(JP6631717) Perfluoro (poly) ether composition comprising modified amidosilane Compound 机翻标题: 暂无翻译,请尝试点击翻译按钮。

源语言标题
(JP6631717) Perfluoro (poly) ether composition comprising modified amidosilane Compound
公开号/公开日
JP6631717 JPWO2018047686 / 2020-01-15 2018-12-13
申请号/申请日
JP2018538370 / 2017-08-30
发明人
三橋 尚志MITSUHASHI HISASHI野村 孝史NOMURA TAKASHI能勢 雅聡NOSE MASAAKI内藤 真人NAITO MASATO;
申请人
DAIKIN INDUSTRIES;
主分类号
IPC分类号
C07C-069/63 C07F-007/18 C09K-003/18
摘要
(JP6631717) The present invention provides a surface treatment agent which contains at least one type of perfluoro(poly)ether-modified amide silane compound represented by formula (1) (In the formula, each symbol has the same meaning as stated in the description), and at least one type of carboxylic acid ester compound represented by formula (2) (In the formula, each symbol has the same meaning as stated in the description), wherein the content of the carboxylic acid ester compound represented by formula (2) constitutes 4.1-35 mol%, inclusive, of the total content of the perfluoro(poly)ether-modified amide silane compound represented by formula (1) and the carboxylic acid ester compound represented by formula (2).  (From WO2018047686 A1)
机翻摘要
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地址
代理人
(JP6631717) Yamada Takuzi Reg. Nb: 100101454 Yoshida Ring Reg. Nb: 100132252
代理机构
;
优先权号
2016JP-0175842 2017WO-JP31086
主权利要求
(JP6631717) 1. 1 At least one (poly) ether represented by (1) the following formula amidosilane modified perfluoro compound: [˜C: Rf1 has, by 1 fluorine atoms or one or more carbon atoms that may be substituted with a 1-16 alkyl group; PFPE1 are, each independently represent, -(OC6F12) a-(OC5F10) b-(OC4F8) c-(OC3F6) d-(OC2F4) e-(OCF2) f-, wherein, a, b, c, d, e and f are, each independently represent an integer of 200 or more at 0, a, b, c, d, e and f is at least 1 and the sum of, a, b, c, d, e or f is assigned to the repeating units within the parentheses is arbitrary in the formula is in the order; X1 is, a single bond or a formula -(CR82) k1-(O) k2-(NR9) k3-,(: R8 is, independently, is a hydrogen atom or fluorine atom; R9 is, independently, a hydrogen atom, an alkyl group having phenyl group or a C1-6; k1 is, is an integer of 1-20; k2 is, an integer of 0-10; k3 is, an integer of 0-10; herein, k1, k3 or k2 are attached within the parentheses in the order of the repeating units in the formula is optionally.) Represents the group represented by the formula; R1 are, each independently represent, -X2-SiRa1l1Rb1m1Rc1n1; X2, -(CR102) k4-(O) k5-(NR11) k6-,(is the formula: R10 is, independently, is a hydrogen atom or fluorine atom; R11 is, independently, a hydrogen atom, a phenyl group or alkyl group having from one C1-6; k4 is, an integer of 1-20; k5 is, an integer of 0-10; k6 is, an integer of 0-10; unfrayed, k4, k6 or k5 by the same reference numerals within the parentheses to which the order of the repeating units is arbitrary in the formula.) Represents the group represented by the formula; Ra1 is, in each occurrence are each independently, -Z1-SiRa2l2Rb2m2Rc2n2 represents; Z1 is, independently at each occurrence, represents an alkylene group or an oxygen atom C1-6, -(CH2) h- (CH2) g-O - (in the formula, g is, 1-6 is an integer of, h is a, an integer of 1-6) or, -phenylene-i - (CH2) (in the formula, i is, an integer of 0-6) represents; Ra2 is, at each occurrence are each independently, Ra1 'represents; Ra1' is, as defined in Ra1; Ra1 in, z1 A straight-chain through a linking group connected to 5 and the number maximum Si; Rb2 is, independently at each occurrence, represents a hydroxyl group or hydrolysable group; Rc2 is, independently at each occurrence, a hydrogen atom or an alkyl group having a carbon number of 1-20; l2 is, independently at each occurrence, an integer of 0-3; m2 is, in each occurrence are each independently, is an integer of 0-3; n2 is, independently at each occurrence, an integer of 0-3; Rb1 is, independently at each occurrence, represents a hydroxyl group or hydrolysable group; Rc1 is, independently at each occurrence, a hydrogen atom or an alkyl group having 1-20 carbon atoms; l1 is, independently at each occurrence, an integer of 0-3; m1 is, independently at each occurrence, an integer of 0-3; n1 is, at each occurrence are each independently, an integer of 0-3; R2 is, independently, a hydrogen atom, alkyl group or the phenyl group C1-6; is p, is 2 or 1, where, in the formula, Rb1 Rb2 or 1 in the presence of the at least one. ] 1 And at least one of a carboxylic acid ester represented by (2) the following equation: [formula: is R3, represents a hydrocarbon group; R4 is, represents Rf2-PFPE2-X3-; Rf2 is, independently, a fluorine atom and 1 is optionally substituted by one or more of the carbon atoms which may have a 1-16 alkyl group; PFPE2 are, each independently represent, -(OC6F12) a-(OC5F10) b-(OC4F8) c-(OC3F6) d-(OC2F4) e-(OCF2) f-, wherein, a, b, c, d, e and f is, 0 each independently represent an integer of 200 or more or less, a, b, c, d, e and f is at least 1 and the sum of, a, b, c, d, e or f given order of the repeating units within the parentheses to which sequence is shown in the formula any; X3 is, a single bond or a formula -(CR152) k7-(O) k8-(NR16) k9-,(: R15 is, independently, a hydrogen atom or a fluorine atom; R16 is, independently of each other, a hydrogen atom, an alkyl group or a phenyl group or represents C1-6; k7 is, an integer of 1-20; k8 is, an integer of 0-10; k9 is, an integer of 0-10; unfrayed, k7, k9 Or k8 by the same reference numerals within the parentheses to which the order of the repeating units is arbitrary in the formula.) Represents the group represented by the formula. ] Wherein, (poly) ether-modified perfluoro represented by the formula to (1) a compound of the formula (2) amidosilane represented by relative to the total amount of the carboxylic acid ester, a carboxylic acid ester represented by the formula to (2) the amount of the compound, greater than or equal to 35mol % less than or equal to 4.1mol %, and the surface treatment agent. 2. Rf1 Is, a perfluoroalkyl group containing 1-16 carbon atoms, and the surface treatment agent according to claim 1. 3. (A) the following formula PFPE1, (c) (b) one or :-(OC3F6) d- (a) [in the formula, 1 is 200 or an integer of d. In the formula]-(OC4F8) c-(OC3F6) d-(OC2F4) e-(OCF2) f- (b) [, c and d are, independently, is an integer of 30 or more 0; f and e are, independently, is an integer of 200 or more 1; c, d, f and the sum of e, is an integer of 10 or more 200; Z_x c, d, e or f within the parentheses to which reference numerals are given to the order of the repeating units, optionally in the formula. ]-(R6-R7) q- (c) [in the formula, R6 is, OCF2 or OC2F4 and; R7 is, OC3F6, OC4F8, OC5F10 or OC6F12 and is selected from the group, or, 2 is selected from the group of 3 or a combination of one group; q is, is an integer of 2-100. ] In, and the surface treatment agent according to claim 1 or 2. 4. X1 Is, -k1 (CF2) '- or-k1 (CF2) ' - (O) k2 '- [formula: k1' is, an integer of 1-6; k2 'is, an integer of 1-3; herein, k1' or k2 ' given order of the repeating units within the parentheses to which in the formula may be in any order. ] And, when X2, -k4 (CH2) '- or-k4 (CH2) ' - Ok5 '- [formula: k4' is, an integer of 1-6; k5 'is, an integer of 1-3; herein, k4' or k5 ' within the parentheses to which reference numerals are given to the order of the repeating units is arbitrary in the formula. ] In, said surface treatment agent of any one of claims 1-3. 5. R2 Is, the number of carbon atoms in the phenyl group or alkyl group of 1-3, and the surface treatment agent according to any one of claims 1-4 of. 6. Rb1 And Rb2 is, at the OCH3 or OC2H5, wherein the surface treatment agent of any one of claims 1-5 to. 7. P is 1 when, in the surface treatment agent of any one of claims 1-6. 8. Is Rf2, a perfluoroalkyl group containing 1-16 carbon atoms, to the surface treatment agent of any one of claims 1-7. 9. (A) the following formula PFPE2, (b) or (c) :-(OC3F6) d- (a) [in the formula, 1 is 200 or an integer of d. In the formula]-(OC4F8) c-(OC3F6) d-(OC2F4) e-(OCF2) f- (b) [, c and d are, independently, is an integer of 30 or more 0; f and e are, independently, is an integer of 200 or more 1; c, d, f and the sum of e, is an integer of 10 or more 200; Z_x c, d, e or f within the parentheses to which reference numerals are given to the order of the repeating units, optionally in the formula. ]-(R6-R7) q- (c) [in the formula, R6 is, OCF2 or OC2F4 and; R7 is, OC3F6, OC4F8, OC5F10 or OC6F12 and is selected from the group, or, each of these groups 3 or 2 are independently selected from a combination of one group; q is, is an integer of 2-100. ] In, of the surface treating agent according to any one of claims 1-8. 10. X3 Is, -k7 (CF2) '- or-k7 (CF2) ' - (O) k8 '- [formula: k7' is, an integer of 1-6; k8 'is, an integer of 1-3; herein, k7' or k8 ' within the parentheses to which by the same reference numerals in the order of the repeating units is arbitrary in the formula. ] In, said surface treatment agent of any one of claims 1-9. 11. R3 Is, the number of carbon atoms in the alkyl group of 1-3, wherein the surface treatment agent of any one of claims 1-10. 12. Represented by the following Equation (1) (poly) ether-modified amidosilane perfluoro compound represented by the following expression (2) with respect to the total amount of the carboxylic acid ester, a carboxylic acid ester represented by the following expression (2) where the content of the compound, greater than or equal to 35mol % less than or equal to 4.5mol %, and the surface treatment agent according to any one of claims 1-11. 13. The fluorine-containing oil, silicone oil, and the catalyst is selected from one or more of 1 further comprising a component of the other, of the surface treating agent according to any one of claims 1-12. 14. The fluorine-containing oil, of the formula (3): formula Rf5-(OC4F8) a'-(OC3F6) b'-(OC2F4) c'-(OCF2) d'-Rf6, (3) [: Rf5 is, a fluorine atom and 1 is optionally substituted by one or more of the carbon atoms which may have a 1-16 alkyl group; Rf6 may, be substituted by one or more of a fluorine atom and 1 is an alkyl group of 1-16 carbon atoms which may have, represents a hydrogen atom or a fluorine atom; a ', b', c'and d'are, to constitute the main skeleton of the polymer and perfluoro (poly) ether respectively represent the number of repeating units of 4, 0 independently of one another an integer of 300 or more, a ', b', c'and d'1 and the sum of the at least one, and the subscript a', b ', c' d'or by the same reference numerals within the parentheses to which the order of the repeating units, optionally in the formula. ] 1 Is represented by one or more of the compounds, and the surface treatment agent according to claim 13. 15. Which further comprises a solvent, and the surface treatment agent according to any one of claims 1-14. 16. An anti-fouling coating agent or for use as a waterproof coating, and the surface treatment agent of any one of claims 1-15 to. 17. And the surface treatment agent of any one of claims 1-16 pellets containing. 18. And the base material, the surface of the substrate, the surface treatment agent of any one of claims 1-16 formed from the layer of the article. 19. Where the substrate is a glass or sapphire glass, according to claim 18 article. 20. When the base material, soda lime glass, alkali aluminosilicate glass acid, borosilicate glass, alkali-free glass, crystal glass selected from the group consisting of quartz glass and the glass, the article according to claim 18. 21. An optical member, article of any one of claims 18-20. 22. The display device, article of any one of claims 18-21.
法律状态
GRANTED
专利类型码
B2 A1
国别省市代码
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