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公开号/公开日
WO2015047105 A1 2015-04-02 [WO201547105] / 2015-04-02
申请号/申请日
2014WO-NO50179 / 2014-09-29
发明人
KILAAS LARS;NORDGÅRD ERLAND;DALAGER DYRLI ANNE;
申请人
RESMAN;
主分类号
IPC分类号
C07C-043/20C07C-043/215C07C-069/42C07C-069/76C07C-309/10E21B-047/10G01N-033/24
摘要
(WO201547105) The present invention relates to novel compounds of polyfunctionalized polyethylene and polypropylene glycols, their synthesis and their use, in particular as tracers in applications related to oil and gas production, and especially as specific markers of various target fluids.
机翻摘要
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地址
代理人
代理机构
;
优先权号
2013NO-0001305 2013-09-30
主权利要求
(WO201547105) Claims   1 .  A compound characterized by the following generic structure    R R2R3-(OCHR4-CH2-)n-R5-[(-CH2-CHR60)m-R7R8R9]p    wherein the core unit R5 is further connected to 2-4 units by carbon, ether or ester bonds;    R4 and R6 is H or -CH3 to give PEG or PPG chains;    n and m are integers between 2 and 12 in which n could be the same or different from m;    p is an integer between 1 and 3 depending on R5;    R3 and R7 are aliphatic or aromatic hydrocarbon moieties with 2 - 40 carbon coupled to the PEG units or the PPG units by an ester or ether bond;    R , R2, R8 and R9 are all H or identical or different hydrophilic functional groups preferably carboxylic, sulfonic or phosphonic acid groups;or salts, hydrates and solvates thereof;    with the exception of 1 ,2-bis(2-(2-(benzyloxy)ethoxy)ethoxy)benzene.   2. A compound according to claim 1 , wherein n and m are integers between 3 and 12.   3. A compound according to claim 1 or 2, wherein the core R5 unit consist of C, O and H atoms.   4. A compound according to claim 3, wherein the core R5 unit consist of at least one halogen atom.   5. A compound according to claim 3 or 4, wherein the core R5 unit consist of at least one sulfonic acid or sulfonic acid salt.   6. A compound according to any of the preceding claims wherein the core R5 unit is selected from aryl or aralkyl units with from 3 to 30 carbon atoms, more preferably 3-24 carbon atoms, specifically preferable 3-15 carbon atoms, which also may contain one or more ether functions and/or ester functions or branched; or linear alkyl units with from 3 to 12 carbon atoms which also may contain one or more ether functions and/or ester functions.   7.  A compound according to claims 1 - 5, wherein the core R5 unit is selected from the group consisting of:    8.  A compound according to claims 1 -6 optionally substituted by additional    functional groups to enhance their detection as tracers by various detection methods like gas chromatography (GC), liquid chromatography (LC),mass spectrometry (MS) or a combination thereof, ultraviolet and visible    spectroscopy, infrared and Raman spectroscopy, nuclear magnetic resonance (NMR) and detection of radiation coupled with suitable separation techniques like liquid column chromatography.   9. A compound according to claim 1 selected from:    Chemical name Ex.  Scheme m/z. as no.  NH4 No.    adduct l,2-bis(2-(2-(benzyloxy)ethoxy)ethoxy)benzene 5 1.2 484.3 l,2-bis(2-(2-(2-(benzyloxy)ethoxy)ethoxy)ethoxy)benzene 1.2 572.3 l,2-bis((l-phenyl-2,5,8,ll-tetraoxatridecan-13-yl)oxy)benzene 1 1.2 660.4 l,2-bis((l-phenyl-2,5,8,ll,14-pentaoxahexadecan-16- 1.2 748.5 yl)oxy)benzene   l,2-bis((l-phenyl-2,5,8,ll,14,17-hexaoxanonadecan-19- 1.2 836.5 yl)oxy)benzene   l,2-bis((l-phenyl-2,5,8,ll,14,17,20,23-octaoxapentacosan-25- 1.2 1012.6/ yl)oxy)benzene    515.4 l,2-bis(2-(2-((4-methylbenzyl)oxy)ethoxy)ethoxy)benzene 1.2 512.4 l,2-bis(2-(2-(2-((4- 1.2 600.4 methylbenzyl)oxy)ethoxy)ethoxy)ethoxy)benzene l,2-bis((l-(p-tolyl)-2,5,8,ll-tetraoxatridecan-13-yl)oxy)benzene 1.2 688.5 l,2-bis((l-(p-tolyl)-2,5,8,ll,14-pentaoxahexadecan-16- 1.2 776.4 yl)oxy)benzene   l,2-bis((l-(p-tolyl)-2,5,8,ll,14,17-hexaoxanonadecan-19- 1.2 864.5 yl)oxy)benzene l,2-bis((l-(4-(tert-butyl)phenyl)-2,5,8,ll-tetraoxatridecan-13- 1.2 772.5 yl)oxy)benzene   l,2-bis((l-(4-(tert-butyl)phenyl)-2,5,8,H,14,17,20,23- 1.2 1124.7 / octaoxapentacosan-25-yl)oxy)benzene 571.5 l,2-bis(2-(2-(naphthalen-2-ylmethoxy)ethoxy)ethoxy)benzene 1.2 584.4 l,2-bis((l-(naphthalen-2-yl)-2,5,8,ll,14,17-hexaoxanonadecan- 1.2 936.4 19-yl)oxy)benzene l,3-bis((l-phenyl-2,5,8,ll-tetraoxatridecan-13-yl)oxy)benzene 1.3 660.4 l,4-bis((l-phenyl-2,5,8,ll-tetraoxatridecan-13-yl)oxy)benzene 1.3 660.4   (((((((4-methyl-l,2-phenylene)bis(oxy))bis(ethane-2,l- 1.2 498.4 diyl))bis(oxy))bis(ethane-2,l-    diyl))bis(oxy))bis(methylene))dibenzene   (((((((((4-methyl-l,2-phenylene)bis(oxy))bis(ethane-2,l- 1.2 586.3 diyl))bis(oxy))bis(ethane-2,l-diyl))bis(oxy))bis(ethane-2,l- diyl))bis(oxy))bis(methylene))dibenzene   13,13'-((4-methyl-l,2-phenylene)bis(oxy))bis(l-phenyl-2,5,8,ll- 1.2 674.5 tetraoxatridecane)   16,16'-((4-methyl-l,2-phenylene)bis(oxy))bis(l-phenyl- 1.2 762.5 2,5,8,11, 14-pentaoxahexadecane)   19,19'-((4-methyl-l,2-phenylene)bis(oxy))bis(l-phenyl- 1.2 850.6 2,5,8,11, 14, 17-hexaoxanonadecane)   25,25'-((4-methyl-l,2-phenylene)bis(oxy))bis(l-phenyl- 1.2 1026.5 / 2,5,8,11,14,17,20,23-octaoxapentacosane) 522.4   4,4'-(((((((4-methyl-l,2-phenylene)bis(oxy))bis(ethane-2,l- 1.2 526.4 diyl))bis(oxy))bis(ethane-2,l- diyl))bis(oxy))bis(methylene))bis(methylbenzene)   4,4'-(((((((((4-methyl-l,2-phenylene)bis(oxy))bis(ethane-2,l- 1.2 614.4 diyl))bis(oxy))bis(ethane-2,l-diyl))bis(oxy))bis(ethane-2,l- diyl))bis(oxy))bis(methylene))bis(methylbenzene)   13,13'-((4-methyl-l,2-phenylene)bis(oxy))bis(l-(p-tolyl)- 1.2 702.5 2,5,8, 11-tetraoxatridecane)   16,16'-((4-methyl-l,2-phenylene)bis(oxy))bis(l-(p-tolyl)- 1.2 790.5 2,5,8,11, 14-pentaoxahexadecane)   19,19'-((4-methyl-l,2-phenylene)bis(oxy))bis(l-(p-tolyl)- 1.2 878.6 2,5,8,11, 14, 17-hexaoxanonadecane)   4,4'-(((((((4-ethyl-l,3-phenylene)bis(oxy))bis(ethane-2,l- 11 1.3 540.5 diyl))bis(oxy))bis(ethane-2,l- diyl))bis(oxy))bis(methylene))bis(methylbenzene)   13,13'-((4-ethyl-l,3-phenylene)bis(oxy))bis(l-(p-tolyl)-2,5,8,ll- 12 1.3 716.4 tetraoxatridecane)   19,19'-((4-ethyl-l,3-phenylene)bis(oxy))bis(l-(p-tolyl)- 13 1.3 892.5 / 2,5,8,11, 14, 17-hexaoxanonadecane) 455.4   (((((((4-(tert-butyl)-l,2-phenylene)bis(oxy))bis(ethane-2,l- 1.2 540.3 diyl))bis(oxy))bis(ethane-2,l- diyl))bis(oxy))bis(methylene))dibenzene    (((((((((4-(tert-butyl)-l,2-phenylene)bis(oxy))bis(ethane-2,l- 1.2 628.5 diyl))bis(oxy))bis(ethane-2,l-diyl))bis(oxy))bis(ethane-2,l- diyl))bis(oxy))bis(methylene))dibenzene   13,13'-((4-(tert-butyl)-l,2-phenylene)bis(oxy))bis(l-phenyl- 1.2 416.5 2,5,8, 11-tetraoxatridecane)   16,16'-((4-(tert-butyl)-l,2-phenylene)bis(oxy))bis(l-phenyl- 1.2 804.5 2,5,8,11, 14-pentaoxahexadecane)   19,19'-((4-(tert-butyl)-l,2-phenylene)bis(oxy))bis(l-phenyl- 1.2 892.6 2,5,8,11, 14, 17-hexaoxanonadecane)   25,25'-((4-(tert-butyl)-l,2-phenylene)bis(oxy))bis(l-phenyl- 1.2 1068.5 / 2,5,8,11,14,17,20,23-octaoxapentacosane) 543.5   4,4'-(((((((4-(tert-butyl)-l,2-phenylene)bis(oxy))bis(ethane-2,l- 1.2 568.4 diyl))bis(oxy))bis(ethane-2,l- diyl))bis(oxy))bis(methylene))bis(methylbenzene)   4,4'-(((((((((4-(tert-butyl)-l,2-phenylene)bis(oxy))bis(ethane-2,l- 1.2 656.6 diyl))bis(oxy))bis(ethane-2,l-diyl))bis(oxy))bis(ethane-2,l- diyl))bis(oxy))bis(methylene))bis(methylbenzene)   13,13'-((4-(tert-butyl)-l,2-phenylene)bis(oxy))bis(l-(p-tolyl)- 1.2 744.5 2,5,8, 11-tetraoxatridecane)   16,16'-((4-(tert-butyl)-l,2-phenylene)bis(oxy))bis(l-(p-tolyl)- 1.2 832.5 2,5,8,11, 14-pentaoxahexadecane)   19,19'-((4-(tert-butyl)-l,2-phenylene)bis(oxy))bis(l-(p-tolyl)- 1.2 920.6 2,5,8,11, 14, 17-hexaoxanonadecane)   25,25'-((4-(tert-butyl)-l,2-phenylene)bis(oxy))bis(l-(4-(tert- 1.2 1180.8 / butyl)phenyl)-2,5,8,ll,14,17,20,23-octaoxapentacosane) 599.5   19,19'-((4-(tert-butyl)-l,2-phenylene)bis(oxy))bis(l- 1.2 992.5 (naphthalen-2-yl)-2,5,8, 11, 14, 17-hexaoxanonadecane)   (((((((3,5-di-tert-butyl-l,2-phenylene)bis(oxy))bis(ethane-2,l- 1.2 596.5 diyl))bis(oxy))bis(ethane-2,l- diyl))bis(oxy))bis(methylene))dibenzene   13,13'-((3,5-di-tert-butyl-l,2-phenylene)bis(oxy))bis(l-phenyl- 1.2 772.6 2,5,8, 11-tetraoxatridecane)   19,19'-((3,5-di-tert-butyl-l,2-phenylene)bis(oxy))bis(l-phenyl- 1.2 948.6 2,5,8,11, 14, 17-hexaoxanonadecane)   25,25'-((3,5-di-tert-butyl-l,2-phenylene)bis(oxy))bis(l-phenyl- 1.2 1124.7 / 2,5,8,11,14,17,20,23-octaoxapentacosane) 571.5   13,13'-((3,5-di-tert-butyl-l,2-phenylene)bis(oxy))bis(l-(4-(tert- 1.2 884.6 butyl)phenyl)-2,5,8,ll-tetraoxatridecane)   25,25'-((3,5-di-tert-butyl-l,2-phenylene)bis(oxy))bis(l-(4-(tert- 1.2 1236.8 / butyl)phenyl)-2,5,8,ll,14,17,20,23-octaoxapentacosane) 627.5 l,2-bis(15-phenyl-2,5,8,ll,14-pentaoxapentadecyl)benzene 1.7 688.2 l,2-bis(27-phenyl-2,5,8,ll,14,17,20,23,26- 1.7 1040.6 nonaoxaheptacosyl)benzene l,2-bis(15-(4-(tert-butyl)phenyl)-2,5,8,ll,14- 18 1.7 800.5 pentaoxapentadecyl)benzene   4,4'-(((((((4-chloro-l,3-phenylene)bis(oxy))bis(ethane-2,l- 1.3 546.2 diyl))bis(oxy))bis(ethane-2,l- diyl))bis(oxy))bis(methylene))bis(methylbenzene)   13,13'-((4-chloro-l,3-phenylene)bis(oxy))bis(l-(p-tolyl)-2,5,8,ll- 15 1.3 722.4 tetraoxatridecane) l,5-bis((l-phenyl-2,5,8,ll-tetraoxatridecan-13- 1.2 710.4 yl)oxy)naphthalene   2,3-bis(2-(2-(benzyloxy)ethoxy)ethoxy)naphthalene 1.2 534.3   2,3-bis(2-(2-(2-(benzyloxy)ethoxy)ethoxy)ethoxy)naphthalene 1.2 622.5   2,3-bis((l-phenyl-2,5,8,ll-tetraoxatridecan-13- 6 1.2 710.4 yl)oxy)naphthalene   2,3-bis((l-phenyl-2,5,8,ll,14-pentaoxahexadecan-16- 1.2 798.4 yl)oxy)naphthalene   2,3-bis((l-phenyl-2,5,8,ll,14,17-hexaoxanonadecan-19- 1.2 886.4 yl)oxy)naphthalene   2,3-bis((l-phenyl-2,5,8,ll,14,17,20,23-octaoxapentacosan-25- 1.2 1062.5 / yl)oxy)naphthalene 540.4   2,3-bis(2-(2-((4-methylbenzyl)oxy)ethoxy)ethoxy)naphthalene 1.2 562.4   2,3-bis(2-(2-(2-((4- 1.2 650.4 methylbenzyl)oxy)ethoxy)ethoxy)ethoxy)naphthalene   2,3-bis((l-(p-tolyl)-2,5,8,ll-tetraoxatridecan-13- 1.2 738.4    yl)oxy)naphthalene   2,3-bis((l-(p-tolyl)-2,5,8,ll,14-pentaoxahexadecan-16- 1.2 826.4 yl)oxy)naphthalene   2,3-bis((l-(p-tolyl)-2,5,8,ll,14,17-hexaoxanonadecan-19- 1.2 914.6 yl)oxy)naphthalene   13,13'-((propane-2,2-diylbis(4,l-phenylene))bis(oxy))bis(l-(p- 1.2 806.4 tolyl)-2,5,8,ll-tetraoxatridecane)   19,19'-((propane-2,2-diylbis(4,l-phenylene))bis(oxy))bis(l-(p- 1.2 982.5 / tolyl)-2,5,8,ll,14,17-hexaoxanonadecane) 500.5 l,33-bis(4-(tert-butyl)phenyl)-15,19-dimethyl- 21 1.6 796.6 2,5,8,11,14,17,20,23,26,29,32-undecaoxatritriacontane l,32-diphenyl-2,5,8,ll,14,19,22,25,28,31- 22 1.8 640.5 decaoxadotriacontane   1,56-diphenyl- 1.8 992.6  2,5,8,11,14,17,20,23,26,31,34,37,40,43,46,49,52,55- octadecaoxahexapentacontane bis(l-phenyl-2,5,8,ll-tetraoxatridecan-13-yl) succinate 5 668.4 bis(l-(4-(tert-butyl)phenyl)-2,5,8,ll-tetraoxatridecan-13-yl) 5 780.5 succinate bis(l-(4-(tert-butyl)phenyl)-2,5,8,ll,14,17,20,23- 5 1132.6 / octaoxapentacosan-25-yl) succinate 575.5 bis(l-phenyl-2,5,8,ll-tetraoxatridecan-13-yl) glutarate 2 5 682.4 bis(l-phenyl-2,5,8,ll,14,17,20,23-octaoxapentacosan-25-yl) 5 1034.5 / glutarate 526.4 bis(l-(4-(tert-butyl)phenyl)-2,5,8,ll-tetraoxatridecan-13-yl) 5 794.5 glutarate bis(l-phenyl-2,5,8,ll-tetraoxatridecan-13-yl) adipate 5 696.4 l,3,5-tris((l-(4-(tert-butyl)phenyl)-2,5,8,ll-tetraoxatridecan-13- 1.2 1110.7 yl)oxy)benzene l,3,5-tris(15-phenyl-2,5,8,ll,14-pentaoxapentadecyl)benzene 24 1.9 984.5 l,3,5-tris(27-phenyl-2,5,8,ll,14,17,20,23,26- 25 1.9 765.6 nonaoxaheptacosyl)benzene    tris(l-phenyl-2,5,8,ll-tetraoxatridecan-13-yl) benzene-1,3,5- 3 5 1026.4 tricarboxylate potassium 3,3'-(((((l,2-phenylenebis(oxy))bis(ethane-2,l- 7 1.2.4 548.2 diyl))bis(oxy))bis(ethane-2,l-diyl))bis(oxy))bis(propane-l- sulfonate) potassium 3,3'-(((((((l,2-phenylenebis(oxy))bis(ethane-2,l- 1.2.4 636.3 diyl))bis(oxy))bis(ethane-2,l-diyl))bis(oxy))bis(ethane-2,l- diyl))bis(oxy))bis(propane-l-sulfonate) potassium l,l'-(l,2-phenylenebis(oxy))bis(3,6,9,12- 8 1.2.4 724.3 tetraoxapentadecane-15-sulfonate) potassium l,l'-(l,2-phenylenebis(oxy))bis(3,6,9,12,15,18- 1.2.4 900.3 / hexaoxahenicosane-21-sulfonate) 459.2 potassium l,l'-(l,2-phenylenebis(oxy))bis(3,6,9,12,15,18,21,24- 1.2.4 1076.8 / octaoxaheptacosane-27-sulfonate) 547.4 potassium 4,4'-(((((l,2-phenylenebis(oxy))bis(ethane-2,l- 1.2.4 567.0 diyl))bis(oxy))bis(ethane-2,l-diyl))bis(oxy))bis(butane-l- sulfonate) potassium l,l'-(l,2-phenylenebis(oxy))bis(3,6,9,12- 1.2.4 752.3 tetraoxahexadecane-16-sulfonate) potassium l,l'-(l,2-phenylenebis(oxy))bis(3,6,9,12,15,18- 1.2.4 928.3 / hexaoxadocosane-22-sulfonate) 473.3 potassium l,l'-(l,2-phenylenebis(oxy))bis(3,6,9,12,15,18,21,24- 1.2.4 1104.4 / octaoxaoctacosane-28-sulfonate) 561.2 potassium 3,3'-((((((4-methyl-l,2- 1.2.4 562.3 phenylene)bis(oxy))bis(ethane-2,l-diyl))bis(oxy))bis(ethane-2,l- diyl))bis(oxy))bis(propane-l-sulfonate) potassium l,l'-((4-methyl-l,2-phenylene)bis(oxy))bis(3,6,9,12- 9 1.2.4 738.1 / tetraoxapentadecane-15-sulfonate) 378.3 potassium l,l'-((4-methyl-l,2- 1.2.4 914.3 / phenylene)bis(oxy))bis(3,6,9,12,15,18-hexaoxahenicosane-21- 466.3 sulfonate) potassium l,l'-((4-methyl-l,2- 1.2.4 1090.8 / phenylene)bis(oxy))bis(3,6,9,12,15,18,21,24- 554.4 octaoxaheptacosane-27-sulfonate)    potassium 4,4'-((((((4-methyl-l,2- 1.2.4 590.0 phenylene)bis(oxy))bis(ethane-2,l-diyl))bis(oxy))bis(ethane-2,l- diyl))bis(oxy))bis(butane-l-sulfonate) potassium l,l'-((4-methyl-l,2-phenylene)bis(oxy))bis(3,6,9,12- 10 1.2.4 766.4 tetraoxahexadecane-16-sulfonate) potassium l,l'-((4-methyl-l,2- 1.2.4 942.0 / phenylene)bis(oxy))bis(3,6,9,12,15,18-hexaoxadocosane-22- 480.3 sulfonate) potassium l,l'-((4-methyl-l,2- 1.2.4 1118 / phenylene)bis(oxy))bis(3,6,9,12,15,18,21,24- 568 octaoxaoctacosane-28-sulfonate) potassium l,l'-((((((4-methyl-l,2- 17 1.2.4 618.3 phenylene)bis(oxy))bis(ethane-2,l-diyl))bis(oxy))bis(ethane-2,l- diyl))bis(oxy))bis(pentane-3-sulfonate) potassium 4,4'-((((((4-methyl-l,2- 16 1.2.4 742.3 phenylene)bis(oxy))bis(ethane-2,l-diyl))bis(oxy))bis(ethane-2,l- diyl))bis(oxy))bis(l-phenylbutane-2-sulfonate) potassium l,l'-((4-methyl-l,2-phenylene)bis(oxy))bis(28- 1.2.4 644.5 phenyl-3,6,9,12,15,18,21,24-octaoxaoctacosane-27-sulfonate) potassium 3,3'-((((((4-ethyl-l,3-phenylene)bis(oxy))bis(ethane- 1.2.4 576.3  2,l-diyl))bis(oxy))bis(ethane-2,l-diyl))bis(oxy))bis(propane-l- sulfonate) potassium l,l'-((4-ethyl-l,3-phenylene)bis(oxy))bis(3,6,9,12- 1.2.4 752.3 tetraoxapentadecane-15-sulfonate) potassium l,l'-((4-ethyl-l,3- 1.2.4 928.3 / phenylene)bis(oxy))bis(3,6,9,12,15,18-hexaoxahenicosane-21- 473.3 sulfonate) potassium l,l'-((4-ethyl-l,3- 1.2.4 1104.4 / phenylene)bis(oxy))bis(3,6,9,12,15,18,21,24- 561.2 octaoxaheptacosane-27-sulfonate) potassium 4,4'-((((((4-ethyl-l,3-phenylene)bis(oxy))bis(ethane- 1.2.4 604.3  2,l-diyl))bis(oxy))bis(ethane-2,l-diyl))bis(oxy))bis(butane-l- sulfonate) potassium l,l'-((4-ethyl-l,3-phenylene)bis(oxy))bis(3,6,9,12- 1.2.4 780.3 tetraoxahexadecane-16-sulfonate)    potassium l,l'-((4-ethyl-l,3- 1.2.4 956.4 / phenylene)bis(oxy))bis(3,6,9,12,15,18-hexaoxadocosane-22- 487.3 sulfonate) potassium l,l'-((4-ethyl-l,3- 1.2.4 1132.2 / phenylene)bis(oxy))bis(3,6,9,12,15,18,21,24- 575.1 octaoxaoctacosane-28-sulfonate) potassium 3,3'-((((((4-(tert-butyl)-l,2- 1.2.4 604.3 phenylene)bis(oxy))bis(ethane-2,l-diyl))bis(oxy))bis(ethane-2,l- diyl))bis(oxy))bis(propane-l-sulfonate) potassium l,l'-((4-(tert-butyl)-l,2- 1.2.4 780.4 / phenylene)bis(oxy))bis(3,6,9,12-tetraoxapentadecane-15- 399.4 sulfonate) potassium l,l'-((4-(tert-butyl)-l,2- 1.2.4 956.5 / phenylene)bis(oxy))bis(3,6,9,12,15,18-hexaoxahenicosane-21- 487.4 sulfonate) potassium l,l'-((4-(tert-butyl)-l,2- 1.2.4 1132.8 / phenylene)bis(oxy))bis(3,6,9,12,15,18,21,24- 575.4 octaoxaheptacosane-27-sulfonate) potassium 4,4'-((((((4-(tert-butyl)-l,2- 1.2.4 632.3 phenylene)bis(oxy))bis(ethane-2,l-diyl))bis(oxy))bis(ethane-2,l- diyl))bis(oxy))bis(butane-l-sulfonate) potassium l,l'-((4-(tert-butyl)-l,2- 1.2.4 808.5 / phenylene)bis(oxy))bis(3,6,9,12-tetraoxahexadecane-16- 413.4 sulfonate) potassium l,l'-((4-(tert-butyl)-l,2- 1.2.4 984.5 / phenylene)bis(oxy))bis(3,6,9,12,15,18-hexaoxadocosane-22- 501.4 sulfonate) potassium l,l'-((4-(tert-butyl)-l,2- 1.2.4 1160 / phenylene)bis(oxy))bis(3,6,9,12,15,18,21,24- 589.4 octaoxaoctacosane-28-sulfonate) potassium l,l'-((3,5-di-tert-butyl-l,2- 1.2.4 836.4 / phenylene)bis(oxy))bis(3,6,9,12-tetraoxapentadecane-15- 427.4 sulfonate) potassium l,l'-((3,5-di-tert-butyl-l,2- 1.2.4 1012.5 / phenylene)bis(oxy))bis(3,6,9,12,15,18-hexaoxahenicosane-21- 515.4 sulfonate)    potassium l,l'-((3,5-di-tert-butyl-l,2- 1.2.4 864.5 / phenylene)bis(oxy))bis(3,6,9,12-tetraoxahexadecane-16- 441.4 sulfonate) potassium 3,3'-((((((4-chloro-l,3-phenylene)bis(oxy))bis(ethane- 1.2.4 582.2  2,l-diyl))bis(oxy))bis(ethane-2,l-diyl))bis(oxy))bis(propane-l- sulfonate) potassium l,l'-((4-chloro-l,3-phenylene)bis(oxy))bis(3,6,9,12- 1.2.4 758.2 tetraoxapentadecane-15-sulfonate) potassium 4,4'-((((((4-chloro-l,3-phenylene)bis(oxy))bis(ethane- 1.2.4 610.2  2,l-diyl))bis(oxy))bis(ethane-2,l-diyl))bis(oxy))bis(butane-l- sulfonate) potassium l,l'-((4-chloro-l,3-phenylene)bis(oxy))bis(3,6,9,12- 1.2.4 786.3 tetraoxahexadecane-16-sulfonate) potassium 3,3'-(((((naphthalene-2,3-diylbis(oxy))bis(ethane-2,l- 1.2.4 598.3 diyl))bis(oxy))bis(ethane-2,l-diyl))bis(oxy))bis(propane-l- sulfonate) potassium l,l'-(naphthalene-2,3-diylbis(oxy))bis(3,6,9,12- 1.2.4 774.3 / tetraoxapentadecane-15-sulfonate) 396.3 potassium l,l'-(naphthalene-2,3-diylbis(oxy))bis(3,6,9,12,15,18- 1.2.4 950.3 / hexaoxahenicosane-21-sulfonate) 484.3 potassium l,l'-(naphthalene-2,3- 1.2.4 1126.8 / diylbis(oxy))bis(3,6,9,12,15,18,21,24-octaoxaheptacosane-27- 572.4 sulfonate) potassium 4,4'-(((((naphthalene-2,3-diylbis(oxy))bis(ethane-2,l- 1.2.4 626.3 diyl))bis(oxy))bis(ethane-2,l-diyl))bis(oxy))bis(butane-l- sulfonate) potassium l,l'-(naphthalene-2,3-diylbis(oxy))bis(3,6,9,12- 1.2.4 802 tetraoxahexadecane-16-sulfonate) potassium l,l'-(naphthalene-2,3-diylbis(oxy))bis(3,6,9,12,15,18- 1.2.4 978.3 / hexaoxadocosane-22-sulfonate) 498.4 potassium l,l'-(naphthalene-2,3- 1.2.4 1154.6 / diylbis(oxy))bis(3,6,9,12,15,18,21,24-octaoxaoctacosane-28- 586.3 sulfonate) l,l'-(l,2-phenylenebis(oxy))bis(3,6,9,12,15,18,21,24- 4 1.2.4 1104.4 /    octaoxaoctacosane-28-sulfonic acid) 561.2   136 25,25'-((4-ethyl-l,3-phenylene)bis(oxy))bis(l-phenyl- 14 1.2 1104.4 / 2,5,8,11,14,17,20,23-octaoxapentacosane) 561.4   137 potassium l,l'-((4-methyl-l,2-phenylene)bis(oxy))bis(3,6,9,12- 1.2.4 794.4 / tetraoxaheptadecane-15-sulfonate) 406.3   138 l,2-bis((l-(naphthalen-2-yl)-2,5,8,ll-tetraoxatridecan-13- 1.2 760.4 yl)oxy)benzene   139 2,2'-(((((((4-(tert-butyl)-l,2-phenylene)bis(oxy))bis(ethane-2,l- 1.2 640.4 diyl))bis(oxy))bis(ethane-2,l- diyl))bis(oxy))bis(methylene))dinaphthalene   140 13,13'-((4-(tert-butyl)-l,2-phenylene)bis(oxy))bis(l- 1.2 816.4 (naphthalen-2-yl)-2,5,8,ll-tetraoxatridecane)   10.  A composition containing one or more compounds according to any of the    claims 1 -8 and one or more additional constituents like solvents, diluents, surfactants, adsorbents, stabilizers and/or formulated into tablets or capsules or other matrix forms and geometrical shapes..   1 1 .  A compound with the following generic structure    R R2R3-(OCHR4-CH2-)n-R5-[(-CH2-CHR60)m-R7R8R9]p    wherein the core unit R5 is further connected to 2-4 units by carbon, ether or ester bonds;    R4 and R6 is H or -CH3 to give PEG or PPG chains;    n and m are integers between 2 and 12 in which n could be the same or different from m;    p is an integer between 1 and 3 depending on R5;    R3 and R7 are aliphatic or aromatic hydrocarbon moieties with 2 - 40 carbon coupled to the PEG units or the PPG units by an ester or ether bond;    R , R2, R8 and R9 are all H or identical or different hydrophilic functional groups preferably carboxylic, sulfonic or phosphonic acid groups; or salts, hydrates and solvates thereof; or    a composition containing one or more of these compounds and one or more additional constituents like solvents, diluents, surfactants, adsorbents, stabilizers and/or formulated into tablets or capsules;    for the use as a tracer.   12.  A compound or a composition according to claim 1 1 for use as tracers in    release systems.    12. A compound or a composition according to claim 1 1 for use as tracers for inflow monitoring during oil and gas production.    13.  A compound or a composition according to claim 1 1 , where components are detected topside after release from oil and gas wells.    14.  A compound or a composition according to claim 1 1 where the components are detected topside after release from oil and gas wells by LCMS, GCMS or a combination thereof.
法律状态
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