Synergistic agent and process for the selective control of weeds, especially in crops 机翻标题: 暂无翻译,请尝试点击翻译按钮。

公开号/公开日
EP0069705 A1 1983-01-12 [EP--69705]EP0069705 B1 1985-05-29 [EP--69705] / 1983-01-121985-05-29
申请号/申请日
1982EP-0810283 / 1982-07-02
发明人
QUADRANTI, MARCO, DR.;MAAG, KURT;
申请人
CIBA GEIGY;
主分类号
IPC分类号
A01N-043/40A01N-047/22A01N-047/30
摘要
(EP--69705) 1.  A synergistic composition for selectively controlling weeds, which composition contains as active ingredients, on the one hand, 3-(4-isopropylphenyl)-1,1-dimethylurea (Ia) or 3-(3-chloro-4-methylphenyl)-1,1-dimethylurea (Ib), and, on the other hand, a halopyridyloxyphenoxyalkanecarboxylic acid derivative of the formula II see diagramm : EP0069705,P17,F1 wherein Hal is halogen, R is hydrogen, halogen or C1 -C4 alkyl, alkylene is a saturated, straight chain or branched C2 -C4 alkylene chain, X is any one of the groups -O(cation) Y(anion), -O-R1 , -S-R2 , -NR3 R4 or -O-N=CR6 R7 , where R1 and R2 are each hydrogen, C1 -C5 alkyl, C1 -C4 haloalkyl, C2 -C6 haloalkenyl, C2 -C6 alkenyl, C3 -C6 alkynyl, C3 -C6 haloalkynyl, C2 -C4 carboxyalkyl, C1 -C4 cyanoalkyl, C1 -C4 hydroxyalkyl, C1 -C4 aminocarboxyalkyl, C3 -C6 alkoxycarboxyalkyl unsubstituted or substituted by cyano, -COO-alkyl or -CO-alkyl, or R1 and R2 are each phenyl or phenylalkyl having 1 to 3 carbon atoms in the alkyl moiety, the phenyl or phenylalkyl each being unsubstituted or substituted by nitro, cyano, halogen or C1 -C4 alkyl, or R1 and R2 are one of the groups C2 -C4 alkylene-NR3 R4 or C2 -C4 alkylene-N(anion) R3 R4 R5 Z(cation), R3 is hydrogen, C1 -C4 alkyl, C3 -C5 alkoxyalkyl, C1 -C4 haloalkyl, C2 -C4 carboxyalkyl, C3 -C6 alkoxycarboxyalkyl, C1 -C4 hydroxyalkyl or -CO-alkyl, R4 is hydrogen, C1 -C4 alkyl, C2 -C4 alkenyl or C1 -C4 hydroxyalkyl, R5 is hydrogen or C1 -C4 alkyl, R6 and R7 are each C1 -C4 alkyl, Y(anion) is a cation of an alkali metal or alkaline earth metal or of ammonium, Z(cation) is a halogen anion, or wherein R3 and R4 together with the nitrogen atom to which they are attached can form a pyrrolidine, piperidine, morpholine, thiomorpholine, piperazine, pyrazole or triazole ring, and R6 and R7 together with the nitrogen atom to which they are attached can form a pyrrolidine or piperidine ring, with the exception of the two compounds : propargyl 4-(3'-5'-dichloropyridyl-2'-oxy)- alpha-phenoxypropionate and propargyl 4-(3'-5'-dichloropyridyl-2'-oxy)- alpha-phenoxythiopropionate, together with carriers and/or other adjuvants.
机翻摘要
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地址
代理人
代理机构
;
优先权号
1981CH-0004485 1981-07-08
主权利要求
(EP--69705)  1. Synergistic Mittel for selective Weed Control, by the fact characterized that it beside Carrier and/or other Aggregates than effective Component on the one hand 3 (4-Isopropylphenyl) - l, l-di- methyl urea (Ia) or 3 (3-Chlor-4-methylphenyl) - 1,1-dimethyl urea (Ib) and on the other hand Halogenpyridyloxy-phenoxy-alkan- carbonic acid derivative of the Formula II contains, EMI24.1 where Hal for Halogen, R for Hydrogen, Halogen or Cl-C4-Alkyl, Alkyls for a satisfied, geradkettige or branched C2-C4 Alkyl Chain and X for one of the Groups -O# Y#, - O-R1, - S-R2, - NR3R4 oder - O-N=CR6R7 stand, how G 1 and R2 in each case Hydrogen, C1-C5-Alkyl, C1-C4-Halogenalkyl, C2-C6 Halogen Alkenyl, C2-C-Alkenyl, C3-C6-Alkinyl, C3-C6-Halogenalkinyl, C2-C4-Carboxylakyl, C1-C4-Cyanoalkyl, C1-C4-Hydroxylakyl, C1-C4 Aminocarboxyalkyl, if necessary by Cyanogen, -000-Alkyl or - CO Alkyl substituted C3-C4-Alkoxycarboxyalkyl, if necessary through Nitro, Cyanogen, Halogen or Cl-C4-Alkyl substituted Phenyl or Phenylalkyl with 1 to 3 Carbon Atoms in the Alkyl Part or one of the Groups of C2-C4-Alkylen-NR3R4 or C2-C4-Alkylen-N#R3R4R5Z#, R3 Hydrogen, C1-C4-Alkyl, C3-C5-Alkoxyalkyl, C1-C4-Halogenalkyl, C2-C4-Carboxyalkyl, C3-C6-Alkoxycaeboxyalkyl, C1-C4-Hydeoxyalkyl or - CO-alkyl, R4 Wasserstorr, Cl-C4-Alkyl, C2-C4-Alkenyl or C1-C4-Hydroxyalkyl, R5 Hydrogen or Cl-C4-Alkyl, R6 and R7 Cl-C4-Alkyl, ein an Alkali, an Alkaline-earth or an ammonium cation and a Z 0ein Halogen Anion means in each case, or whereby they can form binding Nitrogen Atom a Pyrro for R3 and R4 as well as that lidin, Piperidin, Morpholin, Thiomorpholin, Piperazin, Pyrazol or Triazolring and R6 and R7 as well as that them binding Nitrogen Atom a Pyrroli DIN or Piperidinring under Exception of the two Connections 4 (3 ', 5 ' - Dichlorpyridyl-2'-oxy) - .alpha.;   - phenoxy-propionsaure- more propargylester and 4 (3 ', 5 ' - Dichlorpyridil-2'-oxy) - .alpha.-phenoxy-thiopro- more pionsaurepropargylester. 2. Means in accordance with claim 1, by it characterized that in the Mixture Component of the Formula II Hai and R stand for Chlorine, Alkyls the Group - CH (CH3) - embodies and for X for - OR1, - S-R2 or NR3R4 stands, whereby G 1 and R2 mean Hydrogen, Cl-C5-Alkyl, C1-O4-Halo- towards alkyl, C4-C6-Alkinyl, C4-C6-Halogenalkinyl, C3-C6-Alkenyl, C3-C6 Halogen Alkenyl, if necessary by Cyanogen substituted C3-C6-Alkoxycarboxyalkyl, if necessary by Nitro substituted Phenyl or Benzyle or one of the Groups of C2-C4-Alkylen-NR3R5 or C2-C4-Alkylen 3R4R5Z# and R3, R4 and R5 jeweille C1-C4-Alkyl or R3 and R4 as well as that they form for binding Nitrogen Atom a Pyrazolring. 3. Means in accordance with claim 2, by the fact characterized that in Mischungskomponente the Formula II X for - OR1 or - S-R2 stands, whereby G 1 and R2 Hydrogen, <RTI, mean ID=25.12>Cl-C5-Alkyl C3-C6-Alkenyl or C4-C6-Alkinyl. 4. Means in accordance with claim 1, by the fact characterized that the Mixture Component of the Formula II 4 (3 ', 5 ' - Dichlorpyridyl-2'-oxy) - .alpha.-phenoxy- propionsaure or their Methyl, Ethyl, Propyl and Butylester as well as the same Derivatives of the appropriate Thiopropionsaure means. 5. Means in accordance with one of the claims 1 to 4, by the fact characterized that Cie Mixture Component I through 3 (4-Isopropylphenyl) - l, l-dimethyl- urea (Ia) is embodied. 6. Means in accordance with one of the Patent Claims 1 to 5, by the fact characterized that in the Means mentioned the Component (I) in relation to the Component (11) in same Weight Ratio or in the Surplus is present. 7. Mittel in accordance with Patent Claim 6, by the fact characterized that the Weight Ratio between Component (1) and Component (II) 1:1 to 20:1, preferably 4:1 to 10:1 amounts to. 8. Procedure for the selective Weed Control in Grain, by the fact characterized that one post emergent verunkrautete Grain Cultures treated with an effective Menge of a Means in accordance with one of the Patent Claims 1 to 7. 9. Procedure in accordance with Patent Claim 8, thereby characterized that one Grain Cultures, which contain myosuroides, Echinochloa of the Kind Chrysanthemum and Sinapis as Weeds Dikotyledonen as well as Monokotyledonen Alopecurus crus galli as well as Grasses of the Kind Lolium, Setaria, Phalaris, Poa and Kinds Of Game Oats, with which Means mentioned treats. 10. Procedure in accordance with claims 8 and 9, by the fact characterized that one treats the Grain Culture with the Means mentioned in Expenditure Quantities, which correspond to 0, 1 to 4 kg, preferably 0.25 to 1.5 kg Total Active Substances per Hectare. 11. Procedure in accordance with claims 8 to 10, by the fact characterized that the Varieties Of Grain Summer, Winter and Durum Wheat, Winter and Summer Rye and - barley is.
法律状态
(EP--69705) LEGAL DETAILS FOR EP0069705  Actual or expected expiration date=2002-07-02    Legal state=DEAD    Status=EXPIRED     Event publication date=1982-07-02  Event code=EP/APP  Event indicator=Pos  Event type=Examination events  Application details  Application country=EP EP82810283  Application date=1982-07-02  Standardized application number=1982EP-0810283     Event publication date=1983-01-12  Event code=EP/A1  Event type=Examination events  Application published with search report  Publication country=EP  Publication number=EP0069705  Publication stage Code=A1  Publication date=1983-01-12  Standardized publication number=EP--69705     Event publication date=1983-01-12  Event code=EP/AK  Event indicator=Pos  Event type=Designated states  Designated contracting states: Benannte vertragsstaaten AT BE CH DE FR GB IT LI NL    Event publication date=1983-01-12  Event code=EP/17P  Event indicator=Pos  Event type=Examination events  Request for examination filed Pruefungsantrag gestellt  Effective date of the event=1982-07-05     Event publication date=1985-05-29  Event code=EP/B1  Event indicator=Pos  Event type=Event indicating In Force  Patent specification  Publication country=EP  Publication number=EP0069705  Publication stage Code=B1  Publication date=1985-05-29  Standardized publication number=EP--69705     Event publication date=1985-05-29  Event code=EP/AK  Event indicator=Pos  Event type=Designated states  Designated contracting states: Benannte vertragsstaaten AT BE CH DE FR GB IT LI NL    Event publication date=1986-06-04  Event code=EP/26N  Event indicator=Pos  Event type=No opposition filed  Event type=Event indicating In Force  No opposition filed Kein einspruch eingelegt    Event publication date=2002-07-02  Event code=EP/EEDX  Event indicator=Neg  Event type=Event indicating Not In Force  Patent has expired MEMBER STATE LEGAL DETAILS FOR AT13478  Actual or expected expiration date=1990-07-02    Legal state=DEAD    Status=LAPSED   Corresponding cc:  Designated or member state=AT Corresponding appl: AT82810283  Application date in the designated or member state=1982-07-02   Application number in the designated or member state=1982AT-0810283T Corresponding cc:  Designated or member state=AT Corresponding pat: AT13478  Publication stage code in the designated or member state=T  Publication date in the designated or member state=1985-06-15   Publication number in the designated or member state=ATE013478    Event publication date=1985-05-29  Event code=EP/REF  Event type=Entry into national phase  Corresponds to: Corresponding cc:  Designated or member state=AT     Event publication date=1989-06-21  Event code=EP/PGFP  Event indicator=Pos  Event type=Event indicating In Force  Event type=Payment or non-payment notifications  Postgrant: annual fees paid to national office   Annual fees payment date=1989-06-21     Year of payment of annual fees=8  Corresponding cc:  Designated or member state=AT     Event publication date=1990-07-02  Event code=EP/PG25  Event indicator=Neg  Event type=Event indicating Not In Force  Event type=Payment or non-payment notifications  Lapsed in a contracting state announced via postgrant inform. from nat. office to EPO Corresponding cc:  Designated or member state=AT   Effective date of the event=1990-07-02  MEMBER STATE LEGAL DETAILS FOR BE  Actual or expected expiration date=1990-07-31    Legal state=DEAD    Status=LAPSED   Corresponding cc:  Designated or member state=BE     Event publication date=1989-07-18  Event code=EP/PGFP  Event indicator=Pos  Event type=Event indicating In Force  Event type=Payment or non-payment notifications  Postgrant: annual fees paid to national office   Annual fees payment date=1989-07-18     Year of payment of annual fees=8  Corresponding cc:  Designated or member state=BE     Event publication date=1990-07-31  Event code=EP/PG25  Event indicator=Neg  Event type=Event indicating Not In Force  Event type=Payment or non-payment notifications  Lapsed in a contracting state announced via postgrant inform. from nat. office to EPO Corresponding cc:  Designated or member state=BE   Effective date of the event=1990-07-31     Event publication date=1991-01-31  Event code=EP/BERE  Event indicator=Neg  Event type=Event indicating Not In Force  BE: Lapsed BE: Dechu Corresponding cc:  Designated or member state=BE   Effective date of the event=1990-07-31  MEMBER STATE LEGAL DETAILS FOR CH  Actual or expected expiration date=1990-07-31    Legal state=DEAD    Status=EXPIRED   Corresponding cc:  Designated or member state=CH     Event publication date=1989-07-03  Event code=EP/PGFP  Event indicator=Pos  Event type=Event indicating In Force  Event type=Payment or non-payment notifications  Postgrant: annual fees paid to national office   Annual fees payment date=1989-07-03     Year of payment of annual fees=8  Corresponding cc:  Designated or member state=CH     Event publication date=1990-07-31  Event code=EP/PG25  Event indicator=Neg  Event type=Event indicating Not In Force  Event type=Payment or non-payment notifications  Lapsed in a contracting state announced via postgrant inform. from nat. office to EPO Corresponding cc:  Designated or member state=CH   Effective date of the event=1990-07-31     Event publication date=1991-03-28  Event code=EP/REG  Event code=CH/PL  Event indicator=Neg  Event type=Event indicating Not In Force  Reference to a national code Patent ceased Loeschung/radiation/radiazion Corresponding cc:  Designated or member state=CH  MEMBER STATE LEGAL DETAILS FOR DE3263881  Actual or expected expiration date=1991-04-03    Legal state=DEAD    Status=LAPSED   Corresponding cc:  Designated or member state=DE Corresponding appl: DE3263881  Application date in the designated or member state=1982-07-02   Application number in the designated or member state=1982DE-3263881 Corresponding cc:  Designated or member state=DE Corresponding pat: DE3263881  Publication stage code in the designated or member state=D1  Publication date in the designated or member state=1985-07-04   Publication number in the designated or member state=DE3263881    Event publication date=1985-07-04  Event code=EP/REF  Event type=Entry into national phase  Corresponds to: Corresponding cc:  Designated or member state=DE     Event publication date=1989-06-15  Event code=EP/PGFP  Event indicator=Pos  Event type=Event indicating In Force  Event type=Payment or non-payment notifications  Postgrant: annual fees paid to national office   Annual fees payment date=1989-06-15     Year of payment of annual fees=8  Corresponding cc:  Designated or member state=DE     Event publication date=1991-04-03  Event code=EP/PG25  Event indicator=Neg  Event type=Event indicating Not In Force  Event type=Payment or non-payment notifications  Lapsed in a contracting state announced via postgrant inform. from nat. office to EPO Corresponding cc:  Designated or member state=DE   Effective date of the event=1991-04-03  MEMBER STATE LEGAL DETAILS FOR FR  Actual or expected expiration date=1991-03-29    Legal state=DEAD    Status=LAPSED   Corresponding cc:  Designated or member state=FR     Event publication date=1985-07-19  Event code=EP/ET  Event indicator=Pos  Event type=Event indicating In Force  FR: Translation filed FR: Traduction a ete remise Corresponding cc:  Designated or member state=FR     Event publication date=1989-05-31  Event code=EP/PGFP  Event indicator=Pos  Event type=Event indicating In Force  Event type=Payment or non-payment notifications  Postgrant: annual fees paid to national office   Annual fees payment date=1989-05-31     Year of payment of annual fees=8  Corresponding cc:  Designated or member state=FR     Event publication date=1991-03-29  Event code=EP/PG25  Event indicator=Neg  Event type=Event indicating Not In Force  Event type=Payment or non-payment notifications  Lapsed in a contracting state announced via postgrant inform. from nat. office to EPO Corresponding cc:  Designated or member state=FR   Effective date of the event=1991-03-29     Event publication date=1991-05-24  Event code=EP/REG  Event code=FR/ST  Event indicator=Neg  Event type=Event indicating Not In Force  Event type=Payment or non-payment notifications  Reference to a national code Notification of lapse Constatation de decheances Corresponding cc:  Designated or member state=FR  MEMBER STATE LEGAL DETAILS FOR GB  Actual or expected expiration date=1990-07-02    Legal state=DEAD    Status=LAPSED   Corresponding cc:  Designated or member state=GB     Event publication date=1989-06-30  Event code=EP/PGFP  Event indicator=Pos  Event type=Event indicating In Force  Event type=Payment or non-payment notifications  Postgrant: annual fees paid to national office   Annual fees payment date=1989-06-30     Year of payment of annual fees=8  Corresponding cc:  Designated or member state=GB     Event publication date=1990-07-02  Event code=EP/PG25  Event indicator=Neg  Event type=Event indicating Not In Force  Event type=Payment or non-payment notifications  Lapsed in a contracting state announced via postgrant inform. from nat. office to EPO Corresponding cc:  Designated or member state=GB   Effective date of the event=1990-07-02     Event publication date=1991-02-27  Event code=EP/GBPC  Event indicator=Neg  Event type=Event indicating Not In Force  Event type=Payment or non-payment notifications  GB: European patent ceased through non-payment of renewal fee Corresponding cc:  Designated or member state=GB  MEMBER STATE LEGAL DETAILS FOR IT  Actual or expected expiration date=2002-07-02    Legal state=DEAD    Status=EXPIRED   Corresponding cc:  Designated or member state=IT     Event publication date=1985-02-08  Event code=EP/ITF  Event indicator=Pos  Event type=Examination events  IT: Translation for a EP patent filed IT: Deposito traduzione di brevetto europeo Corresponding cc:  Designated or member state=IT     Event publication date=1989-07-31  Event code=EP/ITTA  Event type=Event indicating In Force  Event type=Payment or non-payment notifications  IT: Last paid annual fee IT: Tassa annuale ultimo pagamento Corresponding cc:  Designated or member state=IT  MEMBER STATE LEGAL DETAILS FOR LI  Actual or expected expiration date=1990-07-31    Legal state=DEAD    Status=LAPSED   Corresponding cc:  Designated or member state=LI     Event publication date=1990-07-31  Event code=EP/PG25  Event indicator=Neg  Event type=Event indicating Not In Force  Event type=Payment or non-payment notifications  Lapsed in a contracting state announced via postgrant inform. from nat. office to EPO Corresponding cc:  Designated or member state=LI   Effective date of the event=1990-07-31  MEMBER STATE LEGAL DETAILS FOR NL  Actual or expected expiration date=1991-02-01    Legal state=DEAD    Status=LAPSED   Corresponding cc:  Designated or member state=NL     Event publication date=1989-07-31  Event code=EP/PGFP  Event indicator=Pos  Event type=Event indicating In Force  Event type=Payment or non-payment notifications  Postgrant: annual fees paid to national office   Annual fees payment date=1989-07-31     Year of payment of annual fees=8  Corresponding cc:  Designated or member state=NL     Event publication date=1991-02-01  Event code=EP/PG25  Event indicator=Neg  Event type=Event indicating Not In Force  Event type=Payment or non-payment notifications  Lapsed in a contracting state announced via postgrant inform. from nat. office to EPO Corresponding cc:  Designated or member state=NL   Effective date of the event=1991-02-01     Event publication date=1991-03-18  Event code=EP/NLV4  Event indicator=Neg  Event type=Event indicating Not In Force  Event type=Payment or non-payment notifications  NL: Lapsed or anulled due to non-payment of the annual fee NL: Vervallen wegens niet betalen van een jaarcijns Corresponding cc:  Designated or member state=NL
专利类型码
A1B1
国别省市代码
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