Surface treating agent including perfluoro(poly)ether-group-containing silane compound 机翻标题: 暂无翻译,请尝试点击翻译按钮。

源语言标题
(WO201599085) パーフルオロ(ポリ)エーテル​基​含有​シラン​化合​物​を​含む​表面​処理​剤
公开号/公开日
WO2015099085 A1 2015-07-02 [WO201599085] / 2015-07-02
申请号/申请日
2014WO-JP84402 / 2014-12-25
发明人
KATSUKAWA KENICHI;MITSUHASHI HISASHI;MOHARA KENSUKE;YOSHIDA TOMOHIRO;NOSE MASATOSHI;NAMIKAWA TAKASHI;
申请人
DAIKIN INDUSTRIES;
主分类号
IPC分类号
C07F-007/10C07F-007/18C08G-065/00C09D-005/16C09D-183/12C09K-003/00C09K-003/18
摘要
(WO201599085) The present invention provides a surface treating agent that includes a perfluoro(poly)ether-group-containing silane compound that is represented by formula (1). (The symbols in the formula have the same definition as set forth in the description.) The surface treating agent according to the present invention is water-repellant, oil-repellant, and anti-fouling, and can form a surface treated layer that has excellent friction durability.
机翻摘要
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地址
代理人
代理机构
;
优先权号
2013JP-0269345 2013-12-26 2014JP-0245454 2014-12-04
主权利要求
(WO201599085)  Claims machine translated from Japanese 1. The below-mentioned formula (1): [In formula: Rf is the alkyl group of the carbon count 1-10 which is possible to be substituted 1 or by the fluorine atom above that;    As for PFPE, - (OC [4] F [8]) [a] - (OC [3] F [6]) [b] - (OC [2] F [4]) [c] - (OCF [2]) [d] - (In formula, a and b, as for c and d, becoming independent respectively, being integer of the 0-200, a and b, as for harmony of c and d 1 was at least, a and b, attached c or d and was bound with the parenthesis each it repeats and existence order of the unit is optional in formula) So it is;    Q is the oxygen atom or the organic basis of two value;    R (1) is the hydrogen atom or the alkyl group of the carbon count 1-22;    R (2), becoming independent respectively, is the hydrogen atom or the inactive monobalent organic basis;    X is hydroxyl group or the hydrolysis possible basis;    Y is the hydrogen atom or the halogen atom;    Z is the fluorine atom or the fluoro alkyl group of the carbon count 1-5;    e is integer of the 0-3;    f is 0 or 1;    g is integer of the 1-10;    h is integer of the 0-3;    n is integer of the 1-3. ] So the perfluoro of 1 where it is displayed kinds (including poly-) ether basic content silane chemical compound at least, being the coupling agent which becomes, the perfluoro which is included in the said coupling agent (the or more of 80mol% of poly-) ether basic content silane chemical compound, features that g is the chemical compound of 2 or more, the coupling agent. 2. The perfluoro which is included in the coupling agent (the or more of 90mol% of poly-) ether basic content silane chemical compound, features that g is the chemical compound of 2 or more, in claim 1 the coupling agent of statement. 3. The perfluoro which is included in the coupling agent (the or more of 50mol% of poly-) ether basic content silane chemical compound, features that g is the chemical compound of 3 or more, in claim 1 or 2 the coupling agent of statement. 4. The perfluoro which is included in the coupling agent (the or more of 80mol% of poly-) ether basic content silane chemical compound, features that g is the chemical compound of 3 or more, in either of the claim 1-3 the coupling agent of statement. 5. The angular dispersion of G, to be larger than 1.0 features that it is under 2.0, in either of the claim 1-4 the coupling agent of statement. 6. Rf, is the perfluoro alkyl group of the carbon count 1-10, in either of the claim 1-5 the coupling agent of statement. 7. PFPE, - (OCF [2] CF [2] CF [2]) [b] - [In formula, b is integer of 200 or less of 1 or more] So it is, in either of the claim 1-6 the coupling agent of statement. 8. PFPE, - (OCF [2] CF [2] CF [2] CF [2]) [a] - (OCF [2] CF [2] CF [2]) [b] - (OCF [2] CF [2]) [c] - (OCF [2]) [d] - [In formula, a and b, becoming independent respectively, were optional integer of the 0-30, c and d, becoming independent respectively, was integer of the 1-200, a and b, it attached c or d and was bound with the parenthesis each it repeats and existence order of the unit is optional in formula] So it is, in either of the claim 1-6 the coupling agent of statement. 9. Perfluoro (the Kazuhei equal molecular weight of poly-) ether basic content silane chemical compound, features that it is the 5x10(2)-1x10(5), in either of the claim 1-8 the coupling agent of statement. 10. Perfluoro (the Kazuhei equal molecular weight of poly-) ether basic content silane chemical compound, features that it is the 6x10(3)-1x10(4), in either of the claim 1-9 the coupling agent of statement. 11. Furthermore the solvent is contained, in either of the claim 1-10 the coupling agent of statement. 12. Furthermore, 1 kinds or the other component above that which are selected are contained from containing fluorine oil, silicone oil, and the group which consists of the catalyst, in either of the claim 1-11 the coupling agent of statement. 13. Containing fluorine oil, formula (2): Rf (1)- (OC [4] F [8]) [a'] - (OC [3] F [6]) [b'] - (OC [2] F [4]) [c'] - (OCF [2]) [d'] - Rf (2) ... (2) [In formula:  Rf (1) is the alkyl group of the carbon count 1-16 which is possible to be substituted 1 or by the fluorine atom above that;    Rf (2), the alkyl group of the carbon count 1-16 which is possible to be substituted 1 or by the fluorine atom above that, is the fluorine atom or the hydrogen atom;    a', b', as for c' and d', becoming independent respectively, being integer of the 0-300, a' and b', as for harmony of c' and d' 1 was at least, a' and b', c attached' or d and' was bound with the parenthesis each it repeats and existence order of the unit is optional in formula. ] So they are 1 kinds or the chemical compound above that which are displayed, in claim 12 the coupling agent of statement. 14. Containing fluorine oil, formula (2a) or (2b):  Rf (1)- (OCF [2] CF [2] CF [2]) [b'] - Rf (2)... (2a)  Rf (1)- (OCF [2] CF [2] CF [2] CF [2]) [a'] - (OCF [2] CF [2] CF [2]) [b'] - (OCF [2] CF [2]) [c'] - (OCF [2]) [d'] - Rf (2)... (2b) [In formula:  Rf (1) is the alkyl group of the carbon count 1-16 which is possible to be substituted 1 or by the fluorine atom above that;    Rf (2), the alkyl group of the carbon count 1-16 which is possible to be substituted 1 or by the fluorine atom above that, is the fluorine atom or the hydrogen atom;    Formula (2a) in, b' is integer of 300 or less of 1 or more;    Formula (2b) in, a' and b', becoming independent respectively, were integer of the 0-30, c' and d', becoming independent respectively, was integer of the 1-300, subscript a' and b', c it attached' or d and' was bound with the parenthesis each it repeats and existence order of the unit is optional in formula. ] So they are 1 kinds or the chemical compound above that which are displayed, in claim 12 or 13 the coupling agent of statement. 15. It is used, as the antifouling coating medicine or the waterproof characteristic coating medicine in either of the claim 1-14 the coupling agent of statement. 16. The pellet which contains the coupling agent of statement in either of the claim 1-15. 17. On the surface of the backing material and the said backing material, the goods which include with the layer which was formed to either of the claim 1-15 from coupling agent of statement. 18. The backing material is the glass, in claim 17 the goods of statement. 19. The aforementioned goods are the optical component, in claim 17 or 18 the goods of statement. 20. The aforementioned goods are display, in either of the claim 17-19 the goods of statement. 21. Formula (1): [In formula: Rf is the alkyl group of the carbon count 1-10 which is possible to be substituted 1 or by the fluorine atom above that;    As for PFPE, - (OC [4] F [8]) [a] - (OC [3] F [6]) [b] - (OC [2] F [4]) [c] - (OCF [2]) [d] - (In formula, a and b, as for c and d, becoming independent respectively, being integer of the 0-200, a and b, as for harmony of c and d 1 was at least, a and b, attached c or d and was bound with the parenthesis each it repeats and existence order of the unit is optional in formula) So it is;    Q is the oxygen atom or the organic basis of two value;    R (1) is the hydrogen atom or the alkyl group of the carbon count 1-22;    R (2), becoming independent respectively, is the hydrogen atom or the inactive monobalent organic basis;    X is hydroxyl group or the hydrolysis possible basis;    Y is the hydrogen atom or the halogen atom;    Z is the fluorine atom or the fluoro alkyl group of the carbon count 1-5;    e is integer of the 0-3;    f is 0 or 1;    g is integer of the 1-10;    h is integer of the 0-3;    n is integer of the 1-3. ] So being production method of the chemical compound which is displayed, the below-mentioned formula (1a): [In formula, Rf, PFPE, Q, Z, e and f formula (1) are the same meaning as statement, Y (1), is chlorine, iodine or bromine. ] So the perfluoro which is displayed (the poly-) ether compound, the below-mentioned formula (1b): [In formula, R (1), R (2), h and n formula (1) are the same meaning as statement, X (1), hydroxyl group, is the hydrolysis possible basis or the halogen atom. ] So it reacts in reactivity double bond content silane chemical compound and the containing fluorine aromatic compound which are displayed, Next, with desire, the below-mentioned process (a) and/or (b) (A) When Y and Y (1) differs, Y (1) the process which is converted to Y (B) When X X (1) differs, the process which converts (1) to X X The method of attaching and including thing. 22. The below-mentioned formula (1'): [In formula: Rf is the alkyl group of the carbon count 1-10 which is possible to be substituted 1 or by the fluorine atom above that;    As for PFPE, - (OC [4] F [8]) [a] - (OC [3] F [6]) [b] - (OC [2] F [4]) [c] - (OCF [2]) [d] - (In formula, a and b, as for c and d, becoming independent respectively, being integer of the 0-200, a and b, as for harmony of c and d 1 was at least, a and b, attached c or d and was bound with the parenthesis each it repeats and existence order of the unit is optional in formula.) So it is;    Q is the oxygen atom or the organic basis of two value;    R (1) is the hydrogen atom or the alkyl group of the carbon count 1-22;    X is hydroxyl group or the hydrolysis possible basis;    Z is the fluorine atom or the fluoro alkyl group of the carbon count 1-5;    e is integer of the 0-3;    f is 0 or 1;    g is integer of the 1-10;    h is integer of the 0-3. ] So the perfluoro which is displayed (being production method of poly-) ether basic content silane chemical compound,  The below-mentioned formula (1a): [In formula, Rf, PFPE, Q, Z, e and f are the same meaning as description above, Y (1), is chlorine, iodine or bromine. ] So the perfluoro which is displayed (the poly-) ether compound, the below-mentioned formula (1c): [In formula, R (1) and h is the same meaning as description above. ] So reacting in chemical compound and the containing fluorine aromatic compound which are displayed, formula (1d): [In formula, Rf, PFPE, Q and Y (1), Z and R (1), e, f, g and h are the same meaning as description above. ] So the chemical compound which is displayed profit, next, HX (in formula, X is the same meaning as description above.)So the method of including the fact that it reacts with the chemical compound which is displayed. 23. Containing fluorine aromatic compound, perfluoro benzene and penta- fluorobenzene, 1,2,3,4 - tetra- fluorobenzene, 1,2,3,5 - tetra- fluorobenzene, 1,2,4,5 - tetra- fluorobenzene, 1,2,3 - [torihuruorobenzen], 1,2,4 - [torihuruorobenzen], 1,3,5 - [torihuruorobenzen], [o]-kishirenhekisahuruoraido, [m]-kishirenhekisahuruoraido, [p]-kishirenhekisahuruoraido and [benzotorihuruoraido], fluorobenzene, 1 - [kuroro] - 2 - fluorobenzene, 1 - [kuroro] - 3 - fluorobenzene, 1 - [kuroro] - 4 - fluorobenzene, 2,6 - [jikurorohuruorobenzen], 1 - fluoro - 3- ([torihuruorometokishi]) benzene, 1 - fluoro - 2,4 - dinitrobenzene, 2,4 - dimethoxy - 1 - fluorobenzene, 1 - fluoro - 4 - nitrobenzene, 2 - fluoro toluene, 3 - fluoroToluene, 4 - fluoro toluene, 3 - [huruorobenzotorihuruorido], 1 - [kuroro] - 2,4 - [jihuruorobenzen], 1 - [kuroro] - 3,4 - [jihuruorobenzen], 1 - [kuroro] - 3,5 - [jihuruorobenzen], 2 - [kuroro] - 1,3 - [jihuruorobenzen] and [kuroropentahuruorobenzen], 2,4 - [jikurorohuruorobenzen], 2,5 - [jikurorohuruorobenzen], 2,6 - [jikurorohuruorobenzen], 1,2 - [jikuroro] - 4 - fluorobenzene, 1,3 - [jikuroro] - 5 - fluorobenzene, 1,3 - [jikuroro] - 2,4,6 - [torihuruorobenzen], 3,4 - [jihuruorobenzonitoriru], 3,5 - [jihuruorobenzonitoriru], 3,4 - [jihuruoronitorobenzen], 1 - ethoxy - 2,3 - [jihuruorobenzen], 1,2 - [jishiano] - 4,5 - [jihuruorobenzen], 1 - acetoxy - 3 - fluorobenzene, 1 - acetoxy- 4 - Fluorobenzene, 1 - [asetoniru] - 4 - fluorobenzene, 2 - fluoro - [m]-kishiren, 3 - fluoro - [o]-kishiren, 4 - fluoro - [o]-kishiren, penta- fluoro anisole, [tetorahuruorohutaronitoriru], 2 - [torihuruoromechirubenzarukuroraido], 3 - [torihuruoromechirubenzarukuroraido], 4 - [torihuruoromechirubenzarukuroraido], 3- (trifluoromethyl) benzoic acid methyl, [jihuruorobenzonitoriru], bis trifluoromethyl benzo nitrile, 4 - trifluoromethyl benzo nitrile, it is selected from the group which consists of [aminobenzotorihuruorido], and trifluoromethyl aniline, in claim 21 or 22 method of statement. 24. The containing fluorine aromatic compound, polarizability is the containing fluorine aromatic compound of 3 debye or less of 0 or more, in either of the claim 21-23 method of statement. 25. The containing fluorine aromatic compound, [m]-kishirenhekisahuruoraido, [benzotorihuruoraido] and [jihuruorobenzonitoriru], bis trifluoromethyl benzo nitrile, is selected from the group which consists of, in either of the claim 21-24 method of statement. 26. Formula (1): [In formula: Rf is the alkyl group of the carbon count 1-10 which is possible to be substituted 1 or by the fluorine atom above that;    As for PFPE, - (OC [4] F [8]) [a] - (OC [3] F [6]) [b] - (OC [2] F [4]) [c] - (OCF [2]) [d] - (In formula, a and b, as for c and d, becoming independent respectively, being integer of the 0-200, a and b, as for harmony of c and d 1 was at least, a and b, attached c or d and was bound with the parenthesis each it repeats and existence order of the unit is optional in formula) So it is;    Q is the oxygen atom or the organic basis of two value;    R (1) is the hydrogen atom or the alkyl group of the carbon count 1-22;    R (2), becoming independent respectively, is the hydrogen atom or the inactive monobalent organic basis;    X is hydroxyl group or the hydrolysis possible basis;    Y is the hydrogen atom or the halogen atom;    Z is the fluorine atom or the fluoro alkyl group of the carbon count 1-5;    e is integer of the 0-3;    f is 0 or 1;    g is integer of the 1-10;    h is integer of the 0-3;    n is integer of the 1-3. ] So it is displayed at least the perfluoro of 1 where kinds (including poly-) ether basic content silane chemical compound, becomes being the coupling agent which, is displayed with the above-mentioned formula (1) the perfluoro which (poly-) ether basic content silane chemical compound, the below-mentioned formula (1a): [In formula, Rf, PFPE, Q, Z, e and f formula (1) are the same meaning as statement, Y (1), is chlorine, iodine or bromine. ] So the perfluoro which is displayed (the poly-) ether compound, the below-mentioned formula (1b): [In formula, R (1), R (2), h and n formula (1) are the same meaning as statement, X (1), hydroxyl group, is the hydrolysis possible basis or the halogen atom. ] So it reacts in reactivity double bond content silane chemical compound and the containing fluorine aromatic compound which are displayed, Next, with desire, the below-mentioned process (a) and/or (b) (A) When Y and Y (1) differs, Y (1) the process which is converted to Y (B) When X X (1) differs, the process which converts (1) to X X The coupling agent which features that it is produced by the method of attaching and including thing. 27. The below-mentioned formula (1'): [In formula: Rf is the alkyl group of the carbon count 1-10 which is possible to be substituted 1 or by the fluorine atom above that;    As for PFPE, - (OC [4] F [8]) [a] - (OC [3] F [6]) [b] - (OC [2] F [4]) [c] - (OCF [2]) [d] - (In formula, a and b, as for c and d, becoming independent respectively, being integer of the 0-200, a and b, as for harmony of c and d 1 was at least, a and b, attached c or d and was bound with the parenthesis each it repeats and existence order of the unit is optional in formula.) So it is;    Q is the oxygen atom or the organic basis of two value;    R (1) is the hydrogen atom or the alkyl group of the carbon count 1-22;    X is hydroxyl group or the hydrolysis possible basis;    Z is the fluorine atom or the fluoro alkyl group of the carbon count 1-5;    e is integer of the 0-3;    f is 0 or 1;    g is integer of the 1-10;    h is integer of the 0-3. ] So it is displayed at least the perfluoro of 1 where kinds (including poly-) ether basic content silane chemical compound, becomes being the coupling agent which, the above-mentioned formula (1') with is displayed the perfluoro which (poly-) ether basic content silane chemical compound, the below-mentioned formula (1a): [In formula, Rf, PFPE, Q, Z, e and f are the same meaning as description above, Y (1), is chlorine, iodine or bromine. ] So the perfluoro which is displayed (the poly-) ether compound, the below-mentioned formula (1c): [In formula, R (1) and h is the same meaning as description above. ] So reacting in chemical compound and the containing fluorine aromatic compound which are displayed, formula (1d): [In formula, Rf, PFPE, Q and Y (1), Z and R (1), e, f, g and h are the same meaning as description above. ] So the chemical compound which is displayed profit, next, HX (in formula, X is the same meaning as description above.)The coupling agent which features that it is produced so by the method of including the fact that it reacts with the chemical compound which is displayed. 28. Containing fluorine aromatic compound, perfluoro benzene and penta- fluorobenzene, 1,2,3,4 - tetra- fluorobenzene, 1,2,3,5 - tetra- fluorobenzene, 1,2,4,5 - tetra- fluorobenzene, 1,2,3 - [torihuruorobenzen], 1,2,4 - [torihuruorobenzen], 1,3,5 - [torihuruorobenzen], [o]-kishirenhekisahuruoraido, [m]-kishirenhekisahuruoraido, [p]-kishirenhekisahuruoraido and [benzotorihuruoraido], fluorobenzene, 1 - [kuroro] - 2 - fluorobenzene, 1 - [kuroro] - 3 - fluorobenzene, 1 - [kuroro] - 4 - fluorobenzene, 2,6 - [jikurorohuruorobenzen], 1 - fluoro - 3- ([torihuruorometokishi]) benzene, 1 - fluoro - 2,4 - dinitrobenzene, 2,4 - dimethoxy - 1 - fluorobenzene, 1 - fluoro - 4 - nitrobenzene, 2 - fluoro toluene, 3 - fluoroToluene, 4 - fluoro toluene, 3 - [huruorobenzotorihuruorido], 1 - [kuroro] - 2,4 - [jihuruorobenzen], 1 - [kuroro] - 3,4 - [jihuruorobenzen], 1 - [kuroro] - 3,5 - [jihuruorobenzen], 2 - [kuroro] - 1,3 - [jihuruorobenzen] and [kuroropentahuruorobenzen], 2,4 - [jikurorohuruorobenzen], 2,5 - [jikurorohuruorobenzen], 2,6 - [jikurorohuruorobenzen], 1,2 - [jikuroro] - 4 - fluorobenzene, 1,3 - [jikuroro] - 5 - fluorobenzene, 1,3 - [jikuroro] - 2,4,6 - [torihuruorobenzen], 3,4 - [jihuruorobenzonitoriru], 3,5 - [jihuruorobenzonitoriru], 3,4 - [jihuruoronitorobenzen], 1 - ethoxy - 2,3 - [jihuruorobenzen], 1,2 - [jishiano] - 4,5 - [jihuruorobenzen], 1 - acetoxy - 3 - fluorobenzene, 1 - acetoxy- 4 - Fluorobenzene, 1 - [asetoniru] - 4 - fluorobenzene, 2 - fluoro - [m]-kishiren, 3 - fluoro - [o]-kishiren, 4 - fluoro - [o]-kishiren, penta- fluoro anisole, [tetorahuruorohutaronitoriru], 2 - [torihuruoromechirubenzarukuroraido], 3 - [torihuruoromechirubenzarukuroraido], 4 - [torihuruoromechirubenzarukuroraido], 3- (trifluoromethyl) benzoic acid methyl, [jihuruorobenzonitoriru], bis trifluoromethyl benzo nitrile, 4 - trifluoromethyl benzo nitrile, it is selected from the group which consists of [aminobenzotorihuruorido], and trifluoromethyl aniline, in claim 26 or 27 the coupling agent of statement. 29. The containing fluorine aromatic compound, polarizability is the containing fluorine aromatic compound of 3 debye or less of 0 or more, in either of the claim 26-28 the coupling agent of statement. 30. The containing fluorine aromatic compound, [m]-kishirenhekisahuruoraido, [benzotorihuruoraido] and [jihuruorobenzonitoriru], bis trifluoromethyl benzo nitrile, is selected from the group which consists of, in either of the claim 26-29 the coupling agent of statement.
法律状态
(WO201599085) LEGAL DETAILS FOR WO2015099085  Actual or expected expiration date=2017-06-26    Legal state=ALIVE    Status=PENDING     Event publication date=2014-12-25  Event code=WO/APP  Event indicator=Pos  Event type=Examination events  Application details  Application country=WO WOJP2014084402  Application date=2014-12-25  Standardized application number=2014WO-JP84402     Event publication date=2015-07-02  Event code=WO/A1  Event type=Examination events  Published application with search report  Publication country=WO  Publication number=WO2015099085  Publication stage Code=A1  Publication date=2015-07-02  Standardized publication number=WO201599085  LEGAL DETAILS FOR DESIGNATED STATE CN105849222  Actual or expected expiration date=2034-12-25    Legal state=ALIVE    Status=PENDING   Corresponding cc:  Designated or member state=CN Corresponding appl: CN201480070885  Application date in the designated or member state=2014-12-25   Application number in the designated or member state=2014CN-80070885 Corresponding cc:  Designated or member state=CN Corresponding pat: CN105849222  Publication stage code in the designated or member state=A  Publication date in the designated or member state=2016-08-10   Publication number in the designated or member state=CN105849222 LEGAL DETAILS FOR DESIGNATED STATE DE  Actual or expected expiration date=2016-06-27    Legal state=DEAD    Status=LAPSED   Corresponding cc:  Designated or member state=DE     Event publication date=2016-06-27  Event code=WO/NENP  Event type=Event indicating Not In Force  Non-entry into the national phase in: Corresponding cc:  Designated or member state=DE     Event publication date=2016-06-27  Event code=WO/NENP  Event type=Event indicating Not In Force  Non-entry into the national phase in: Corresponding cc:  Designated or member state=DE  LEGAL DETAILS FOR DESIGNATED STATE EP3088487  Actual or expected expiration date=2034-12-25    Legal state=ALIVE    Status=PENDING   Corresponding cc:  Designated or member state=EP Corresponding appl: EP14874253  Application date in the designated or member state=2014-12-25   Application number in the designated or member state=2014EP-0874253 Corresponding cc:  Designated or member state=EP Corresponding pat: EP3088487  Publication stage code in the designated or member state=A1  Publication date in the designated or member state=2016-11-02   Publication number in the designated or member state=EP3088487    Event publication date=2015-08-19  Event code=WO/121  Event type=Designated states  EP: The EPO has been informed by wipo that ep was designated in this application Corresponding cc:  Designated or member state=EP     Event publication date=2015-08-19  Event code=WO/121  Event type=Designated states  EP: The EPO has been informed by wipo that ep was designated in this application Corresponding cc:  Designated or member state=EP  LEGAL DETAILS FOR DESIGNATED STATE KR20160072164  Actual or expected expiration date=2034-12-25    Legal state=ALIVE    Status=PENDING   Corresponding cc:  Designated or member state=KR Corresponding appl: KR20167012612  Application date in the designated or member state=2014-12-25   Application number in the designated or member state=2016KR-7012612 Corresponding cc:  Designated or member state=KR Corresponding pat: KR20160072164  Publication stage code in the designated or member state=A  Publication date in the designated or member state=2016-06-22   Publication number in the designated or member state=KR20160072164 LEGAL DETAILS FOR DESIGNATED STATE US2016340544  Actual or expected expiration date=2034-12-25    Legal state=ALIVE    Status=PENDING   Corresponding cc:  Designated or member state=US Corresponding appl: US15108165  Application date in the designated or member state=2014-12-25   Application number in the designated or member state=2014US-15108165 Corresponding cc:  Designated or member state=US Corresponding pat: US2016340544  Publication stage code in the designated or member state=A1  Publication date in the designated or member state=2016-11-24   Publication number in the designated or member state=US20160340544    Event publication date=2016-06-24  Event code=WO/WWE  Event indicator=Pos  Event type=Entry into national phase  Wipo information: entry into national phase Corresponding cc:  Designated or member state=US
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