Benzoyl derivatives, method for producing them and their use as herbicides and plant growth regulators 机翻标题: 暂无翻译,请尝试点击翻译按钮。

公开号/公开日
WO200014087 A1 2000-03-16 [WO200014087] / 2000-03-16
申请号/申请日
1999WO-EP06259 / 1999-08-26
发明人
VAN ALMSICK ANDREAS;WILLMS LOTHAR;AULER THOMAS;BIERINGER HERMANN;ROSINGER CHRISTOPHER;
申请人
HOECHST SCHERING AGREVO;
主分类号
IPC分类号
A01N-043/18A01N-043/40A01N-043/50A01N-043/54A01N-043/56A01N-043/60A01N-043/80A01N-057/12A01P-013/00C07D-333/56C07D-335/06C07D-335/16C07D-409/04C07D-409/06C07D-409/12C07D-409/14C07D-413/12C07D-413/14C07D-417/12C07D-417/14C07F-009/09C07F-009/6553C07F-009/6574
摘要
(WO200014087) The invention relates to benzoyl derivatives of general formula (I), to a method for producing them and to their use as herbicides and plant growth regulators.  In said general formula (I), R<1>, R<2>, R<3>, R<4> and R<5> represent different organic radicals, Q represents an isothiazole, isoxazole, cyclohexanedione or beta -ketonitrile radical and A, B, E and X represent mono- or polyatomic divalent units.
机翻摘要
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地址
代理人
代理机构
;
优先权号
1998DE-1040337 1998-09-04
主权利要求
(WO200014087) Claims: Benzoyl derivatives of the general formula (I),  (I) where π n A radical of the formula Q (iii), (iii) or (IV)  (II) (III) (IV) R1, R2, R3independently of one another hydrogen, hydroxy, Thio, amino, Cyano, Nitro, halogen or an optionally substituted hydrocarbon radical, optionally in addition one or more, identical or different heteroatoms from the group consisting of oxygen, sulfur, nitrogen, fluorine, chlorine, bromine and iodine comprises; R4hydrogen, Cyano, alkyl, alkenyl, alkynyl, Cycloalkyl, Alkoxycarbonyl, phenyl, where the six last-mentioned groups is optionally substituted by one or more, identical or different radicals from the group consisting of halogen, Nitro, Cyano, alkyl, Cycloalkyl, alkenyl, alkynyl, alkoxy and Alkylthio are substituted; R5an optionally monosubstituted or polysubstituted by identical or different radicals substituted heteroaryl -, Heterocyclyl or aryl, or a radical from the group - O-N=Cr ' Rm, - P (=O) (ori) (Rj), - P (=O) (orj) (ork) or 0 ^ (CH2)m or, in the case, that E is a bond and I represents zero, R can5also is hydroxy, A is a divalent unit from the group consisting of O, S, so, so2, NRa, CHRaand CRaRb; A saturated or containing one or more multiple bonds B and from one to four carbon atoms to form a chain, optionally substituted by alkyl, haloalkyl, alkoxy, haloalkoxy or by an optionally substituted by alkyl, haloalkyl, alkoxy, haloalkoxy, halogen, Cyano or Nitro-substituted phenyl radical is substituted; E is a bond, a saturated or one or more multiple bonds - to six-membered chain consisting of divalent units containing a group C, crC, crcRd, N, nrC, S, so, so2, O and co; Is a divalent unit from the group consisting of X O, S and NRe; R6Alkylthio, haloalkylthio, alkylsulphinyl, haloalkylsulphinyl, alkylsulphonyl, haloalkylsulphonyl, Cyano, Cyanato, Thiocyanato, halogen or orf; Is a divalent unit from the group consisting of Y O, S, NH, N-alkyl or CHR7; R7hydrogen, tetrahydropyran 3-yl, tetrahydropyran-4-yl, Tetrahydrothiopyran - 3-yl, alkyl, Cycloalkyl, alkoxy, Alkoxyalkyl, Alkylcarbonyl, Alkoxycarbonyl, Alkylthio, phenyl, wherein the hydrocarbon portion of the eight last-mentioned radicals optionally substituted by one or more, identical or different radicals from the group consisting of halogen, Alkylthio and Alkyloxy is, or two residues bound to a common carbon atom R7form a chain from the group consisting of OCH2CH2O, OCH2CH2CH2O, sch2CH2S and sch2CH2CH2S, said optionally substituted by one to four methyl groups is, or two directly adjacent carbon atoms bonded radicals R7form a bond with the carbon atoms carrying them form an optionally substituted or 3 - to 6-membered ring; Z is a bond, a divalent unit from the group consisting of O, S, so, so2, NH, N-alkyl or CHR7, wherein Y and Z are not simultaneously represent a divalent moiety, an oxygen - as a chain link, - or sulfur atom and nitrogen; G1- G2a divalent unit from the group consisting of OCR9, SCR9and NR10COR11, wherein the ring system is to be carried out so the oring, that the carbon atom of this divalent unit is in each case via a double bond to the carbon atom of the ring system; R8hydrogen, alkyl or Alkoxycarbonyl; R9hydrogen, alkyl, Cycloalkyl, haloalkyl or halocycloalkyl; R10hydrogen, alkyl, alkenyl, alkynyl, Cycloalkyl, phenyl, benzyl, where the six last-mentioned groups is optionally substituted by one or more, identical or different radicals from the group consisting of halogen, Cyano, Nitro and alkoxy are optionally substituted; R11hydrogen, Formyl, alkyl, haloalkyl, Alkoxyalkyl or a group L-R12; A divalent moiety L is selected from the group SO2, CO, CHR9CO or CR9Rh; R12alkyl, haloalkyl, alkoxy, haloalkoxy, Alkylamino, Dialkylamino, Cycloalkyl or a gegegenes if substituted by one or more, identical or different radicals from the group consisting of Cyano, Nitro, alkyl, alkoxy, haloalkyl and haloalkoxy-substituted phenyl; Raand Rbindependently of one another hydrogen, halogen, Cyano, Nitro, Formyl, alkyl, Cycloalkyl, alkenyl, alkynyl, Alkylcarbonyl and Alkylsulfonyl, wherein the hydrocarbon portion of the six last-mentioned radicals optionally substituted by one or more, identical or different radicals from the group consisting of halogen, Nitro, Cyano, alkyl, Cycloalkyl, alkenyl, alkynyl, alkoxy and Alkylthio is; Rcand Rdindependently of one another hydrogen, halogen, nitro, Cyano, alkyl, haloalkyl, Cycloalkyl, alkenyl, haloalkenyl, alkynyl, haloalkynyl, alkoxy, haloalkoxy, Alkylthio, haloalkylthio, Alkylcarbonyl, haloalkylcarbonyl, Alkoxycarbonyl, haloalkoxy carbonyl, Aminocarbonyl, Alkylaminocarbonyl, Dialkylaminocarbonyl, haloalkylcarbonyl amino, Alkylcarbonyl-N-alkylamino, Alkylsulfonyl, Alkylsulfinyl, alkylsulfonylamino, haloalkylsulfonyl, haloalkyl, alkylsulfonylamino and Alkylsulfonyl-N-alkylamino; Rθhydrogen, Formyl, alkyl, Cycloalkyl, alkenyl, alkynyl, Alkylcarbonyl and Alkylsulfonyl, wherein the hydrocarbon portion of the six last-mentioned radicals optionally substituted by one or more, identical or different radicals from the group consisting of halogen, Nitro, Cyano, alkyl, Cycloalkyl, alkenyl, alkynyl, alkoxy and Alkylthio may be substituted; Rfhydrogen, alkyl, haloalkyl, Alkoxyalkyl, Formyl, Alkylcarbonyl, Alkoxycarbonyl, Alkylaminocarbonyl, Dialkylaminocarbonyl, Alkylsulfonyl, haloalkylsulfonyl, Benzoyl or Phenylsulfonyl, where the aromatic part of the two last-mentioned radicals optionally substituted by one or more, identical or different radicals from the group consisting of alkyl, haloalkyl, alkoxy, haloalkoxy, halogen, Cyano or by Nitro and; R9and Rhare each independently hydrogen or alkyl; R′ and Rkindependently of one another hydrogen or Rj; Rjalkyl, alkenyl, haloalkyl, haloalkenyl, phenyl, benzyl, where these six mentioned radicals may be optionally substituted by one or more, identical or different radicals from the group consisting of halogen, cyano, Nitro, (Cι-C4) - alkyl, (C1 - C4) - alkoxy, halo - (crc4) - alkyl or halo - (crc4) - alkoxy substituted by; R1and Rmindependently of one another hydrogen or substituted by one or more, identical or different radicals R1substituted alkyl, alkenyl, alkynyl, haloalkyl, haloalkenyl or haloalkynyl, or R1and R form together with the carbon atom, to which they are attached to, a 3 -, 4 -, 5 -, 6 -, 7 - or 8-membered saturated or partially unsaturated ring, optionally incorporating one to three heteroatoms from the group of oxygen, sulfur and nitrogen and is optionally substituted by one or more, identical or different radicals R1is substituted; 0 I or 1; m 0, 1 or 2; n is 0, 1, 2 or 3; v 1 or 2; w is 0, 1, 2, 3 or 4 means, with the proviso, that a) the compound 4 - [2- Tetrahydrofuryi] methyloxy-5.8-dimethyl-6 - [(cyclohexyl - 2.6-dioxo) carbonyl] -1, 2, 3, 4-tetrahydro-1λ6- thiochromen-1, 1-dione is not intended to be included as defined above, and b) in R5aryl is not phenyl, when E is methylene and G1in G1- G2represents sulfur. 2. Benzoyl derivatives according to claim 1, wherein R1, R2, R3are independently hydrogen, alkyl, alkenyl, alkynyl, Cycloalkyl, Cycloalkenyl, cycloalkylalkyl, Cycloalkyl alkenyl, alkynyl Cycloalkyl, aryl, Arylalkyl, Arylalkenyl, arylalkynyl, heteroaryl, Heteroarylalkyl, Heteroarylalkenyl, heteroarylalkynyl, Heterocyclyl, heterocyclylalkyl, Heterocyclyl-alkenyl, Heterocyclyl-alkynyl, hydroxy, alkoxy, Alkenyloxy, Alkinyioxy, Cycloalkoxy, cycloalkylalkoxy, Cycloalkyl Alkenyloxy, alkynyloxy Cycloalkyl, cycloalkene yloxy, Aryloxy, Arylalkoxy, Alkenyloxy or aryl, aryl alkynyloxy, Heteroaryloxy, Heteroarylalkoxy, Alkenyloxy heteroaryl, heteroaryl alkynyloxy, heterocyclyloxy, heterocyclylalkoxy, alkenyloxycarbonyl Heterocyclyl, Heterocyclyl thioalkynyloxy, Thio, Alkylthio, Alkenylthio, alkynylthio, cycloalkylthio, Cycloalkyl-alkyl-Thio, Cycloalkyl Alkenylthio, alkynylthio Cycloalkyl, cyclo-Alkenylthio, Arylthio, arylalkylthio, Arylalkenyl Thio, aryl Thio alkynyl, Heteroarylthio, Heteroaryialkylthio, heteroaryl Alkenylthio, alkynylthio heteroaryl, Heterocyclyl Thio, Thio-Heterocyclyl-alkyl, Heterocyclyl Alkenylthio, alkynylthio Heterocyclyl, amino, optionally substituted Mono - or Dialkylamino, Mono - or Diarylamino or substituted, Mono - or Di - Heteroarylamino optionally substituted, - N - - N alkyl optionally substituted arylamino, N - - N - alkyl optionally substituted Heteroarylamino, Alkenylamino, Alkinyiamino, cycloalkylamino, cycloalkenylamino, Heterocyclyl alkylamino, Alkenylamino Heterocyclyl, Alkylsulfonyl, Alkenylsulfonyl, alkynylsulfonyl, cycloalkylsulfonyl, Cycloalkyl-alkyl-sulfonyl, sulfonyl Cycloalkyl alkenyl, alkynyl Cycloalkyl sulfonyl, Arylsulfonyl, aryl sulfonyl, aryl sulfonyl alkenyl, alkynyl aryl sulfonyl, heteroaryl sulfonyl, heteroaryl alkyl sulfonyl, heteroaryl sulfonyl alkenyl, alkynyl heteroaryl sulfonyl, Heterocyclyl suif onyl, heterocyclylalkylsulfonyl, Heterocyclylalkenyisulfonyl, Heterocyclyl alkynyl sulfonyl, Alkylsulfinyl, Alkenyisulfinyl, Alkinyisulfinyl, cycloalkylsulfinyl, Cycloalkyl Alkylsulfinyl, alkenylsulfinyl Cycloalkyl, cyclo -alkyl alkynylsulfinyl, Arylsulfinyl, Alkylsulfinyl aryl, aryl alkenyl sulfinyl, aryl alkynyl sulfinyl, aryl-sulfinyl, heteroaryl Alkylsulfinyl, alkenylsulfinyl heteroaryl, heteroarytatkynyt sulfinyl, Heterocyclyl sulfinyl, aryl Alkylsulfinyl, alkenylsulfinyl Heterocyclyl, Heterocyclyl alkynyl sulfinyl, Aminosulfonyl, optionally substituted Mono - or dialkyl amino suif onyl, optionally substituted Mono - or Diaryiaminosulfonyl, optionally substituted Mono - or Di - Heteroarylamino sulfonyl, optionally substituted N - alkyl - N - arylaminosulfonyl, alkyl - heteroaryl - N N - optionally substituted amino sulfonyl, alkylsulfonyloxy, phenylsulfonyloxy alkenyl, alkynyl sulfonyloxy, Cycloalkylsulfonyioxy, Cycloalkyl-alkyl-sulfonyloxy, Cycloalkylalkenyisulfonyloxy, Cycloalkyl alkynyl sulfonyloxy, arylsulfonyloxy, aryl alkyl sulfonyloxy, aryl sulfonyloxy alkenyl, alkynyl aryl sulfonyloxy, heteroalylsulfonyloxy, heteroaryl alkyl sulfonyloxy, Heteroarylalkenyl sulfonyloxy, Heteroarytatkynyt sulfonyloxy, phenylsulfonyloxy heterocyclyl, heterocyclyl alkyl sulfonyloxy, heterocyclylalkylenyl sulfonyloxy, heterocyclyl alkynyl sulfonyloxy, Alkylsulfonylamino, alkenylsulfonylaminocarbonyloxystyrenes, alkynyl sulfonylamino, phenylsulfonylamino cycloalkyl, cycloalkyl-alkyl-sulfonylamino, cycloalkyl alkenylsulfonylaminocarbonyloxystyrenes, cycloalkylalkynyl sulfonylamino, Arylsulfonylamino, aryl-alkyl sulfonyl amino, aryl amino sulfonopropane alkenyl, alkynyl aryl sulfonylamino, heteroaryl sulfonyl amino, alkyl sulfonyl amino heteroaryl, heteroaryl alkenyl sulfonopropane amino, phenylsulphonylamino heteroarytatkynyt, N - alkylamino - Alkylsulfonyl, alkenylsulphonylamino Nalkylamino-, - N - alkynyl-sulfonyl-amino, - N - cycloalkyl-sulfonyl-amino, - N - alkyl-sulfonyl-amino, N - - cycloalkyl alkenylsulphonylamino alkylamino, - N - alkylamino Cycioalkylalkinylsulfonyl, - N - Arylsulfonyl alkylamino, - N - alkylamino heteroaryl sulfonyl, alkyl sulfonyl - N - aryl-amino, - N - alkylamino heteroaryl alkyl sulfonyl, aryl alkenyl sulfonopropane amino, heteroaryl amino sulfonopropane alkenyl, - alkynyl - aryl sulfonyl N alkylamino, - N - sulfonyl heteroarytatkynyt alkylamino, - N - heterocyclyl-sulfonyl-amino, heterocyclyl alkyl sulfonylamino, N - alkylamino - alkenylsulphonylamino heterocyclyl, - N - alkynylsulfonyl heterocyclyl alkylamino, Alkylcarbonyl, Alkenylcarbonyl, Alkinylcarbonyl, Cycloalkylcarbonyl, Cycioalkylalkylcarbonyl, cycloalkyl alkenyl carbonyl, cycloalkyl carbonyl alkynyl, Arylcarbonyl, Arylalkylcarbonyl, Arylalkenyicarbonyl, arylalkynyl carbonyl, Heteroarylcarbonyl, Heteroarylalkylcarbonyl, Heteroarylalkenyl, heteroarylalkynyl carbonyl, heterocyclyl carbonyl, heterocyclylalkyl carbonyl, heterocyclyl-alkenyl, heterocyclyl alkynyl carbonyl, Carboxyl, Alkoxycarbonyl, Alkenyloxycarbonyl, alkyne biphenylpropyloxycarbonyl, Cycloalkoxycarbonyl, Cycloalkylalkoxycarbonyl, cycloalkyl carbonyl alkenyloxy, alkynyloxy carbonyl cycloalkyloxycarbonyl, Aryloxycarbonyl, Arylalkoxycarbonyl, aryl carbonyl alkenyloxy, alkynyloxy or aryl carbonyl, Heteroaryloxycarbonyl, heteroaryl Alkoxycarbonyl, heteroaryl Alkoxycarbonyl alkenyloxy, alkynyloxy carbonyl heteroaryl, Heterocyclyloxycarbonyl, heterocyclyl Alkoxycarbonyl, Alkenyloxycarbonyl heterocyclyl, heterocyclyl carbonyl alkynyloxy, Aminocarbonyl, optionally substituted Mono-or Dialkylaminocarbonyl -, optionally substituted Mono - or diaryl-amino-carbonyl, optionally substituted Mono - or Di - Heteroarylamino carbonyl, - N N - alkyl - optionally substituted aryl Aminocarbonyl, - N N - heteroaryl - or optionally substituted alkyl carbonyl, optionally substituted alkylcarbonylamino, optionally substituted Alkylcarbonyl - N - alkylamino, optionally substituted aryl carbonyl amino, optionally substituted Arylcarbonyl - N - arylamino, optionally substituted heteroaryl carbonyl amino, optionally substituted Heteroarylcarbonyl - N - heteroaryl, - N - optionally substituted Alkylcarbonyl arylamino, optionally substituted Arylcarbonyl - alkylamino - N, - N - heteroaryl optionally substituted Alkylcarbonyl, optionally substituted heteroaryl - N - carbonyl-amino, alkoxycarbonylamino, alkylcarbonylamino and alkenyloxy, Alkinyioxycarbonylamino, Cycloalkoxycarbonyl amino, Cycloalkylalkoxycarbonyl amino, cyclo -alkyl Alkenyloxycarbonyl amino, alkynyloxy carbonyl amino cycloalkyl, aryloxycarbonylamino, aryl Alkoxycarbonyl amino, aryl carbonyl amino alkenyloxy, Arylalkinyoxycarbonylamino, Heteroaryloxycarbonyl amino, Heteroarylalkoxycarbonyiamino, heteroaryl carbonyl amino alkenyloxy, Heteroarylalkinyoxycarbonylamino, Heterocyclyloxycarbonyl amino, alkoxy carbonyl amino-heterocyclyl, heterocyclyl-carbonylamino alkenyloxy, Heterocyclylalkinyoxycarbonylamino, N - alkylamino - Alkoxycarbonyl, Alkenyloxycarbonyl - alkylamino - N, - N - yloxycarbonyl lkyne alkylamino, N - alkylamino - Cycloalkoxycarbonyl, Cycloalkylalkoxycarbonyl - N - alkylamino, N - alkylamino carbonyl - alkenyloxy cycloalkyl, N - alkylamino - Cycioalkylalkinyloxycarbonyl, N - alkylamino - Aryloxycarbonyl, Arylalkoxycarbonyl - N - alkylamino, N - alkylamino - aryl and alkenyloxy-carbonyl, N - alkylamino - Arylalkinyoxycarbonyl, alkoxy carbonyl - N - alkylamino heteroaryl, heteroaryl - N - alkylamino carbonyl alkenyloxy, alkynyloxy carbonyl - N - alkylamino heteroaryl, alkoxy carbonyl - N - heterocyclyl-amino, - N - alkenyloxycarbonyl Heterocyclyl alkylamino, - N - alkylamino Heterocyclylalkinyoxycarbonyl, Formyl, halogen, haloalkyl, haloalkenyl, haloalkynyl, haloalkoxy, halogen and Alkenyloxy, alkynyloxy halogen, haloalkylthio, halogen Alkenylthio, alkynylthio halogen, halogen alkyl amino, halogen Alkenylamino, alkynylamino halogen, haloalkylsulfonyl, halo alkenyl sulfonyl, halo sulfonyl alkynyl, haloalkyl, halo alkenyl sulfinyl, halo alkynylsulfinyl, haloalkylcarbonyl, halogen alkenylcarbonyl, alkinylcarbonyl halogen, haloalkoxycarbonylphenyl, haloalkenyloxyalkyl carbonyl, halogen alkynyloxy carbonyl, haloalkyl carbonyl, halo alkenyl amino carbonyl, amino carbonyl halcgenation naik ynyl, haloalkoxycarbonylphenyl amino, Halogenalkenyioxycarbonylamino, halogen amino alkynyloxy, Alkoxyalkoxy, Arylalkoxy alkoxy, Cyano, nitro, or a radical from the group - nh - N - CH=alkyl, aryl - (CH2)n- NH - N=CH -, - N=CH - alkoxy, aryl - (CH2)n- O - N=CH -, - nh - - Co - and Arylalkyl-nh-alkyl - nh - - Co - and R-nh5- or polysubstituted by an optionally, by the same or different alkyl, alkenyl, alkynyl, Cycloalkyl, Cycloalkenyl, cycloalkylalkyl, Cycloalkyl alkenyl, alkynyl Cycloalkyl, aryl, Arylalkyl, Arylalkenyl, arylalkynyl, heteroaryl, Heteroarylalkyl, Heteroarylalkenyl, heteroarylalkynyl, Heterocyclyl, heterocyclylalkyl, Heterocyclyl-alkenyl, Heterocyciylalkinyl, hydroxy, alkoxy, Alkenyloxy, alkynyloxy, Cycloalkoxy, cycloalkylalkoxy, Cycloalkylalkenyioxy, Cycloalkyl alkynyloxy, cycloalkene yloxy, Aryloxy, Arylalkoxy, Alkenyloxy or aryl, aryl alkynyloxy, Heteroaryloxy, Heteroarylalkoxy, Alkenyloxy heteroaryl, heteroaryl alkynyloxy, heterocyclyloxy, heterocyclylalkoxy, Heterocyclyl alkenyloxycarbonyl, Heterocyclylalkinyioxy, Thio, Alkylthio, Alkenylthio, alkynylthio, cycloalkylthio, Cycloalkyl-alkyl Thio, Alkenylthio Cycloalkyl, alkynylthio Cycloalkyl, cyclo alkenyl Thio, Arylthio, arylalkylthio, Arylalkenyl Thio, aryl Thio alkynyl, Heteroarylthio, heteroaryl Alkylthio, heteroaryl Alkenylthio, alkynylthio heteroaryl, Heterocyclyl Thio, Thio-Heterocyclyl-alkyl, Heterocyclyl Alkenylthio, alkynylthio Heterocyclyl, amino, Mono - or Di-alkylamino optionally substituted, optionally substituted Mono - or Diarylamino, Mono - or Di - Heteroarylamino optionally substituted, - N - - N alkyl optionally substituted arylamino, N - - N - alkyl optionally substituted Heteroarylamino, Alkenylamino, alkynylamino, cycloalkylamino, cycloalkenylamino, Heterocyclyl alkylamino, Alkenylamino Heterocyclyl, Alkylsulfonyl, Alkenylsulfonyl, alkynylsulfonyl, cycloalkylsulfonyl, Cycloalkyl-alkyl-sulfonyl, sulfonyl Cycloalkyl alkenyl, alkynyl Cycloalkyl sulfonyl, Arylsulfonyl, Arylalkyl suif onyl, Arylalkenyl sulfonyl, aryl sulfonyl alkynyl, heteroaryl sulfonyl, heteroaryl sulfonyl, Heteroarylalkenyisulfonyl, heteroarytatkynyt sulfonyl, Heterocyclyl sulfonyl, Heterocyclyl sulfonyl, Heterocyclyl sulfonyl alkenyl, Heterocyclyl alkynyl sulfonyl, Alkylsulfinyl, Alkenylsulfinyl, alkynylsulfinyl, cycloalkylsulfinyl, Cycloalkyl-alkyl-sulfinyl, Cycloalkyl alkenyl sulfinyl, Cycloalkyl alkynyl sulfinyl, Arylsulfinyl, Alkylsulfinyl aryl, aryl alkenyl sulfinyl, aryl alkynyl sulfinyl, aryl-sulfinyl, heteroaryl Alkylsulfinyl, Alkenylsulfinyl heteroaryl, heteroarytatkynyt sulfinyl, Heterocyclylsulfinyi, aryl Alkylsulfinyl, Alkenylsulfinyl Heterocyclyl, Heterocyclyl alkynyl sulfinyl, Aminosulfonyl, optionally substituted Mono - or Di-alkyl amino sulfonyl, optionally substituted Mono - or Diarylaminosulfonyi, optionally substituted Mono - or Di - Heteroarylamino sulfonyl, optionally substituted N - alkyl - N - aryl amino sulfonyl, N - - N - optionally substituted alkyl Heteroarylaminosulfonyi, alkylsulfonyloxy, phenylsulfonyloxy alkenyl, alkynyl sulfonyloxy, cyclo -alkyl sulfonyloxy, Cycloalkylalkylsulfonyioxy, alkenyl Cycloalkyl sulfonyloxy, Cycloalkyl alkynyl sulfonyloxy, arylsulfonyloxy, aryl alkyl sulfonyloxy, aryl sulfonyloxy alkenyl, alkynyl aryl sulfonyloxy, heteroalylsulfonyloxy, heteroaryl alkyl sulfonyloxy, Heteroarylalkenyl sulfonyloxy, Heteroarytatkynyt sulfonyloxy, phenylsulfonyloxy heterocyclyl, heterocyclyl alkyl sulfonyloxy, heterocyclylalkylenyl sulfonyloxy, heterocyclyl alkynyl sulfonyloxy, Alkylsulfonylamino, alkenyl sulfonyl amino, phenylsulphonylamino alkynyl, cycloalkyl sulfonylamino, Cycloalkylalkylsulfonyiamino, cycloalkyl alkenylsulfonylaminocarbonyloxystyrenes, cycloalkylalkynyl sulfonylamino, Arylsulfonylamino, aryl-alkyl sulfonyl amino, arylalkenyl sulfonopropane amino, Arylalkinylsulfonyiamino, heteroaryl sulfonyl amino, alkyl sulfonyl amino heteroaryl, heteroaryl alkenyl sulfonopropane amino, phenylsulphonylamino heteroarytatkynyt, Alkylsulfonyl-N-alkylamino, alkenyl sulfonyl-N - alkylamino, alkynylsulfonyl-N-alkylamino, cycloalkyl-sulfonyl-N-alkylamino, cycloalkyl-alkyl-sulfonyl-N-alkylamino, alkenyl sulfonyl-N-alkylamino-cycloalkyl, cycloalkyl-sulfonyl-N-alkylamino or alkynyl, aryl-N-alkylamino, N-alkylamino - heteroaryl sulfonyl, aryl sulfonyl-N-alkylamino alkyl, Alkylsulfonyl-N-alkylamino heteroaryl, aryl-sulfonyl-N-alkylamino alkenyl, Heteroarylalkenyl sulfo-nonyl-N-alkylamino, aryl-sulfonyl-N-alkylamino alkynyl, heteroaryl alkynyl sulfonyl-N-alkylamino, Heterocyclylsulfonyl-N-alkylamino, heterocyclyl-alkyl onyl-N-alkylamino suif, alkenyl sulfonyl-N-alkylamino-heterocyclyl, heterocyclyl-sulfonyl-N-alkylamino alkynyl, Alkylcarbonyl, Alkenylcarbonyl, Alkinyicarbonyl, Cycloalkylcarbonyl, cycloalkyl-alkyl carbonyl, cycloalkyl carbonyl alkenyl, alkynyl cycloalkyl carbonyl, Arylcarbonyl, Arylalkylcarbonyl, cycloalkyl and aryl, aryl alkynyl carbonyl, Heteroarylcarbonyl, Heteroarylalkylcarbonyl, Heteroarylalkenyl, Heteroarylalkinyicarbonyl, heterocyclyl carbonyl, heterocyclylalkyl carbonyl, heterocyclyl-alkenyl, Heterocyclyialkinylcarbonyl, Carboxyl, Alkoxycarbonyl, Alkenyloxycarbonyl, alkyne biphenylpropyloxycarbonyl, Cycloalkoxycarbonyl, Cycloalkylalkoxycarbonyl, alkenyloxy carbonyl cycloalkyl, cycloalkyl carbonyl alkynyloxy, Aryioxycarbonyl, arylalkoxy carbonyl, aryl carbonyl alkenyloxy, alkynyloxy or aryl carbonyl, Heteroaryloxycarbonyl, heteroaryl Alkoxycarbonyl, alkenyloxy carbonyl heteroaryl, Heteroaryl carbonyl alkynyloxy, Heterocyclyloxycarbonyl, Heterocyclyl Alkoxycarbonyl, Alkenyloxycarbonyl Heterocyclyl, Heterocyclyl carbonyl alkynyloxy, Aminocarbonyl, Mono - or Dialkylaminocarbonyl optionally substituted, Mono - or diaryl-amino-carbonyl optionally substituted, Mono - or Di - heteroaryl optionally substituted Aminocarbonyl, optionally substituted N - - N - aryl-alkyl-Aminocarbonyl, N - - N - heteroaryl optionally substituted alkyl carbonyl, optionally substituted Alkylcarbonyiamino, - N - alkylamino optionally substituted Alkylcarbonyl, optionally substituted aryl carbonyl amino, optionally substituted Arylcarbonyl - arylamino - N, optionally substituted heteroaryl carbonyl amino, optionally substituted - heteroaryl - N Heteroarylcarbonyi, Alkylcarbonyl - N - optionally substituted arylamino, optionally substituted Arylcarbonyl - N - alkylamino, optionally substituted Alkylcarbonyl - N - heteroaryl, optionally substituted heteroaryl carbonyl - N - alkylamino, Alkoxycarbonylamino, alkylcarbonylamino and alkenyloxy, alkynyloxy carbonyl-amino, amino substituted Cycloalkoxycarbonyl, Cycloalkylalkoxycarbonyl amino, Cycloalkylalkenyloxycarbonyiamino, cycloalkyl amino carbonyl alkynyloxy, Aryloxycarbonylamino, aryl Alkoxycarbonyl amino, aryl carbonyl amino alkenyloxy, Arylalkinyoxycarbonylamino, heteroaryloxycarbonyl amino, heteroaryl Alkoxycarbonylamino, Heteroaryialkenyloxycarbonylamino, Heteroarylalkinyoxycarbonylamino, Heterocyclyloxycarbonyl amino, Heterocyclyl Alkoxycarbonylamino, Heterocyclylalkenyloxycarbonyiamino, Heterocyclylalkinyoxycarbonylamino, N - alkylamino - Alkoxycarbonyl, Alkenyloxycarbonyl - alkylamino - N, - N - yloxycarbonyl lkyne alkylamino, N - alkylamino - Cycloalkoxycarbonyl, Cycloalkylalkoxycarbonyl - N - alkylamino, N - alkylamino carbonyl - cycloalkyl alkenyloxy, alkynyloxy carbonyl - N - cycloalkyl-amino, N - Aryloxycarbonyl-amino -, alkylamino - Arylalkoxycarbonyl - N, - N - aryl and alkenyloxy carbonyl alkylamino, - N - alkylamino Arylalkinyoxycarbonyl, - N - heteroaryl Alkoxycarbonyl alkylamino, carbonyl - alkylamino - N haloalkenyloxy heteroaryl, - N - alkylamino Heteroarylalkinyoxycarbonyl, - N - alkoxy-carbonyl amino -alkyl Heterocyclyl, Heterocyclyl - Alkenyloxycarbonyl - N alkylamino, - Heterocyclylalkinyoxycarbonyl Nalkylamino, Formyl, halogen, haloalkyl, haloalkenyl, haloalkynyl, haloalkoxy, halogen and alkenyloxy, alkynyloxy halogen, haloalkylthio, halogen alkenylthio, alkynylthio halogen, halogen alkyl amino, halogen alkenylamino, alkynylamino halogen, haloalkylsulfonyl, halo-alkenyl sulfonyl, halo sulfonyl alkynyl, haloalkyl, halo alkenyl cyclobutanecarboxamidinyl suif, halogen alkynylsulfinyl, halo -alkyl carbonyl, alkenylcarbonyl halogen, Halogenalkinyicarbonyl, haloalkoxycarbonylphenyl, haloalkenyl - oxycarbonyl, alkynyloxy carbonyl halogen, halogen alkyl-amino-carbonyl, Aminocarbonyl - haloalkyl, halo lower alkynyl amino carbonyl, Halogenalkoxycarbonyiamino, Halogenalkenyioxycarbonylamino, halogen amino alkynyloxy, Alkoxyalkoxy, arylalkoxy alkoxy, Cyano, nitro, or a radical from the group - nh - N - CH=alkyl, aryl - (CH2) n - NH - N=CH -, - N=CH - alkoxy, aryl - (CH2)n- O - N=CH -, - nh - - Co - and Arylalkyl-alkyl-nh - - nh - - nh-Co-substituted heteroaryl, Heterocyclyl or aryl, or a radical from the group - O - N=CR ' Rm, - P (O=) (ori) (Rj), - P (=O) (ori) (ork) or ^ O (CH2)m or, in case, E represents a bond and I is zero in that, R can5also are hydroxy, mean. 3. Benzoyl derivatives according to claim 1 or 2, wherein R1, R2, R3independently of one another hydrogen, halogen, nitro, Cyano, alkyl, Cycloalkyl, alkenyl, alkynyl, alkoxy, Alkylthio, Alkylsulfinyl, Alkylsulfonyl, alkylsulfonyloxy, alkylsulfonylamino, Alkylsulfonyl-N-alkylamino, phenyl, benzyl, where the thirteen last-mentioned groups is optionally substituted by one or more, identical or different radicals from the group consisting of halogen, nitro, Cyano, alkyl, haloalkyl, Cycloalkyl, alkenyl, alkynyl, alkoxy, haloalkoxy and Alkylthio substituted; R4hydrogen, Cyano, alkyl, alkenyl, alkynyl, Cycloalkyl, wherein the four last-mentioned groups is optionally substituted by one or more, identical or different radicals from the group consisting of halogen, nitro, Cyano, alkyl, Cycloalkyl, alkynyl, alkoxy, substituted Alkylthio; R5a - is an optionally singly or multiply, identically or differently by halogen, nitro, cyano, Formyl, amino, phenyl, benzyl, (ci - J alkyl - C β, (C2- C6) - alkenyl, (C2- C6) - alkynyl, (ca - cycloalkyl - CeJ, (C C6) - alkoxy, (crc6) - Alkylamino, Di - (C - C ι6) - Alkylamino, (- C C ι6) - Alkoxycarbonyl, (ci - C β J - alkylaminocarbonyl, Di - (C - - C ι6) - alkylaminocarbonyl, (C C6) - Alkylcarbonyl, (crc6) - alkylcarbonylamino, (C C6) - Alkylcarbonyl - (crc6) - Alkylamino, (CrC6) - Alkylcarbonyl - Di - (C - C ι6) Alkylamino, (d - C6) - Alkylthio, (C C6) - Alkylsulfinyl, (d - Alkylsulfonyl - CeJ, (- CrCeJ Alkylsulfonyiamino, (C - C ι6) - Alkylsulfonyl - (CrC6) - AlkylaminoI(C ι - C6) - Alkylsulfonyl - Di - (C - C ι6) - Alkylamino, where the 22 last-mentioned groups is optionally substituted by one or more, identical or different radicals from the group consisting of halogen, nitro, cyano, (ci - C β) - alkyl, (C3- C6) - cycloalkyl, (C2- C6) - Alkenyi, (C2- C6) - Alkinyi, (C - C ι6) - alkoxy, (CrC6) - Alkylthio or a three to six-membered, saturated, partially saturated or unsaturated heterocycle, containing up to four heteroatoms from the group of nitrogen, and may contain oxygen atom, substituted, substituted phenyl -, - tri, - or six-membered heteroaryl group is five, the up to three heteroatoms selected from nitrogen, oxygen and may contain Schwefeiatom, or three to six-membered, saturated, part saturated or unsaturated heterocycle moiety, the up to four heteroatoms from the group nitrogen, oxygen and sulfur atom may be included, or a radical from the group - O - N=CR ' Rm, - P (=O) (ori) (Rj), - P (=O) (ori) (ork) or  or, in case, E represents a bond and I is zero in that, R can5also is hydroxy, A is a divalent unit from the group consisting of S, so, so2, and Nra; A saturated B-bond-containing and one or two carbon atoms or from existing chain, optionally substituted by alkyl, haloalkyl, substituted alkoxy or haloalkoxy; Is a bond E, CRcRd, NrC, S, so, so2, O and Co; R6(d- CeJ-Alkylthio, (C C6) - Alkylsulfinyl, (crc6) - Alkylsulfonyl, cyano, cyanato, Thiocyanato, halogen Or Orf; Is a divalent unit from the group consisting of Y O, S, N - (crc6) - alkyl or CHR7; R7hydrogen, (Cι-C6) - alkyl, (C3- C8) - cycloalkyl, (C.-C6) - alkoxy, (Cι-C6) - alkoxy - (crc6) - alkyl, (Cι-C6) - Alkylcarbonyl, (crc6) - Alkoxycarbonyl, (Cι-C6) - Alkylthio, phenyl, wherein the hydrocarbon portion of the eight last-mentioned radicals optionally substituted by one or more, identical or different radicals from the group consisting of halogen, ( CrCa) - Alkylthio and (crc3) - substituted Alkyloxy; Z is a bond, CH2 or CHR7; R8hydrogen, (C C6) - alkyl or (crc6) - Alkoxycarbonyl; R9hydrogen, (crc6) - alkyl, (C3- C8) - cycloalkyl or halo - (crc6) - alkyl; R10hydrogen, (C C6) - alkyl, (C2- C6) - alkenyl, (crc6) - alkynyl, (C3- C8) - cycloalkyl, phenyl, benzyl, where the six last-mentioned radicals is optionally substituted by one or more groups, identical or different radicals from the group consisting of halogen, cyano, Nitro and (C CβJ-alkoxy substituted by; R1hydrogen, Formyl, (C C6) - alkyl, halo - (crc6) - alkyl, (C C6) - alkoxy - (C - β C ι) - alkyl or a group L-R12; L is a divalent unit selected from the group of SO2, co and chr9co; R12(Cι-C6) - alkyl, halo - (crc6) - alkyl, optionally substituted by one or more genes or gege, identical or different radicals from the group consisting of cyano, Nitro, (d-C3) - alkyl, (crc3) - alkoxy, halo - (C C3) - alkyl and halo - (Cι-C3) - alkoxy substituted phenyl; Rahydrogen, halogen, cyano, Nitro, Formyl, (crc6) - alkyl, (C3- C8) - cycloalkyl, (C2- C6) - alkenyl, (C2- C6) - alkynyl, (C C6) - Alkylcarbonyl and (C C6) - Alkylsulfonyl, where the six last-mentioned radicals is optionally substituted by a part of the hydrocarbon one or more, identical or different radicals from the group consisting of halogen, Nitro, cyano, (d- CeJ-alkyl, (C3- C8) - cycloalkyl, (C2- C6) - alkenyl, (C2- C6) - alkynyl, (C C β) - alkoxy and (Cι-C6) - Alkylthio which is substituted by; Rcand Rdare independently hydrogen, halogen, Nitro, cyano, (d-Cβ) - alkyl, halo - (Cι-C6) - alkyl, (C3- C8) - cycloalkyl, (C2- C6) - alkenyl, halo - (C2- C6) - alkenyl, (C2- C6) - alkynyl, halo - (C2- C6) - alkynyl, (C C6) - alkoxy, halogen - (C C6) - alkoxy, (crc6) - Alkylthio, halo - (crc6) - Alkylthio, (Cι-C6) - Alkylcarbonyl, halo - (ci-CβJ-lower Alkylcarbonyl, (crc6) - Alkoxycarbonyl, halo - (Cι-C6) - Alkoxycarbonyl, Aminocarbonyl, (CrCβJ-Alkylcarbonyl and (ci-CβJ-alkylsulphonyl; Rehydrogen, Formyl, (C C6) - alkyl, (C3- C8) - cycloalkyl, (C2- C6) - alkenyl, (C2CβJ-alkynyl -, (d-CβJ-Alkylcarbonyl and (CrCβJ-Alkylsulfonyl, wherein the hydrocarbon portion of the six last-mentioned radicals optionally substituted by one or more, identical or different radicals from the group consisting of halogen, Nitro, cyano, (d-C6) - alkyl, cycloalkyl, (C2- C6) - alkenyl, (C2- C6) - (d-C6) - alkynyl, (C C6) - alkoxy and (CrCβJ-Alkylthio may be substituted; Rfhydrogen, (C C6) - alkyl, halogen - (d-C6) - alkyl, (...)
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