Biphenyl derivatives and their use as fungicides 机翻标题: 暂无翻译,请尝试点击翻译按钮。

公开号/公开日
WO2004058723 A1 2004-07-15 [WO200458723] / 2004-07-15
申请号/申请日
2003WO-EP14248 / 2003-12-15
发明人
EHRENFREUND JOSEF;LAMBERTH CLEMENS;TOBLER HANS;WALTER HARALD;
申请人
SYNGENTA PARTICIPATIONS;
主分类号
IPC分类号
A01N-043/06A01N-043/14A01N-043/32A01N-043/36A01N-043/40A01N-043/54A01N-043/56A01N-043/58A01N-043/60A01N-043/74A01N-043/80C07C-025/24C07C-211/45C07C-211/52C07C-217/76C07C-219/32C07C-233/03C07D-207/34C07D-213/82C07D-231/14C07D-231/16C07
摘要
(WO200458723) A fungicidally active compound of formula (I): where Het is a substituted 5- or 6-membered heterocyclic ring; R<1> is hydrogen, formyl, CO-C1-4 alkyl, COO-C1-4 alkyl, C1-4 alkoxy(C1-4)alkylene, CO-C1-4 alkylenoxy(C1-4)alkyl, propargyl or allenyl; R<2>, R<3>, R<4> and R<5> are each, independently, hydrogen, halogen, methyl or CF3; each R<6> is, independently, halogen, methyl or CF3; R<7> is (Z)mC=C(Y<1>), (Z)mC(Y<1>)=C(Y<2>)(Y<3>) or tri(C1-4)alkylsilyl; X is O or S; Y<1>, Y<2> and Y<3> are each, independently, hydrogen, halogen, C1-6 alkyl [optionally substituted by one or more substituents each independently selected from halogen, hydroxy, C1-4 alkoxy, C1-4 haloalkoxy, C1-4 alkylthio, C1-4 haloalkylthio, C1-4 alkylamino, di(C1-4)alkylamino, C1-4 alkoxycarbonyl, C1-4 alkylcarbonyloxy and tri(C1-4)alkylsilyl], C2-4 alkenyl [optionally substituted by one or more substituents each independently selected from halogen], C2-4 alkynyl [optionally substituted by one or more substituents each independently selected from halogen], C3-7 cycloalkyl [optionally substituted by one or more substituents each independently selected from halogen, C1-4 alkyl and C1-4 haloalkyl] or tri(C1­4)alkylsilyl; Z is C1-4 alkylene [optionally substituted by one or more substituents each independently selected from hydroxy, cyano, C1-4 alkoxy, halogen, C1-4 haloalkyl, C1-4 haloalkoxy, C1-4 alkylthio, COOH and COO-C1-4 alkyl]; m is 0 or 1; and n is 0, 1 or 2; the invention also relates to novel intermediates used in the preparation of these compounds, to agrochemical compositions which comprise at least one of the novel compounds as active ingredient and to the use of the active ingredients or compositions in agriculture or horticulture for controlling or preventing infestation of plants by phytopathogenic microorganisms, preferably fungi.
机翻摘要
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地址
代理人
代理机构
;
优先权号
2002GB-0030155 2002-12-24
主权利要求
(WO200458723) CLAIMS A compound of formula (I): where Het is a 5- or 6-membered heterocyclic ring containing one to three heteroatoms, each independently selected from oxygen, nitrogen and suphur, provided that the ring is not 1,2,3-triazole, the ring being substituted by one, two or three groups Ry; R1is hydrogen, formyl, CO-C]-4alkyl, COO-Cι-4alkyl, Cι-4alkoxy(Cι.4)alkylene, CO-Cι- alkylenoxy(Cι-4)alkyl, propargyl or allenyl; R2, R3, R4and R5are each, independently, hydrogen, halogen, methyl or CF3; each R6is, independently, halogen, methyl or CF3; R7is (Z)mCsC(Y1), (Z)mC(Y1)=C(Y2)(Y3) or tri(Cι-4)alkylsilyl; each Ryis, independently, halogen, C1-3alkyl, Cj-3haloalkyl, Cι-3alkoxy(C]-3)alkylene or cyano; X is O or S; Y1, Y2and Y3are each, independently, hydrogen, halogen, C].6alkyl [optionally substituted by one or more substituents each independently selected from halogen, hydroxy, C alkoxy, Cι-4haloalkoxy, Cι-4alkylthio, Cι-4haloalkylthio, Cι-4alkylamino, di(Cι-4)alkylamino, Cι-4alkoxycarbonyl, Cι-4alkylcarbonyloxy and tri(C]-4)alkylsilyl], C2-4alkenyl [optionally substituted by one or more substituents each independently selected from halogen], C2-4alkynyl [optionally substituted by one or more substituents each independently selected from halogen], C3- cycloalkyl [optionally substituted by one or more substituents each independently selected from halogen, CMalkyl and CM haloalkyl] or tri(Cι.4)alkylsilyl; Z is Cι-4alkylene [optionally substituted by one or more substituents each independently selected from hydroxy, cyano, Cι-4alkoxy, halogen, Cι-4haloalkyl, Cι-4haloalkoxy, CMalkylthio, COOH and COO-Cι-4alkyl]; m is 0 or 1; and n is 0, 1 or 2. 2. A compound of formula (I) as claimed in claim 1 where Het is pyrazole, pyrrole, thiophene, fiiran, thiazole, isothiazole, oxazole, isoxazole, pyridine, pyrazine, pyrimidine, pyridazine, 5.6-dihydropyran or 5.6-dihydro-1.4-oxathiine. 3. A compound of formula (I) as claimed in claim 1 or 2 where R1is hydrogen, propargyl, allenyl, formyl, COMe, COEt or COCH2OMe. 4. A compound of formula (I) as claimed in claim 1 , 2 or 3 where Y1, Y2and Y3are, independently, hydrogen, halogen, Cι-6alkyl, Cι-3haloalkyl, Cι-4(haloalkoxy)Cι.4alkyl, Cι-4(haloalkylthio)Cι-4alkyl, trimethylsilyl, CMalkenyl, C2- haloalkenyl or C3-6cycloalkyl (optionally substituted by one or more substituents each independently selected from halogen and Cι_2alkyl). 5. A compound of formula (I) as claimed in claim 1, 2, 3 or 4 where m = 0. 6. A compound of formula (I) as claimed in claim 1, 2, 3, 4 or 5 where Z is Cι-2alkylene [which may be optionally substituted by one or more substituents each independently selected from halogen, CMhaloalkyl and Cι-4haloalkoxy]. 7. A compound of formula (I) as claimed in claim 1, 2, 3, 4 5 or 6 where R7is in the 4' position. 8. A compound of formula (I) as claimed in claim 1, 2, 3, 4 5, 6 or 7 where n = 0. 9. A compound of formula (II): where R1, R2, R3, R4, R5, R , R7and n are as defined in claim 1 ; provided that when R1, R &amp;gt;2, R , IC and R0are each hydrogen and n is 0 then R 7' i■s not CH=C(H)CH2CO2H 10. A compound of formula (III) : where R2, R3, R4, R5, R6, R7and n are as defined in claim 1 and Hal is bromo, chloro or iodo; provided that the compound is not a compound of formula (Ilia) according to Table 0. 11. A composition for controlling microorganisms and preventing attack and infestation of plants therewith, wherein the active ingredient is a compound of formula (I) as claimed in claim 1 together with a suitable carrier. 2. A method of controlling or preventing infestation of cultivated plants by phytopathogenic microorganisms by application of a compound of formula (I) as claimed in claim 1 to plants, to parts thereof or the locus thereof.
法律状态
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member state=US20060100250    Event publication date=2005-06-22  Event code=WO/ENP  Event type=Entry into national phase  Entry into the national phase in: Corresponding cc:  Designated or member state=US     Event publication date=2005-06-22  Event code=WO/WWE  Event indicator=Pos  Event type=Entry into national phase  Wipo information: entry into national phase Corresponding cc:  Designated or member state=US     Event publication date=2006-05-11  Event code=WO/WWP  Event indicator=Pos  Event type=Examination events  Wipo information: published in national office Corresponding cc:  Designated or member state=US     Event publication date=2015-08-10  Event code=US/STCHG  Patent Status changed by the national office Corresponding cc:  Designated or member state=US  LEGAL DETAILS FOR DESIGNATED STATE VN0007344  Actual or expected expiration date=2023-12-15    Legal state=ALIVE    Status=GRANTED   Corresponding cc:  Designated or member state=VN Corresponding appl: VN2005001042  Application date in the designated or member state=2003-12-15   Application number in the designated or member state=2005VN-1001042 Corresponding cc:  Designated or member state=VN Corresponding pat: VN0007344  Publication stage code in the designated or member state=B  Publication date in the designated or member state=2008-12-25   Publication number in the designated or member state=VN---7344B    Event publication date=2008-12-25  Event code=VN/STCHG  Patent Status changed by the national office Corresponding cc:  Designated or member state=VN  LEGAL DETAILS FOR DESIGNATED STATE ZA200504644  Actual or expected expiration date=2023-12-15    Legal state=ALIVE    Status=GRANTED   Corresponding cc:  Designated or member state=ZA Corresponding appl: ZA200504644  Application date in the designated or member state=2005-06-07   Application number in the designated or member state=2005ZA-0004644 Corresponding cc:  Designated or member state=ZA Corresponding pat: ZA200504644  Publication stage code in the designated or member state=B  Publication date in the designated or member state=2007-03-28   Publication number in the designated or member state=ZA200504644    Event publication date=2005-06-07  Event code=WO/WWE  Event indicator=Pos  Event type=Entry into national phase  Wipo information: entry into national phase Corresponding cc:  Designated or member state=ZA     Event publication date=2007-03-28  Event code=ZA/STCHG  Patent Status changed by the national office Corresponding cc:  Designated or member state=ZA
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