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公开号/公开日
EP1763302 A2 2007-03-21 [EP1763302]EP1763302 B1 2013-03-06 [EP1763302] / 2007-03-212013-03-06
申请号/申请日
2005EP-0757532 / 2005-06-22
发明人
MAIENFISCH PETER;MOLLEYRES LOUIS-P;CASSAYRE JEROME;CEDERBAUM FREDRIK;CORSI CAMILLA;PITTERNA THOMAS;
申请人
SYNGENTA PARTICIPATIONS;
主分类号
IPC分类号
A01N-043/40C07D-211/06C07D-211/68C07D-213/04C07D-401/04C07D-401/12C07D-401/14
摘要
(EP1763302) The use of a compound of formula (I), Y is a single bond, C=O, C=S or S(O)<SUB>m</SUB> where m is 0, 1 or 2; the ring (II) is a 6 membered oaromatic ring or is a 5 or 6 membered heteroaromatic ring; Z and Z' are =C- or -N- provided that both are not N; R<SUP>1</SUP>, R<SUP>2</SUP> R<SUP>3</SUP> , R<SUP>3a</SUP>,<SUP/>R<SUP>4</SUP> , R<SUP>8</SUP> and Ra are specified organic groups and n and p are independently 0, 1, 2, 3 or 4; or salts or N-oxides thereof or compositions containing them in controlling insects, acarines, nematodes or molluscs.  Novel compounds are also provided.
机翻摘要
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地址
代理人
代理机构
;
优先权号
2004GB-0014438 2004-06-28 2005WO-IB02002 2005-06-22
主权利要求
(EP1763302) 1. A method of combating and controlling insects or acarines which comprises applying to a pest, to a locus of a pest, or to a plant susceptible to attack by a pest an insecticidally or acaricidally effective amount of a compound of formula I (see diagramm) where Y is a single bond, C=O or C=S;  the ring (see diagramm) is a benzene, pyridine, pyrimidine, pyrazine, pyridazine, triazine, pyrrole, imidazole, quinoline, isoquinoline, thiophene, pyrazole, oxazole, thiazole, isoxazole, isothiazole, [1,2,3]triazole, [1,2,3]oxadiazole or [1,2,3]thiadiazole ring;  R **1 is hydrogen, C 1-6 alkyl, C 1-6 cyanoalkyl, C 1-6 haloalkyl, C 3-7 cycloalkyl(C 1-4)alkyl, C 1-6 alkoxy(C 1-6)alkyl, heteroaryl(C 1-6)alkyl (wherein the heteroaryl group may be optionally substituted by halo, nitro, cyano, C 1-6 alkyl, C 1-6 haloalkyl, C 1-6 alkoxy, C 1-6 haloalkoxy, C 1-6 alkylsulfonyl, C 1-6 alkylsulfinyl, C 1-6 alkylthio, C 1-6 alkoxycarbonyl, C 1-6 alkylcarbonylamino, arylcarbonyl, or two adjacent positions on the heteroaryl system may be cyclised to form a 5, 6 or 7 membered carbocyclic or heterocyclic ring, itself optionally substituted with halogen), aryl(C 1-6)alkyl (wherein the aryl group may be optionally substituted by halo, nitro, cyano, C 1-6 alkyl, C 1-6 haloalkyl, C 1-6 alkoxy, C 1-6 haloalkoxy, C 1-6 alkylsulfonyl, C 1-6 alkylsulfinyl, C 1-6 alkylthio, C 1-6 alkoxycarbonyl, C 1-6 alkylcarbonylamino, arylcarbonyl, or two adjacent positions on the aryl system may be cyclised to form a 5, 6 or 7 membered carbocyclic or heterocyclic ring, itself  optionally substituted with halogen), C 1-6 alkylcarbonylamino(C 1-6)alkyl, aryl (which may be optionally substituted by halo, nitro, cyano, C 1-6 alkyl, C 1-6 haloalkyl, C 1-6 alkoxy, C 1-6 haloalkoxy, C 1-6 alkylsulfonyl, C 1-6 alkylsulfinyl, C 1-6 alkylthio, C 1-6 alkoxycarbonyl, C 1-6 alkylcarbonylamino, arylcarbonyl, or two adjacent positions on the aryl system may be cyclised to form a 5, 6 or 7 membered carbocyclic or heterocyclic ring, itself optionally substituted with halogen), heteroaryl (which may be optionally substituted by halo, nitro, cyano, C 1-6alkyl, C 1-6 haloalkyl, C 1-6 alkoxy, C 1-6 haloalkoxy, C 1-6 akylsulfonyl, C 1-6 alkylsulfinyl, C 1-6 alkylthio, C 1-6 alkoxycarbonyl, C 1-6 alkylcarbonylamino, arylcarbonyl, or two adjacent positions on the heteroaryl system may be cyclised to form a 5, 6 or 7 membered carbocyclic or heterocyclic ring, itself optionally substituted with halogen), C 1-6 alkoxy, C 1-6 haloalkoxy, phenoxy (wherein the phenyl group is optionally substituted by halogen, C 1-4 alkyl, C 1-4 alkoxy, C 1-4 haloalkyl, C 1-4 haloalkoxy, CN, NO 2, aryl, heteroaryl, amino or dialkylamino), heteroaryloxy (optionally substituted by halo, nitro, cyano, C 1-6 alkyl, C 1-6 haloalkyl, C 1-6 alkoxy or C 1-6 haloalkoxy), heterocyclyloxy (optionally substituted by halo, C 1-6 alkyl, C 1-6 haloalkyl, C 1-6 alkoxy or C 1-6 haloalkoxy), cyano, C 2-6 alkenyl, C 2-6 alkynyl, C 3-6 cycloalkyl, C 5-7 cycloalkenyl, heterocyclyl (optionally substituted by halo, nitro, cyano, C 1-6 alkyl, C 1-6 haloalkyl, C 1-6 alkoxy or C 1-6 haloalkoxy), C 1-6 alkylthio, C 1-6 haloalkylthio or NR **13R **14 where R **13 and R **14 are independently hydrogen, C 1-6 alkyl, C 1-6 haloalkyl, C 1-6 alkoxy(C 1-6)alkyl, phenyl (which may be optionally substituted by halogen, C 1-4 alkyl, C 1-4 alkoxy, C 1-4 haloalkyl, C 1-4 haloalkoxy, CN, NO 2, aryl, heteroaryl, amino, dialkylamino or C 1-4 alkoxycarbonyl), phenyl (C 1-6)alkyl (wherein the phenyl group may be optionally substituted by halogen, C 1-4 alkyl, C 1-4 alkoxy, C 1-4 haloalkyl, C 1-4 haloalkoxy, CN, NO 2, aryl, heteroaryl, amino, dialkylamino, C 1-6 alkylsulfonyl, C 1-6 alkoxycarbonyl, or two adjacent positions on the phenyl ring may be cyclised to form a 5, 6 or 7 membered carbocyclic or heterocyclic ring, itself optionally substituted with halogen), heteroaryl (C 1-6)alkyl (wherein the heteroaryl group may be optionally substituted by halo, nitro, cyano, C 1-6 alkyl, C 1-6 haloalkyl, C 1-6 alkoxy, C 1-6 haloalkoxy, C 1-6 alkylsulfonyl, C 1-6 alkylsulfinyl, C 1-6 alkylthio, C 1-6 alkoxycarbonyl, C 1-6 alkylcarbonylamino, arylcarbonyl, or two adjacent positions on the heteroaryl system may be cyclised to form a 5, 6 or 7 membered carbocyclic or heterocyclic ring, itself optionally substituted with halogen) or heteroaryl (which may be optionally substituted by halo, nitro, cyano, C 1-6 alkyl, C 1-6 haloalkyl, C 1-6 alkoxy or C 1-6 haloalkoxy, C 1-4 alkoxycarbonyl C 1-6 alkylcarbonylamino, phenyloxycarbonylamino (wherein the phenyl group is optionally substituted by halogen, C 1-4 alkyl, C 1-4 alkoxy, C 1-4 haloalkyl, C 1-4 haloalkoxy, CN, NO 2, aryl, heteroaryl, amino or dialkylamino), amino, C 1-6 alkylamino or phenylamino (wherein the phenyl group is optionally substituted halogen, C 1-4 alkyl, C 1-4 alkoxy, C 1-4 haloalkyl, C 1-4 haloalkoxy, CN, NO 2, aryl, heteroaryl, amino or dialkylamino));  R **2 is is hydrogen, hydroxy, C 1-6 alkyl or C 1-6 haloalkyl;  R **3 is hydrogen, hydroxy, halogen, C 1-6 alkyl or C 1-6 haloalkyl;  R **3a is H or R **3 and R **3a together form a bond;  each R **4 is independently halogen, cyano, C 1-8 alkyl, C 1-8 haloalkyl, C 1-8 alkoxy, C 1-6 haloalkoxy, cyanoalkyl, C 1-6 alkoxy(C 1-6)alkyl, C 3-7 cycloakyl(C 1-6)alkyl, C 5-6 cycloalkenyl(C 1-6)alkyl, C 3-6 alkenyloxy(C 1-6)alkyl, C 3-6 alkynyloxy(C 1-6)alkyl, aryloxy(C 1-6)alkyl, C 1-6 carboxyalkyl, C 1-6 alkylcarbonyl(C 1-6)alkyl, C 2-6 alkenylcarbonyl(C 1-6)alkyl, C 2-6 alkynylcarbonyl(C 1-6)-alkyl, C 1-6 alkoxycarbonyl(C 1-6)alkyl, C 3-6 alkenyloxycarbonyl(C 1-6)akyl, C 3-6 alkynyloxycarbonyl(C 1-6)alkyl, aryloxycarbonyl(C 1-6)alkyl, C 1-6 alkylthio(C 1-6)alkyl, C 1-6 alkylsulfinyl(C 1-6)alkyl, C 1-6 alkylsulfonyl(C 1-6)alkyl, aminocarbonyl(C 1-6)alkyl, C 1-6 alkylaminocarbonyl(C 1-6)alkyl, di(C 1-6)alkylaminocarbonyl(C 1-6)alkyl, phenyl(C 1-4)alkyl (wherein the phenyl group is optionally substituted by halogen, C 1-4alkyl, C 1-4 alkoxy, C 1-4 haloalkyl, C 1-4 haloalkoxy, CN, NO 2, aryl, heteroaryl, amino or dialkylamino), heteroaryl(C 1-4)alkyl (wherein the heteroaryl group is optionally substituted by halo, nitro, cyano, C 1-6 alkyl, C 1-6 haloalkyl, C 1-6 alkoxy or C 1-6 haloalkoxy), heterocyclyl(C 1-4)alkyl (wherein the heterocyclyl group is optionally substituted by halo, nitro, cyano, C 1-6 alkyl, C 1-6 haloalkyl, C 1-6 alkoxy or C 1-6 haloalkoxy), C 2-6 alkenyl, aminocarbonyl(C 2-6)alkenyl, C 1-6alkylaminocarbonyl(C 2-6)alkenyl, di(C 1-6)alkylaminocarbonyl(C 2-6)alkenyl, phenyl(C 2- 4)-alkenyl, (wherein the phenyl group is optionally substituted by halogen, C 1-4 alkyl, C 1-4 alkoxy, C 1-4 haloalkyl, C 1-4 haloalkoxy, CN, NO 2, aryl, heteroaryl, amino or dialkylamino), C 2-6 alkynyl, trimethylsilyl(C 2-6)alkynyl, aminocarbonyl(C 2-6)alkynyl, C 1-6 alkylaminocarbonyl(C 2-6)alkynyl, di(C 1-6)alkylaminocarbonyl(C 2-6)alkynyl, C 1-6 alkoxycarbonyl, C 3-7 cycloalkyl, C 3-7 halocycloalkyl, C 3-7 cyanocycloalkyl, C 1-3 alkyl(C 3- 7)-cycloakyl, C 1-3akyl(C 3-7)halocycloalkyl,phenyl (optionally substituted by halogen, C 1-4 alkyl, C 1-4 alkoxy, C 1-4 haloalkyl, C 1-4 haloalkoxy, CN, NO 2, aryl, heteroaryl, amino or dialkylamino), heteroaryl (optionally substituted by halo, nitro, cyano, C 1-6 alkyl, C 1-6 haloalkyl, C 1-6 alkoxy or C 1-6 haloalkoxy), heterocyclyl (wherein the heterocyclyl group is optionally substituted by halo, nitro, cyano, C 1-6 alkyl, C 1-6 haloalkyl, C 1-6 alkoxy or C 1-6 haloalkoxy), or 2 adjacent groups R **4 together with the carbon atoms to which they are attached form a 4, 5, 6 or 7 membered carbocylic or heterocyclic ring which may be optionally substituted by halogen, C 1-8 alkoxy, C 1-6 haloalkoxy, phenoxy (optionally substituted by halo, nitro, cyano, C 1-6 alkyl, C 1-6 haloalkyl, C 1-6 alkoxy or C 1-6 haloalkoxy), heteroaryloxy (optionally substituted by halo, nitro, cyano, C 1-6 alkyl, C 1-6 haloalkyl, C 1-6 alkoxy or C 1-6 haloalkoxy), C 1-8 alkylthio or R **19R **20N where R **19 and R **20 are, independently, hydrogen, C 1-8 alkyl, C 3-7 cycloalkyl, C 3-6 alkenyl, C 3-6 alkynyl, C 2-6 haloalkyl,  C 1-6 alkoxycarbonyl or R **19 and R **20 together with the N atom to which they are attached form a five, six or seven-membered heterocyclic ring which may contain one or two further heteroatoms selected from O, N or S and which may be optionally substituted by one or two C 1-6 alkyl groups; n is 0, 1, 2 or 3;  R **8 is C 1-10 alkyl, C 1-10 haloalkyl, aryl(C 1-6)alkyl (wherein the aryl group is optionally substituted by halogen, C 1-4 alkyl, C 1-4 alkoxy, C 1-4 haloalkyl, C 1-4haloalkoxy, CN, NO 2, aryl, heteroaryl, amino or dialkylamino), heteroaryl(C 1-6)alkyl (wherein the heteroaryl group is optionally substituted by halogen, C 1-4 alkyl, C 1-4 alkoxy, C 1-4 haloalkyl, C 1-4 haloalkoxy, CN, NO 2, aryl, heteroaryl, amino or dialkylamino), arylcarbonyl-(C 1-6)alkyl (wherein the aryl group may be optionally substituted by halogen, C 1-4 alkyl, C 1-4 alkoxy, C 1-4 haloalkyl, C 1-4 haloalkoxy, CN, NO 2, aryl, heteroaryl, amino or dialkylamino and the alkyl group may be optionally substituted by aryl), C 2-8 alkenyl, C 2-8 haloalkenyl, aryl(C 2-6)-alkenyl (wherein the aryl group is optionally substituted halogen, C 1-4 alkyl, C 1-4 alkoxy, C 1-4 haloalkyl, C 1-4 haloalkoxy, CN, NO 2, aryl, heteroaryl, amino or dialkylamino, C 1-6 alkoxycarbonyl, or two adjacent substituents can cyclise to form a 5, 6 or 7 membered carbocyclic or heterocyclic ring), heteroaryl(C 2-6)-alkenyl (wherein the heteroaryl group is optionally substituted halogen, C 1-4 alkyl, C 1-4 alkoxy, C 1-4 haloalkyl, C 1-4 haloalkoxy, CN, NO 2, aryl, heteroaryl, amino or dialkylamino, C 1-6 alkoxycarbonyl, or two adjacent substituents can cyclise to form a 5, 6 or 7 membered carbocyclic or heterocyclic ring), C 2-6 alkynyl, phenyl(C 2- 6)alkynyl (wherein the phenyl group is optionally substituted by halogen, C 1-4 alkyl, C 1-4 alkoxy, C 1-4 haloalkyl, C 1-4 haloalkoxy, CN, NO 2, aryl, heteroaryl, amino or dialkylamino), C 3-7 cycloalkyl, C 1-6 alkoxycarbonyl, C 1-6 alkylcarbonyl, C 1-6 haloalkylcarbonyl or aryl(C 2-6)alkenylcarbonyl (wherein the aryl group may be optionally substituted halogen, C 1-4 alkyl, C 1-4 alkoxy, C 1-4 haloalkyl, C 1-4 haloalkoxy, CN, NO 2, aryl, heteroaryl, amino or dialkylamino), or -C(R **51)(R **52)-[CR **53=CR  **54]z-R **55 where z is 1 or 2, R **51 and R **52 are each independently H, halo or C 1-2 alkyl, R **53 and R **54 are each independently H, halogen, C 1-4 alkyl or C 1-4 haloalkyl and R **55 is optionally substituted aryl or optionally substituted heteroaryl or salts or N-oxides thereof, provided the method is not for the treatment of the human or animal body by therapy. 2. A method according to claim 1 wherein the ring (see diagramm) is a benzene, pyridine, pyrimidine, pyrazine, thiophene or pyrazole ring. 3. A method according to claim 1 or claim 2 wherein Y is a single bond or C=O. 4. A method according to any preceding claim wherein R **1 is C 1-6 alkyl, C 1-6 haloalkyl, C 1- 6 alkoxy(C 1-6)alkyl, heteroaryl(C 1-3)alkyl (wherein the heteroaryl group may be optionally substituted by halo, nitro, cyano, C 1-6 alkyl, C 1-6 haloalkyl, C 1-6 alkoxy, C 1-6 haloalkoxy, C 1-6 alkylsulfonyl, C 1-6 alkoxycarbonyl, or two adjacent positions on the heteroaryl system may be cyclised to form a 5, 6 or 7 membered carbocyclic or heterocyclic ring, itself optionally substituted with halogen), phenyl(C 1-3)alkyl (wherein the phenyl group may be optionally substituted by halogen, C 1-4 alkyl, C 1-4 alkoxy, C 1-4 haloalkyl, C 1-4 haloalkoxy, CN, NO 2, aryl, heteroaryl, amino, dialkylamino, C 1-6 alkylsulfonyl, C 1-6 alkoxycarbonyl, or two adjacent positions on the phenyl ring may be cyclised to form a 5, 6 or 7 membered carbocyclic or heterocyclic ring, itself optionally substituted with halogen), phenyl (which may be optionally substituted by halogen, C 1-4 alkyl, C 1-4 alkoxy, C 1-4 haloalkyl, C 1-4 haloalkoxy, CN, NO 2, aryl, heteroaryl, amino, dialkylamino, C 1-6 alkylsulfonyl, C 1-6 alkoxycarbonyl, or two adjacent positions on the phenyl ring may be cyclised to form a 5, 6 or 7 membered carbocyclic or heterocyclic ring, itself optionally substituted with halogen), heteroaryl (which may be optionally substituted by halo, nitro, cyano, C 1-6 alkyl, C 1-6 haloalkyl, C 1-6 alkoxy, C 1-6 haloalkoxy, C 1-6 alkylsulfonyl, C 1-6 alkoxycarbonyl, or two adjacent positions on the heteroaryl system may be cyclised to form a 5, 6 or 7 membered carbocyclic or heterocyclic ring, itself optionally substituted with halogen), C 1-6 alkoxy, C 1-6 haloalkoxy, C 2-6 alkenyl, heterocyclyl (optionally substituted by halo, cyano, C 1-6 akyl, C 1-6 haloakyl, C 1-6 alkoxy or C 1-6 haloalkoxy), C 1-6 alkylthio, C 1-6 haloalkylthio or NR **13R **14 where R **13 and R **14 are independently hydrogen, C 1-6 alkyl or C 1-6haloalkyl, C 1-6 alkoxy(C 1-6)alkyl, C 2-6 alkylcarbonyl, phenylcarbonyl, (where the phenyl is optionally substituted by halogen, C 1-4 alkyl, C 1-4 alkoxy, C 1-4 haloalkyl, C 1-4 haloalkoxy, CN, NO 2, aryl, heteroaryl, amino or dialkylamino), phenyl(C 1-3)alkyl (wherein the phenyl group may be optionally substituted by halogen, C 1-4 alkyl, C 1-4 alkoxy, C 1-4 haloalkyl, C 1-4 haloalkoxy, CN, NO 2, aryl, heteroaryl, amino, dialkylamino, C 1-6 alkylsulfonyl, C 1-6 alkoxycarbonyl, or two adjacent positions on the phenyl ring may be cyclised to form a 5, 6 or 7 membered carbocyclic or heterocyclic ring, itself optionally substituted with halogen) or heteroaryl(C 1-3)alkyl (wherein the heteroaryl group may be optionally substituted by halo, nitro, cyano, C 1-6 alkyl, C 1-6 haloalkyl, C 1-6 alkoxy, C 1-6 haloalkoxy, C 1-6 akylsulfonyl, C 1-6 akylsulfinyl, C 1-6 alkylthio, C 1-6 alkoxycarbonyl, C 1-6 alkylcarbonylamino, arylcarbonyl, or two adjacent positions on the heteroaryl system may be cyclised to form a 5, 6 or 7 membered carbocyclic or heterocyclic ring, itself optionally substituted with halogen). 5. A method according to any preceding claim wherein R **2 is hydrogen, C 1-4 alkyl or C 1-4 haloalkyl. 6. A method according to any preceding claim wherein each R **4 is independently halogen, cyano, C 1-8 alkyl, C 1-8 haloalkyl, C 1-8 cyanoalkyl, C 1-6 alkoxy(C 1-6)akyl, C 2-6 alkynyl, trimethylsilyl(C 2- 6)alkynyl, C 1-6 alkoxycarbonyl, C 3-7 cycloalkyl, C 1-3 alkyl (C 3-7) cycloalkyl, phenyl (optionally substituted by halogen, C 1-4 alkyl, C 1-4 alkoxy, C 1-4 haloalkyl, C 1-4 haloalkoxy, CN, NO 2, aryl, heteroaryl, amino or dialkylamino), heterocyclyl (optionally substituted by halo, nitro, cyano, C 1-6 alkyl, C 1-6 haloalkyl, C 1- 6 alkoxy or C 1-6 haloalkoxy), C 1-8 alkoxy, C 1-6 haloalkoxy, phenoxy (optionally substituted by halogen, C 1-4 akyl, C 1-4 alkoxy, C 1-4 haloalkyl, C 1-4 haloalkoxy, CN, NO 2, aryl, heteroaryl, amino or dialkylamino), heteroaryloxy (optionally substituted by halo, nitro, cyano, C 1-3 alkyl, C 1-3 haloalkyl, C 1-3 alkoxy or C 1-3 haloalkoxy), di(C 1-8)alkylamino, or 2 adjacent groups R **4 together with the carbon atoms to which they are attached form a 4, 5, 6 or 7 membered carbocylic or heterocyclic ring which may be optionally substituted by halogen; n is 0, 1, 2 or 3. 7. A method according to any preceding claim wherein R **8 is phenyl(C 1-4)alkyl (wherein the phenyl group is optionally substituted by halogen, C 1-4 alkyl, C 1-4 alkoxy, C 1-4 haloalkyl, C 1-4 haloalkoxy, CN, NO 2, aryl, heteroaryl, amino or dialkylamino), heteroaryl(C 1-6)alkyl (wherein the heteroaryl group is optionally substituted halogen, C 1-4 alkyl, C 1-4 alkoxy, C 1-4 haloalkyl, C 1-4 haloalkoxy, CN, NO 2, aryl, heteroaryl, amino or dialkylamino), phenyl(C 2-6)alkenyl (wherein the phenyl group is optionally substituted by halogen, C 1-4 alkyl, C 1-4 alkoxy, C 1-4 haloalkyl, C 1-4 haloalkoxy, CN, NO 2, aryl, heteroaryl, amino or dialkylamino), heteroaryl(C 2-6)alkenyl (wherein the heteroaryl group is optionally substituted by halogen, C 1-4 alkyl, C 1-4 alkoxy, C 1-4 haloalkyl, C 1-4 haloalkoxy, CN, NO 2, aryl, heteroaryl, amino or dialkylamino) or phenyl(C 2-6)alkynyl (wherein the phenyl group is optionally substituted by halogen, C 1- 4 alkyl, C 1-4 alkoxy, C 1-4 haloalkyl, C 1-4 haloalkoxy, CN, NO 2, aryl, heteroaryl, amino or dialkylamino, or -C(R **51)(R **52)-[CR **53=CR **54]z-R **55 where z is 1 or 2, R **51 and R **52 are each independently H, halo or C 1-2 alkyl, R **53 and R **54 are each independently H, halogen, C 1-4 alkyl or C 1-4 haloalkyl and R **55 is optionally substituted aryl or optionally substituted heteroaryl. 8. A method according to any proceding claim wherein R **3 is hydrogen, hydroxy, halogen, C 1-4 alkyl or C 1-4 haloalkyl. 9. A compound of formula I' (see diagramm) wherein; the ring (see diagramm) and R **1, R **2, R **3, R **3a, R **4, Y and n are as defined in relation to formula I in claim 1 and R **8 is -C(R **51)(R **52)-[CR **53=CR **54]z-R **55 where z is 1 or 2, R **51 and R **52 are each independently H or C 1-2 alkyl, R **53 and R **54 are each independently H, halogen, C 1-4 alkyl or C 1-4 haloalkyl and R **55 is phenyl substituted by halogen, C 1-4 alkyl, C 1-4 alkoxy, C 1-4 haloalkyl, C 1-4 haloalkoxy, CN, NO 2, aryl, heteroaryl, amino or dialkylamino or heteroaryl substituted by halogen, C 1-4 alkyl, C 1-4 alkoxy, C 1-4 haloalkyl, C 1-4 haloalkoxy, CN, NO 2 aryl, heteroaryl, amino or dialkylamino or salts or N-oxides thereof. 10. An insecticidal and acaricidal composition comprising an insecticidally or acaricidally effective amount of a compound of formula I' as defined in claim 9.
法律状态
(EP1763302) LEGAL DETAILS FOR EP1763302  Actual or expected expiration date=2025-06-22    Legal state=ALIVE    Status=GRANTED     Event publication date=2005-06-22  Event code=EP/APP  Event indicator=Pos  Event type=Examination events  Application details  Application country=EP EP05757532  Application date=2005-06-22  Standardized application number=2005EP-0757532     Event publication date=2007-03-21  Event code=EP/A2  Event type=Examination events  Application published without search report  Publication country=EP  Publication number=EP1763302  Publication stage Code=A2  Publication date=2007-03-21  Standardized publication number=EP1763302     Event publication date=2007-03-21  Event code=EP/17P  Event indicator=Pos  Event type=Examination events  Request for examination filed Pruefungsantrag gestellt  Effective date of the event=2007-01-29     Event publication date=2007-03-21  Event code=EP/AK  Event indicator=Pos  Event type=Designated states  Designated contracting states: Benannte vertragsstaaten AT BE BG CH CY CZ DE DK EE ES FI FR GB GR HU IE IS IT LI LT LU MC NL PL PT RO SE SI SK TR    Event publication date=2007-03-21  Event code=EP/AX  Event indicator=Pos  Event type=Designated states  Extension of the European patent to Request for extension of the european patent to AL BA HR LV MK YU    Event publication date=2009-04-08  Event code=EP/17Q  Event indicator=Pos  Event type=Examination events  First examination report Erster pruefungsbescheid  Effective date of the event=2009-03-04     Event publication date=2012-08-22  Event code=EP/RIC1  Event type=Classification modifications  Event type=Corrections  Classification (correction) IPC: C07D 211/06        20060101ALI20120716BHEP    Event publication date=2012-08-22  Event code=EP/RIC1  Event type=Classification modifications  Event type=Corrections  Classification (correction) IPC: C07D 401/14        20060101ALI20120716BHEP    Event publication date=2012-08-22  Event code=EP/RIC1  Event 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indicating Not In Force  Event type=Payment or non-payment notifications  Lapsed in a contracting state announ(...)
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