polypeptides, hydrogels based on a coiled coil motif, triblock polypeptides, polyaspartic acid, polyaspartates, polyglutamic acid, polyglutamates; (513) Peptide/protein-based SAP other than those listed in (S1 1 ) or (S12); (S20) Polysaccharide selected from the groups (S21 ), (S22), (S23), (S24), and (S25): (S21 ) Naturally occurring polysaccharide: agar, alginate, beta-glucan, carrageenan, cellulose, micro-/nanofibrillar cellulose, chitin, d extra n, galactomannan, glucomannan, guar gum, gum arabic, hyaluronan, pectin starch, starch, starch derivatives, xanthan; (522) Semi-synthetic or fully-synthetic polysaccharide: carboxymethyl starch (CMS), sulfoethyl starch (SES), carboxymethyl cellulose (CMC), sulfoethyl cellulose (SEC), hydroxypropyl cellulose, hydroxyethyl cellulose, methylcellulose, chitosan; (523) Cross-linked polysaccharide: CMS cross-linked with multi-functional carboxylic acids (MFC) or multi-functional epoxides (MFE), SES cross-linked with MFC or MFE, CMC cross-linked with MFC or MFE, SEC cross-linked with MFC or MFE, hydroxypropyl cellulose cross-linked with MFC or MFE, hydroxyethyl cellulose cross-linked with MFC or MFE, methylcellulose cross-linked with MFC or MFE, chitosan cross-linked with MFC or MFE; (524) Polysaccharide graft copolymer: Polysaccharides obtained by graft polymerizing a monomer onto a polysaccharide, wherein the monomer is selected from acrylonitrile, acrylic acid, methacrylic acid, acrylamide, methacrylamide, 2-acrylamido-2-methyl- propanesulfonic acid (AMPS), vinyl sulfonic acid, ethyl acrylate, and potassium acrylate; (525) Polysaccharide other than those listed in (S21 ), (S22), (S23) or (S24); (S30) Polymer containing one or more unsaturated carboxylic acid, or its salts thereof, as monomeric units, selected from the groups (S31 ), (S32), (S33), (S34), and (S35): (531 ) Polymer containing acrylic acid, or its salts thereof, as monomeric units; (532) Polymer containing methacrylic acid, or its salts thereof, as monomeric units; (533) Polymer containing as monomeric units at least one of the unsaturated carboxylic acids - or salts thereof - selected from: crotonic acid, isocrotonic acid, 2'- methylisocrotonic acid, maleic acid, fumaric acid, vinyl acetic acid, ethacrylic acid, alpha-chloroacrylic acid, alpha-cyanoacrylic acid, alpha-phenylacrylic acid, beta- acryloxypropionic acid, sorbinic acid, alpha-chlorosorbinic acid, cinnamic acid, p- chlorocinnamic acid, beta-stearic acid, itaconic acid, citraconic acid, mesaconic acid, glutaconic acid, aconitic acid, tricarboxy ethylene, and maleic acid anhydride; (534) Polymer containing as monomeric units at least one of the unsaturated carboxylic acids - or salts thereof - selected from: terephthalic acid, dimethyl terephthalate, phthalic acid, isophthalic acid, naphthalene dicarboxylic acid, 4-hydroxybenzoic acid, 6-hydroxynaphthalene-2-carboxylic acid; (535) Polymer containing as monomeric units one or more unsaturated carboxylic acid - or salts thereof - which are not listed in (S31 ), (S32), (S33), or (S34); (S40) Polymer containing one or more unsaturated sulfonic acid, or one or more unsaturated phosphonic acid, or its salts thereof, as monomeric units, selected from the groups (S41 ), (S42), and (S43): 9b (541 ) Polymer containing as monomeric units at least one of the unsaturated sulfonic acids - or salts thereof - selected from: 2-acrylamido-2-methyl-1 -propanesulfonic acid (AMPS), methallyl sulfonic acid, allyl sulfonic acid, acrylic sulfonic acid, methacrylic sulfonic acid, vinyl sulfonic acid, 4-vinylbenzylsulfonic acid, vinyltoluenesulfonic acid, styrenesulfonic acid, sulfoethyl(meth)acrylate, sulfopropyl(meth)acrylate, and 2-hydroxy-3-methacryloxypropylsulfonic acid; (542) Polymer containing as monomeric units at least one of the unsaturated phosphonic acids - or salts thereof - selected from: vinylphosphonic acid, allylphosphonic acid, vinylbenzylphosphonic acid, (meth)acrylamidoalkylphosphonic acids, acrylamidoalkyldiphosphonic acids, phosphonomethylated vinylamines and (meth)acrylphosphonic acid derivatives; (543) Polymer containing as monomeric units one or more unsaturated sulfonic acids not listed in (S41 ) or one or more unsaturated phosphonic acids not listed in (S42); (S50) Polymer containing one or more amines or amides as monomeric units, selected from the groups (S51 ), (S52), (S53), (S54) and (S55): (551 ) Polymer containing acrylamide or methacrylamide as monomeric units; (552) Polymer containing as monomeric units at least one of the unsaturated amides selected from; N-methylol(meth)acrylamide, N, N-dimethylamino(meth)acrylamide, dimethyl(meth)acrylamide, diethyl(meth)acrylamide, N-vinylamides, N- vinylformamides, N-vinylacetamides, N-vinyl-N-methylacetamide, N-vinyl-N- methylformamides, vinylpyrrolidone; (553) Polymer containing as monomeric units one or more amides not listed in (S51 ) or (S52); (554) Polymer containing as monomeric units at least one primary amine, secondary amine, tertiary amine, or quarternary ammonium salt; (555) Polyamidoamines; (S60) Polymer containing optionally cross-linked polyethers or polyols, selected from the groups (S61 ), (S62), (S63), (S64), and (S65): (S61 ) Polymer containing optionally cross-linked polyethylene glycol (PEG); (S62) Polymer containing optionally cross-linked polypropylene glycol (PPG) or poly(oxyethylene-oxypropylene) copolymer; (S63) Polymer containing at least one optionally cross-linked polyether selected from: polyoxymethylene, poly(tetrahydrofuran), polyphenyl ether (PPE), and poly(p- phenyiene oxide) (PPO); (564) Polymer containing optionally cross-linked polyvinyl alcohol; (565) Polymer containing optionally cross-linked polyethers or polyols not listed in (S61 ), (S62), (S63) or (S64); Polymer selected from the groups (S71 ), (S72), (S73), and (S74): (S71 ) Polymer containing monoethylenically unsaturated acidic group-containing monomers S70A and monoethylenically unsaturated monomers S70B which are cross-linked with at least one cr(...)
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