Use of malonic acid derivative compounds for retarding plant growth 机翻标题: 暂无翻译,请尝试点击翻译按钮。

公开号/公开日
WO8705898 A2 1987-10-08 [WO8705898]WO8705898 A3 1988-05-05 [WO8705898] / 1987-10-081988-05-05
申请号/申请日
1987WO-US00649 / 1987-03-30
发明人
MANNING DAVID TREADWAY;CAPPY JAMES JOSEPH;SEE RAYMOND MICHAEL;COOKE ANSON RICHARD;FRITZ CHARLES DAVID;WHEELER THOMAS NEIL;
申请人
RHONE POULENC;
主分类号
IPC分类号
A01NA01N-037/02A01N-037/04A01N-037/08A01N-037/24A01N-037/30A01N-037/34A01N-037/44A01N-039/02A01N-041/02A01N-043/10A01N-043/28A01N-043/40A01N-043/54A01N-043/72A01N-043/78A01N-043/80A01N-043/82A01N-053/00A01N-053/10A01N-053/12A01N-055/10A01N-057/22A01P-021/00C07CC07C-055/08C07C-067/00C07C-069/38C07C-069/74C07C-069/743C07C-233/00C07C-233/03C07C-233/04C07C-233/07C07C-233/12C07C-233/15C07C-233/59C07C-233/60C07C-237/26C07C-239/00C07C-327/20C07C-327/22C07D-213/64C07D-213/70C07D-213/75C07D-213/84C07D-237/20C07D-237/22C07D-239/42C07D-241/20C07D-251/44C07D-251/66C07D-257/02C07D-261/14C07D-267/00C07D-271/12C07D-275/02C07D-275/03C07D-277/20C07D-277/46C07D-277/82C07D-285/12C07D-285/135C07D-295/08C07D-307/66C07D-311/02C07D-311/16C07D-317/18C07D-317/22C07D-317/28C07D-317/32C07D-317/40C07D-317/50C07D-333/20C07D-333/36C07D-339/06C07D-521/00C07F-009/38C07F-009/40
摘要
(WO8705898) Method for retarding plant growth by applying to the plant an effective amount of a malonic acid derivative compound.  This invention also relates to novel malonic acid derivative compounds and processes for the preparation thereof.
机翻摘要
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地址
代理人
代理机构
;
优先权号
1986US-06846670 1986-03-31 1987US-07018129 1987-03-06
主权利要求
(WO8705898) Claims 1. A method of re@@@@ing plant growth which comprises applying cote plant an effective amount, sufficient to @@@@@ plant growth, of a compound having the form@la: EMI138.1 wherein: R1 and R2 are independently a substituted or unsubstituted, carbocyclic or heterocyclic ring system selected from a monocyclic aromatic or nonaromatic ring s'; elm, a bicyclic aromatic or nonaromatic ring ,;; -;, a polycyclic aromatic or nonaromatic ring system, and a bridged ring system which may be saturated or unsaturated in which the permissible substituents (Z) are the same or different and are one or more hydrogen halogen, alkylcarbonyl, alkylcarbonylalkyl, formyl, alkoxycarbonylalkyl, alkoxycarbonylalkylthio, polyhaloalkenylthio, thiocyano, prqpargylthio, hydroxyimino, alkoxyimino. trialkylsilyoxy, aryldialkylsilyloxy,. triarylsilyloxy, formamidino, alkylsulfamido, dialkylsulfamido, alkoxysulfonyl, polyhaloalkoxysulfonyl, hydroxy, amino, azido, azo, aminocarbonyl, alkylaminocarbonyl, hydrazono, dialkylaminocarbonyl, aminothiocarbonyl, alkylaminothiocarbonyl, dialkylaminothiocarbonyl, nitro, cyano, hydroxycarbonyl and derivative salts, formamido, alkyl, alkoxy, polyhaloalkyl, polyhaloalkoxy, alkoxycarbonyl, substituted amino in which the permissible substituents are the same or different and are one or two propargyl, alkoxyalkyl, alkylthioalkyl, alkyl, alkenyl, haloalkenyl or polyhal oalkenyl; alkylthio, polyhaloalkylthGo, alkylsulfinyl, polyhaloalkylsulfinyl, alkylsulfonyl, polyhaloalkylsulfonyl, alkylsulfonylamino, alkylcarbonylamino, polyhaloalkylsulfonylamino, polyhaloalkylcarbonylamino, trialkylsilyl, aryldialkylsilyl, triarylsilyl, sulfonic acid and derivative salts, phosphonic acid and derivative salts. alkoxycarbonylamino, alkylaminocarbonyloxy, dialkylaminocarbonyloxy, alkenyl, polyhaloalkenyl, alkenyloxy, alkynyl, alkynyloxy, polyhaloalkenyloxy, polyhaloalkynyl, polyhaloalkynyloxy, polyfluoroa)kanol, cyanoalkylamino, semicarbazonomethyl, alkoxycarbonylhydrazonomethyl, alkoxyiminomethyl, unsubstituted or substituted aryloxyNmlnomethyl, hydrazonomethyl, unsubstituted or substituted arylhydrazonomethyl, a hydroxy group condensed with a mono-, di- or polysaccharide, haloalkyl, haloalkenyl, haloalkynyl, alkoxyalkyl, aryloxy, aralkoxy, arylthio, aralkylthio, alkylthioalkyl, arylthioalkyl, aryl,sulflnyl, arylsulfonyl, haloalkylsulf1.nyl, haloalkylsulfonyl, haloalke nyloxy, haloalkynyloxy, haloalkynylthio, haloalkenylsulfonyl, polyhaloalkenylsulfonyl, isocyano, aryloxysulfonyl, propargyloxy, aroyl, haloacyl, polyhaloacyl, aryloxycarbonyl, aminosulfonyl, alkylaminosulfonyl, dialkylaminosulfonyl, arylaminosulfonyl, carboxyalkoxy, carboxyalkylthio, alkoxycarbonylalkoxy, acyloxy, haloacyloxy, polyhaloacyloxy, aroyloxy, alkylsulfonyloxy, alkenylsulfonyloxy, arylsulfonyloxy, haloalkylsulfonyloxy, polyhalodlkylsul fonyl.oxy, aroylamtno, haloacylamino, alkoxycarbonyloxy, arylsulfonylamlno, aminocarbonyloxy, cyanato, isocyanato, isothiocyano, cycloalkylamino, trialkylammonium, arylamino, aryl(alkyl)amino, aralkylamino, alkoxyalkylphosphinyl, alkoxyalkylphosphinothioyl, alkylhydroxyphosphinyl, dialkoxyphosphino, hydroxyamino, alkoxyamino, aryloxyamino, aryloxyimino, oxo, thiono, diazo, alkyildene, alkylimino, hydrazono, semlcarbazono, dialkylsulfonium, dialkylsulfuranylidene, dialkyoxosulfuranylidene, -X, = X, -X = R3. = X-R3, EMI140.1 R1 and R2 are independently hydrogen or derivative salts, or a substituted heteroatom or substituted carbon atom, or a substituted or unsubstituted, branched or straight chain containing two or more carbon atoms or heteroatoms in any combination in which the permissible substituents dre Z; Y1 and Y2 are independently a substituted or unsubstituted heteroatom in which the permissible. substituents are Z;; Y3 and Y4 are independently hydrogen, or a substituted or unsubstituted heteroatom or substituted carbon atom, or a substituted or unsubstituted, branched or straight chain containing two or more carbon atoms or heteroatoms in any combination, or halogen, alkylcarbonyl, formyl, alkylcarbonylalkyl, alkoxycarbonylalkyl, alkoxycarbonylalkylthio, polyhaloalkenylhio, thiocyano, propargylthio, trialkylsilyloxy, aryldialkylsilyioxy, triarylsiyloxy, formamidino, alkylsulfamido, dialkylsulfamido, alkoxysulfonyl, polyhaloalkoxysulfonyl, hydroxy, amino hydrazono, azo, aminocarbonyl, alkylaminocarbonyl, azido, dialkylaminocarbonyl, aminothiocarbonyl, alkylaminothiocarbonyl, dialkylaminothiocarbonyl, nitro; cyano, hydroxycarbonyl and derivative salts, formamido, alkyl, alkoxy, polyhaloalkyl, polyhaloalkoxy, alkoxycarbonyl, substituted amino in which the permissible substituents are the same or different and are one or two propargyl, alkoxyalkyl, alkylthioalkyl, alkyl, alkenyl, haloalkenyl or polyhaloalkenyl; alkylthio, polyhaloalkylthio, alkylsulfinyl, polyhaloalkylsulfinyl, alkylsulfonyl, polyhaloalkylsulfonyl, alkylsulfonylamino, alkylcarbonylamino, polyhaloalkylsulfonylamino, polyhaloalkylcarbonylamino, trialkylsilyl, aryldialkylsilyl, triarylsilyl, sulfonic acid and derivative salts, phosphonic acid and derivative salts, alkoxycarbonylamino, alkylaminocarbonyloxy, dialkylaminocarbonyloxy, alkenyl, polyhaloalkenyl, alkenyloxy, alkynyl, alkynyloxy, polyhaloalkenyloxy, polyhaloalkynyl, polyhaloalkynyloxy, polyfluoroalkanol, cyanoalkylamino, semicarbazonomethyl, alkoxycarbonylhydrazonomethyl, alkoxyiminomethyl, unsubstituted or substituted aryloxyiminomethyl, hydrazonomethyl, unsubstituted or substituted arylhydrazonomethyl, a hydroxy group condensed with a mono-, di- or polysaccharide, haloalkyl, haloalkenyl, haloalkynyl, alkoxyalkyl, aryoxy, aralkoxy, arylthio, aralkylthio, alkylthioalkyl, arylthioalkyl, arylsulfinyl, arylsulfonyl, haloalkylsulfinyl, haloalkylsulfonyl, haloalkenylox y, haloalkynyloxy, haloalkynylthio, haloalkenylsulfonyl, polyhaloalkenylsuifonyl, tsocyano, aryloxysulfonyl, propargyloxy, aroyl, haloacyl, polyhaloacyl, aryloxycarbonyl, aminosulfonyl, alkylamlnosulfonyl, dlalkylaminosulfonyl, arylaminosulfonyl, carboxyalkoxy, carboxyalkylthio, alkoxycarbonylalkoxy, acyloxy, haloacyloxy, polyhaloacyloxy, aroyloxy, arlkylsufonyloxy, alkenylsulfonyloxy, arylsulfonyloxy, paloalkylsulfonyloxy, polyhaloalkylsulfonyloxy, aroylamino, haloacylamtno, alkoxycarbonyloxy, arylsulfonylamino, aminocarbonyloxy, cyanato, tsocyanato, isothiocyano, cycloalkylamino, trialkylammonium, arylamino, aryl (alkyl )amno, aralkylamino, alkoxyalkylphosphinyl, alkoxyalkylphosphinothioyl, alkylhydroxyphosphinyl, dialkoxyphoxphino, hydroxyamino, alkoxyamino, aryloxyamino, -X, -X = R3, EMI143.1 in which the permissible substituents are Z; Y3 and Y4 taken together are oxo, thiono, diazo, = X or = X - R3, or substituted or unsubstituted alkyliden, alkylimino, hydrazono, dialkylsulfuranylidene, dialkyloxosulfuranylidene. semtcarbazono, hydroxyimino, alkoxyimino or aryloxyimino in which the permissible substituents are Z; Y3 and Y4 may be linked together to form a substituted or unsubstituted, carbocyclic or heterocyclic ring system selected from a monocyclic aromatic or nonaromatic ring system, a bicyclic aromatic or nonaromatic ring system, a polycyclic aromatic or nonaromatic ring system, and a bridged ring system which may be saturated or unsaturated in which the permissible substituents are Z; and Y5 and Y6 are independently oxygen or sulfur; wherein: X is a covalent single bond or double bond, a substituted or unsubstituted heteroatom or substituted carbon atom, or a substituted or unsubstituted, branched or straight chain containing two or more carbon atoms or hetçroatoms in any combination in which the permissible substituents are Z;R3 is a substituted or unsubstituted, carbocyclic or heterocyclic ring system selected from a monocyclic aromatic or nonaromatic ring system, a bicyclic aromatic or nonaromatic ring system, a polycyclic aromatic or nonaromatic ring system, and a bridged ring system which may be saturated or unsaturated in which the permissible substltuents are Z; or R3 is a substituted heteroatom or substituted carbon atom, or a substituted or unsubstituted, branched or straight chain containing two or more carbon atoms or heteroatoms in any combination in which the permissible substituents are Z; Y7 and Y10 are independently oxygen or sulfur; Y8 and Yg are independently oxygen, sulfur, amino or a covalent single bond; and R4 and R5 are independently hydrogen or substituted or unsubstituted alkyl, alkenyl, alkynyl, polyhaloalkyl, phenyl or benzyi in which the permiss4ble substituents are Z. 2. The method of claim .i in which the compound has the formula: EMI145.1 wherein: R1 and R2 are independently a substituted or unsubstituted, carbocyclic or heterocyclic ring system selected from a monocyclic aromatic or nonaromatic ring system, a bicyclic aromatic or nonaromatic ring system, a polycyclic aromatic or nonaromatic ring system, and a bridged ring system which may be saturated or unsaturated in which the permissible substituents are Z as defined in Claim 1; or EMI145.2 ; or R1 and R2 are independently hydrogen or derivative salts, or a substituted heteroatom or substituted carbon atom, or a substituted or unsubstituted, branched or straight chain containing two or more carbon atoms or heteroatoms in any combination in which the permissible substituents are Z; Y1 and Y2 are independently a substituted or unsubstituted heteroatom in which the permissible. substituents are Z;; Y3 and Y4 are independently hydrogen, or a substituted or unsubstituted heteroatom or substituted carbon atom, or a substituted or unsubstituted, branched or straight chain containing two or more, carbon atoms or heteroatoms in any combination, or halogen, alkylcarbonyl, formyl, alkylcarbonylalkyl, alkoxycarbonylalkyl, alkoxycarbonylalkylthio, polyhaloalkenylthio, thiocyano, proparylthio, trialkylsilyloxy, aryldialkylsilyloxy. triarylsilyloxy, formamidino, alkylsulfamido, dialkylsulfamido, alkoxysulfonyl, polyhaloalkoxysulfonyl, hydroxy, amino, hydrazino, azo, aminocarbonyl, alkylaminocarbonyl, azido, dialkylaminocarbonyl, aminothiocarbonyl, alkylaminothiocarbonyl, dialkylaminothiocarbonyl, nitro;; cyano, hydroxycarbonyl and derivative salts, formamido, alkyl, alkoxy, polyhaloalkyl, polyhaloalkoxy, alkoxycarbonyl, substituted amino in which the permissible substituents are the same or different and are one or two propargyl, alkoxyalkyl, alkylthioalkyl. alkyl, alkenyl, haloalkenyl or polyhaloalkenyl; alkylthio, polyhaloalkylhio. alkylsulfinyl. polyhaloalkylsulfinyl. alkylsulfonyl. polyhaloalkylsulfonyl, alkylsulfonylamino, alkylcarbonylamlno, polyhaloalkylsulfonylamino, polyhaloalkylcarbonylamlno, trialkylsilyl, aryldialkylsilyl. triarylsilyl, sulfonic atid and derivative salts, phosphonic acid and derivative salts, alkoxycarbonylamino, alkylaminocarbonyloxy. dialkylaminocarbonyloxy, alkenyl, polyhaloalkenyl, alkenyloxy, alkynyl, alkynyloxy, polyhaloalkenyloxy, polyhaloalkynyl, polyhaloalkynyloxy, polyfluoroalkanol, cyanoalkylamino, semlcarbazonomethy', alkoxycarbonylhydrazonomethyl, alkoxyiminomehyl, unsubstituted or substituted aryloxyiminomethyl, hydrazonomethyl, unsubstitutd or substituted arylhydrazonomethyl, a hydroxy group condensed with a mono-, di- or polysaccharide, haloalkyl, haloalkenyl, haloalkynyl, alkoxyalk'yl, aryloxy, aralkoxy, arylthlo, aralkylthto, alkylthioalkyl, arylthioalkyl, arylsulfinyl, arylsulfonyl, haloalkylsulfinyl, haloalkylsulfonyl, haloalkenyloxy, haloalkynyloxy, haloalkynylthio, haloalkenylsulfonyl, polyhaloalkenylsulfonyl, isocyano, aryloxysulfonyl, propargyloxy, aroyl, haloacyl, polyhaloacyl, aryloxycarbonyl, aminosulfonyl, alkylaminosulfonyl, dialkylaminosulfonyl, arylaminosulfonyl. carboxyalkoxy, carboxyalkylthio, alkoxycarbonylalkoxy, acyloxy, haloacyloxy, polyhaloacyloxy, aroyloxy, alkylsulfonyloxy, alkenylsulfonyloxy, arylsulfonyloxy, haloalkylsulfonyloxy, polyhaloalkylsulfonyloxy, aroylamino, haloacylamino. alkoxycarbonyloxy. arylsulfonylamino, aminocarbonyloxy, cranato. isocyanato, isothiocyano, cycloalkylamino, trialkylammonium, arylamino, aryl(alkyl)amino, aralkylamino, alkoxyalkylphosphinyl, alkoxyalkylphosphinothioyl, alkylhydroxyphosphinyl, dialkoxyphosphino, hydroxyamino, alkoxyamino, aryloxyamino, -X, -X = R3, EMI148.1 in which the permissible substituents are z; or Y3 and Y4 taken together are oxo, thiono, diazo, = X or = X - R3, or substituted or unsubstituted alkylidene, alkylimino, hydrazono, dialkylsulfuranylidene, dialkyloxosulfuranylidene, semicarbazono, hydroxyimino, alkoxyimino or aryloxyimino In which the permissible substituents are Z;; Y5 and Y6 are independently oxygen or sulfur'; wherein: X is a covalent single bond or double bond, a substituted or unsubstituted heteroatom or substituted carbon atom, or a substituted or unsubstituted, branched or straight chain containing two or more. carbon atoms or heteroatoms in any combination in which the permissible substituents are Z;; R3 is a substituted or unsubstltuted, carbocyclic or heterocyclic rlng system selected from a monocyclic aromatic or nonaromatic ring system, a bicyclic aromatic or nonaromatic ring system, a polycyclic aromatic or nonaromatic ring system, and a bridged ring system which may be saturated or unsaturated in which the permissible substituents are Z; R3 tis a substituted heteroatom or substituted carbon atom, or a substituted or unsubstituted, branched or straight chain containing two or more carbon atoms or heteroatoms in any combination in which the permissible substituents are Z; Y7 and Y10 are independently oxygen or sulfur;; Y8 and Yg are independently oxygen, sulfur, amino or a covalent single bond; and R4 and R5 are independently hydrogen or substituted or unsubstituted alkyl, alkenyl, alkynyl, polyhaloalkyl, phenyl or benzyl in which the permissible substituents are Z. 3. The method of claim 1 in which the compound has the formula: EMI150.1 wherein: R1, R2, Y1, Y2, Y5, Y6 and Z are as defined in Claim 1 and Y3 and Y4 are linked together to form a substituted or unsubstituted, carbocyclic or heterocyclic rlng system selected from a monocyclic aromatic or nonaromatic ring system, a bicyclic aromatic or nonaromatic ring system, a polycyclic aromatic or nonaromatic ring system, and a bridged ring system which may be saturated or unsaturated in which the permissible substituents are Z. 4. The method of claim 1 in which the compound has the formula: EMI150.2 wherein: Z'8 is the same or different and is one or more hydrogen, or substituted or unsubstituted halogen, haloalkyl, polyhaloalkyl, polyhaloalkoxy, alkyl, alkoxy, alkylthio, alkylsulfonyl, alkylsulfinyl, aryl, aryloxy, arylthio, arylsulfonyl, nitro, cyano, dialkoxyphosphinyl, acyl, aroyl, alkoxycarbonyl, alkoxycarbonylalkyl, acylamino, sulfonylamino, alkylsulfonylamtno, acyloxy, alkenyl or -CH=CHCH=CH-; 38 is 0, S, NH or N (alkyl); and 7 is hydrogen, ammonium, alkylammonium, polyalkylammonium, hydroxyalkylammonium. poly(hydroxyalkyl)ammonium, an alkali metal or alkallne earth metal or substituted or unsubstituted alkyl, hydroxyalkyl, alkoxyalkyl, alkoxycarbonylalkyl, alkylaminoalkyl, dialkylaminoalkyl, aryl, mercaptoalkyl, alkylthioalkyl, arylthioalkyl, aryloxyalkyl, alkylsulfonylalkyl, alkylsulfinylalkyl, acylalkyl, aroylalkyl, dialkoxyphosphinylalkyl, diaryloxyphoxphinylalkyl, hydroxyalkylthioalkyl, hydroxyalkylsulfonylalkyl, alkoxyalkylthioalkyl, alkoxyalkylsulfonylalkyl, poly(oxyalkylene)alkyl, cyanoalkyl, nitroalkyl, alkylideneamino, carbamoylalkyl, alkylcarbamoylalkyl, dialkylcarbamoylalkyl, amtnoalkyl, acylaminoalkyl, acyloxyalkyl, alkoxycarbonylaminoalkyl, cyanoaminoalkyl, carbamoyloxyalkyl, alkylcarbamoyloxyalkyl, dialkylcarbamoyloxyalkyl, alkoxycarbonyloxyalkyl, alkoxycarbonylthioalkyl, aminosulfonylalkyl, alkylaminosulfonylalkyl or dialkylaminosulfonylalkyl: in which the permissible substituents are Z as defined in Claim 1. 5. The method of claim 1 in which the compound has the formula: EMI152.1 Z'g is the same or different and is one or more hydrogen, or substituted of unsubstttuted halogen, haloalkyl, polyhaloalkyl, polyhaloalkoxy, alkyl, alkoxy, alkylthio, alkylsulfonyl, alkylsulfinyl, aryl, aryloxy, arylthio, arylsulfonyl, nitro, cyano, dialkoyphosphinyl, acyl, aroyl, alkoxycarbonyl, alkoxycarbonylalkyl, acylamino, sulfonylamino, alkylsulfonylamino, acyloxy, alkenyl or -CH=CHCH=CH-; Y'39 is 0, S, NH or N (alkyl); and R'8 is a or derivative salts or Z as defined in Claim 1. 6. The method of claim 1 in which the compound has the formula: EMI153.1 wherein: 10 is the same or different and is one or more hydrogen, or substituted or unsubstituted halogen, haloalkyl, polyhaloalkyl,. polyhaloalkoxy, alkyl, alkoxy, alkylthio, alkylsulfonyl, alkylsulfinyl, aryl, aryloxy, arylthio, arylsulfonyl, nitro, cyano, dialkoxyphosphinyl, acyl, aroyl, alkoxycarbonyl, alkoxycarbonylalkyl, acylamino, sulfonylamino. alkylsulfonylamino, acyloxy, alkenyl or -CH=CHCH=CH-; T'40 is 0, S, NH or N (alkyl);; 4 and Y' are independently hydrogen 5 or substituted or unsubstituted halogen, alkyl, cycloalkyl, alkenyl, alkynyl, alkoxy, alkylthio, cyano, nitro, tsocyano, formyl, amino, hydroxy, alkylcarbonyl, alkylsulfonyl, alkylsulfinyl, dialkoxyalkyl, alkylcarbonylamino, formylamino. alkylamino, dialkylamino, alkoxycarbonyl, hydroxyalkyl, polyhaloalkyl or haloalkyl; or Y'4 and Y'5 may be linked together to form a substituted or unsubstituted, carbocyclic or heterocyclic ring system selected from a monocyclic aromatic or nonaromatic ring system, a bicyclic aromatic or nonaromatic ring system, a polycyclic aromatic or nonaromatic rlng system and a bridged ring system which may be saturated or unsaturated, and R'g is hydrogen, ammonium, alkylammonium, polyalkylammonium, hydroxyalkylammontum, poly(hydroxyalkyl)ammonium, an alkali metal or alkaline earth metal or substituted or unsubstituted alkyl, hydroxyalkyl, alkoxyalkyl, alkoxycarbonylalkyl. alkylaminoalkyl. dialkylaminoalkyl, aryl. mercaptoalkyl, alkylthioalkyl, arylthioalkyl, aryloxyalkyl, alkylsulfonylalkyl, alkylsulfinylalkyl, acylalkyl, aroylalkyl, dialkoxyphosphinjylalkyl, diaryloxyphosphinylalkyl, hydroxyalkylthioalkyl, hydroxyalkylsulfonylalkyl, alkoxyalkylthioalkyl, alkoxyalkylsulfonylalkyl, poly(oxyalkylene)alkyl, cyanoalkyl, nitroalkyl, alkylideneamino, carbamoylalkyl, alkylcarbamoylalkyl, dialkylcarbamoylalkyl, aminoalkyl, acylaminoalkyl, acyloxyalkyl, alkoxycarbonyla,minoalkyl, cyanoaminoalkyl, carbamoyloxyalkyl, alkylcarbamoyloxyalkyl, dialkylcarbamoyloxyalkyl, alkoxycarbonyloxyalkyl, alkoxycarbonylthioalikyl, aminosulfonylalkyl, alkylaminosulfonylalkyl or dialkylaminosulfonylalkyl in which the permissible substituents are Z as defined in Claim 1. 7. The method of claim 1 in which the compound has the formula: EMI155.1 wherein: 11 is the same or different and is one or more hydrogen, or substituted or unsubstituted halogen, haloalkyl, polyhaloalkyl, polyhaloalkoxy, alkyl., alkoxy, alkylthio, alkylsulfonyl, alkylsulfinyl, aryl, aryloxy, arylthio, arylsulfonyl, nitro, cyano, dialkoxyphosphinyl, acyl, aroyl, alkoxycarbonyl, alkoxycarbonylalkyl, acylaminho, sulfonylamino, alkylsulfonylamino, acyloxy, alkenyl or -CH=CHCH=CH-; Y'6 is hydrogen or alkyl; Y'7.Y'8, Y'9 and Y'10 are independently hydrogen, halogen or alkyl; Y'41 is 0, S, NH or N (alkyl); and R'10 is hydrogen, ammonium, alkylammonium, polyalkylammonium, hydroxyalkylammonium, poly(hydroxyalkyl)ammonium,an alkali metal or alkaline earth metal or substituted or unsubstituted alkyl, hydroxyalkyl, alkoxyalkyl, alkocycarbonylalkyl, alkylaminoalkyl, dialkylaminoalkyl, aryl, mercaptoalkyl, alkylthioalkyl, arylthioalkyl, aryloxyalkyl, alkylsulfonylalkyl, alkylsulfinylalkyl, acylalkyl, aroylalkyl, dialkoxyphosphinylalkyl, diaryloxyphosphinylalkyl, hydroxyalkylthioalkyl, hydroxyalkylsulfonylalkyl, alkoxyalkylthioalkyl, alkoxyalkylsulfonylalkyl, poly(oxyalkylene)alkyl, cyanoalkyl, nitroalkyl, alkylideneamino, carbamoylalkyl, alkylcarbamoylalkyl, dialkylcarbamoylalkyl, aminoalkyl, acylaminhoalkyl, acyloxyalkyl, alkoxycarbonylaminoalkyl, cyanoaminoalkyl, carbamoyloxyalkyl, alkylcarbamoyloxyalkyl, dialkylcarbamoyloxyalkyl, alkoxycarbonyloxyalkyl, alkoxycarbonylthioalkyl, aminosulfonylalkyl, alkylaminosulfonylalkyl or dialkylaminosulfonylalkyl;in which the permissible subsit utents are Z as defined ill Claim 1. 8. The method of claim 1 in which the compound has the formul EMI156.1 wherein: 12 is the same or different and is one or more hydrogen, or substituted or unsubstituted halogen, haloalkyl, polyhaloalkyl, polyhaloalkoxy, alkyl, alkoxy, alkylthio, alkylsulfonyl, alkylsulfinyl, aryl, aryloxy, arylthio, arylsulfonyl, nitro, cyano, dialkoxyphosphinyl, acyl, aroyl, alkoxycarbonyl, alkoxycarbonylalkyl, acylamino, sulfonylamino, alkylsulfonylamino, acyloxy, alkenyl or -CH-=CHCH=CH-: Y'11, Y'12, Y'13, Y'14, Y'15, and Y'16 are independently hydrogen,halogen or alkyl; Y'42 is 0, S, NH or N (alkyl); and 11 is hydrogen, ammonium, alkylammonium, polyalkylammonium, hydroxyalkylammonium, poly(hydroxyalkyl)ammonium, an alkali metal or alkaline earth metal or substituted or unsubstituted alkyl, hydroxyalkyl, alkoxyalkyl, alkoxycarbonylalkyl, alkylaminoalkyl, dialkylaminoalkyl, aryl, mercaptoalkyl, alkylthioalkyl, arylthioalkyl, aryloxyalkyl, alkylsulfonylalkyl, alkylsulftnyla.lkyl, acylalkyl, aroylalkyl, dlalkoxyphosphlnylal,kyl, diaryloxyphosphinylalkyl, hydroxyalkylthioalkyl, hydroxyalkylsulfonylalkyl, alkoxyalkylthioalkyl, alkoxyalkylsulfonylalkyl, poly(oxyalkylene)alkyl, cyanoalkyl, nitroalkyl, alkylideneamino, carbamoylalkyl, alkylcarbamoylalkyl, dialkylcarbamoylalkyl, aminoalkyl, acylaminoalkyl, acyloxyalkyl, alkoxycarbonylaminoalkyl, cyanoaminoalkyl, carbamoyloxyalkyl, alkylcarbamoyloxyalkyl, dialkylcarbamoyloxyalkyl, alkoxycarbonyloxyalkyl, alkoxycarbonylthioalkyl, aminosulfonylalkyl, alkylaminosulfonylalkyl or dialkylaminosulfonylalkyl; in which the permissible substituents are Z as defined in Claim 1. 9. The method of claim 1 in which the compound has the formula: EMI157.1 wherein: 13 is the same or different and is one or more hydrogen, or substituted or unsubstituted halogen, haloalkyl, polyhaloalkyl, polyhaloalkoxy, alkyl, alkoxy, alkylthio, alkylsulfonyl, alkylsulf1nyl, aryl, aryloxy, arylthio, arylsulfonyl, nitro, cyano, dGalkoxyphosphtnyl, acyl, aroyl, alkoxycarbonyl, alkoxycarbonylalkyl, acylamino, sulfonylamino, alkylsulfonylamino, acyloxy, alkenyl or -CH=CHCH=CH-; 17 is hydrogen or alkyl; Y'18, Y'19, Y'20 and Y'21, are independently hydrogen, halogen or alkyl; Y143 is 0, S, NH or N (alkyl); and 12 is a derivative salt or Z as defined in Claim 1. 10. The method of claim 1 in which the compound has the formula: EMI158.1 wherein: Z'14 is the same or different and is one or more hydrogen, or substituted or unsubstituted halogen, haloalkyl, polyhaloalkyl, polyhaloalkoxy, alkyl, alkoxy, alkylthio, alkylsulfonyl, alkylsulfinyl, aryl, aryloxy, arylthio, arylsulfonyl, nitro, cyano, dialkoxyphosphinyl, acyl, aroyl, alkoxycarbonyl, alkoxycarbonylalkyl, acylarnino, sulfonylamino, alkylsulfonylamino, acyloxy, alkenyl or -CH=CHCH=CH-; 21' Y'22, Y'23, Y'24, Y'25, and 26 are independently hydrogen, halogen or alkyl; 44 is 0, S, NH or N (alkyl); and 13 is a derivative salt or Z'as defined in Claim 1. 11. The method of claim 1 in which the compound has the formula: EMI159.1 wherein: 15 is the same or different and is one or more hydrogen, or substituted or unsubstituted halogen, haloalkyl, polyhaloalkyl, polyhaloalkoxy, alkyl, alkoxy, alkylthio, alkylsulfonyl, alkylsulfinyl, aryl, aryloxy, arylthio, arylsulfonyl, nitro, cyano, dialkoxyphosphinyl, acyl, aroyl, alkoxycarbonyl, alkoxycarbonylalkyl, acylamino, sulfonylamino, alkylsulfonylamino, acyloxy, alkenyl or -CH=CHCH=CH-; 27 is 0, S, NH or N (alkyl);; Y'28 completes a substituted or unsubstituted, carbocylic or heterocyclic ring system selected from a monocyclic aromatic or nonaromatic ring system, a bicyclic aromatic or nonaromatic ring system, a polycyclic aromatic or nonaromatic ring system and a bridged ring system which may be saturated or unsaturated; y'45, is 0, 5, NH or N (alkyl); and R'14 is a derivative salt or Z as defined In Claim 1. 12. The method of claim 1 in which the compound has the formula: EMI160.1 wherein: 16 is the same or different and is one or more hydrogen, or subst1tuted or unsubstituted halogen, haloalkyl, polyhaioalkyl, polyhaloalkoxy, alkyl,' alkoxy, alkylthio, alkylsulfonyl, alkylsulfinyl, aryl, aryloxy, arylthio, arylsulfonyl, nitro, cyano, dialkoxyphosphinyl, acyl, aroyl, alkoxycarbonyl, alkoxycarbonylalkyl, acylamino, sulfonylamino, alkylsulfonylamino, acyloxy, alkenyl or -CH=CHCH=CH-; yi29 is 0, S, NH or N (alkyl); ; Y'30 and Y'31 are Independently hydrogen, or substituted or unsubstituted halogen, cycloalkyl, isocyano, alkylsulfonyl, alkylsulfinyl, alkylamino, dlalkylamWno, alkoxycarbonyl, alkenyl, alkynyl, alkyl, alkoxy, alkylthio-, cyano, notio, formyl, amino, hydroxy, alkylcarbonyl, dialkoxyalkyl, alkylcarbonylamino. formylamino, hydroxyalkyl, polyhaloalkyl or haloalkyl; or 30 and Y131 may be linked together to form a substituted or unsubstituted, carbocyclic or heterocyclic ring system selected from a monocyclic aromatic or nonaromatic ring system, a bicyclic aromatic or nonaromatic ring system, a polycyclic aromatic or nonaromatic ring system and a bridged ring system which may be saturated or unsaturated; Y'46 is 0, S, NH or N (alkyl); and R'15 Is a derivative salt or Z as defined In Claim 1. 13. The method of claim 1 in which the compound has the formula: EMI161.1 whereon: 17 is the same or different and Is one or more hydrogen, or substituted or unsubstituted halogen, haloalkyl, polyhaloalkyl, polyhaloalkoxy, alkyl, alkoxy, alkylthio, alkylsulfonyl, alkylsulflnyl, aryl, aryloxy, arylthio, arylsulfonyl, nitro, cyano, dialkoxyphosphinyl, acyl, aroyl, alkoxycarbonyl, alkoxycarbonylalkyl, acylamino, sulfonylamino, alkylsulfonylamino, acyloxy, alkenyl or -CH=CHCH=CH-; Y'32 jis 0, S, N or N (alkyl); Y'33 and Y'34 ar independently hydrogen, or substituted or unsubstituted halogen, alkyl, alkoxy, alkylthio, polyhaloalkyl or haloalkyl; or Y'33 and Y # 34 may be linked together to form a substituted or unsubstituted, carboxyclic or heterocyclic ring system selected from a monocyclic aromatic or nonaromatic ring system, a bicyclic aromatic or nonaromatic ring system, a polycyclic aromatic or nonaromatic ring system and a bridged ring system which may be saturated or unsaturated; Y'47 1s 0, S, NH or N (alkyl), and 16 is a derivative salt or Z as defined in Claim 1. 14. The method of,claim 1 in which the compound has the formula: EMI162.1 wherein: 17 is a substituted or unsubstituted heterocyclic ring system selected from a monocyclic aromatic or nonaromatic ring system, a bicyclic aromatic or nonaromatic ring system, or polycyclic aromatic or nonaromatic ring system, and a bridged ring system which may be saturated or unsaturated; Y'35 is 0, S, N or N (alkyl);; Y'36 and Y'37 are independently hydrogen, or substituted or unsubstituted halogen, cycloalkyl, isocyano, alkylsulfonyl, alkylsulfinyl, alkylamino, dialkylamino, alkoxycarbonyl, alkenyl, alkynyl, alkyl, alkoxy, alkylthio, cyano, nitro, formyl, amino, hydroxy, alkylcarbonyl, dialkoxyalkyl, alkylcarbonylamlno, formylamtno, hydroxyalkyl, polyhaloalkyl or haloalkyl; or and and Y' may be linked together to 37 form a substituted or unsubstituted, carbocyclic or heterocyclic ring system selected from a monocyclic aromatic or nonaromatic ring system, a bicyclic aromatic or nonaromatic ring system, a polycyclic aromatic or nonaromatic ring system and a bridged ring system, which may be saturated or unsaturated; 48 is 0, S, N or N (alkyl); and 18 is a derivative salt qr Z as defined in Claim 1. 15. The method of claim l in which the compound has the formula: EMI163.1 16. The method of claim l in which the compound has the formula: EMI163.2 17. The method of claim 1 in which the compound has the formula: EMI164.1 18. The method of claim l in which the compound has the formula: EMI164.2 19. The method of claim 1 in which the compound has the formula: EMI164.3 20. The method of claim 1 in which the compound has the formula: EMI165.1 21. The method of claim 1 in which the compound has the formula: EMI165.2 22. The method of claim 1 in which the compound has the formula: EMI165.3 23. The method of claim l in which the compound has the formula: EMI166.1 24.The method of claim 1 in which the compound has the formula: EMI166.2 25. The method of claim 1 in which the compound has the formula: EMI166.3 26. The method of claim 1 in which the compound has the formula: EMI167.1 27. The method of claim 1 in which the compound has the formula: EMI167.2 2a. The method of claim 1 in which the compound has the formula: EMI167.3 29. A method of retarding plant growth which' comprises applying to the plant an effective amount, sufficient to retard plant growths of a compound of claim. 6. 30. The method of claim 1 wherein the compound is applied to the plant in an amount sufficient to retard plant growth without causing substantiai phytotoxicity. 31. The method of claim 1 wherein the compound is applied to the plant at a period prior to the plant reproductive growth phase. 32. The method of claim 1 wherein the compound is applied to the plant at a period during the plant reproductive growth phase. 33. The method of claim # wherein the compound is applied to the plant at a concentration of from about 0.001 to about 100 pounds of compound per acre. 34. The method of claim 1 wherein the compound is applied to the plant at a concentration of from about 0.01 to about 15 pounds of compound per acre. 35. The method of claim 1 wherein the plant is any agronomic or horticultural plant, woody plants, ornamental or, turfgrass. 36. The method of claim 1 wherein the plant is a woody plant selected from red maple, sycamore, red oak, American elm, linden, ginkgo, oaks, ashes, maples, app(...)
法律状态
(WO8705898) LEGAL DETAILS FOR WO8705898  Actual or expected expiration date=1989-09-30    Legal state=DEAD    Status=LAPSED     Event publication date=1987-03-30  Event code=WO/APP  Event indicator=Pos  Event type=Examination events  Application details  Application country=WO WOUS8700649  Application date=1987-03-30  Standardized application number=1987WO-US00649     Event publication date=1987-10-08  Event code=WO/A2  Event type=Examination events  International application published without international search report  Publication country=WO  Publication number=WO8705898  Publication stage Code=A2  Publication date=1987-10-08  Standardized publication number=WO8705898     Event publication date=1987-10-08  Event code=WO/AK  Event indicator=Pos  Event type=Designated states  Designated states AU BR DK FI HU JP KR MW NO SD SU    Event publication date=1987-10-08  Event code=WO/AL  Event indicator=Pos  Event type=Designated states  Designated countries for regional patents AT BE CH DE FR GB IT NL SE    Event publication date=1988-05-05  Event code=WO/A3  Event indicator=Pos  Event type=Examination events  Later publication of ISR with revised front page  Publication country=WO  Publication number=WO8705898  Publication stage Code=A3  Publication date=1988-05-05  Standardized publication number=WO8705898     Event publication date=1988-05-05  Event code=WO/AL  Event indicator=Pos  Event type=Designated states  Designated countries for regional patents AT BE CH DE FR GB IT NL SE    Event publication date=1988-05-05  Event code=WO/AK  Event indicator=Pos  Event type=Designated states  Designated states AU BR DK FI HU JP KR MW NO SD SU    Event publication date=1989-09-30  Event code=WO/EETL  Event type=Event indicating Not In Force  PCT Application validity period expired. LEGAL DETAILS FOR DESIGNATED STATE DK623787  Actual or expected expiration date=2007-03-30    Legal state=DEAD    Status=EXPIRED   Corresponding cc:  Designated or member state=DK Corresponding appl: DK623787  Application date in the designated or member state=1987-11-27   Application number in the designated or member state=1987DK-0006237 Corresponding cc:  Designated or member state=DK Corresponding pat: DK623787  Publication stage code in the designated or member state=D0  Publication date in the designated or member state=1987-11-27   Publication number in the designated or member state=DK8706237    Event publication date=2007-04-16  Event code=DK/STCHG  Patent Status changed by the national office Corresponding cc:  Designated or member state=DK  LEGAL DETAILS FOR DESIGNATED STATE EP0269656  Actual or expected expiration date=2007-03-30    Legal state=DEAD    Status=EXPIRED   Corresponding cc:  Designated or member state=EP Corresponding appl: EP87902948  Application date in the designated or member state=1987-03-30   Application number in the designated or member state=1987EP-0902948 Corresponding cc:  Designated or member state=EP Corresponding pat: EP0269656  Publication stage code in the designated or member state=A1  Publication date in the designated or member state=1988-06-08   Publication number in the designated or member state=EP-269656    Event publication date=1987-11-04  Event code=WO/WWE  Event indicator=Pos  Event type=Entry into national phase  Wipo information: entry into national phase Corresponding cc:  Designated or member state=EP     Event publication date=1988-06-08  Event code=WO/WWP  Event indicator=Pos  Event type=Examination events  Wipo information: published in national office Corresponding cc:  Designated or member state=EP     Event publication date=1993-12-29  Event code=WO/WWG  Event indicator=Pos  Event type=Event indicating In Force  Wipo information: grant in national office Corresponding cc:  Designated or member state=EP   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date=1988-10-07  Event code=WO/WWE  Event indicator=Pos  Event type=Entry into national phase  Wipo information: entry into national phase Corresponding cc:  Designated or member state=FI     Event publication date=1997-08-25  Event code=WO/WWG  Event indicator=Pos  Event type=Event indicating In Force  Wipo information: grant in national office Corresponding cc:  Designated or member state=FI     Event publication date=2004-08-31  Event code=FI/STCHG  Patent Status changed by the national office Corresponding cc:  Designated or member state=FI  LEGAL DETAILS FOR DESIGNATED STATE HK80394  Actual or expected expiration date=2007-03-29    Legal state=DEAD    Status=EXPIRED   Corresponding cc:  Designated or member state=HK Corresponding appl: HK80394  Application date in the designated or member state=1994-08-11   Application number in the designated or member state=1994HK-0000803 Corresponding cc:  Designated or member state=HK Corresponding pat: HK80394  Publication stage code in the designated or member state=A  Publication date in the designated or member state=1994-08-19   Publication number in the designated or member state=HK9400803    Event publication date=2007-04-27  Event code=HK/STCHG  Patent Status changed by the national office Corresponding cc:  Designated or member state=HK  LEGAL DETAILS FOR DESIGNATED STATE HUT48433  Actual or expected expiration date=2007-03-30    Legal state=DEAD    Status=EXPIRED   Corresponding cc:  Designated or member state=HU Corresponding appl: HU206287  Application date in the designated or member state=1987-03-30   Application number in the designated or member state=1987HU-0002062 Corresponding cc:  Designated or member state=HU Corresponding pat: HUT48433  Publication stage code in the designated or member state=A  Publication date in the designated or member state=1989-06-28   Publication number in the designated or member state=HU-T48433    Event publication date=1990-11-28  Event code=HU/STCHG  Patent Status changed by the national office Corresponding cc:  Designated or member state=HU  LEGAL DETAILS FOR DESIGNATED STATE KR19887001224  Actual or expected expiration date=2003-07-26    Legal state=DEAD    Status=EXPIRED   Corresponding cc:  Designated or member state=KR Corresponding appl: KR19877001129  Application date in the designated or member state=1987-03-30   Application number in the designated or member state=1987KR-7001129 Corresponding cc:  Designated or member state=KR Corresponding pat: KR19887001224  Publication stage code in the designated or member state=A  Publication date in the designated or member state=1988-07-26   Publication number in the designated or member state=KR19887001224    Event publication date=1995-10-24  Event code=KR/STCHG  Patent Status changed by the national office Corresponding cc:  Designated or member state=KR  LEGAL DETAILS FOR DESIGNATED STATE NO874930  Actual or expected expiration date=2007-03-30    Legal state=DEAD    Status=EXPIRED   Corresponding cc:  Designated or member state=NO Corresponding appl: NO874930  Application date in the designated or member state=1987-11-26   Application number in the designated or member state=1987NO-0004930 Corresponding cc:  Designated or member state=NO Corresponding pat: NO874930  Publication stage code in the designated or member state=D0  Publication date in the designated or member state=1987-11-26   Publication number in the designated or member state=NO8704930    Event publication date=1994-06-08  Event code=NO/STCHG  Patent Status changed by the national office Corresponding cc:  Designated or member state=NO  LEGAL DETAILS FOR DESIGNATED STATE SU2088571  Actual or expected expiration date=2002-03-30    Legal state=DEAD    Status=EXPIRED   Corresponding cc:  Designated or member state=SU Corresponding appl: SU4203733  Application date in the designated or member state=1987-03-30   Application number in the designated or member state=1987SU-4203733 Corresponding cc:  Designated or member 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