Heterocyclocarboxamide derivatives 机翻标题: 暂无翻译,请尝试点击翻译按钮。

公开号/公开日
WO2004035589 A1 2004-04-29 [WO200435589] / 2004-04-29
申请号/申请日
2003WO-EP11388 / 2003-10-14
发明人
EHRENFREUND JOSEF;TOBLER HANS;WALTER HARALD;
申请人
SYNGENTA PARTICIPATIONS;
主分类号
IPC分类号
A01N-043/32A01N-043/36A01N-043/40A01N-043/56A01N-043/76A01N-043/78A01N-043/90C07C-211/61C07D-207/34C07D-213/82C07D-231/14C07D-263/34C07D-277/56C07D-327/06C07D-487/08C07D-493/08C07D-495/08
摘要
(WO200435589) The invention relates to a fungicidally active compound of formula (I): where Het is a 5- or 6-membered heterocyclic ring containing one to three heteroatoms, each independently selected from oxygen, nitrogen and sulphur, provided that the ring is not 1,2,3-triazole, the ring being substituted by groups R<8>, R<9> and R<10>; X is a single or double bond; Y is O, S, N(R<11>) or (CR<12>R<13>)(CR<14>R<15>)m(CR<16>R<17)>n; m is 0 or 1; n is 0 or 1; and R<1 >to R<17> each, independently, have a range of values; to the preparation of these compounds, to novel intermediates used in the preparation of these compounds, to agrochemical compositions which comprise at least one of the novel compounds as active ingredient, to the preparation of the compositions mentioned and to the use of the active ingredients or compositions in agriculture or horticulture for controlling or preventing infestation of plants by phytopathogenic microorganisms, preferably fungi.
机翻摘要
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地址
代理人
代理机构
;
优先权号
2002GB-0024316 2002-10-18
主权利要求
(WO200435589) CLAIMS A compound of formula (I):  where Het is a 5- or 6-membered heterocyclic ring containing one to three heteroatoms, each independently selected from oxygen, nitrogen and sulphur, provided that the ring is not 1,2,3-triazole, the ring being substituted by groups R8, R9and R10; X is a single or double bond; Y is O, S, N(Rn) or (CR12R,3)(CR14R15)m(CR16R17)n; m is 0 or 1; n is 0 or 1; R1is hydrogen, 01-43 !, Cι-4 haloalkyl, C alkoxy, CMhaloalkoxy, CH2C≡CR18, CH2CRI9=CHR20, CH=C=CH2or COR21; R2and R3are each, independently, hydrogen, halogen, C1-4 alkyl, C alkoxy or d -4haloalkoxy; R4, R5, R6and R7are each, independently, hydrogen, halogen, CMalkyl, CMhaloalkyl, C alkoxy, CMhaloalkoxy, CMalkylthio, C haloalkylthio, hydroxymethyl, C,-4alkoxymethyl, C(O)CH3or C(O)OCH3; R8, R9and R10are each, independently, hydrogen, halogen, cyano, nitro, CMalkyl, C haloalkyl, Cι- alkoxy(Cι-4)alkylene or CMhaloalkoxy(CM)alkylene, provided that at least one of R8, R9and R10is not hydrogen; R11is hydrogen, CMalkyl, benzyl (in which the phenyl group is optionally substituted with up to three substituents, each independently selected from halogen, CMalkyl, CMhaloalkyl and C alkoxy), formyl, C(0)CMalkyl (optionally substituted by halogen or C alkoxy), C(=O)O-Cι-6alkyl (optionally substituted by halogen, C alkoxy or cyano) or C alkoxy(C )alkylene; R12, R13, R14, R15, R16and R17are each, independently, hydrogen, halogen, hydroxy, C].6alkyl, C2.6alkenyl [both optionally substituted by halogen, hydroxy, C alkoxy, =O, aryl or O-C(O-CM alkyl or a 3-7 membered carboxylic ring (itself optionally substituted by up to three methyl groups)], a 3-7 membered saturated ring (optionally substituted by up to three methyl groups and optionally containing one heteroatom selected from nitrogen and oxygen) or d-4alkoxy; or R12and R13together with the carbon atom to which they are attached form the group C=O or a 3-5 membered carbocyclic ring (optionally substituted by up to three methyl groups and optionally with up to 2 heteroatoms each independently selected from O and N); or R12and R13together form a Cι.6alkylidene (optionally substituted by up to three methyl groups) or a C3.6cycloalkylidene group (optionally substituted by up to three methyl groups); R18, R19and R20are each, independently, hydrogen, halogen, CMalkyl, CMhaloalkyl or CMalkoxy(C )alkylene; and R21is hydrogen, Cι-6alkyl, Cι_s haloalkyl, CM alkoxy(Cι-4 )alkylene, CM alkyl-S-(CM.alky_εne, CM alkoxy or aryl. 2. A compound of formula (I) as claimed in claim 1 where Het is pyrrolyl, pyrazolyl, thiazolyl, oxazolyl, pyridinyl, pyrimidyl, pyridazinyl, 2,3-dihydro-[l,4]oxathϋne-6-yl, oxazinyl, thiazinyl or triazinyl. 3. A compound of formula (I) as claimed in claim 1 or 2 where Y is O, N(R' ') or (CRl2R,3)(CR14R15)m(CRl0R,7)„. 4. A compound of formula (I) as claimed in claim 1, 2 or 3 where R1is hydrogen, CH2C≡CR18, CH=C=CH2or COR21. A compound of formula (I) as claimed in claim 1, 2, 3 or 4 where R2is hydrogen, halogen or CM alkyl. A compound of formula (I) as claimed in claim 1, 2, 3, 4 or 5 where R3is hydrogen or methyl. 7. A compound of formula (C):  where Y is O or S; and R4, R5, R6and R7are each C(O)OCH3; or Y isN(R") or (CR12R13)(CR14R15)m(CR16Rl7)n; R4, R5, R6, R7, R14, R15, R16, R17, m and n are each as defined in claim 1 ; R1' is benzyl (in which the phenyl group is optionally substituted with up to three substituents, each independently selected from halogen, CMalkyl, C haloalkyl and CMalkoxy); and R12and R13together with the carbon atom to which they are attached form a 3-5 membered carbocyclic ring (optionally substituted by up to three methyl groups and containing 1 or 2 heteroatoms each independently selected from O and N). 8. A compound of formula (D):  where Y is O or S; and R4, R5, R6and R7are each C(O)OCH3; or Y isN(Rπ) or (CRI2Rl3)(CR14R15)m(CRI6R17)n; R4, R5, R6, R7, R14, R15, R16, R17, m and n are each as defined in claim 1 ; Rnis benzyl (in which the phenyl group is optionally substituted with up to three substituents, each independently selected from halogen, CM alkyl, CM haloalkyl and CMalkoxy); and R12and R13together with the carbon atom to which they are attached form a 3-5 membered carbocyclic ring (optionally substituted by up to three methyl groups and containing 1 or 2 heteroatoms each independently selected from O and N). 9. A composition for controlling microorganisms and preventing attack and infestation of plants therewith, wherein the active ingredient is a compound of formula (I) as claimed in claim 1 together with a suitable carrier. 10. A method of controlling or preventing infestation of cultivated plants by phytopathogenic microorganisms by application of a compound of formula (I) as claimed in claim 1 to plants, to parts thereof or the locus thereof.
法律状态
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