Characterizing distributions, composition profiles, sources and potential health risk of polybrominated diphenyl ethers (PBDEs) in the coastal sediments from East China Sea 机翻标题: 暂无翻译,请尝试点击翻译按钮。

来源
Environmental Pollution
年/卷/期
2016 / 213 / Jun.
页码
468-481
ISSN号
0269-7491
作者单位
Ocean Univ China, Minist Educ, Key Lab Marine Chem Theory & Technol, Qingdao 266100, Peoples R China;Ocean Univ China, Minist Educ, Key Lab Marine Chem Theory & Technol, Qingdao 266100, Peoples R China;Ocean Univ China, Minist Educ, Key Lab Marine Chem Theory & Technol, Qingdao 266100, Peoples R China;Ocean Univ China, Minist Educ, Key Lab Marine Chem Theory & Technol, Qingdao 266100, Peoples R China;
作者
Wang, Guoguang;Peng, Jialin;Zhang, Dahai;Li, Xianguo;
摘要
Sediment samples (n = 20) were collected from Yangtze River Estuary (YRE) and the adjacent East China Sea (ECS) inner shelf to explore spatial and temporal distributions, environmental fate, sources and potential health risk of polybrominated diphenyl ethers (PBDEs). Concentrations of BDE-209 and total 7 PBDEs (without BDE-209; Sigma 7ERBDEs) ranged from 62.3 to 1758 pg g(-1) and from 36.9 to 233.6 pg g(-1) dry weight, respectively; both of the highest values occurred near the city of Wenzhou. Concentrations of BDE-209 and Sigma 7PBDEs both indicated a decreasing trend from inshore areas toward outer shelf. Significantly positive linear correlations were only observed between logBDE-183 concentrations and TOC/grain size (r(2) = 0.6734 and 0.5977 for TOC and grain size, respectively) as well as BDE-209 and TOC/ grain size (r(2) = 0.4137 and 0.5332 for TOC and grain size, respectively) in the north of 28 degrees N, indicating that YR had significant influence on the distribution of higher brominated congeners only in the north part. Depth profiles of PBDEs in a sediment core P01 (n = 1, m 11) collected from YRE showed that the input of BDE-209 gradually increased from 1930 to 2010, while the levels of Sigma 7RBDEs peaked in 1986 and obviously decreased in recent years. Partial Least-Squares Regression (PLSR) revealed that PBDEs in the coastal ECS were mainly from direct discharge of local anthropogenic activities (80.7%), followed by surface runoff of contaminated soils (15.1%), microbial degradation after sedimentation (2.6%) and photodegradation during atmospheric transportation (1.6%). The cancer risk of human exposure to BDE209 at the 95% confidence level was 3.09 x 10(-7), 1.67 x 10(-7) and 8.86 x 10(-7) for children, teens and adults, respectively, significantly lower than the threshold level (10(-6)). Hazard index (HI) calculated for non-cancer risk was also far less than 1 for the three groups, suggesting no non-cancer risk. (C) 2016 Elsevier Ltd. All rights reserved.
机翻摘要
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关键词/主题词
Polybrominated diphenyl ether;Source identification;Composition profile;Health risk assessment;East China Sea sediment;Yangtze River;
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