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* * * Section 1 - PRODUCT AND COMPANY IDENTIFICATION  * * *


Material Name: 
BRASS SCRAP
ChemADVISOR, Inc.
Stone Quarry Crossing 811 Camp Horne Road, Suite 220 Pittsburgh, PA 15237
E-mail: info@chemadvisor.com MSDS is for reference use only; please contact manufacturer for emergency response information, routine product inquiries and orders.
Chemical Family 
metal 

* * * Section 2 - HAZARDS IDENTIFICATION  * * *


Emergency Overview 

Color:  gray to red 

Change in color: Not available

Physical Form: solid

Health Hazards:  harmful if swallowed, respiratory tract irritation, skin irritation, eye irritation, nerve damage, kidney damage, birth defects, cancer 

Physical Hazards:  Negligible fire and explosion hazard in bulk form. Dust/air mixtures may ignite or explode. 

Potential Health Effects 
Inhalation 
Short Term:  irritation, allergic reactions, metal fume fever, difficulty breathing, wheezing, irregular heartbeat, symptoms of drunkenness, fainting, joint pain, bluish skin color, lung congestion, lung damage, heart damage, kidney damage, liver damage, nerve damage, paralysis, reproductive effects, convulsions, coma 

Long Term:  lack of sense of smell, black lines on the gums, hair loss, headache, disorientation, enlargement of breasts in males, impaired fertility, lung damage, bleeding, reproductive effects, cancer 

Skin Contact 
Short Term:  irritation, allergic reactions, burns, rash, itching, hair loss, wheezing 

Long Term:  skin disorders, tingling sensation 

Eye Contact 
Short Term:  irritation, burns, itching, blurred vision, dilated pupils or pin-point pupils, blindness 

Long Term:  same as effects reported in short term exposure 

Ingestion 
Short Term:  same as effects reported in short term inhalation, metallic taste, vomiting, loss of voice, irregular heartbeat, symptoms of drunkenness, fainting, hyperactivity, tingling sensation, joint pain, lung damage, heart damage, kidney damage, liver damage, reproductive effects, convulsions 

Long Term:  same as effects reported in long term inhalation, hair loss, lung congestion, bleeding, kidney damage, liver damage, reproductive effects, cancer 


* * * Section 3 - COMPOSITION / INFORMATION ON INGREDIENTS  * * *


CAS EC No Registration NoComponent Name Synonyms1272/2008 (CLP)Percent
7440-66-6 231-175-3 --ZINC--<51.0
7440-50-8 231-159-6 --COPPER-->=49.0
7439-96-5 231-105-1 --MANGANESE--<13.0
7439-92-1 231-100-4 --LEADAcute Tox. 4 (Oral) - H302 Acute Tox. 4 (Inh.) - H332 Repr. 1A - H360Df STOT RE 2 - H373 Aquatic Acute 1 - H400 Aquatic Chronic 1 - H410 Note(s): A, 1<=8.0
7429-90-5 231-072-3 --ALUMINUM, METALLIC, POWDERFlam. Sol. 1 - H228 Water-react. 2 - H261 Note(s): T<7.0
7440-31-5 231-141-8 --TIN--<6.0
7440-21-3 231-130-8 --SILICON--<=4.0
7439-89-6 231-096-4 --IRON--<=4.0
7440-02-0 231-111-4 --NICKELSkin Sens. 1 - H317 Carc. 2 - H351 STOT RE 1 - H372 Note(s): S, 7<1.0
7440-22-4 231-131-3 --SILVER--<1.0
7440-36-0 231-146-5 --ANTIMONYAcute Tox. 4 (Oral) - H302 Acute Tox. 4 (Inh.) - H332 Aquatic Chronic 2 - H411 Note(s): A, 1<1.0
7440-38-2 231-148-6 --ARSENICAcute Tox. 3 (Oral) - H301 Acute Tox. 3 (Inh.) - H331 Aquatic Acute 1 - H400 Aquatic Chronic 1 - H410<1.0
Component Related Regulatory Information 
This product may be regulated, have exposure limits or other information identified as the following: Zinc compounds, Copper, inorganic compounds, Copper compounds, n.o.s., Manganese compounds, n.o.s., Manganese compounds, inorganic, Lead compounds, Lead, inorganic compounds, Aluminium compounds, Aluminum, welding fumes, Antimony compounds, Antimony compounds, inorganic, n.o.s., Arsenic compounds, n.o.s., Arsenic, inorganic compounds, Silver compounds (inorganic), Silver compounds, Nickel compounds.

* * * Section 4 - FIRST AID MEASURES  * * *


Inhalation 
If adverse effects occur, remove to uncontaminated area. Give artificial respiration if not breathing. If breathing is difficult, oxygen should be administered by qualified personnel. Get immediate medical attention. 
Skin 
Wash skin with soap and water for at least 15 minutes while removing contaminated clothing and shoes. Get medical attention, if needed. Thoroughly clean and dry contaminated clothing and shoes before reuse. 
Eyes 
Flush eyes with plenty of water for at least 15 minutes. Then get immediate medical attention. 
Ingestion 
If a large amount is swallowed, get medical attention. 
Note to Physicians 
For inhalation, consider oxygen. 

* * * Section 5 - FIRE FIGHTING MEASURES  * * *


See Section 9 for Flammability Properties 
NFPA Ratings: 
Health: 3 Fire: 3 Reactivity: 0 Hazard Scale: 0 = Minimal 1 = Slight 2 = Moderate 3 = Serious 4 = Severe
Flammable Properties 
Negligible fire and explosion hazard in bulk form. Dust/air mixtures may ignite or explode. 
Extinguishing Media 
dolomite, dry powder for metal fires, dry sand, graphite, soda ash, sodium chloride Do not get water directly on material. 
Fire Fighting Measures 
Move container from fire area if it can be done without risk. Cool containers with water spray until well after the fire is out. Stay away from the ends of tanks. For fires in cargo or storage area: Cool containers with water from unmanned hose holder or monitor nozzles until well after fire is out. If this is impossible then take the following precautions: Keep unnecessary people away, isolate hazard area and deny entry. Let the fire burn. Use extinguishing agents appropriate for surrounding fire. Avoid inhalation of material or combustion by-products. 

* * * Section 6 - ACCIDENTAL RELEASE MEASURES  * * *


Water Release 
Subject to California Safe Drinking Water and Toxic Enforcement Act of 1986 (Proposition 65). Keep out of water supplies and sewers. 
Occupational spill/release 
Clean up residue with a high-efficiency particulate filter vacuum. Notify Local Emergency Planning Committee and State Emergency Response Commission for release greater than or equal to RQ (U.S. SARA Section 304). If release occurs in the U.S. and is reportable under CERCLA Section 103, notify the National Response Center at (800)424-8802 (USA) or (202)426-2675 (USA). 

* * * Section 7 - HANDLING AND STORAGE  * * *


Storage Procedures 
Store and handle in accordance with all current regulations and standards. 

* * * Section 8 - EXPOSURE CONTROLS / PERSONAL PROTECTION  * * *


Exposure Guidelines 
If an employee is exposed to lead for more than 8 hours in any work day, the permissible exposure limit, as a time weighted average (TWA) for that day, shall be reduced according to the following formula: Maximum permissible limit (in ug/m3) = 400 divided by hours worked in the day. 

Component Exposure Limits 

COPPER 7440-50-8
ACGIH:  0.2 mg/m3 TWA fume
NIOSH:  1 mg/m3 TWA dust and mist; 0.1 mg/m3 TWA fume
100 mg/m3 IDLH dust, fume and mist
OSHA (US):  0.1 mg/m3 TWA fume; 1 mg/m3 TWA dust and mist
Mexico:  0.2 mg/m3 TWA VLE-PPT as Cu fume; 1 mg/m3 TWA VLE-PPT as Cu dust and mist
2 mg/m3 STEL [PPT-CT] as Cu fume; 2 mg/m3 STEL [PPT-CT] as Cu dust and mist
MANGANESE 7439-96-5
ACGIH:  0.02 mg/m3 TWA respirable particulate matter; 0.1 mg/m3 TWA inhalable particulate matter
NIOSH:  1 mg/m3 TWA fume
3 mg/m3 STEL
500 mg/m3 IDLH
OSHA (US):  5 mg/m3 Ceiling fume
Mexico:  0.2 mg/m3 TWA VLE-PPT; 1 mg/m3 TWA VLE-PPT as Mn fume
3 mg/m3 STEL [PPT-CT] as Mn fume
LEAD 7439-92-1
ACGIH:  0.05 mg/m3 TWA
NIOSH:  0.05 mg/m3 TWA
100 mg/m3 IDLH
Europe:  0.15 mg/m3 TWA (air at 20°C and 101.3 kPa)
OSHA (US):  50 µg/m3 TWA
30 µg/m3 Action Level (See 29 CFR 1910.1025); 50 µg/m3 TWA (See 29 CFR 1910.1025)
Mexico:  0.15 mg/m3 TWA VLE-PPT as Pb dust and fume
ALUMINUM, METALLIC, POWDER 7429-90-5
ACGIH:  1 mg/m3 TWA respirable particulate matter
NIOSH:  10 mg/m3 TWA total dust; 5 mg/m3 TWA respirable dust
OSHA (US):  15 mg/m3 TWA total dust; 5 mg/m3 TWA respirable fraction
Mexico:  10 mg/m3 TWA VLE-PPT dust
TIN 7440-31-5
ACGIH:  2 mg/m3 TWA
NIOSH:  2 mg/m3 TWA
100 mg/m3 IDLH
Mexico:  2 mg/m3 TWA VLE-PPT
4 mg/m3 STEL [PPT-CT]
Skin - potential for cutaneous absorption
SILICON 7440-21-3
NIOSH:  10 mg/m3 TWA total dust; 5 mg/m3 TWA respirable dust
OSHA (US):  15 mg/m3 TWA total dust; 5 mg/m3 TWA respirable fraction
Mexico:  10 mg/m3 TWA VLE-PPT inhalable fraction
20 mg/m3 STEL [PPT-CT]
NICKEL 7440-02-0
ACGIH:  1.5 mg/m3 TWA inhalable particulate matter
NIOSH:  0.015 mg/m3 TWA
10 mg/m3 IDLH
OSHA (US):  1 mg/m3 TWA
Mexico:  1 mg/m3 TWA VLE-PPT
SILVER 7440-22-4
ACGIH:  0.1 mg/m3 TWA dust and fume
NIOSH:  0.01 mg/m3 TWA dust
10 mg/m3 IDLH dust
Europe:  0.1 mg/m3 TWA
OSHA (US):  0.01 mg/m3 TWA
Mexico:  0.1 mg/m3 TWA VLE-PPT
ANTIMONY 7440-36-0
ACGIH:  0.5 mg/m3 TWA
NIOSH:  0.5 mg/m3 TWA
50 mg/m3 IDLH
OSHA (US):  0.5 mg/m3 TWA
Mexico:  0.5 mg/m3 TWA VLE-PPT
ARSENIC 7440-38-2
ACGIH:  0.01 mg/m3 TWA
NIOSH:  0.002 mg/m3 Ceiling 15 min
5 mg/m3 IDLH
OSHA (US):  10 µg/m3 TWA as As (related to Arsenic inorganic compounds)
10 µg/m3 TWA (See 29 CFR 1910.1018, except Arsine) as As; 5 µg/m3 Action Level (See 29 CFR 1910.1018, except Arsine) as As (related to Arsenic inorganic compounds)
Mexico:  0.01 mg/m3 TWA VLE-PPT
Component Analysis 
Biological limit value 
There are no biological limit values for any of this product's components. 
LEAD (7439-92-1) 70 µg/100 mL Medium: blood Time: no restriction Parameter: Lead (binding biological limit value); 0.075 mg/m3 Medium: air Time: 40 hours per week Parameter: Lead (TWA medical surveillance threshold in air measured as a time weighted average over 40 hours per week); 40 µg/100 mL Medium: blood Time: no restriction Parameter: Lead (medical surveillance threshold measured in individual workers)
Ventilation 
Provide local exhaust or process enclosure ventilation system. Ensure compliance with applicable exposure limits. 
PERSONAL PROTECTIVE EQUIPMENT 
Eyes/Face Wear splash resistant safety goggles with a faceshield. Provide an emergency eye wash fountain and quick drench shower in the immediate work area. 
Protective Clothing 
Wear appropriate chemical resistant clothing. 
Glove Recommendations 
Wear appropriate chemical resistant gloves. 
Respiratory Protection 
Under conditions of frequent use or heavy exposure, respiratory protection may be needed. Respiratory protection is ranked in order from minimum to maximum. Consider warning properties before use. Any supplied-air respirator with a full facepiece that is operated in a pressure-demand or other positive-pressure mode. Any self-contained breathing apparatus that has a full facepiece and is operated in a pressure-demand or other positive-pressure mode. For Unknown Concentrations or Immediately Dangerous to Life or Health - Any supplied-air respirator with a full facepiece that is operated in a pressure-demand or other positive-pressure mode in combination with an auxiliary self-contained breathing apparatus operated in pressure-demand or other positive-pressure mode. Any self-contained breathing apparatus that has a full facepiece and is operated in a pressure-demand or other positive-pressure mode. 

* * * Section 9 - PHYSICAL AND CHEMICAL PROPERTIES  * * *


Appearance Not available  Physical State Solid
Odor Not available  Color gray to red
Odor Threshold Not available  pH Not available 
Melting Point 888 - 1083 °C Boiling Point 907 °C
Freezing point Not available  Evaporation Rate Not available 
Boiling Point Range Not available  Flammability (solid, gas) Not available 
Autoignition Not available  Flash Point flammable
Lower Explosive Limit Not available  Decomposition Not available 
Upper Explosive Limit Not available  Vapor Pressure 1 mmHg at 1628 °C
Vapor Density (air=1) Not available  Specific Gravity (water=1) 7.7 - 8.86
Water Solubility (insoluble) Partition coefficient: n-octanol/water Not available 
Viscosity Not available  Solubility (Other) Not available 
Density Not available  Physical Form solid
Solvent Solubility 
Soluble 
nitric acid, sulfuric acid 

* * * Section 10 - STABILITY AND REACTIVITY  * * *


Chemical Stability 
Water may react explosively with molten material. 
Conditions to Avoid 
Avoid generating dust. Avoid heat, flames, sparks and other sources of ignition. 
Incompatible Materials 
combustible materials, acids, oxidizing materials, metal salts, bases, halo carbons, halogens, peroxides, reducing agents, metal oxides, metals, amines, metal carbide, 

COPPER: ACETYLENE: Forms explosive copper acetylide. ACETYLENIC COMPOUNDS: Formation of explosive acetylides. ACIDS: May react. ALUMINUM + SULFUR: Possible explosion. AMMONIUM NITRATE: Violent or explosive reaction. BARIUM BROMATE: Explosive reaction by heat, impact or friction. BARIUM CHLORATE: Explosive reaction by heat, impact or friction. BARIUM IODATE: Explosive reaction by heat, impact or friction. BASES: May react. 1-BROMO-2-PROPYNE: Formation of explosive compound. CALCIUM BROMATE: Explosive reaction by heat, impact or friction. CALCIUM CHLORATE: Explosive reaction by heat, impact or friction. CALCIUM IODATE: Explosive reaction by heat, impact or friction. CHLORATES: Explosive reaction. CHLORINE: Ignition reaction. CHLORINE + OXYGEN DIFLUORIDE: Explosive reaction at -10 C. CHLORINE TRIFLUORIDE: Intense reaction with possible ignition. DIMETHYL SULFOXIDE + TRICHLOROACETIC ACID: Possible explosion. ETHYLENE OXIDE: Possible explosion. FLUORINE: Ignition reaction. HYDRAZINIUM NITRATE: Ignition reaction. HYDRAZOIC ACID: Possible explosion. HYDROGEN PEROXIDE: Violent decomposition. HYDROGEN SULFIDE: Intense exothermic reaction with possible ignition. LEAD AZIDE: Forms explosive copper azide. MAGNESIUM BROMATE: Explosive reaction by heat, impact or friction. MAGNESIUM CHLORATE: Explosive reaction by heat, impact or friction. MAGNESIUM IODATE: Explosive reaction by heat, impact or friction. OXIDIZERS: May react. PHOSPHORUS: Incandescent reaction. POTASSIUM BROMATE: Explosive reaction by heat, impact or friction. POTASSIUM CHLORATE: Explosive reaction by heat, impact or friction. POTASSIUM DIOXIDE: Incandescent reaction. POTASSIUM IODATE: Explosive reaction by heat, impact or friction. SODIUM AZIDE: Forms explosive compound. SODIUM BROMATE: Explosive reaction by heat, impact or friction. SODIUM CHLORATE: Explosive reaction by heat, impact or friction. SODIUM IODATE: Explosive reaction by heat, impact or friction. SODIUM PEROXIDE: Incandescent reaction. SULFUR + CHLORATES: Spontaneous explosion. SULFURIC ACID: Intense reaction. ZINC BROMATE: Explosive reaction by heat, impact or friction. ZINC CHLORATE: Explosive reaction by heat, impact or friction. ZINC IODATE: Explosive reaction by heat, impact or friction. LEAD: AMMONIUM NITRATE: Violent or explosive reaction. CHLORINE TRIFLUORIDE: Violent reaction. DISODIUM ACETYLIDE: Trituration in mortar may be violent and liberate carbon. HYDROGEN PEROXIDE (52% OR GREATER): Violent decomposition. HYDROGEN PEROXIDE (60% SOLUTION) + TRIOXANE: Spontaneously detonable. METALS (ACTIVE): Incompatible. NITRIC ACID: Lead-containing rubber may ignite. OXIDIZERS (STRONG): Incompatible. SODIUM AZIDE: Forms lead azide and copper azide in copper pipe. SODIUM CARBIDE: Vigorous reaction. SULFURIC ACID (HOT): Reacts. ZIRCONIUM-LEAD ALLOYS: Ignition on impact. TIN: ACIDS (STRONG): Can produce toxic organic or inorganic tin compounds. AMMONIUM NITRATE: Forms shock-sensitive mixture. BICARBONATE POWDER: Violent reaction. BROMINE (EXCEPT IN HALOCARBON SOLUTION): Violent reaction. BROMINE TRIFLUORIDE: Violent reaction. CARBON DIOXIDE: Violent reaction. CARBON TETRACHLORIDE + WATER: Violent reaction. CHLORINE (LIQUID): Ignites @ -34 C. CHLORINE TRIFLUORIDE: Violent reaction and possible ignition. CUPRIC NITRATE: Possible ignition. DISULFUR DICHLORIDE: Violent reaction. FLUORINE: Ignites @ 100 C. IODINE BROMIDE: Violent reaction. IODINE HEPTAFLUORIDE: Vigorous exothermic reaction when heated. PEROXIDE: Oxidation with incandescence may occur. POTASSIUM PEROXIDE: Incandescent reaction. POTASSIUM OXIDE: Oxidation with incandescence may occur. SODIUM PEROXIDE: Incandescent reaction. SODIUM PEROXIDE + CARBON DIOXIDE: Explodes. SULFUR: Ignition reaction. TELLURIUM: Vigorous exothermic reaction. TURPENTINE: Fire and explosion hazard. SILICON: ALUMINUM + LEAD OXIDE: Mixture may explode on heating. BROMINE TRIFLUORIDE: Ignition reaction. CESIUM ACETYLIDE: Vigorous reaction on heating. CALCIUM: Violently incandescent reaction above 1050 C, after a short delay. CHLORINE (GASEOUS): Ignition on contact at ambient temperatures. CHLORINE TRIFLUORIDE: Ignition reaction. COBALT TRIFLUORIDE: Exothermic reaction, attaining red heat on warming. FLUORINE: Ignites at room temperature; attains temperatures above 1400 C. HYDROFLUORIC ACID: Attacks silicon. HYDROFLUORIC ACID + NITRIC ACID MIXTURE: Attacks silicon. IODINE PENTAFLUORIDE: Incandescent reaction. IRIDIUM HEXAFLUORIDE: During reduction to pentafluoride, hexafluoride must not be condensed directly onto undiluted silicon powder or explosion may occur. LEAD OXIDE: An initiating mixture of silicon and lead dioxide (2: 1) attains a temperature around 1100 C after ignition by small flame. MANGANESE TRIFLUORIDE: Violent reaction. METAL CARBONATES (ALKALI): Exothermic reaction on heating, attaining incandescence and evolving carbon monoxide. MOLYBDENUM HEXAFLUORIDE: During reduction to pentafluoride, hexafluoride must not be condensed directly onto undiluted silicon powder or explosion may occur. NITROSYL FLUORIDE: Reacts with incandescence. OSMIUM HEXAFLUORIDE: During reduction to pentafluoride, hexafluoride must not be condensed directly onto undiluted silicon powder or explosion may occur. OXIDIZERS (STRONG): Fire and explosion hazard. OXYGEN DIFLUORIDE: Generates sparks on heating. PEROXYFORMIC ACID: Traces of manganese dioxide may promote oxidation with ignition. RHENIUM HEXAFLUORIDE: During reduction to pentafluoride, hexafluoride must not be condensed directly onto undiluted silicon powder or explosion may occur. RUBIDIUM ACETYLIDE: Reacts vigorously on warming. SILVER FLUORIDE: Violent reaction. SODIUM-POTASSIUM ALLOY: The reaction forms sodium silicide, which is spontaneously flammable in air. URANIUM HEXAFLUORIDE: During reduction to pentafluoride, hexafluoride must not be condensed directly onto undiluted silicon powder or explosion may occur. WATER: Combustible or explosive reaction at sufficiently high temperatures and pressures. IRON: ACETALDEHYDE: Polymerizes readily. AMMONIUM NITRATE: Violent or explosive reaction. AMMONIUM PEROXODISULFATE: Violent reaction. BROMINE PENTAFLUORIDE: Violent reaction and possible ignition. CHLORIC ACID: Forms explosive compound. CHLORINE (GAS): Ignites. CHLORINE TRIFLUORIDE: Violent reaction and possible ignition. CHLOROFORMAMIDINIUM NITRATE: Explosive ignition. DINITROGEN TETRAOXIDE: Ignites. FLUORINE: Ignites. HYDROGEN PEROXIDE: Violent decomposition. MINERAL ACIDS: Readily attacked. NITROGEN DIOXIDE: Incandescent reaction. NITRYL FLUORIDE: Incandesces when heated. ORGANIC ACIDS: Attacked or dissolved. PEROXYFORMIC ACID: Incompatible. PHOSPHORUS: Incandesces when heated. POLYSTYRENE BEADS: Possible static ignition. POTASSIUM DICHROMATE: Ignites on contact. POTASSIUM PERCHLORATE + MANGANESE DIOXIDE: Ignites. SODIUM ACETYLIDE: Possible violent reaction. SODIUM PEROXIDE: Ignites under friction @ 240 C. SULFURIC ACID: Possible explosion hazard. NICKEL: ACIDS (STRONG): Possible violent reaction. ALUMINUM: May react explosively on heating. AMMONIA: Possible violent reaction. AMMONIUM NITRATE: Violent or explosive reaction. BROMINE PENTAFLUORIDE: Violent reaction with possible ignition. ETHYLENE + ALUMINUM CHLORIDE: Violent, exothermic reaction. DIOXANE: Explosive reaction above 210 C. FLUORINE: Violent reaction. HYDRAZINE: Vigorous decomposition. HYDRAZOIC ACID: Vigorous decomposition. HYDROGEN: Exothermic above 150 C. METHANOL: Possible ignition. NITRIC ACID: Attacks. NITRYL FLUORIDE: Incandescence on warming. ORGANIC SOLVENTS: Possible explosion on heating. OXIDANTS: Violent reaction. PERFORMIC ACID: Violent reaction. PHOSPHORUS: Incandescence on heating. POTASSIUM PERCHLORATE, TITANIUM, AND INFUSORIAL EARTH: Shock-sensitive mixture. SELENIUM: Incandescent reaction with heating. SULFUR AND COMPOUNDS: Incandescent reaction with heating. ARSENIC: ACIDS: Reacts vigorously. BROMATES: Reacts vigorously. CHLORATES: Reacts vigorously. FLUORINE: Reacts vigorously. HYDROGEN GAS: Reacts vigorously. LITHIUM: Reacts vigorously. OXIDIZING MATERIALS: Reacts vigorously. PALLADIUM: Reacts vigorously. POTASSIUM: Reacts vigorously. ZINC: ACIDS: Evolves hydrogen gas which may be ignited by the heat of the reaction ALKALIES: Evolves hydrogen gas which may be ignited by the heat of the reaction. ALUMINUM (POWDER): Possible ignition. ALUMINUM-MAGNESIUM ALLOY + RUSTED STEEL: May spark on impact. AMMONIUM NITRATE: Violent reaction or formation of explosive mixture. AMMONIUM SULFIDE: May explode in a closed container. ARSENIC: Incandescent reaction when heated. ARSENIC TRIOXIDE: Explosive reaction on heating. BROMOMETHANE: Forms flammable compounds. CADMIUM: Incandescent reaction. CALCIUM CHLORIDE: Evolves hydrogen gas which may be ignited by the heat of the reaction. CARBON DISULFIDE: Incandescent reaction. CARBON TETRACHLORIDE + METHANOL: Extremely vigorous reaction. CHLORATES: Forms shock-sensitive mixtures. CHLORINATED RUBBER: Violent or explosive reaction at elevated temperatures. CHROMIC ANHYDRIDE: Violent reaction and possible ignition. COBALT HALIDE (METHANOLIC SOLUTION) + IRON PENTACARBONYL: Violent reaction. ETHYL ACETOACETATE + TRIBROMONEOPENTYL ALCOHOL: May react explosively. HALOCARBONS: Possible violent reaction with ignition. HALOGENS: Possible ignition. HYDRAZINE NITRATE: Ignites on warming. HYDROXYLAMINE: May ignite or explode when heated. INTERHALOGENS: Violent reaction and possible ignition. LEAD AZIDE: Increased sensitivity to explosive decomposition. MANGANESE DICHLORIDE: Explosive reaction when heated. METAL OXIDES: Possible ignition or incandescent reaction. NITRIC ACID: Incandescent reaction. 2-NITROANISOLE + SODIUM HYDROXIDE: Exothermic reaction. NITROBENZENE: May form pyrophoric residue. NITRYL FLUORIDE: Incandesces when warmed. OXIDIZERS (STRONG): Fire and explosion hazard. PEROXYFORMIC ACID: Violent explosion on contact. POTASSIUM NITRATE: Explosive reaction on heating. POTASSIUM PEROXIDE: Incandescent reaction. RHODIUM HALIDES (METHANOLIC SOLUTION) + IRON PENTACARBONYL: Violent reaction. RUTHENIUM HALIDES (METHANOLIC SOLUTION) + IRON PENTACARBONYL: Violent reaction. SELENIUM: Incandescent reaction. SELENINYL BROMIDE: Ignition. SILVER + ELECTROLYTES (BATTERIES): May spontaneously combust. SODIUM PEROXIDE: Incandescent reaction. SULFUR: Violent reaction. TELLURIUM: Incandescent reaction. ZINC CHLORIDE: May increase flammability. MANGANESE: ALUMINUM (DUST): Forms explosive mixtures with air. AMMONIUM NITRATE (FUSED): Violent or explosive reaction. BROMINE PENTAFLUORIDE: Violent reaction and possible ignition. CARBON DIOXIDE: Ignites. CHLORINE: Ignites. FLUORINE: Incandescent reaction. HYDROGEN PEROXIDE: Violent decomposition and/or ignition. NITRIC ACID: Incandescent reaction and feeble explosion. NITROGEN DIOXIDE: Ignition. OXIDIZERS (STRONG): Fire and explosion hazard. PHOSPHORUS: Incandescent reaction when heated. SULFUR DIOXIDE: Burns brilliantly on warming.

Hazardous Decomposition Products 
miscellaneous decomposition products 

Thermal decomposition products: miscellaneous decomposition products.

Possibility of Hazardous Reactions 
Will not polymerize. 

* * * Section 11 - TOXICOLOGICAL INFORMATION  * * *


Component Analysis - LD50/LC50 

The components of this material have been reviewed in various sources and the following selected endpoints are published: 
MANGANESE (7439-96-5) Oral LD50 Rat 9 g/kg TIN (7440-31-5) Oral LD50 Rat 700 mg/kg SILICON (7440-21-3) Oral LD50 Rat 3160 mg/kg IRON (7439-89-6) Oral LD50 Rat 984 mg/kg NICKEL (7440-02-0) Oral LD50 Rat >9000 mg/kg SILVER (7440-22-4) Oral LD50 Rat >2000 mg/kg ANTIMONY (7440-36-0) Oral LD50 Rat 7 g/kg ARSENIC (7440-38-2) Oral LD50 Rat 15 mg/kg

Component Carcinogenicity

MANGANESE 7439-96-5
ACGIH:  A4 - Not Classifiable as a Human Carcinogen
LEAD 7439-92-1
ACGIH:  A3 - Confirmed Animal Carcinogen with Unknown Relevance to Humans
IARC:  Monograph 87 [2006] (Monograph 87 evaluates inorganic lead compounds as Group 2A and organic lead compounds as Group 3. CAS 7439-92-1 still assigned 2B on IARC website even though Monograph 87 assigns 2A with more recent date) (Group 2A (probably carcinogenic to humans))
NTP:  Reasonably Anticipated To Be A Human Carcinogen
DFG:  Category 2 (considered to be carcinogenic for man)
OSHA:  Present
ALUMINUM, METALLIC, POWDER 7429-90-5
ACGIH:  A4 - Not Classifiable as a Human Carcinogen
NICKEL 7440-02-0
ACGIH:  A5 - Not Suspected as a Human Carcinogen
IARC:  Monograph 100C [2012]; Monograph 49 [1990] (evaluated as a group) (related to Nickel compounds) (Group 1 (carcinogenic to humans))
IARC:  Monograph 49 [1990]; Supplement 7 [1987] (Group 2B (possibly carcinogenic to humans))
NTP:  Known Human Carcinogen (related to Nickel compounds)
NTP:  Reasonably Anticipated To Be A Human Carcinogen
DFG:  Category 1 (causes cancer in man)
OSHA:  Present
ANTIMONY 7440-36-0
DFG:  Category 2 (considered to be carcinogenic for man)
ARSENIC 7440-38-2
ACGIH:  A1 - Confirmed Human Carcinogen
IARC:  Monograph 100C [2012]; Monograph 84 [2004] (in drinking water); Supplement 7 [1987]; Monograph 23 [1980] (Group 1 (carcinogenic to humans))
NTP:  Known Human Carcinogen
DFG:  Category 1 (causes cancer in man)
OSHA:  Present
OSHA:  see 29 CFR 1910.1018 except Arsine) (related to Arsenic inorganic compounds)

Iron itself has not been evaluated by IARC However iron and steel founding has been evaluated as IARC Group 1 (Human Sufficient Evidence) Studies have shown that certain exposures in iron and steel founding can cause lung cancer in humans Excesses of leukemia and urogenital and digestive system cancers have also been reported Renal tumors were produced in animals by lead acetate, lead subacetate, and lead phosphate given orally, subcutaneously, or intraperitoneally Two studies in rats exposed to lead powder orally or by intramuscular injection and one study on intrarenal injection did not produce tumors Aluminum itself has not been evaluated by IARC However, aluminum production has been evaluated as IARC Group 1 (Human Sufficient Evidence) There is sufficient evidence that certain exposures occurring during aluminum production cause cancer An increased incidence of urinary bladder, skin, lung, liver, and kidney cancer has been associated with inorganic arsenic compounds through medical treatment, contaminated drinking water, arsenical pesticide residues or occupational exposure Cancers at other sites have also been reported, but a clear association has not been confirmed Metallic nickel was tested by inhalation exposure in mice, rats and guinea-pigs, by intratracheal instillation in rats, by intramuscular injection in rats and hamsters, and by intrapleural, subcutaneous, intraperitoneal and intrarenal injection in rats The studies by inhalation exposure were inadequate for an assessment of carcinogenicity After intratracheal instillation, it produced significant numbers of squamous-cell carcinomas and adenocarcinomas of the lung Intrapleural injections induced sarcomas in rats Subcutaneous administration of metallic nickel pellets induced sarcomas in rats, intramuscular injection of nickel powder induced sarcomas in rats and hamsters, and intraperitoneal injections induced carcinomas and sarcomas in rats There is inadequate evidence in humans and limited evidence in experimental animals for the carcinogenicity of nickel alloys A ferronickel alloy did not induce local tumors after intramuscular or intrarenal injection in rats Two powdered nickel alloys induced malignant tumors following intraperitoneal injection in rats, and one nickel alloy induced sarcomas following subcutaneous implantation of pellets in rats. 

Medical Conditions Aggravated by Exposure 
blood system disorders, blood system disorders, Alzheimer's disease, immune system disorders or allergies, respiratory disorders, diabetes, history of alcoholism, gastrointestinal disorders, kidney disorders, kidney disorders, respiratory disorders, skin disorders and allergies, heart or cardiovascular disorders, blood system disorders, nervous system disorders, liver disorders, respiratory disorders, skin disorders and allergies, immune system disorders or allergies, liver disorders, respiratory disorders, respiratory disorders, kidney disorders, nervous system disorders, skin disorders and allergies, liver disorders, respiratory disorders, nervous system disorders, skin disorders and allergies, 
Additional Data 
May cross the placenta Smoking may result in higher blood lead levels May be excreted in breast milk. 

Nephrotoxicity has been demonstrated with excessive exposure to silicon Elevated aluminum levels have been associated with Alzheimer's disease, neurofibrillary degeneration, and anemia Excessive zinc intake has been associated with a copper-deficiency anemia Symptoms may depend on a combination of contributing factors including genetic predisposition, age, nutrition, anemia or alcohol. 

Inhalation - Acute Exposure 
COPPER: Powdered dust may cause irritation of the upper respiratory tract and ulceration and perforation of the nasal septum A feeling of illness similar to the common cold has been reported with symptoms of chills and stuffiness of the head Workers exposed to copper dust in concentrations of 0.075 to 0.120 mg/m3 complained of mild nasal discomfort Exposure to copper fume may cause irritation to the mucous membranes Freshly formed copper fumes may cause metal fume fever Symptoms may include a sweet, metallic, or foul taste in the mouth, dry throat, coughing, fever, chills, muscle aches, weakness, lassitude, nausea, rarely vomiting, mild to severe headaches, and sometimes exaggerated mental activity Workers exposed to concentrations of 1 to 3 mg/m3 experienced an altered taste response but no nausea ZINC: Inhalation of dust may cause irritation with difficulty in breathing and sneezing Neurological and psychiatric symptomology including irritability, upper extremity coarse intention tremor, incoordination, and ataxia have also been reported Metal fume fever, an influenza-like illness, may occur due to the inhalation of freshly formed metal oxide particles sized below 1.5 microns and usually between 0.02-0.05 microns Symptoms may be delayed 4-12 hours and begin with a sudden onset of thirst, and a sweet, metallic, or foul taste in the mouth Other symptoms may include upper respiratory tract irritation accompanied by coughing and a dryness of the mucous membranes, lassitude, and a generalized feeling of malaise Fever, chills, muscular pain, mild to severe headache, nausea, occasional vomiting, exaggerated mental activity, profuse sweating, excessive urination, diarrhea, and prostration may also occur Tolerance to fumes develops rapidly, but it is quickly lost All symptoms usually subside within 24-36 hours MANGANESE: Dust or fumes may be irritating to the mucous membranes Occupational exposure to dust or fumes has been reported to cause upper respiratory tract problems, black mucous membrane discharge from the nose, and neurological damage Metal fume fever, an influenza-like illness, may occur due to the inhalation of freshly formed metal oxide particles sized below 1.5 microns and usually between 0.02-0.05 microns Symptoms may be delayed 4-12 hours and begin with a sudden onset of thirst, and a sweet, metallic or foul taste in the mouth Other symptoms may include upper respiratory tract irritation accompanied by coughing and a dryness of the mucous membranes, lassitude and a generalized feeling of malaise Fever, chills, muscular pain, mild to severe headache, nausea, occasional vomiting, exaggerated mental activity, profuse sweating, excessive urination, diarrhea and prostration may also occur Tolerance to fumes develops rapidly, but is quickly lost All symptoms usually subside within 24-36 hours LEAD COMPOUNDS: Absorption of large amounts of lead may cause a metallic taste, thirst, a burning sensation in the mouth and throat, salivation, abdominal pain with severe colic, vomiting, diarrhea of black or bloody stools, constipation, fatigue, sleep disturbances, dullness, restlessness, irritability, memory loss, loss of concentration, delirium, oliguria often with hematuria and albuminuria, encephalopathy with visual failure, paresthesias, muscle pain and weakness, convulsions, and paralysis Death may result from cardiorespiratory arrest or shock Survivors of acute exposure may experience the onset of chronic intoxication Liver effects may include enlargement and tenderness, and jaundice The fatal dose of absorbed lead is approximately 0.5 grams Pathological findings include gastrointestinal inflammation and renal tubular degeneration METAL FUME FEVER: Metal fume fever, an influenza-like illness, may occur due to the inhalation of freshly formed metal oxide particles sized below 1.5 microns and usually between 0.02-0.05 microns Symptoms may be delayed 4-12 hours and begin with a sudden onset of thirst, and a sweet, metallic or foul taste in the mouth Other symptoms may include upper respiratory tract irritation accompanied by coughing and a dryness of the mucous membranes, lassitude and a generalized feeling of malaise Fever, chills, muscular pain, mild to severe headache, nausea, occasional vomiting, exaggerated mental activity, profuse sweating, excessive urination, diarrhea and prostration may also occur Tolerance to fumes develops rapidly, but is quickly lost All symptoms usually subside within 24-36 hours TIN: Inhalation of inorganic tin compounds may cause respiratory irritation Metal fume fever, an influenza-like illness, may occur due to the inhalation of freshly formed metal oxide particles sized below 1.5 microns and usually between 0.02-0.05 microns Symptoms may be delayed 4-12 hours and begin with a sudden onset of thirst and a sweet, metallic or foul taste in the mouth Other symptoms may include upper respiratory tract irritation accompanied by coughing and a dryness of the mucous membranes, lassitude and a generalized feeling of malaise Fever, chills, muscular pain, mild to severe headache, nausea, occasional vomiting, exaggerated mental activity, profuse sweating, excessive urination, diarrhea, and prostration may also occur Tolerance to fumes develops rapidly, but is quickly lost All symptoms usually subside within 24-36 hours SILICON: Dust may cause respiratory and mucous membrane irritation and cough Intratracheal administration of 25 mg in rabbits produced slight pulmonary lesions IRON: Dust may cause mucous membrane and respiratory irritation due to mechanical action Metal fume fever, an influenza-like illness, may occur due to the inhalation of freshly formed iron oxide particles sized below 1.5 microns and usually between 0.02-0.05 microns Symptoms may be delayed 4-12 hours and begin with a sudden onset of thirst, and a sweet, metallic or foul taste in the mouth Other symptoms may include upper respiratory tract irritation accompanied by coughing and a dryness of the mucous membranes Lassitude and a generalized feeling of malaise Fever, chills, muscular pain, mild to severe headache, nausea, occasional vomiting, exaggerated mental activity, profuse sweating, excessive urination, diarrhea and prostration may also occur Tolerance to fumes develops rapidly, but is quickly lost All symptoms usually subside within 24-36 hours NICKEL: May cause respiratory irritation, cough, pneumonitis and fever Overexposure may cause headache, dizziness, and difficult breathing Pulmonary edema may be a delayed symptom Pulmonary sensitization may occur causing eosinophilic pneumonitis, asthma and host rejection of nickel containing prostheses Two workers experienced severe but transient pneumonitis after being exposed to 0.26 mg/m3 for six hours ARSENIC: Inhalation of inorganic arsenic compounds may cause severe irritation of the nasal mucosa, larynx, and bronchi, cough with foamy sputum, pain in the chest on inspiration, dyspnea, lassitude, cyanosis, giddiness, headache, extreme general weakness, nausea, vomiting, colic, diarrhea, pain in the limbs, initial rise and then fall of temperature, leucocytosis, hypotension, and possibly pulmonary edema.
Inhalation - Chronic Exposure 
COPPER: Prolonged industrial exposure may cause a green discoloration of the skin, hair and teeth Welders exposed to copper fume experienced atrophic rhinitis, metallic taste, runny nose, and mucosal irritation of the mouth and eyes Exposure in animals has caused destruction of red blood cells and lung cell injury It is inconclusive as to whether prolonged exposure has any affect on the nervous system A small number of studies suggest an affinity of copper for the sympathetic system, however, there is no proof that chronic poisoning will affect either the central or peripheral nervous system ZINC: Severe gastrointestinal disturbances and hypochromic anemia have been reported, but other chemicals may have contributed to the effects MANGANESE: If sufficient quantities of manganese dust or fumes are inhaled and absorbed, systemic poisoning known as 'manganism', a Parkinsonian-like syndrome may occur It is characterized initially by anorexia, asthenia, headache, insomnia or somnolence, irritability, restlessness, and spasm or pain in the muscles Manganese psychosis may follow with uncontrollable behavior, unaccountable laughing or crying, visual hallucinations, confusion and euphoria Sexual excitement followed by impotence may occur These symptoms may disappear with the onset of true neurological manifestations of slow, slurred and irregular speech, monotonous tone, double vision, impaired hearing, difficulty with fine motor movements, and disturbances in gait and balance with frequent propulsion or retropulsion Mask-like face, decreased movement of the eyelids and eyes and tremors of the upper extremities and head may also occur Other signs and symptoms may include urinary bladder disturbances, excessive salivation and sweating, hematological changes, vasomotor disorders, decreased pulmonary function, kidney and possibly liver damage Removal from exposure shortly after onset of symptoms usually results in improvement, although there may be residual disturbances in gait and speech Once manganism is well established it becomes irreversible and progressive, but not fatal An increased incidence of bronchitis and pneumonitis has been reported in studies of workers exposed to manganese dust and fume, and although these effects have been confirmed by animal experiments, they may represent an aggravation of a pre-existing condition Allergic diseases of the respiratory tract have also been reported in one study LEAD COMPOUNDS: Prolonged or repeated exposure to low levels of lead may result in an accumulation in body tissues and exert adverse effects on the blood, nervous systems, heart, endocrine and immune systems, kidneys, and reproduction Early stages of lead poisoning, 'plumbism', may be evidenced by anorexia, weight loss, constipation, apathy or irritability, occasional vomiting, fatigue, headache, weakness, metallic taste in the mouth, gingival lead line in persons with poor dental hygiene, and anemia Loss of recently developed motor skills is generally observed only in children More advanced stages of poisoning may be characterized by intermittent vomiting, irritability and nervousness, myalgia of the arms, legs, joints and abdomen, paralysis of the extensor muscles of the arms and legs with wrist and/or foot drop Severe 'plumbism' may result in persistent vomiting, ataxia, periods of stupor or lethargy, encephalopathy with visual disturbances which may progress to optic neuritis and atrophy, hypertension, papilledema, cranial nerve paralysis, delirium, convulsions, and coma Neurologic sequelae may include mental retardation, seizures, cerebral palsy, and dystonia musculorum deformans Irreversible kidney damage has been associated with industrial exposure Reproductive effects have been exhibited in both males and females Paternal effects may include decreased sex drive, impotence, sterility and adverse effects on the sperm which may increase the risk of birth defects Maternal effects may include miscarriage and stillbirths in exposed women or women whose husbands were exposed, abortion, sterility or decreased fertility, and abnormal menstrual cycles Lead crosses the placenta and may affect the fetus causing birth defects, mental retardation, behavioral disorders, and death during the first year of childhood Animal studies indicate that reproductive effects may be additive if both parents are exposed to lead METAL FUME FEVER: There is no form of chronic metal fume fever, however, repeated bouts with symptoms as described above are quite common Resistance to the condition develops after a few days of exposure, but is quickly lost in 1 or 2 days TIN: Repeated or prolonged exposure to dust or fumes may cause a benign pneumoconiosis without fibrosis SILICON: Inert dust may cause excessive production of mucous, mucous gland hypertrophy, and increased airway resistance and may contribute to chronic bronchitis IRON: Prolonged or repeated exposure may cause a mottling of the lungs, a condition called siderosis which is considered to be a benign pneumoconiosis that does not cause significant physiologic impairment Symptoms may include chronic bronchitis, emphysema, and dyspnea on exertion NICKEL: Repeated or prolonged inhalation may cause mucous membrane irritation and pulmonary sensitization Workers exposed to nickel dust frequently developed chronic hypertrophic rhinitis and nasal sinusitis Anosmia, nasal polyposis and perforation of the nasal septum may also occur Rabbits exposed to 1 mg/m3 dust for 6 hours per day, five days a week for up to six months showed two- to three- fold increases in the volume density of alveolar type II cells The six-month exposure caused focal pneumonia Rats injected intratracheally once a week with 0.9 mg for ten weeks or 0.3 mg for 20 weeks showed adenocarcinomas, squamous-cell carcinomas, one adenoma and one mixed tumor ARSENIC: May cause weakness, loss of appetite, nausea, occasional vomiting, a sense of heaviness in the stomach, diarrhea, salivation, upper respiratory inflammation and discharge, conjunctivitis, a catarrhal state of the mucous membranes of the nose, larynx, and respiratory passages, coryza, hoarseness, mild tracheobronchitis, and perforation of the nasal septum Skin lesions may occur and take many forms including increased pigmentation, keratosis of palms and soles eczema-like lesions, pale bands on the fingernails, alopecia and vitiligo Peripheral neuritis may develop initially of the hands and feet, which is usually sensory In very severe cases, motor paralysis may occur; the first muscles affected are usually the toe extensors and the peronei, and in only the most severe cases will paralysis of the flexor muscles of the feet or of the extensor muscles of the hands occur Liver disease with cirrhosis, and depression of bone marrow may occur with various blood dyscrasias including aplastic anemia Inorganic arsenic compounds have been shown to be lung carcinogens in humans The latency time between onset of exposure and the appearance of cancer is usually between 15 and 30 years.
Inhalation - Other Toxicity Information 
LEAD: See information on lead compounds and metal fume fever ALUMINUM, METALLIC, POWDER: May cause irritation with coughing and shortness of breath Exposure to freshly formed fumes of aluminum may result in metal fume fever See information on metal fume fever Prolonged or repeated exposure to large concentrations of fine dust may cause emphysema, bronchial asthma and pulmonary fibrosis characterized by coughing, sputum production, weakness, anorexia, basal crackles, dyspnea, pneumothorax, and cardiac failure Radiographic and pathological changes in the lungs may occur The lung disease may be rapidly progressive, irreversible, and fatal Bacterial infection may cause progression of the lung disease A few rare cases of encephalophathy have been reported from occupational exposure; symptoms included mental deterioration and seizures In sensitive individuals, aluminum may exacerbate asthma Epidemiological studies of aluminum production have reported increased incidences of lung, bladder, and other cancers among exposed workers However, the causative agents for these cancers have not been determined.
Skin Contact - Acute Exposure 
ZINC: Dust may cause mechanical irritation and mild dermatitis in intertriginous areas Reaction with moisture on skin may result in serious burns MANGANESE: 500 mg applied to the skin of rabbits caused mild irritation LEAD COMPOUNDS: Contact with lead powders or dust may be irritating TIN: No reported effects in humans from tin dust Inorganic tin compounds may cause irritation ALUMINUM, METALLIC, POWDER: May cause irritation by abrasion SILICON: May cause mechanical irritation COPPER: May be irritating and cause keratinization Allergic dermatitis although rare, has been reported Dermal absorption is negligible through intact skin IRON: Dust may cause irritation Penetration of iron particles in the skin may cause an exogenous siderosis which may be characterized by a red-brown pigmentation of the affected area.
Skin Contact - Chronic Exposure 
COPPER: Repeated or prolonged contact may cause irritation and discoloration of the skin LEAD COMPOUNDS: Prolonged or repeated exposure to the powder or dust may result in dermatitis ALUMINUM, METALLIC, POWDER: May cause dermatitis with itching Rarely, sensitization reactions have been reported Vascular changes in the skin and congestive numbness of the fingers have been reported from occupational exposure ZINC: 300 ug applied to human skin intermittently for 3 days caused mild irritation Allergic reactions are rare, but have been reported SILICON: No data available MANGANESE: Sensitization has been reported in guinea pigs TIN: Repeated or prolonged contact with inorganic tin compounds may cause dermatitis IRON: May cause same effects as reported in acute exposure.
Skin Contact - Other Toxicity Information 
LEAD See information on lead compounds.
Eye Contact - Acute Exposure 
ALUMINUM, METALLIC, POWDER: May cause irritation due to abrasion and corneal necrosis Intraocular aluminum deposits in human eyes have been well tolerated for several years without injurous effect, except occasionally slight depigmentation of adjacent iris A low-grade uveal inflammation with posterior synechias, partial atrophy of the iris, and small opacities in the lenses and pigmentation of the fundus was reported in rabbits from intraocular deposits MANGANESE: Dust or fumes may be irritating to the eyes 500 mg applied to the eyes of rabbits caused mild irritation ZINC: Dust may cause mechanical irritation or injury to the surface of the eye, with discomfort, reddening, and tearing Direct contact may cause serious corneal burns TIN: Powder may cause moderate irritation SILICON: Silicon dust may cause irritation IRON: May cause irritation due to mechanical action Iron particles imbedded in the eye may cause ocular siderosis Effects may include discoloration of the cornea and iris, and pupillary effects including poor reaction to light and accomodation If a particle enters the lens there may be cataract formation Glaucoma occurs rarely in some cases of ocular siderosis COPPER: The dust may cause irritation with redness and pain, tearing, and blurred vision Copper particles in the eye may result in a foreign body response with characteristic discoloration of ocular tissue, degeneration and/or detachment of the retina, and atrophy of the globe LEAD COMPOUNDS: Lead dust or powders may be irritating Metallic lead particles may cause an inflammatory foreign body reaction Injury is generally thought to be mechanical and not toxic.
Eye Contact - Chronic Exposure 
ZINC: No data available IRON: Repeated and prolonged contact may cause conjunctivitis and other effects reported in acute exposure ALUMINUM, METALLIC, POWDER: Capillary changes in the conjunctiva were observed in workers of one aluminum plant MANGANESE: Fumes may cause conjunctivitis COPPER: Repeated or prolonged exposure to irritants may cause conjunctivitis SILICON: No data available TIN: Repeated or prolonged exposure to inorganic tin compounds may cause conjunctivitis LEAD COMPOUNDS: Prolonged exposure may cause conjunctivitis.
Eye - Other Toxicity Information 
LEAD See information on lead compounds.
Ingestion - Acute Exposure 
COPPER: May cause headache, weakness, diarrhea, or weight loss 120 ug/kg ingested by a human caused gastrointestinal disorder with nausea and vomiting ZINC: Large oral doses may cause gastrointestinal distress with stomach cramps, dehydration, electrolyte imbalance, abdominal pain, nausea, vomiting, hematemesis, diarrhea, lethargy, immune system effects, fever, dizziness, tightness in the throat, shock, collapse, renal failure, and death Survivors may have residual nephritis and strictures of the esophagus and pyloric end of the stomach MANGANESE: Extremely large doses may cause gastrointestinal irritation and possibly systemic toxicity LEAD COMPOUNDS: Absorption of large amounts of lead from the intestinal tract may cause effects as detailed in acute inhalation The fatal dose of absorbed lead is approximately 0.5 grams ALUMINUM, METALLIC, POWDER: Large doses may cause gastrointestinal irritation, vomiting and diarrhea Aluminum is poorly absorbed and may decrease absorption of other substances Neurotoxic effects may occur in persons with impaired kidney function or chronic renal failure TIN: Relatively non-toxic because of poor absorption At very high levels, abdominal pain, nausea, vomiting, gastric irritation, and diarrhea may occur SILICON: May cause digestive tract irritation IRON: There are no reports available on poisoning from metallic iron, which is poorly absorbed The principal manifestations of poisoning with iron compounds are vomiting, diarrhea, and circulatory collapse NICKEL: Insoluble nickel compounds have a low level of toxicity due to poor absorption from the gastrointestinal tract Overexposure may cause headache, nausea, vomiting, dizziness, and gastrointestinal irritation ARSENIC: Ingestion of large doses may cause systemic poisoning with delayed symptoms usually appearing one hour after absorption Symptoms may include burning and colicky pains in the esophagus, stomach and bowel, contriction in the throat, difficulty in swallowing, muscular cramps, weakness, a sweetish metallic taste and a garlicky odor of the breath and feces Violent gastroenteritis may occur with vomiting, copious watery or bloody diarrhea containing shreds of mucus, and dehydration with intense thirst and muscular cramps Vertigo, frontal headache, delirium and even mania may develop without prominent gastrointestinal signs Later symptoms may include, cold and clammy skin, fall in blood pressure, extreme weakness, edema of the face and eyelids, tachycardia, vasomotor collapse, convulsions, shock, coma and death due to circulatory failure Death after a fatal dose occurs usually between 12 and 48 hours If the victim recovers, a symmetrical peripheral neuropathy may occur with numbness and paresthesias beginning in the distal extremities, lower limbs before the upper, which spreads rapidly and increases in intensity Motor weakness of the distal extremities may occur and the palsy is likely to affect the long extensors of fingers and toes Horizontal white lines (striations) on the fingernails and toenails are commonly seen and are considered to be a diagnostic accompaniment of arsenical polyneuritis Other adverse effects seen after recovery may include jaundice, oliguria or anuria, anemia, leukopenia and exfoliative dermatitis Inorganic arsenic crosses the placenta barrier, and neonatal death from arsenic has been reported following acute maternal intoxication.
Ingestion - Chronic Exposure 
COPPER: Copper is an essential element and is found in most human diets in minute amounts Prolonged ingestion through the diet is not known to cause toxic effects except in people with a recessive gene disorder termed Wilson's disease which causes an abnormally high absorption, retention, and storage of copper by the body This disease may cause a dysfunction of and structural damage to the liver, central nervous system, kidney, bones and eyes The disease is usually progressive and may be fatal if left untreated Reproductive effects have been reported in animals ZINC: Patients taking zinc in amounts 10 times the RDA for months and years have not shown any adverse reactions Excessive absorption may cause copper-deficiency anemia Ingestion of approximately 85.7 mg/kg/day for 2 days caused lethargy, lightheadedness, staggering, and difficulty in writing clearly 2 people who ingested 40 ppm in drinking water for several months experienced lack of concentration, drowsiness, mental and physical fatigue, pain in the arms and legs, headache, stiffness, muscle pains, loss of appetite, nausea, weight loss, and lassitude 90 ppm in the diet for 5 weeks has resulted in a decrease in the HDL cholesterol level Pancreatic abnormalities have also been observed A diet of 0.25% in rats caused no injury; above 0.25% there was breakdown of the homeostatic mechanism, growth retardation, hypochromic anemia, and defective mineralization of the bones Mice fed 500 ppm for 14 months exhibited hypertrophy of the adrenal cortex and changes indicating hyperactivity of the pancreatic islets and pituitary gland; 30,000 ppm for 13 weeks caused liver and kidney damage and some deaths Cows fed 2% for 2 days developed severe enteritis, with 7 of 40 dying Severe pulmonary emphysema and changes in the myocardium, kidneys, and liver were observed Pigs fed >1000 ppm had reduced food intake and weight gain; at >2000 ppm, death occurred after 2 weeks Bone changes were observed in foals fed 5400 ppm High dietary levels of zinc have been associated with reduced fetal weights, altered concentrations of fetal iron and copper, and alopecia and reduced growth of offspring in animals MANGANESE: Manganese poisoning has been reported in persons drinking manganese-contaminated well water Prolonged ingestion of manganese in water has produced lethargy, edema, and decreased movement of the eyes and eyelids LEAD COMPOUNDS: Prolonged or repeated exposure to low levels of lead may result in an accumulation in body tissues and adverse effects on the kidneys, heart and blood and on the nervous, reproductive, endocrine and immune systems as detailed in chronic inhalation ALUMINUM, METALLIC, POWDER: Animals with a diet of 340 ppm showed decreased growth in 2nd and 3rd generations TIN: Repeated or prolonged ingestion of small quantities may cause abdominal pain, nausea, constipation, and loss of weight SILICON: No data available IRON: Repeated or prolonged exposure may cause hemosiderosis or hemochromatosis NICKEL: Reproductive effects have been reported in animals ARSENIC: Repeated ingestion of small amounts may cause gastrointestinal symptoms such as diarrhea alternating with constipation, nausea, vomiting, abdominal cramps, salivation, malaise, fatigue, and loss of appetite and weight Damage to the nervous system may be apparent with polyneuritis, anesthesias, paresthesia such as burning pain in the hands and feet, and optic neuritis The skin may be affected with pigmentation, localized edema, dermatitis, hyperkeratosis, and alopecia Eye involvement may occur causing conjunctivitis with a sensation of irritation and tearing Pigment spots in the epithelium of both the cornea and conjunctiva may appear Other signs of poisoning may include anemia, leukopenia, thrombocytopenia, disturbed erythropoiesis in the bone marrow cells, depressed or disturbed myelopoiesis, hepatitis, cirrhosis or noncirrhotic portal entry Skin and lung cancer in humans is associated with chronic exposure to arsenic Repeated administration to female rats prior to mating produced effects on fertility Repeated administration during gestation produced specific developmental abnormalities in the offspring.
Ingestion - Other Toxicity Information 
LEAD See information on lead compounds.

* * * Section 12 - ECOLOGICAL INFORMATION  * * *


Component Analysis - Aquatic Toxicity 

ZINC 7440-66-6
Fish:  LC50 96 h Pimephales promelas 2.16 - 3.05 mg/L [flow-through]; LC50 96 h Pimephales promelas 0.211 - 0.269 mg/L [semi-static]; LC50 96 h Pimephales promelas 2.66 mg/L [static]; LC50 96 h Cyprinus carpio 30 mg/L; LC50 96 h Cyprinus carpio 0.45 mg/L [semi-static]; LC50 96 h Cyprinus carpio 7.8 mg/L [static]; LC50 96 h Lepomis macrochirus 3.5 mg/L [static]; LC50 96 h Oncorhynchus mykiss 0.24 mg/L [flow-through]; LC50 96 h Oncorhynchus mykiss 0.59 mg/L [semi-static]; LC50 96 h Oncorhynchus mykiss 0.41 mg/L [static]
Algae:  EC50 96 h Pseudokirchneriella subcapitata 0.11 - 0.271 mg/L [static] EPA; EC50 72 h Pseudokirchneriella subcapitata 0.09 - 0.125 mg/L [static] EPA
Invertebrate:  EC50 48 h Daphnia magna 0.139 - 0.908 mg/L [Static] EPA
COPPER 7440-50-8
Fish:  LC50 96 h Pimephales promelas 0.0068 - 0.0156 mg/L; LC50 96 h Pimephales promelas <0.3 mg/L [static]; LC50 96 h Pimephales promelas 0.2 mg/L [flow-through]; LC50 96 h Oncorhynchus mykiss 0.052 mg/L [flow-through]; LC50 96 h Lepomis macrochirus 1.25 mg/L [static]; LC50 96 h Cyprinus carpio 0.3 mg/L [semi-static]; LC50 96 h Cyprinus carpio 0.8 mg/L [static]; LC50 96 h Poecilia reticulata 0.112 mg/L [flow-through]
Algae:  EC50 72 h Pseudokirchneriella subcapitata 0.0426 - 0.0535 mg/L [static] EPA; EC50 96 h Pseudokirchneriella subcapitata 0.031 - 0.054 mg/L [static] EPA
Invertebrate:  EC50 48 h Daphnia magna 0.03 mg/L [Static] EPA
LEAD 7439-92-1
Fish:  LC50 96 h Cyprinus carpio 0.44 mg/L [semi-static]; LC50 96 h Oncorhynchus mykiss 1.17 mg/L [flow-through]; LC50 96 h Oncorhynchus mykiss 1.32 mg/L [static]
Invertebrate:  EC50 48 h water flea 600 µg/L
NICKEL 7440-02-0
Fish:  LC50 96 h Brachydanio rerio >100 mg/L; LC50 96 h Cyprinus carpio 1.3 mg/L [semi-static]; LC50 96 h Cyprinus carpio 10.4 mg/L [static]
Algae:  EC50 72 h Pseudokirchneriella subcapitata 0.18 mg/L IUCLID; EC50 96 h Pseudokirchneriella subcapitata 0.174 - 0.311 mg/L [static] EPA
Invertebrate:  EC50 48 h Daphnia magna >100 mg/L IUCLID; EC50 48 h Daphnia magna 1 mg/L [Static] EPA
SILVER 7440-22-4
Fish:  LC50 96 h Pimephales promelas 0.00155 - 0.00293 mg/L [static]; LC50 96 h Oncorhynchus mykiss 0.0062 mg/L [flow-through]; LC50 96 h Lepomis macrochirus 0.064 mg/L [static]
Invertebrate:  EC50 48 h Daphnia magna 0.00024 mg/L [Static] EPA

* * * Section 13 - DISPOSAL CONSIDERATIONS  * * *


Disposal Methods 
Hazardous Waste Number(s): D008. Dispose of in accordance with U.S. EPA 40 CFR 262 for concentrations at or above the Regulatory level. Regulatory level- 5.0 mg/L. Dispose in accordance with all applicable regulations. Hazardous Waste Number(s): D004. Dispose of in accordance with U.S. EPA 40 CFR 262 for concentrations at or above the Regulatory level. Regulatory level- 5.0 mg/L. 

Component Waste Numbers 

LEAD 7439-92-1
RCRA:  5 mg/L regulatory level
SILVER 7440-22-4
RCRA:  5 mg/L regulatory level
ARSENIC 7440-38-2
RCRA:  5 mg/L regulatory level

* * * Section 14 - TRANSPORT INFORMATION  * * *


US DOT Information: No Classification assigned.

Component Marine Pollutants 

This material contains one or more of the following chemicals required by US DOT to be identified as marine pollutants 
Component  CAS #  Minimum Concentration 
COPPER 7440-50-8 DOT regulated severe marine pollutant (powder)
TDG Information: No Classification assigned.
ADR Information: No Classification assigned.

ADR Tunnel Code Restrictions 

This list contains tunnel restriction codes for those substances and/or chemically related entries which are found in chapter 3.2 of the ADR regulations 
ZINC (7440-66-6) Restriction(s): E [UN1435] (III, ashes); E [UN1436] (I, dust or powder); D/E [UN1436] (II, dust or powder); E [UN1436] (III, dust or powder) ALUMINUM, METALLIC, POWDER (7429-90-5) Restriction(s): E [UN1309] (III, coated); E [UN1309] (II, coated); D/E [UN1396] (II, uncoated); E [UN1396] (III, uncoated) SILICON (7440-21-3) Restriction(s): E [UN1346] (III, amorphous) ANTIMONY (7440-36-0) Restriction(s): E [UN2871] (III) ARSENIC (7440-38-2) Restriction(s): D/E [UN1558] (II); D/E [UN1562] (II)
RID Information: No Classification assigned.
IATA Information: No Classification assigned.
ICAO Information: No Classification assigned.
IMDG Information: No Classification assigned.

Component Marine Pollutants (IMDG) 

This material contains one or more of the following chemicals required by IMDG to be identified as marine pollutants 
COPPER 7440-50-8
IMDG regulated marine pollutant (Listed in the index)

* * * Section 15 - REGULATORY INFORMATION  * * *


US Federal Regulations 
This material contains one or more of the following chemicals required to be identified under SARA Section 302 (40 CFR 355 Appendix A), SARA Section 311/312 (40 CFR 370.21), SARA Section 313 (40 CFR 372.65), CERCLA (40 CFR 302.4), TSCA 12(b), and/or require an OSHA process safety plan 
ZINC 7440-66-6
SARA 313:  1 % de minimis concentration (dust or fume only)
CERCLA:  454 kg final RQ (no reporting of releases of this hazardous substance is required if the diameter of the pieces of the solid metal released is >100 µm); 1000 lb final RQ (no reporting of releases of this hazardous substance is required if the diameter of the pieces of the solid metal released is >100 µm)
COPPER 7440-50-8
SARA 313:  1 % de minimis concentration
CERCLA:  5000 lb final RQ (no reporting of releases of this hazardous substance is required if the diameter of the pieces of the solid metal released is >100 µm); 2270 kg final RQ (no reporting of releases of this hazardous substance is required if the diameter of the pieces of the solid metal released is >100 µm)
MANGANESE 7439-96-5
SARA 313:  1 % de minimis concentration
LEAD 7439-92-1
SARA 313:  0.1 % Supplier notification limit; 0.1 % de minimis concentration (when contained in stainless steel, brass, or bronze)
CERCLA:  10 lb final RQ (no reporting of releases of this hazardous substance is required if the diameter of the pieces of the solid metal released is >100 µm); 4.54 kg final RQ (no reporting of releases of this hazardous substance is required if the diameter of the pieces of the solid metal released is >100 µm)
ALUMINUM, METALLIC, POWDER 7429-90-5
SARA 313:  1 % de minimis concentration (dust or fume only)
NICKEL 7440-02-0
SARA 313:  0.1 % de minimis concentration
CERCLA:  100 lb final RQ (no reporting of releases of this hazardous substance is required if the diameter of the pieces of the solid metal released is >100 µm); 45.4 kg final RQ (no reporting of releases of this hazardous substance is required if the diameter of the pieces of the solid metal released is >100 µm)
SILVER 7440-22-4
SARA 313:  1 % de minimis concentration
CERCLA:  1000 lb final RQ (no reporting of releases of this hazardous substance is required if the diameter of the pieces of the solid metal released is >100 µm); 454 kg final RQ (no reporting of releases of this hazardous substance is required if the diameter of the pieces of the solid metal released is >100 µm)
ANTIMONY 7440-36-0
SARA 313:  1 % de minimis concentration
CERCLA:  5000 lb final RQ (no reporting of releases of this hazardous substance is required if the diameter of the pieces of the solid metal released is >100 µm); 2270 kg final RQ (no reporting of releases of this hazardous substance is required if the diameter of the pieces of the solid metal released is >100 µm)
ARSENIC 7440-38-2
SARA 313:  0.1 % de minimis concentration
CERCLA:  1 lb final RQ (no reporting of releases of this hazardous substance is required if the diameter of the pieces of the solid metal released is >100 µm); 0.454 kg final RQ (no reporting of releases of this hazardous substance is required if the diameter of the pieces of the solid metal released is >100 µm)

SARA Section 311/312 (40 CFR 370 Subparts B and C) 

Fire: YesPressure: NoReactivity: No
U.S. State Regulations 
The following components appear on one or more of the following state hazardous substances lists: 
Component  CAS  CA  MA  MN  NJ  PA 
ZINC 7440-66-6 Yes  Yes  No  Yes  Yes 
COPPER 7440-50-8 Yes  Yes  Yes  Yes  Yes 
MANGANESE 7439-96-5 Yes  Yes  Yes  Yes  Yes 
LEAD 7439-92-1 Yes  Yes  Yes  Yes  Yes 
ALUMINUM, METALLIC, POWDER 7429-90-5 Yes  Yes  Yes  Yes  Yes 
TIN 7440-31-5 Yes  Yes  Yes  Yes  Yes 
SILICON 7440-21-3 No  Yes  Yes  Yes  Yes 
IRON 7439-89-6 Yes  No  No  No  No 
NICKEL 7440-02-0 Yes  Yes  Yes  Yes  Yes 
SILVER 7440-22-4 Yes  Yes  Yes  Yes  Yes 
ANTIMONY 7440-36-0 Yes  Yes  Yes  Yes  Yes 
ARSENIC 7440-38-2 Yes  Yes  Yes  Yes  Yes 

The following statement(s) are provided under the California Safe Drinking Water and Toxic Enforcement Act of 1986 (Proposition 65): 

WARNING! This product contains a chemical known to the state of California to cause cancer WARNING! This product contains a chemical known to the state of California to cause reproductive/developmental effects
Component Analysis 
LEAD 7439-92-1
Carc:  carcinogen , 10/1/1992
Repro/Dev. Tox  developmental toxicity , 2/27/1987
male reproductive toxicity , 2/27/87
female reproductive toxicity , initial date 2/27/87
NICKEL 7440-02-0
Carc:  carcinogen , 10/1/1989 (metallic)
ARSENIC 7440-38-2
Carc:  carcinogen , 2/27/1987 (related to Arsenic inorganic compounds)

Canadian WHMIS Ingredient Disclosure List (IDL) 

Components of this material have been checked against the Canadian WHMIS Ingredients Disclosure List. The List is composed of chemicals which must be identified on MSDSs if they are included in products which meet WHMIS criteria specified in the Controlled Products Regulations and are present above the threshold limits listed on the IDL 
COPPER 7440-50-8
1 %
MANGANESE 7439-96-5
1 %
LEAD 7439-92-1
0.1 %
ALUMINUM, METALLIC, POWDER 7429-90-5
1 %
TIN 7440-31-5
1 %
NICKEL 7440-02-0
0.1 %
SILVER 7440-22-4
1 %
ANTIMONY 7440-36-0
1 %
ARSENIC 7440-38-2
0.1 %

Germany Water Classification 

ZINC (7440-66-6) ID Number 1349 , not considered hazardous to water (particle size >1mm) ID Number 7325 , hazard class 2 - hazard to waters (particle size <=1 mm) COPPER (7440-50-8) ID Number 1443 , not considered hazardous to water MANGANESE (7439-96-5) ID Number 1443 , not considered hazardous to water LEAD (7439-92-1) ID Number 1443 , not considered hazardous to water ALUMINUM, METALLIC, POWDER (7429-90-5) ID Number 1443 , not considered hazardous to water TIN (7440-31-5) ID Number 1443 , not considered hazardous to water IRON (7439-89-6) ID Number 748 , not considered hazardous to water NICKEL (7440-02-0) ID Number 7182 , hazard class 2 - hazard to waters (footnote 47) ID Number 7616 , hazard class 2 - hazard to waters (particle size <1 mm;footnote 47); ID Number 7182 , hazard class 1 - low hazard to waters (particle size >=1 mm;footnote 47) SILVER (7440-22-4) ID Number 1443 , not considered hazardous to water ID Number 1031 , hazard class 3 - severe hazard to waters ARSENIC (7440-38-2) ID Number 7954 , hazard class 3 - severe hazard to waters

REACH List of Substances Subject to Restriction (Annex XVII) - Reg. (EU) No. 1907/2006 

This list includes substances subject to Restriction. Under REACH, these substances are subject to restrictions on manufacture, placing on the market and use of certain dangerous substances, mixtures and articles 
LEAD (7439-92-1) Use restricted. See item 63. NICKEL (7440-02-0) Use restricted. See item 27. ARSENIC (7440-38-2) Use restricted. See item 19. (related to Arsenic compounds)

REACH List of Substances on Community Rolling Action Plan - Reg. (EU) No. 1907/2006 

This LOLI list includes substances listed on the CoRAP List of Substances to be evaluated under the Community Rolling Action Plan. This list includes substances to be evaluated under the Community Rolling Action Plan. These substances may be subject to additional scrutiny during the registration process 
SILVER (7440-22-4) Assigned to Member State The Netherlands (Initial Grounds for Concern: Other (Nanoparticles/ Ecotoxicity of different forms of the substance;Environmental fate);Exposure/Wide dispersive use, High aggregated tonnage) ANTIMONY (7440-36-0) Assigned to Member state Germany (Initial grounds for concern: Exposure of workers, high (aggregated) tonnage, high RCR, other exposure/risk based concern, suspected Carcinogenic, wide dispersive use)
Symbol(s) Xi Irritant T Toxic N Dangerous for the Environment Risk Phrases R22 Harmful if swallowed. R48/20 Harmful: danger of serious damage to health by prolonged exposure through inhalation. R36/37 Irritating to eyes and respiratory system. R43 May cause sensitization by skin contact. R33 Danger of cumulative effects. R40 Limited evidence of a carcinogenic effect. R62 Possible risk of impaired fertility. R61 May cause harm to the unborn child. R50/53 Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
Component Analysis - Inventory 
Component  CAS#  US  CA  EU  AU  PH  JP  KR  CN  NZ 
ZINC 7440-66-6 Yes  DSL  EIN  Yes  Yes  No  Yes  Yes  Yes 
COPPER 7440-50-8 Yes  DSL  EIN  Yes  Yes  No  Yes  Yes  Yes 
MANGANESE 7439-96-5 Yes  DSL  EIN  Yes  Yes  No  Yes  Yes  Yes 
LEAD 7439-92-1 Yes  DSL  EIN  Yes  Yes  Yes  Yes  Yes  Yes 
ALUMINUM, METALLIC, POWDER 7429-90-5 Yes  DSL  EIN  Yes  Yes  No  Yes  Yes  Yes 
TIN 7440-31-5 Yes  DSL  EIN  Yes  Yes  No  Yes  Yes  Yes 
SILICON 7440-21-3 Yes  DSL  EIN  Yes  Yes  No  Yes  Yes  Yes 
IRON 7439-89-6 Yes  DSL  EIN  Yes  Yes  No  Yes  Yes  Yes 
NICKEL 7440-02-0 Yes  DSL  EIN  Yes  Yes  No  Yes  Yes  Yes 
SILVER 7440-22-4 Yes  DSL  EIN  Yes  Yes  No  Yes  Yes  Yes 
ANTIMONY 7440-36-0 Yes  DSL  EIN  Yes  Yes  No  Yes  Yes  Yes 
ARSENIC 7440-38-2 Yes  DSL  EIN  Yes  Yes  No  Yes  Yes  Yes 
Globally Harmonized System of Classification and Labeling (GHS) 

The listed component(s) of this material have been checked for country-specific published classifications according to the Globally Harmonized System of Classification and Labeling (GHS). The results of the queries are displayed below. Please see the individual country listings, as additional interpretations or reference information may be available. For a reference list of H- or P-statements, please visit ChemADVISOR’s website at http://www.chemadvisor.com/product-resources/26-pure-substance-and-mixture-databases/247-ghs-hazard-and-physical-statements 

Australia GHS Classifications 

Classifications below published by Australia's Department of Employment and Workplace Relations, through the Office of the Australian Safety and Compensation Council (ASCC) 
ZINC (7440-66-6) Pyrophoric Solids Category 1 H250 Catches fire spontaneously if exposed to air (dust and powder; pyrophoric) Substances and Mixtures which, in Contact with Water, Emit Flammable Gases Category 1 H260 In contact with water releases flammable gases which may ignite spontaneously (dust and powder; pyrophoric) Hazardous to the Aquatic Environment - Acute Category 1 H400 Very toxic to aquatic life (dust and powder; stabilised) Hazardous to the Aquatic Environment - Chronic Category 1 H410 Very toxic to aquatic life with long lasting effects (dust and powder, pyrophoric) LEAD (7439-92-1) Acute toxicity Oral Category 4 H302 Harmful if swallowed (except those specified elsewhere in this database) Acute toxicity Inhalation Category 4 H332 Harmful if inhaled (except those specified elsewhere in this database) Reproductive Toxicity Category 1A H360Df May damage the unborn child. Suspected of damaging fertility (except those specified elsewhere in this database) Specific Target Organ Toxicity - Repeated Exposure Category 2 H373 May cause damage to organs through prolonged or repeated exposure (except those specified elsewhere in this database) Hazardous to the Aquatic Environment - Acute Category 1 H400 Very toxic to aquatic life (except those specified elsewhere in this database) Hazardous to the Aquatic Environment - Chronic Category 1 H410 Very toxic to aquatic life with long lasting effects (except those specified elsewhere in this database) ALUMINUM, METALLIC, POWDER (7429-90-5) Flammable Solids Category 1 H228 Flammable solid (powder; stabilised) Pyrophoric Solids Category 1 H250 Catches fire spontaneously if exposed to air (powder; pyrophoric) Substances and Mixtures which, in Contact with Water, Emit Flammable Gases Category 2 H261 In contact with water releases flammable gases (powder; pyrophoric or stabilised) NICKEL (7440-02-0) Skin Sensitization Category 1 H317 May cause allergic skin reaction Carcinogenicity Category 2 H351 Suspected of causing cancer Specific Target Organ Toxicity - Repeated Exposure Category 1 H372 Causes damage to organs through prolonged or repeated exposure ANTIMONY (7440-36-0) Acute toxicity Oral Category 4 H302 Harmful if swallowed (except the tetroxide (Sb2O4), pentoxide (Sb2O5), trisulphide (Sb2S3), pentasulphide (Sb2S5) and those specified elsewhere in this database) Acute toxicity Inhalation Category 4 H332 Harmful if inhaled (except Tetroxide (Sb2O4), Pentoxide (Sb2O5), Trisulphide (Sb2S3), Pentasulphide (Sb2S5) and those specified elsewhere in this database) Hazardous to the Aquatic Environment - Chronic Category 2 H411 Toxic to aquatic life with long lasting effects (except the tetroxide (Sb2O4), pentoxide (Sb2O5), trisulphide (Sb2S3), pentasulphide (Sb2S5) and those specified elsewhere in this database) ARSENIC (7440-38-2) Acute toxicity Oral Category 3 H301 Toxic if swallowed Acute toxicity Inhalation Category 3 H331 Toxic if inhaled Germ Cell Mutagenicity Category 2 H341 Suspected of causing genetic defects Carcinogenicity Category 1A H350 May cause cancer Specific Target Organ Toxicity - Repeated Exposure Category 2 H373 May cause damage to organs through prolonged or repeated exposure Hazardous to the Aquatic Environment - Acute Category 1 H400 Very toxic to aquatic life Hazardous to the Aquatic Environment - Chronic Category 1 H410 Very toxic to aquatic life with long lasting effects

Australia GHS Labeling Information 

Labeling information below according to classifications published by Australia's Department of Employment and Workplace Relations, through the Office of the Australian Safety and Compensation Council (ASCC) 
ZINC (7440-66-6) Symbol(s)
Signal Word Danger Hazard(s) H250 Catches fire spontaneously if exposed to air H260 In contact with water releases flammable gases which may ignite spontaneously H410 Very toxic to aquatic life with long lasting effects Prevention P210 Keep away from heat/sparks/open flames/hot surfaces. - No smoking P222 Do not allow contact with air P223 Keep away from any possible contact with water, because of violent reaction and possible flash fire P231+P232 Handle under inert gas. Protect from moisture P280 Wear protective gloves/protective clothing/eye protection/face protection P273 Avoid release to the environment Response P335+P334 Brush off loose particles from skin. Immerse in cool water/wrap in wet bandages P370+P378 In case of fire: Use appropriate media for extinction P391 Collect spillage Storage P402+P404 Store in a dry place. Store in a closed container P422 Store contents under appropriate liquid or inert gas as specified Disposal P501 Dispose of contents/container in accordance with local/regional/national/international regulations LEAD (7439-92-1) Symbol(s)
Signal Word Danger Hazard(s) H302 Harmful if swallowed H332 Harmful if inhaled H360Df May damage the unborn child. Suspected of damaging fertility H373 May cause damage to organs through prolonged or repeated exposure H410 Very toxic to aquatic life with long lasting effects Prevention P271 Use only outdoors or in a well-ventilated area P280 Wear protective gloves/protective clothing/eye protection/face protection P260 Do not breathe dust/fume/gas/mist/vapours/spray P264 Wash thoroughly after handling P201 Obtain special instructions before use P202 Do not handle until all safety precautions have been read and understood P270 Do not eat, drink or smoke when using this product P273 Avoid release to the environment Response P308+P313 IF exposed or concerned: Get medical advice/attention P304+P340 IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing P312 Call a POISON CENTER or doctor/physician if you feel unwell P301+P312 IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell P330 Rinse mouth P391 Collect spillage Storage P405 Store locked up Disposal P501 Dispose of contents/container in accordance with local/regional/national/international regulations ALUMINUM, METALLIC, POWDER (7429-90-5) Symbol(s)
Signal Word Danger Hazard(s) H228 Flammable solid H250 Catches fire spontaneously if exposed to air H261 In contact with water releases flammable gases Prevention P210 Keep away from heat/sparks/open flames/hot surfaces. - No smoking P222 Do not allow contact with air P223 Keep away from any possible contact with water, because of violent reaction and possible flash fire P231+P232 Handle under inert gas. Protect from moisture P240 Ground/Bond container and receiving equipment P241 Use explosion-proof electrical/ventilating/lighting equipment P280 Wear protective gloves/protective clothing/eye protection/face protection Response P303+P361+P353 IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower P335+P334 Brush off loose particles from skin. Immerse in cool water/wrap in wet bandages P370+P378 In case of fire: Use appropriate media for extinction Storage P402+P404 Store in a dry place. Store in a closed container P422 Store contents under appropriate liquid or inert gas as specified Disposal P501 Dispose of contents/container in accordance with local/regional/national/international regulations NICKEL (7440-02-0) Symbol(s)
Signal Word Danger Hazard(s) H317 May cause allergic skin reaction H351 Suspected of causing cancer H372 Causes damage to organs through prolonged or repeated exposure Prevention P272 Contaminated work clothing should not be allowed out of the workplace P280 Wear protective gloves/protective clothing/eye protection/face protection P260 Do not breathe dust/fume/gas/mist/vapours/spray P264 Wash thoroughly after handling P201 Obtain special instructions before use P202 Do not handle until all safety precautions have been read and understood P270 Do not eat, drink or smoke when using this product Response P308+P313 IF exposed or concerned: Get medical advice/attention P302+P352 IF ON SKIN: Wash with plenty of soap and water P362+P364 Take off contaminated clothing and wash it before reuse P333+P313 If skin irritation or rash occurs: Get medical advice/attention P321 Specific treatment (see label) Storage P405 Store locked up Disposal P501 Dispose of contents/container in accordance with local/regional/national/international regulations ANTIMONY (7440-36-0) Symbol(s)
Signal Word Warning Hazard(s) H302 Harmful if swallowed H332 Harmful if inhaled H411 Toxic to aquatic life with long lasting effects Prevention P271 Use only outdoors or in a well-ventilated area P261 Avoid breathing dust/fume/gas/mist/vapours/spray P264 Wash thoroughly after handling P270 Do not eat, drink or smoke when using this product P273 Avoid release to the environment Response P304+P340 IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing P312 Call a POISON CENTER or doctor/physician if you feel unwell P301+P312 IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell P330 Rinse mouth P391 Collect spillage Disposal P501 Dispose of contents/container in accordance with local/regional/national/international regulations ARSENIC (7440-38-2) Symbol(s)
Signal Word Danger Hazard(s) H301 Toxic if swallowed H331 Toxic if inhaled H341 Suspected of causing genetic defects H350 May cause cancer H373 May cause damage to organs through prolonged or repeated exposure H410 Very toxic to aquatic life with long lasting effects Prevention P271 Use only outdoors or in a well-ventilated area P280 Wear protective gloves/protective clothing/eye protection/face protection P260 Do not breathe dust/fume/gas/mist/vapours/spray P264 Wash thoroughly after handling P201 Obtain special instructions before use P202 Do not handle until all safety precautions have been read and understood P270 Do not eat, drink or smoke when using this product P273 Avoid release to the environment Response P308+P313 IF exposed or concerned: Get medical advice/attention P304+P340 IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing P311 Call a POISON CENTER or doctor/physician P301+P310 IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician P321 Specific treatment (see label) P330 Rinse mouth P391 Collect spillage Storage P403+P233 Store in a well-ventilated place. Keep container tightly closed P405 Store locked up Disposal P501 Dispose of contents/container in accordance with local/regional/national/international regulations

European Union GHS Classifications 

Classifications below according to Regulation (EC) No 1272/2008 on classification, labeling and packaging of substances and mixtures (CLP) 
LEAD (7439-92-1) Acute toxicity Oral Category 4 H302 Harmful if swallowed (Minimum classification, except those specified elsewhere in this Annex) Acute toxicity Inhalation Category 4 H332 Harmful if inhaled (Minimum classification, except those specified elsewhere in this Annex) Reproductive Toxicity Category 1A H360Df May damage the unborn child. Suspected of damaging fertility (except those specified elsewhere in this Annex) Specific Target Organ Toxicity - Repeated Exposure Category 2 H373 May cause damage to organs through prolonged or repeated exposure (Minimum classification; No information to prove exclusion of certain routes of exposure; except those specified elsewhere in this Annex) Hazardous to the Aquatic Environment - Acute Category 1 H400 Very toxic to aquatic life (except those specified elsewhere in this Annex) Hazardous to the Aquatic Environment - Chronic Category 1 H410 Very toxic to aquatic life with long lasting effects (except those specified elsewhere in this Annex) ALUMINUM, METALLIC, POWDER (7429-90-5) Flammable Solids Category 1 H228 Flammable solid Substances and Mixtures which, in Contact with Water, Emit Flammable Gases Category 2 H261 In contact with water releases flammable gases NICKEL (7440-02-0) Skin Sensitization Category 1 H317 May cause allergic skin reaction Carcinogenicity Category 2 H351 Suspected of causing cancer Specific Target Organ Toxicity - Repeated Exposure Category 1 H372 Causes damage to organs through prolonged or repeated exposure (No information to prove exclusion of certain routes of exposure) ANTIMONY (7440-36-0) Acute toxicity Oral Category 4 H302 Harmful if swallowed (Minimum classification, except Antimony tetroxide, Antimony pentoxide, Antimony trisulphide, Antimony pentasulphide and those specified elsewhere in this Annex) Acute toxicity Inhalation Category 4 H332 Harmful if inhaled (Minimum classification, except Antimony tetroxide, Antimony pentoxide, Antimony trisulphide, Antimony pentasulphide, and those specified elsewhere in this Annex) Hazardous to the Aquatic Environment - Chronic Category 2 H411 Toxic to aquatic life with long lasting effects (except Antimony tetroxide, Antimony pentoxide, Antimony trisulphide, Antimony pentasulphide and those specified elsewhere in this Annex) ARSENIC (7440-38-2) Acute toxicity Oral Category 3 H301 Toxic if swallowed (Minimum classification) Acute toxicity Inhalation Category 3 H331 Toxic if inhaled (Minimum classification) Hazardous to the Aquatic Environment - Acute Category 1 H400 Very toxic to aquatic life Hazardous to the Aquatic Environment - Chronic Category 1 H410 Very toxic to aquatic life with long lasting effects

European Union GHS Labeling Information 

Labeling information below is according to Regulation (EC) No 1272/2008 on classification, labeling and packaging of substances and mixtures (CLP) 
LEAD (7439-92-1) Symbol(s)
Signal Word Danger Hazard(s) H302 Harmful if swallowed H332 Harmful if inhaled H360Df May damage the unborn child. Suspected of damaging fertility H373 May cause damage to organs through prolonged or repeated exposure H410 Very toxic to aquatic life with long lasting effects Prevention P271 Use only outdoors or in a well-ventilated area P280 Wear protective gloves/protective clothing/eye protection/face protection P260 Do not breathe dust/fume/gas/mist/vapours/spray P264 Wash thoroughly after handling P201 Obtain special instructions before use P202 Do not handle until all safety precautions have been read and understood P270 Do not eat, drink or smoke when using this product P273 Avoid release to the environment Response P308+P313 IF exposed or concerned: Get medical advice/attention P304+P340 IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing P312 Call a POISON CENTER or doctor/physician if you feel unwell P301+P312 IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell P330 Rinse mouth P391 Collect spillage Storage P405 Store locked up Disposal P501 Dispose of contents/container in accordance with local/regional/national/international regulations ALUMINUM, METALLIC, POWDER (7429-90-5) Symbol(s)
Signal Word Danger Hazard(s) H228 Flammable solid H261 In contact with water releases flammable gases Prevention P210 Keep away from heat/sparks/open flames/hot surfaces. - No smoking P223 Keep away from any possible contact with water, because of violent reaction and possible flash fire P231+P232 Handle under inert gas. Protect from moisture P240 Ground/Bond container and receiving equipment P241 Use explosion-proof electrical/ventilating/lighting equipment P280 Wear protective gloves/protective clothing/eye protection/face protection Response P303+P361+P353 IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower P335+P334 Brush off loose particles from skin. Immerse in cool water/wrap in wet bandages P370+P378 In case of fire: Use appropriate media for extinction Storage P402+P404 Store in a dry place. Store in a closed container Disposal P501 Dispose of contents/container in accordance with local/regional/national/international regulations NICKEL (7440-02-0) Symbol(s)
Signal Word Danger Hazard(s) H317 May cause allergic skin reaction H351 Suspected of causing cancer H372 Causes damage to organs through prolonged or repeated exposure Prevention P272 Contaminated work clothing should not be allowed out of the workplace P280 Wear protective gloves/protective clothing/eye protection/face protection P260 Do not breathe dust/fume/gas/mist/vapours/spray P264 Wash thoroughly after handling P201 Obtain special instructions before use P202 Do not handle until all safety precautions have been read and understood P270 Do not eat, drink or smoke when using this product Response P308+P313 IF exposed or concerned: Get medical advice/attention P302+P352 IF ON SKIN: Wash with plenty of soap and water P362+P364 Take off contaminated clothing and wash it before reuse P333+P313 If skin irritation or rash occurs: Get medical advice/attention P321 Specific treatment (see label) Storage P405 Store locked up Disposal P501 Dispose of contents/container in accordance with local/regional/national/international regulations ANTIMONY (7440-36-0) Symbol(s)
Signal Word Warning Hazard(s) H302 Harmful if swallowed H332 Harmful if inhaled H411 Toxic to aquatic life with long lasting effects Prevention P271 Use only outdoors or in a well-ventilated area P261 Avoid breathing dust/fume/gas/mist/vapours/spray P264 Wash thoroughly after handling P270 Do not eat, drink or smoke when using this product P273 Avoid release to the environment Response P304+P340 IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing P312 Call a POISON CENTER or doctor/physician if you feel unwell P301+P312 IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell P330 Rinse mouth P391 Collect spillage Disposal P501 Dispose of contents/container in accordance with local/regional/national/international regulations ARSENIC (7440-38-2) Symbol(s)
Signal Word Danger Hazard(s) H301 Toxic if swallowed H331 Toxic if inhaled H410 Very toxic to aquatic life with long lasting effects Prevention P271 Use only outdoors or in a well-ventilated area P261 Avoid breathing dust/fume/gas/mist/vapours/spray P264 Wash thoroughly after handling P270 Do not eat, drink or smoke when using this product P273 Avoid release to the environment Response P304+P340 IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing P311 Call a POISON CENTER or doctor/physician P301+P310 IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician P321 Specific treatment (see label) P330 Rinse mouth P391 Collect spillage Storage P403+P233 Store in a well-ventilated place. Keep container tightly closed P405 Store locked up Disposal P501 Dispose of contents/container in accordance with local/regional/national/international regulations

Indonesia GHS Classifications 

No published information available This material may be hazardous according to published criteria for classification

Japan GHS Classifications 

Classifications below published under Japan's Chemicals Classification Program according to the Globally Harmonized System of Classification and Labeling of Chemicals (GHS) 
ZINC (7440-66-6) Approval: 20A2067 Serious Eye Damage/Eye Irritation Category 2B H320 Causes eye irritation Hazardous to the Aquatic Environment - Acute Category 1 H400 Very toxic to aquatic life Hazardous to the Aquatic Environment - Chronic Category 1 H410 Very toxic to aquatic life with long lasting effects COPPER (7440-50-8) Skin Sensitization Category 1A H317 May cause allergic skin reaction Approval: 25B0005 Specific Target Organ Toxicity - Single Exposure Category 1 H370 Causes damage to organs (digestive system) Approval: 25B0005 Specific Target Organ Toxicity - Single Exposure Category 3 H335 May cause respiratory irritation Approval: 25B0005 MANGANESE (7439-96-5) Skin Corrosion/Irritation Category 3 H316 Causes mild skin irritation Approval: 200 Serious Eye Damage/Eye Irritation Category 2B H320 Causes eye irritation Approval: 200 Reproductive Toxicity Category 1B H360 May damage fertility or the unborn child Approval: 200 Specific Target Organ Toxicity - Single Exposure Category 1 H370 Causes damage to organs (respiratory system) Approval: 200 Specific Target Organ Toxicity - Repeated Exposure Category 1 H372 Causes damage to organs through prolonged or repeated exposure (nervous system,respiratory system) Approval: 200 Hazardous to the Aquatic Environment - Chronic Category 4 H413 May cause long lasting harmful effects to aquatic life Approval: 200 LEAD (7439-92-1) Germ Cell Mutagenicity Category 2 H341 Suspected of causing genetic defects Approval: 168 Carcinogenicity Category 2 H351 Suspected of causing cancer Approval: 168 Reproductive Toxicity Category 1A H360 May damage fertility or the unborn child Approval: 168 Specific Target Organ Toxicity - Repeated Exposure Category 1 H372 Causes damage to organs through prolonged or repeated exposure (cardiovascular system,Central Nervous System,hematopoietic system,immune system,kidneys,Peripheral Nervous System) Approval: 168 ALUMINUM, METALLIC, POWDER (7429-90-5) Substances and Mixtures which, in Contact with Water, Emit Flammable Gases Category 2 H261 In contact with water releases flammable gases (Source Ambiguous - Also Cat. 3 H261) Approval: H27-B-015/C-036B_P Substances and Mixtures which, in Contact with Water, Emit Flammable Gases Category 3 H261 In contact with water releases flammable gases (Source Ambiguous - Also Cat. 2 H261) Approval: H27-B-015/C-036B_P Specific Target Organ Toxicity - Single Exposure Category 1 H370 Causes damage to organs (respiratory system) Approval: H27-B-015/C-036B_P Specific Target Organ Toxicity - Repeated Exposure Category 1 H372 Causes damage to organs through prolonged or repeated exposure (respiratory system) Approval: H27-B-015/C-036B_P TIN (7440-31-5) Specific Target Organ Toxicity - Repeated Exposure Category 1 H372 Causes damage to organs through prolonged or repeated exposure (lungs) Approval: 815 SILICON (7440-21-3) Flammable Solids Category 2 H228 Flammable solid Approval: 21A3549 Serious Eye Damage/Eye Irritation Category 2B H320 Causes eye irritation Approval: 21A3549 NICKEL (7440-02-0) Respiratory Sensitization Category 1 H334 May cause allergic or asthmatic symptoms or breathing difficulties if inhaled Approval: 21C0012 Skin Sensitization Category 1 H317 May cause allergic skin reaction Approval: 21C0012 Carcinogenicity Category 2 H351 Suspected of causing cancer Approval: 21C0012 Specific Target Organ Toxicity - Single Exposure Category 1 H370 Causes damage to organs (kidneys,respiratory system) Approval: 21C0012 Specific Target Organ Toxicity - Repeated Exposure Category 1 H372 Causes damage to organs through prolonged or repeated exposure (respiratory system) Approval: 21C0012 SILVER (7440-22-4) Serious Eye Damage/Eye Irritation Category 2B H320 Causes eye irritation Approval: 106 Skin Sensitization Category 1 H317 May cause allergic skin reaction Approval: 106 Specific Target Organ Toxicity - Single Exposure Category 1 H370 Causes damage to organs (respiratory system) Approval: 106 Specific Target Organ Toxicity - Repeated Exposure Inhalation Category 1 H372 Causes damage to organs through prolonged or repeated exposure if inhaled (eyes,respiratory system) Approval: 106 ANTIMONY (7440-36-0) Specific Target Organ Toxicity - Repeated Exposure Category 2 H373 May cause damage to organs through prolonged or repeated exposure (respiratory system) Approval: 87 ARSENIC (7440-38-2) Acute toxicity Oral Category 4 H302 Harmful if swallowed Approval: 20A2336 Serious Eye Damage/Eye Irritation Category 2 H319 Causes serious eye irritation Approval: 20A2336 Carcinogenicity Category 1A H350 May cause cancer Approval: 20A2336 Reproductive Toxicity Category 2 H361 Suspected of damaging fertility or the unborn child Approval: 20A2336 Specific Target Organ Toxicity - Single Exposure Category 1 H370 Causes damage to organs (Hematopoietic System,circulatory system,digestive system,kidneys,liver,nervous system,respiratory system,skin) Approval: 20A2336 Specific Target Organ Toxicity - Repeated Exposure Category 1 H372 Causes damage to organs through prolonged or repeated exposure (Hematopoietic System,circulatory system,digestive system,kidneys,liver,nervous system,respiratory system,skin) Approval: 20A2336 Hazardous to the Aquatic Environment - Chronic Category 4 H413 May cause long lasting harmful effects to aquatic life Approval: 54

Japan GHS Labeling Information 

Labeling information below according to classifications published by Japan's Chemicals Classification Program according to the Globally Harmonized System of Classification and Labeling of Chemicals (GHS) 
ZINC (7440-66-6) Symbol(s)
Signal Word Warning Hazard(s) H320 Causes eye irritation H410 Very toxic to aquatic life with long lasting effects Prevention P264 Wash thoroughly after handling P273 Avoid release to the environment Response P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing P337+P313 If eye irritation persists: Get medical advice/attention P391 Collect spillage Disposal P501 Dispose of contents/container in accordance with local/regional/national/international regulations COPPER (7440-50-8) Symbol(s)
Signal Word Danger Hazard(s) H317 May cause allergic skin reaction H370 Causes damage to organs H335 May cause respiratory irritation Prevention P271 Use only outdoors or in a well-ventilated area P272 Contaminated work clothing should not be allowed out of the workplace P280 Wear protective gloves/protective clothing/eye protection/face protection P260 Do not breathe dust/fume/gas/mist/vapours/spray P264 Wash thoroughly after handling P270 Do not eat, drink or smoke when using this product Response P308+P313 IF exposed or concerned: Get medical advice/attention P304+P340 IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing P302+P352 IF ON SKIN: Wash with plenty of soap and water P362+P364 Take off contaminated clothing and wash it before reuse P333+P313 If skin irritation or rash occurs: Get medical advice/attention P312 Call a POISON CENTER or doctor/physician if you feel unwell P321 Specific treatment (see label) Storage P403+P233 Store in a well-ventilated place. Keep container tightly closed P405 Store locked up Disposal P501 Dispose of contents/container in accordance with local/regional/national/international regulations MANGANESE (7439-96-5) Symbol(s)
Signal Word Danger Hazard(s) H316 Causes mild skin irritation H320 Causes eye irritation H360 May damage fertility or the unborn child H370 Causes damage to organs H372 Causes damage to organs through prolonged or repeated exposure H413 May cause long lasting harmful effects to aquatic life Prevention P280 Wear protective gloves/protective clothing/eye protection/face protection P260 Do not breathe dust/fume/gas/mist/vapours/spray P264 Wash thoroughly after handling P201 Obtain special instructions before use P202 Do not handle until all safety precautions have been read and understood P270 Do not eat, drink or smoke when using this product P273 Avoid release to the environment Response P308+P313 IF exposed or concerned: Get medical advice/attention P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing P337+P313 If eye irritation persists: Get medical advice/attention P332+P313 If skin irritation occurs: Get medical advice/attention P321 Specific treatment (see label) Storage P405 Store locked up Disposal P501 Dispose of contents/container in accordance with local/regional/national/international regulations LEAD (7439-92-1) Symbol(s)
Signal Word Danger Hazard(s) H341 Suspected of causing genetic defects H351 Suspected of causing cancer H360 May damage fertility or the unborn child H372 Causes damage to organs through prolonged or repeated exposure Prevention P280 Wear protective gloves/protective clothing/eye protection/face protection P260 Do not breathe dust/fume/gas/mist/vapours/spray P264 Wash thoroughly after handling P201 Obtain special instructions before use P202 Do not handle until all safety precautions have been read and understood P270 Do not eat, drink or smoke when using this product Response P308+P313 IF exposed or concerned: Get medical advice/attention Storage P405 Store locked up Disposal P501 Dispose of contents/container in accordance with local/regional/national/international regulations ALUMINUM, METALLIC, POWDER (7429-90-5) Symbol(s)
Signal Word Danger Hazard(s) H261 In contact with water releases flammable gases H370 Causes damage to organs H372 Causes damage to organs through prolonged or repeated exposure Prevention P223 Keep away from any possible contact with water, because of violent reaction and possible flash fire P231+P232 Handle under inert gas. Protect from moisture P280 Wear protective gloves/protective clothing/eye protection/face protection P260 Do not breathe dust/fume/gas/mist/vapours/spray P264 Wash thoroughly after handling P270 Do not eat, drink or smoke when using this product Response P308+P313 IF exposed or concerned: Get medical advice/attention P335+P334 Brush off loose particles from skin. Immerse in cool water/wrap in wet bandages P321 Specific treatment (see label) P370+P378 In case of fire: Use appropriate media for extinction Storage P402+P404 Store in a dry place. Store in a closed container P405 Store locked up Disposal P501 Dispose of contents/container in accordance with local/regional/national/international regulations TIN (7440-31-5) Symbol(s)
Signal Word Danger Hazard(s) H372 Causes damage to organs through prolonged or repeated exposure Prevention P260 Do not breathe dust/fume/gas/mist/vapours/spray P264 Wash thoroughly after handling P270 Do not eat, drink or smoke when using this product Response P314 Get medical advice/attention if you feel unwell Disposal P501 Dispose of contents/container in accordance with local/regional/national/international regulations SILICON (7440-21-3) Symbol(s)
Signal Word Warning Hazard(s) H228 Flammable solid H320 Causes eye irritation Prevention P210 Keep away from heat/sparks/open flames/hot surfaces. - No smoking P240 Ground/Bond container and receiving equipment P241 Use explosion-proof electrical/ventilating/lighting equipment P280 Wear protective gloves/protective clothing/eye protection/face protection P264 Wash thoroughly after handling Response P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing P337+P313 If eye irritation persists: Get medical advice/attention P303+P361+P353 IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower P370+P378 In case of fire: Use appropriate media for extinction NICKEL (7440-02-0) Symbol(s)
Signal Word Danger Hazard(s) H334 May cause allergic or asthmatic symptoms or breathing difficulties if inhaled H317 May cause allergic skin reaction H351 Suspected of causing cancer H370 Causes damage to organs H372 Causes damage to organs through prolonged or repeated exposure Prevention P272 Contaminated work clothing should not be allowed out of the workplace P280 Wear protective gloves/protective clothing/eye protection/face protection P284 Wear respiratory protection P260 Do not breathe dust/fume/gas/mist/vapours/spray P264 Wash thoroughly after handling P201 Obtain special instructions before use P202 Do not handle until all safety precautions have been read and understood P270 Do not eat, drink or smoke when using this product Response P308+P313 IF exposed or concerned: Get medical advice/attention P304+P340 IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing P342+P311 If experiencing respiratory symptoms: Call a POISON CENTER or doctor/physician P302+P352 IF ON SKIN: Wash with plenty of soap and water P362+P364 Take off contaminated clothing and wash it before reuse P333+P313 If skin irritation or rash occurs: Get medical advice/attention P321 Specific treatment (see label) Storage P405 Store locked up Disposal P501 Dispose of contents/container in accordance with local/regional/national/international regulations SILVER (7440-22-4) Symbol(s)
Signal Word Danger Hazard(s) H320 Causes eye irritation H317 May cause allergic skin reaction H370 Causes damage to organs H372 Causes damage to organs through prolonged or repeated exposure Prevention P272 Contaminated work clothing should not be allowed out of the workplace P280 Wear protective gloves/protective clothing/eye protection/face protection P260 Do not breathe dust/fume/gas/mist/vapours/spray P264 Wash thoroughly after handling P270 Do not eat, drink or smoke when using this product Response P308+P313 IF exposed or concerned: Get medical advice/attention P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing P337+P313 If eye irritation persists: Get medical advice/attention P302+P352 IF ON SKIN: Wash with plenty of soap and water P362+P364 Take off contaminated clothing and wash it before reuse P333+P313 If skin irritation or rash occurs: Get medical advice/attention P321 Specific treatment (see label) Storage P405 Store locked up Disposal P501 Dispose of contents/container in accordance with local/regional/national/international regulations ANTIMONY (7440-36-0) Symbol(s)
Signal Word Warning Hazard(s) H373 May cause damage to organs through prolonged or repeated exposure Prevention P260 Do not breathe dust/fume/gas/mist/vapours/spray Response P314 Get medical advice/attention if you feel unwell Disposal P501 Dispose of contents/container in accordance with local/regional/national/international regulations ARSENIC (7440-38-2) Symbol(s)
Signal Word Danger Hazard(s) H302 Harmful if swallowed H319 Causes serious eye irritation H350 May cause cancer H361 Suspected of damaging fertility or the unborn child H370 Causes damage to organs H372 Causes damage to organs through prolonged or repeated exposure H413 May cause long lasting harmful effects to aquatic life Prevention P280 Wear protective gloves/protective clothing/eye protection/face protection P260 Do not breathe dust/fume/gas/mist/vapours/spray P264 Wash thoroughly after handling P201 Obtain special instructions before use P202 Do not handle until all safety precautions have been read and understood P270 Do not eat, drink or smoke when using this product P273 Avoid release to the environment Response P308+P313 IF exposed or concerned: Get medical advice/attention P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing P337+P313 If eye irritation persists: Get medical advice/attention P301+P312 IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell P321 Specific treatment (see label) P330 Rinse mouth Storage P405 Store locked up Disposal P501 Dispose of contents/container in accordance with local/regional/national/international regulations

Korea GHS Classifications 

Classifications below published by Korea's Ministry of Environment (MOE), Ministry of Employment and Labor (MOEL) or Office of National Emergency Management (NEMA, physical hazards only) 
ZINC (7440-66-6)
MOEL: Acute toxicity Oral Category 3 H301 Toxic if swallowedCarcinogenicity Category 1A H350 May cause cancerHazardous to the Aquatic Environment - Acute Category 1 H400 Very toxic to aquatic life
NEMA: Flammable Solids Category 2 H228 Flammable solid
COPPER (7440-50-8)
MOEL: Specific Target Organ Toxicity - Single Exposure Category 3 H335 May cause respiratory irritationSpecific Target Organ Toxicity - Repeated Exposure Category 1 H372 Causes damage to organs through prolonged or repeated exposure liverHazardous to the Aquatic Environment - Chronic Category 4 H413 May cause long lasting harmful effects to aquatic life
MANGANESE (7439-96-5)
MOEL: Reproductive Toxicity Category 1B H360 May damage fertility or the unborn childSpecific Target Organ Toxicity - Single Exposure Category 1 H370 Causes damage to organs respiratory systemSpecific Target Organ Toxicity - Repeated Exposure Category 1 H372 Causes damage to organs through prolonged or repeated exposure nervous system,respiratory systemHazardous to the Aquatic Environment - Chronic Category 4 H413 May cause long lasting harmful effects to aquatic life
LEAD (7439-92-1)
MOE: Acute toxicity Oral Category 4 H302 Harmful if swallowed. (Except substances specified in the public notice)Acute toxicity Inhalation Category 4 H332 Harmful if inhaled. (Except substances specified in the public notice)Reproductive Toxicity Category 1 H360 May damage fertility or the unborn child. (Except substances specified in the public notice)Specific target organ toxicity - Repeated exposure Category 2 H373 May cause damage to organs through prolonged or repeated exposure. (Except substances specified in the public notice)Hazardous to aquatic environment - acute hazard Category 1 H400 Very toxic to aquatic life. (Except substances specified in the public notice)Hazardous to aquatic environment - chronic hazard Category 1 H410 Very toxic to aquatic life with long lasting effects. (Except substances specified in the public notice)
MOEL: Germ Cell Mutagenicity Category 2 H341 Suspected of causing genetic defectsCarcinogenicity Category 2 H351 Suspected of causing cancerReproductive Toxicity Category 1A H360 May damage fertility or the unborn childSpecific Target Organ Toxicity - Repeated Exposure Category 1 H372 Causes damage to organs through prolonged or repeated exposure cardiovascular system,Central Nervous System,hematopoietic system,immune system,kidneys,Peripheral Nervous System
ALUMINUM, METALLIC, POWDER (7429-90-5)
MOEL: Carcinogenicity Category 1A H350 May cause cancer (metal powder)Specific Target Organ Toxicity - Repeated Exposure Category 1 H372 Causes damage to organs through prolonged or repeated exposure (metal powder)
TIN (7440-31-5)
MOEL: Specific Target Organ Toxicity - Repeated Exposure Category 1 H372 Causes damage to organs through prolonged or repeated exposure lungs
SILICON (7440-21-3)
NEMA: Flammable Solids Category 2 H228 Flammable solid
IRON (7439-89-6)
MOEL: Acute toxicity Oral Category 4 H302 Harmful if swallowedSkin Corrosion/Irritation Category 2 H315 Causes skin irritation
NEMA: Flammable Solids Category 2 H228 Flammable solid
NICKEL (7440-02-0)
MOEL: Respiratory Sensitization Category 1 H334 May cause allergic or asthmatic symptoms or breathing difficulties if inhaledCarcinogenicity Category 1A H350 May cause cancerSpecific Target Organ Toxicity - Single Exposure Category 1 H370 Causes damage to organsSpecific Target Organ Toxicity - Repeated Exposure Category 1 H372 Causes damage to organs through prolonged or repeated exposure
SILVER (7440-22-4)
MOEL: Skin Sensitization Category 1 H317 May cause allergic skin reactionSpecific Target Organ Toxicity - Single Exposure Category 1 H370 Causes damage to organs respiratory systemSpecific Target Organ Toxicity - Repeated Exposure Category 1 H372 Causes damage to organs through prolonged or repeated exposure eyes,respiratory system
ANTIMONY (7440-36-0)
MOE: Acute toxicity Oral Category 4 H302 Harmful if swallowed. (Except substances specified in the public notice)Acute toxicity Inhalation Category 4 H332 Harmful if inhaled. (Except substances specified in the public notice)Skin corrosion/irritation Category 1 H314 Causes severe skin burns and eye damage. (Except substances specified in the public notice)Hazardous to aquatic environment - chronic hazard Category 2 H411 Toxic to aquatic life with long lasting effects. (Except substances specified in the public notice)
MOEL: Specific Target Organ Toxicity - Repeated Exposure Category 2 H373 May cause damage to organs through prolonged or repeated exposure respiratory system
NEMA: Flammable Solids Category 2 H228 Flammable solid
ARSENIC (7440-38-2)
MOE: Acute toxicity Oral Category 3 H301 Toxic if swallowed.Acute toxicity Inhalation Category 3 H331 Toxic if inhaled.Carcinogenicity Category 1 H350 May cause cancer.Hazardous to aquatic environment - acute hazard Category 1 H400 Very toxic to aquatic life.Hazardous to aquatic environment - chronic hazard Category 1 H410 Very toxic to aquatic life with long lasting effects.
MOEL: Acute toxicity Oral Category 4 H302 Harmful if swallowedCarcinogenicity Category 1A H350 May cause cancerReproductive Toxicity Category 1A H360 May damage fertility or the unborn childHazardous to the Aquatic Environment - Chronic Category 4 H413 May cause long lasting harmful effects to aquatic life

Korea GHS Labeling Information 

Labeling information below according to classifications published by Korea's Ministry of Environment (MOE), Ministry of Employment and Labor (MOEL) or Office of National Emergency Management (NEMA, physical hazards only) 
ZINC (7440-66-6) Symbol(s)
Signal Word Danger Hazard(s) H301 Toxic if swallowed H350 May cause cancer H400 Very toxic to aquatic life Prevention P280 Wear protective gloves/protective clothing/eye protection/face protection P264 Wash thoroughly after handling P201 Obtain special instructions before use P202 Do not handle until all safety precautions have been read and understood P270 Do not eat, drink or smoke when using this product P273 Avoid release to the environment Response P308+P313 IF exposed or concerned: Get medical advice/attention P301+P310 IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician P321 Specific treatment (see label) P330 Rinse mouth P391 Collect spillage Storage P405 Store locked up Disposal P501 Dispose of contents/container in accordance with local/regional/national/international regulations Symbol(s)
Signal Word Warning Hazard(s) H228 Flammable solid Prevention P210 Keep away from heat/sparks/open flames/hot surfaces. - No smoking P240 Ground/Bond container and receiving equipment P241 Use explosion-proof electrical/ventilating/lighting equipment P280 Wear protective gloves/protective clothing/eye protection/face protection Response P303+P361+P353 IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower P370+P378 In case of fire: Use appropriate media for extinction Symbol(s)
Signal Word Danger Hazard(s) H335 May cause respiratory irritation H372 Causes damage to organs through prolonged or repeated exposure H413 May cause long lasting harmful effects to aquatic life Prevention P271 Use only outdoors or in a well-ventilated area P260 Do not breathe dust/fume/gas/mist/vapours/spray P264 Wash thoroughly after handling P270 Do not eat, drink or smoke when using this product P273 Avoid release to the environment Response P304+P340 IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing P312 Call a POISON CENTER or doctor/physician if you feel unwell Storage P403+P233 Store in a well-ventilated place. Keep container tightly closed P405 Store locked up Disposal P501 Dispose of contents/container in accordance with local/regional/national/international regulations Symbol(s)
Signal Word Danger Hazard(s) H360 May damage fertility or the unborn child H370 Causes damage to organs H372 Causes damage to organs through prolonged or repeated exposure H413 May cause long lasting harmful effects to aquatic life Prevention P280 Wear protective gloves/protective clothing/eye protection/face protection P260 Do not breathe dust/fume/gas/mist/vapours/spray P264 Wash thoroughly after handling P201 Obtain special instructions before use P202 Do not handle until all safety precautions have been read and understood P270 Do not eat, drink or smoke when using this product P273 Avoid release to the environment Response P308+P313 IF exposed or concerned: Get medical advice/attention P321 Specific treatment (see label) Storage P405 Store locked up Disposal P501 Dispose of contents/container in accordance with local/regional/national/international regulations Symbol(s)
Signal Word Danger Hazard(s) H302 Harmful if swallowed H332 Harmful if inhaled H360 May damage fertility or the unborn child H373 May cause damage to organs through prolonged or repeated exposure H410 Very toxic to aquatic life with long lasting effects Prevention P271 Use only outdoors or in a well-ventilated area P280 Wear protective gloves/protective clothing/eye protection/face protection P260 Do not breathe dust/fume/gas/mist/vapours/spray P264 Wash thoroughly after handling P201 Obtain special instructions before use P202 Do not handle until all safety precautions have been read and understood P270 Do not eat, drink or smoke when using this product P273 Avoid release to the environment Response P308+P313 IF exposed or concerned: Get medical advice/attention P304+P340 IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing P312 Call a POISON CENTER or doctor/physician if you feel unwell P301+P312 IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell P330 Rinse mouth P391 Collect spillage Storage P405 Store locked up Disposal P501 Dispose of contents/container in accordance with local/regional/national/international regulations Symbol(s)
Signal Word Danger Hazard(s) H341 Suspected of causing genetic defects H351 Suspected of causing cancer H360 May damage fertility or the unborn child H372 Causes damage to organs through prolonged or repeated exposure Prevention P280 Wear protective gloves/protective clothing/eye protection/face protection P260 Do not breathe dust/fume/gas/mist/vapours/spray P264 Wash thoroughly after handling P201 Obtain special instructions before use P202 Do not handle until all safety precautions have been read and understood P270 Do not eat, drink or smoke when using this product Response P308+P313 IF exposed or concerned: Get medical advice/attention Storage P405 Store locked up Disposal P501 Dispose of contents/container in accordance with local/regional/national/international regulations Symbol(s)
Signal Word Danger Hazard(s) H350 May cause cancer H372 Causes damage to organs through prolonged or repeated exposure Prevention P280 Wear protective gloves/protective clothing/eye protection/face protection P260 Do not breathe dust/fume/gas/mist/vapours/spray P264 Wash thoroughly after handling P201 Obtain special instructions before use P202 Do not handle until all safety precautions have been read and understood P270 Do not eat, drink or smoke when using this product Response P308+P313 IF exposed or concerned: Get medical advice/attention Storage P405 Store locked up Disposal P501 Dispose of contents/container in accordance with local/regional/national/international regulations Symbol(s)
Signal Word Danger Hazard(s) H372 Causes damage to organs through prolonged or repeated exposure Prevention P260 Do not breathe dust/fume/gas/mist/vapours/spray P264 Wash thoroughly after handling P270 Do not eat, drink or smoke when using this product Response P314 Get medical advice/attention if you feel unwell Disposal P501 Dispose of contents/container in accordance with local/regional/national/international regulations Symbol(s)
Signal Word Warning Hazard(s) H228 Flammable solid Prevention P210 Keep away from heat/sparks/open flames/hot surfaces. - No smoking P240 Ground/Bond container and receiving equipment P241 Use explosion-proof electrical/ventilating/lighting equipment P280 Wear protective gloves/protective clothing/eye protection/face protection Response P303+P361+P353 IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower P370+P378 In case of fire: Use appropriate media for extinction Symbol(s)
Signal Word Warning Hazard(s) H302 Harmful if swallowed H315 Causes skin irritation Prevention P280 Wear protective gloves/protective clothing/eye protection/face protection P264 Wash thoroughly after handling P270 Do not eat, drink or smoke when using this product Response P302+P352 IF ON SKIN: Wash with plenty of soap and water P362+P364 Take off contaminated clothing and wash it before reuse P332+P313 If skin irritation occurs: Get medical advice/attention P301+P312 IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell P321 Specific treatment (see label) P330 Rinse mouth Disposal P501 Dispose of contents/container in accordance with local/regional/national/international regulations Symbol(s)
Signal Word Warning Hazard(s) H228 Flammable solid Prevention P210 Keep away from heat/sparks/open flames/hot surfaces. - No smoking P240 Ground/Bond container and receiving equipment P241 Use explosion-proof electrical/ventilating/lighting equipment P280 Wear protective gloves/protective clothing/eye protection/face protection Response P303+P361+P353 IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower P370+P378 In case of fire: Use appropriate media for extinction Symbol(s)
Signal Word Danger Hazard(s) H334 May cause allergic or asthmatic symptoms or breathing difficulties if inhaled H350 May cause cancer H370 Causes damage to organs H372 Causes damage to organs through prolonged or repeated exposure Prevention P280 Wear protective gloves/protective clothing/eye protection/face protection P284 Wear respiratory protection P260 Do not breathe dust/fume/gas/mist/vapours/spray P264 Wash thoroughly after handling P201 Obtain special instructions before use P202 Do not handle until all safety precautions have been read and understood P270 Do not eat, drink or smoke when using this product Response P308+P313 IF exposed or concerned: Get medical advice/attention P304+P340 IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing P342+P311 If experiencing respiratory symptoms: Call a POISON CENTER or doctor/physician P321 Specific treatment (see label) Storage P405 Store locked up Disposal P501 Dispose of contents/container in accordance with local/regional/national/international regulations Symbol(s)
Signal Word Danger Hazard(s) H317 May cause allergic skin reaction H370 Causes damage to organs H372 Causes damage to organs through prolonged or repeated exposure Prevention P272 Contaminated work clothing should not be allowed out of the workplace P280 Wear protective gloves/protective clothing/eye protection/face protection P260 Do not breathe dust/fume/gas/mist/vapours/spray P264 Wash thoroughly after handling P270 Do not eat, drink or smoke when using this product Response P308+P313 IF exposed or concerned: Get medical advice/attention P302+P352 IF ON SKIN: Wash with plenty of soap and water P362+P364 Take off contaminated clothing and wash it before reuse P333+P313 If skin irritation or rash occurs: Get medical advice/attention P321 Specific treatment (see label) Storage P405 Store locked up Disposal P501 Dispose of contents/container in accordance with local/regional/national/international regulations Symbol(s)
Signal Word Danger Hazard(s) H302 Harmful if swallowed H332 Harmful if inhaled H314 Causes severe skin burns and eye damage H411 Toxic to aquatic life with long lasting effects Prevention P271 Use only outdoors or in a well-ventilated area P280 Wear protective gloves/protective clothing/eye protection/face protection P260 Do not breathe dust/fume/gas/mist/vapours/spray P264 Wash thoroughly after handling P270 Do not eat, drink or smoke when using this product P273 Avoid release to the environment Response P304+P340 IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing P312 Call a POISON CENTER or doctor/physician if you feel unwell P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing P310 Immediately call a POISON CENTER or doctor/physician P303+P361+P353 IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower P363 Wash contaminated clothing before reuse P301+P312 IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell P301+P330+P331 IF SWALLOWED: Rinse mouth. Do NOT induce vomiting P321 Specific treatment (see label) P330 Rinse mouth P391 Collect spillage Storage P405 Store locked up Disposal P501 Dispose of contents/container in accordance with local/regional/national/international regulations Symbol(s)
Signal Word Warning Hazard(s) H373 May cause damage to organs through prolonged or repeated exposure Prevention P260 Do not breathe dust/fume/gas/mist/vapours/spray Response P314 Get medical advice/attention if you feel unwell Disposal P501 Dispose of contents/container in accordance with local/regional/national/international regulations Symbol(s)
Signal Word Warning Hazard(s) H228 Flammable solid Prevention P210 Keep away from heat/sparks/open flames/hot surfaces. - No smoking P240 Ground/Bond container and receiving equipment P241 Use explosion-proof electrical/ventilating/lighting equipment P280 Wear protective gloves/protective clothing/eye protection/face protection Response P303+P361+P353 IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower P370+P378 In case of fire: Use appropriate media for extinction Symbol(s)
Signal Word Danger Hazard(s) H301 Toxic if swallowed H331 Toxic if inhaled H350 May cause cancer H410 Very toxic to aquatic life with long lasting effects Prevention P271 Use only outdoors or in a well-ventilated area P280 Wear protective gloves/protective clothing/eye protection/face protection P261 Avoid breathing dust/fume/gas/mist/vapours/spray P264 Wash thoroughly after handling P201 Obtain special instructions before use P202 Do not handle until all safety precautions have been read and understood P270 Do not eat, drink or smoke when using this product P273 Avoid release to the environment Response P308+P313 IF exposed or concerned: Get medical advice/attention P304+P340 IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing P311 Call a POISON CENTER or doctor/physician P301+P310 IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician P321 Specific treatment (see label) P330 Rinse mouth P391 Collect spillage Storage P403+P233 Store in a well-ventilated place. Keep container tightly closed P405 Store locked up Disposal P501 Dispose of contents/container in accordance with local/regional/national/international regulations Symbol(s)
Signal Word Danger Hazard(s) H302 Harmful if swallowed H350 May cause cancer H360 May damage fertility or the unborn child H413 May cause long lasting harmful effects to aquatic life Prevention P280 Wear protective gloves/protective clothing/eye protection/face protection P264 Wash thoroughly after handling P201 Obtain special instructions before use P202 Do not handle until all safety precautions have been read and understood P270 Do not eat, drink or smoke when using this product P273 Avoid release to the environment Response P308+P313 IF exposed or concerned: Get medical advice/attention P301+P312 IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell P330 Rinse mouth Storage P405 Store locked up Disposal P501 Dispose of contents/container in accordance with local/regional/national/international regulations

New Zealand GHS Classifications 

Classifications below according to the Environmental Risk Management Authority's (ERMA) Hazardous Substances and New Organisms (HSNO) Act, as amended. For a reference list defining the alphanumeric categories, please visit ChemADVISOR's website at www.chemadvisor.com\sdsoncommand\ghs_NZ.html 
ZINC (7440-66-6) Approval: HSR001301 Self-Heating Substances and Mixtures Category 1 H251 Self-heating, may catch fire (powder/dust, PG I) Substances and Mixtures which, in Contact with Water, Emit Flammable Gases Category 1 H260 In contact with water releases flammable gases which may ignite spontaneously (powder/dust, PG I) Acute toxicity Inhalation Category 5 H333 May be harmful if inhaled (powder/dust, PG I) Hazardous to the Aquatic Environment - Acute Category 1 H400 Very toxic to aquatic life (algal,crustacean,fish) (powder/dust, PG I) COPPER (7440-50-8) Approval: HSR002948 Acute toxicity Oral Category 2 H300 Fatal if swallowed (powder) Acute toxicity Inhalation Category 2 H330 Fatal if inhaled (powder) Serious Eye Damage/Eye Irritation Category 2 H319 Causes serious eye irritation (powder) Skin Sensitization Category 1 H317 May cause allergic skin reaction (powder) Germ Cell Mutagenicity Category 1 H340 May cause genetic defects (powder) Specific Target Organ Toxicity - Repeated Exposure Inhalation Category 2 H373 May cause damage to organs through prolonged or repeated exposure if inhaled (digestive system,Hematopoietic System,kidneys,nose,upper respiratory system,skin) (powder) Specific Target Organ Toxicity - Repeated Exposure Oral Category 2 H373 May cause damage to organs through prolonged or repeated exposure if swallowed (kidneys,liver,stomach) (powder) Hazardous to the Aquatic Environment - Acute Category 1 H400 Very toxic to aquatic life (algal,crustacean,fish) (powder) Hazardous to the Terrestrial Environment - Soil Category 4 H423 Harmful to the soil environment (powder) Hazardous to the Terrestrial Environment - Vertebrates Category 1 H431 Very toxic to terrestrial vertebrates (powder) MANGANESE (7439-96-5) Approval: HSR003013 Acute toxicity Inhalation Category 5 H333 May be harmful if inhaled Hazardous to the Aquatic Environment - Chronic Category 3 H412 Harmful to aquatic life with long lasting effects (crustacean,fish) LEAD (7439-92-1) Approval: HSR002809 Acute toxicity Oral Category 3 H301 Toxic if swallowed Germ Cell Mutagenicity Category 2 H341 Suspected of causing genetic defects Carcinogenicity Category 2 H351 Suspected of causing cancer Reproductive Toxicity Category 1 H360 May damage fertility or the unborn child Reproductive Toxicity Effects on or via lactation H362 May cause harm to breast-fed children Specific Target Organ Toxicity - Repeated Exposure Inhalation Category 1 H372 Causes damage to organs through prolonged or repeated exposure if inhaled Specific Target Organ Toxicity - Repeated Exposure Oral Category 1 H372 Causes damage to organs through prolonged or repeated exposure if swallowed (blood,Cardiovascular system,Hematopoietic System,kidneys) Specific Target Organ Toxicity - Repeated Exposure Dermal Category 1 H372 Causes damage to organs through prolonged or repeated exposure in contact with skin (Nervous System) Hazardous to the Aquatic Environment - Chronic Category 1 H410 Very toxic to aquatic life with long lasting effects (crustacean) Hazardous to the Aquatic Environment - Chronic Category 2 H411 Toxic to aquatic life with long lasting effects (fish) Hazardous to the Terrestrial Environment - Vertebrates Category 2 H432 Toxic to terrestrial vertebrates ALUMINUM, METALLIC, POWDER (7429-90-5) Approval: HSR001263 Flammable Solids Category 1 H228 Flammable solid (powder, coated PG II) Specific Target Organ Toxicity - Repeated Exposure Inhalation Category 2 H373 May cause damage to organs through prolonged or repeated exposure if inhaled (powder, coated PG II) Hazardous to the Aquatic Environment - Acute Category 3 H402 Harmful to aquatic life (fish,crustacean,algal) (powder, coated PG II) TIN (7440-31-5) Approval: HSR002803 Acute toxicity Oral Category 4 H302 Harmful if swallowed Serious Eye Damage/Eye Irritation Category 2 H319 Causes serious eye irritation Hazardous to the Aquatic Environment - Acute Category 1 H400 Very toxic to aquatic life (algal,crustacean,fish) SILICON (7440-21-3) Approval: HSR001306 Flammable Solids Category 2 H228 Flammable solid Acute toxicity Oral Category 5 H303 May be harmful if swallowed NICKEL (7440-02-0) Approval: HSR003031 Skin Sensitization Category 1 H317 May cause allergic skin reaction Carcinogenicity Category 2 H351 Suspected of causing cancer Hazardous to the Aquatic Environment - Acute Category 1 H400 Very toxic to aquatic life (crustacean) Hazardous to the Aquatic Environment - Chronic Category 2 H411 Toxic to aquatic life with long lasting effects (algal,fish) Hazardous to the Terrestrial Environment - Soil Category 3 H423 Harmful to the soil environment SILVER (7440-22-4) Approval: HSR003077 Hazardous to the Aquatic Environment - Acute Category 1 H400 Very toxic to aquatic life (algal,crustacean,fish) ANTIMONY (7440-36-0) Approval: HSR001527 Skin Corrosion/Irritation Category 3 H316 Causes mild skin irritation Serious Eye Damage/Eye Irritation Category 2 H319 Causes serious eye irritation Carcinogenicity Category 2 H351 Suspected of causing cancer Reproductive Toxicity Category 2 H361 Suspected of damaging fertility or the unborn child Specific Target Organ Toxicity - Repeated Exposure Inhalation Category 2 H373 May cause damage to organs through prolonged or repeated exposure if inhaled (lungs,skin) Specific Target Organ Toxicity - Repeated Exposure Oral Category 2 H373 May cause damage to organs through prolonged or repeated exposure if swallowed (blood,Hematopoietic System) Hazardous to the Aquatic Environment - Acute Category 2 H401 Toxic to aquatic life (fish) ARSENIC (7440-38-2) Approval: HSR001528 Acute toxicity Oral Category 2 H300 Fatal if swallowed Acute toxicity Inhalation Category 2 H330 Fatal if inhaled Germ Cell Mutagenicity Category 2 H341 Suspected of causing genetic defects Carcinogenicity Category 1 H350 May cause cancer Specific Target Organ Toxicity - Repeated Exposure Inhalation Category 1 H372 Causes damage to organs through prolonged or repeated exposure if inhaled (brain,Nervous System) Specific Target Organ Toxicity - Repeated Exposure Oral Category 1 H372 Causes damage to organs through prolonged or repeated exposure if swallowed (circulatory system,liver,Nervous System,skin) Hazardous to the Aquatic Environment - Acute Category 1 H400 Very toxic to aquatic life (algal,crustacean) Hazardous to the Aquatic Environment - Chronic Category 2 H411 Toxic to aquatic life with long lasting effects (fish) Hazardous to the Terrestrial Environment - Vertebrates Category 1 H431 Very toxic to terrestrial vertebrates

New Zealand GHS Labeling Information 

Labeling information below according to classifications published by New Zealand's Environmental Risk Management Authority's (ERMA) Hazardous Substances and New Organisms (HSNO) Act, as amended. For a reference list defining the alphanumeric categories, please visit ChemADVISOR's website at www.chemadvisor.com\sdsoncommand\ghs_NZ.html 
ZINC (7440-66-6) Symbol(s)
Signal Word Danger Hazard(s) H251 Self-heating, may catch fire H260 In contact with water releases flammable gases which may ignite spontaneously H333 May be harmful if inhaled H400 Very toxic to aquatic life Prevention P235+P410 Keep cool. Protect from sunlight P223 Keep away from any possible contact with water, because of violent reaction and possible flash fire P231+P232 Handle under inert gas. Protect from moisture P280 Wear protective gloves/protective clothing/eye protection/face protection P273 Avoid release to the environment Response P304+P312 IF INHALED: Call a POISON CENTER or doctor/physician if you feel unwell P335+P334 Brush off loose particles from skin. Immerse in cool water/wrap in wet bandages P370+P378 In case of fire: Use appropriate media for extinction P391 Collect spillage Storage P402+P404 Store in a dry place. Store in a closed container P407 Maintain air gap between stacks/pallets P413 Store bulk masses at temperatures not exceeding manufacturer recommendations P420 Store away from other materials Disposal P501 Dispose of contents/container in accordance with local/regional/national/international regulations COPPER (7440-50-8) Symbol(s)
Signal Word Danger Hazard(s) H300 Fatal if swallowed H330 Fatal if inhaled H319 Causes serious eye irritation H317 May cause allergic skin reaction H340 May cause genetic defects H373 May cause damage to organs through prolonged or repeated exposure H400 Very toxic to aquatic life H423 Harmful to the soil environment H431 Very toxic to terrestrial vertebrates Prevention P271 Use only outdoors or in a well-ventilated area P272 Contaminated work clothing should not be allowed out of the workplace P280 Wear protective gloves/protective clothing/eye protection/face protection P284 Wear respiratory protection P260 Do not breathe dust/fume/gas/mist/vapours/spray P264 Wash thoroughly after handling P201 Obtain special instructions before use P202 Do not handle until all safety precautions have been read and understood P270 Do not eat, drink or smoke when using this product P273 Avoid release to the environment Response P308+P313 IF exposed or concerned: Get medical advice/attention P304+P340 IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing P310 Immediately call a POISON CENTER or doctor/physician P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing P337+P313 If eye irritation persists: Get medical advice/attention P302+P352 IF ON SKIN: Wash with plenty of soap and water P362+P364 Take off contaminated clothing and wash it before reuse P333+P313 If skin irritation or rash occurs: Get medical advice/attention P301+P310 IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician P320 Specific treatment is urgent (see label) P330 Rinse mouth P391 Collect spillage Storage P403+P233 Store in a well-ventilated place. Keep container tightly closed P405 Store locked up Disposal P501 Dispose of contents/container in accordance with local/regional/national/international regulations MANGANESE (7439-96-5) Signal Word Warning Hazard(s) H333 May be harmful if inhaled H412 Harmful to aquatic life with long lasting effects Prevention P273 Avoid release to the environment Response P304+P312 IF INHALED: Call a POISON CENTER or doctor/physician if you feel unwell Disposal P501 Dispose of contents/container in accordance with local/regional/national/international regulations LEAD (7439-92-1) Symbol(s)
Signal Word Danger Hazard(s) H301 Toxic if swallowed H341 Suspected of causing genetic defects H351 Suspected of causing cancer H360 May damage fertility or the unborn child H362 May cause harm to breast-fed children H372 Causes damage to organs through prolonged or repeated exposure H410 Very toxic to aquatic life with long lasting effects H411 Toxic to aquatic life with long lasting effects H432 Toxic to terrestrial vertebrates Prevention P280 Wear protective gloves/protective clothing/eye protection/face protection P260 Do not breathe dust/fume/gas/mist/vapours/spray P263 Avoid contact during pregnancy/while nursing P264 Wash thoroughly after handling P201 Obtain special instructions before use P202 Do not handle until all safety precautions have been read and understood P270 Do not eat, drink or smoke when using this product P273 Avoid release to the environment Response P308+P313 IF exposed or concerned: Get medical advice/attention P301+P310 IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician P321 Specific treatment (see label) P330 Rinse mouth P391 Collect spillage Storage P405 Store locked up Disposal P501 Dispose of contents/container in accordance with local/regional/national/international regulations ALUMINUM, METALLIC, POWDER (7429-90-5) Symbol(s)
Signal Word Danger Hazard(s) H228 Flammable solid H373 May cause damage to organs through prolonged or repeated exposure H402 Harmful to aquatic life Prevention P210 Keep away from heat/sparks/open flames/hot surfaces. - No smoking P240 Ground/Bond container and receiving equipment P241 Use explosion-proof electrical/ventilating/lighting equipment P280 Wear protective gloves/protective clothing/eye protection/face protection P260 Do not breathe dust/fume/gas/mist/vapours/spray P273 Avoid release to the environment Response P303+P361+P353 IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower P314 Get medical advice/attention if you feel unwell P370+P378 In case of fire: Use appropriate media for extinction Disposal P501 Dispose of contents/container in accordance with local/regional/national/international regulations TIN (7440-31-5) Symbol(s)
Signal Word Warning Hazard(s) H302 Harmful if swallowed H319 Causes serious eye irritation H400 Very toxic to aquatic life Prevention P280 Wear protective gloves/protective clothing/eye protection/face protection P264 Wash thoroughly after handling P270 Do not eat, drink or smoke when using this product P273 Avoid release to the environment Response P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing P337+P313 If eye irritation persists: Get medical advice/attention P301+P312 IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell P330 Rinse mouth P391 Collect spillage Disposal P501 Dispose of contents/container in accordance with local/regional/national/international regulations SILICON (7440-21-3) Symbol(s)
Signal Word Warning Hazard(s) H228 Flammable solid H303 May be harmful if swallowed Prevention P210 Keep away from heat/sparks/open flames/hot surfaces. - No smoking P240 Ground/Bond container and receiving equipment P241 Use explosion-proof electrical/ventilating/lighting equipment P280 Wear protective gloves/protective clothing/eye protection/face protection Response P303+P361+P353 IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower P312 Call a POISON CENTER or doctor/physician if you feel unwell P370+P378 In case of fire: Use appropriate media for extinction NICKEL (7440-02-0) Symbol(s)
Signal Word Warning Hazard(s) H317 May cause allergic skin reaction H351 Suspected of causing cancer H400 Very toxic to aquatic life H411 Toxic to aquatic life with long lasting effects H423 Harmful to the soil environment Prevention P272 Contaminated work clothing should not be allowed out of the workplace P280 Wear protective gloves/protective clothing/eye protection/face protection P261 Avoid breathing dust/fume/gas/mist/vapours/spray P201 Obtain special instructions before use P202 Do not handle until all safety precautions have been read and understood P273 Avoid release to the environment Response P308+P313 IF exposed or concerned: Get medical advice/attention P302+P352 IF ON SKIN: Wash with plenty of soap and water P362+P364 Take off contaminated clothing and wash it before reuse P333+P313 If skin irritation or rash occurs: Get medical advice/attention P321 Specific treatment (see label) P391 Collect spillage Storage P405 Store locked up Disposal P501 Dispose of contents/container in accordance with local/regional/national/international regulations SILVER (7440-22-4) Symbol(s)
Signal Word Warning Hazard(s) H400 Very toxic to aquatic life Prevention P273 Avoid release to the environment Response P391 Collect spillage Disposal P501 Dispose of contents/container in accordance with local/regional/national/international regulations ANTIMONY (7440-36-0) Symbol(s)
Signal Word Warning Hazard(s) H316 Causes mild skin irritation H319 Causes serious eye irritation H351 Suspected of causing cancer H361 Suspected of damaging fertility or the unborn child H373 May cause damage to organs through prolonged or repeated exposure H401 Toxic to aquatic life Prevention P280 Wear protective gloves/protective clothing/eye protection/face protection P260 Do not breathe dust/fume/gas/mist/vapours/spray P264 Wash thoroughly after handling P201 Obtain special instructions before use P202 Do not handle until all safety precautions have been read and understood P273 Avoid release to the environment Response P308+P313 IF exposed or concerned: Get medical advice/attention P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing P337+P313 If eye irritation persists: Get medical advice/attention P332+P313 If skin irritation occurs: Get medical advice/attention Storage P405 Store locked up Disposal P501 Dispose of contents/container in accordance with local/regional/national/international regulations ARSENIC (7440-38-2) Symbol(s)
Signal Word Danger Hazard(s) H300 Fatal if swallowed H330 Fatal if inhaled H341 Suspected of causing genetic defects H350 May cause cancer H372 Causes damage to organs through prolonged or repeated exposure H400 Very toxic to aquatic life H411 Toxic to aquatic life with long lasting effects H431 Very toxic to terrestrial vertebrates Prevention P271 Use only outdoors or in a well-ventilated area P280 Wear protective gloves/protective clothing/eye protection/face protection P284 Wear respiratory protection P260 Do not breathe dust/fume/gas/mist/vapours/spray P264 Wash thoroughly after handling P201 Obtain special instructions before use P202 Do not handle until all safety precautions have been read and understood P270 Do not eat, drink or smoke when using this product P273 Avoid release to the environment Response P308+P313 IF exposed or concerned: Get medical advice/attention P304+P340 IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing P310 Immediately call a POISON CENTER or doctor/physician P301+P310 IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician P320 Specific treatment is urgent (see label) P330 Rinse mouth P391 Collect spillage Storage P403+P233 Store in a well-ventilated place. Keep container tightly closed P405 Store locked up Disposal P501 Dispose of contents/container in accordance with local/regional/national/international regulations

South Africa GHS Classifications 

Information below presented according to the South African Bureau of Standards (SANS 10234:2008 - Globally Harmonized System (GHS) of Classification and Labeling of Chemicals). The information below identifies substances with recommended GHS classifications by CAS or RR numbers and chemical names; the data field contains the word ''Present'' along with any clarifying information in parenthesis. NOTE: Due to copyright laws on the standard, we are not able to publish the classification. Details about South Africa's implementation of GHS are available by ordering the Standard and its supplement through the South African Bureau of Standards website 
ZINC (7440-66-6) Listing: Present (powder) ALUMINUM, METALLIC, POWDER (7429-90-5) Listing: Present (coated powder stabilized)

Taiwan GHS Classifications 

Information below presented according to Taiwan's Bureau of Standards, Metrology and Inspection (BSMI) of the Ministry of Economic Affairs. This agency has published a series of standards (CNS 15030 1-27 Chemical Classification and Labelling) which provide guidance on classification and labeling of chemicals according to GHS 
ZINC (7440-66-6)
Taiwan: Pyrophoric Solids Category 1 H250 Catches fire spontaneously if exposed to air (powder)
Substances and Mixtures which, in Contact with Water, Emit Flammable Gases Category 2 H261 In contact with water releases flammable gases (powder)
Skin Corrosion/Irritation Category 3 H316 Causes mild skin irritation (powder)
Hazardous to the Aquatic Environment - Chronic Category 1 H410 Very toxic to aquatic life with long lasting effects (powder)
MANGANESE (7439-96-5)
Taiwan: Flammable Solids Category 2 H228 Flammable solid
Skin Corrosion/Irritation Category 3 H316 Causes mild skin irritation
Serious Eye Damage/Eye Irritation Category 2B H320 Causes eye irritation
Reproductive Toxicity Category 1 H360 May damage fertility or the unborn child
Specific Target Organ Toxicity - Repeated Exposure Category 1 H372 Causes damage to organs through prolonged or repeated exposure
LEAD (7439-92-1)
Taiwan: Carcinogenicity Category 2 H351 Suspected of causing cancer
Reproductive Toxicity Category 1 H360 May damage fertility or the unborn child
ALUMINUM, METALLIC, POWDER (7429-90-5)
Taiwan: Substances and Mixtures which, in Contact with Water, Emit Flammable Gases Category 2 H261 In contact with water releases flammable gases
NICKEL (7440-02-0)
Taiwan: Serious Eye Damage/Eye Irritation Category 2A H319 Causes serious eye irritation
Respiratory Sensitization Category 1 H334 May cause allergic or asthmatic symptoms or breathing difficulties if inhaled
Skin Sensitization Category 1 H317 May cause allergic skin reaction
Carcinogenicity Category 2 H351 Suspected of causing cancer
Hazardous to the Aquatic Environment - Chronic Category 3 H412 Harmful to aquatic life with long lasting effects
SILVER (7440-22-4)
Taiwan: Hazardous to the Aquatic Environment - Acute Category 3 H402 Harmful to aquatic life
ANTIMONY (7440-36-0)
Taiwan: Skin Corrosion/Irritation Category 3 H316 Causes mild skin irritation
Serious Eye Damage/Eye Irritation Category 2B H320 Causes eye irritation
Specific Target Organ Toxicity - Repeated Exposure Category 2 H373 May cause damage to organs through prolonged or repeated exposure
ARSENIC (7440-38-2)
Taiwan: Acute toxicity Oral Category 4 H302 Harmful if swallowed
Acute toxicity Inhalation Category 3 H331 Toxic if inhaled
Germ Cell Mutagenicity Category 2 H341 Suspected of causing genetic defects
Carcinogenicity Category 1 H350 May cause cancer
Specific Target Organ Toxicity - Repeated Exposure Category 1 H372 Causes damage to organs through prolonged or repeated exposure
Hazardous to the Aquatic Environment - Chronic Category 2 H411 Toxic to aquatic life with long lasting effects

Taiwan GHS Labeling Information 

Labeling information below according to classifications published by Taiwan's Bureau of Standards, Metrology and Inspection (BSMI) of the Ministry of Economic Affairs. This agency has published a series of standards (CNS 15030 1-27 Chemical Classification and Labelling) which provide guidance on classification and labeling of chemicals according to GHS 
ZINC (7440-66-6) Symbol(s)
Signal Word Danger Hazard(s) H250 Catches fire spontaneously if exposed to air H261 In contact with water releases flammable gases H316 Causes mild skin irritation H410 Very toxic to aquatic life with long lasting effects Prevention P210 Keep away from heat/sparks/open flames/hot surfaces. - No smoking P222 Do not allow contact with air P223 Keep away from any possible contact with water, because of violent reaction and possible flash fire P231+P232 Handle under inert gas. Protect from moisture P280 Wear protective gloves/protective clothing/eye protection/face protection P273 Avoid release to the environment Response P332+P313 If skin irritation occurs: Get medical advice/attention P335+P334 Brush off loose particles from skin. Immerse in cool water/wrap in wet bandages P370+P378 In case of fire: Use appropriate media for extinction P391 Collect spillage Storage P402+P404 Store in a dry place. Store in a closed container P422 Store contents under appropriate liquid or inert gas as specified Disposal P501 Dispose of contents/container in accordance with local/regional/national/international regulations MANGANESE (7439-96-5) Symbol(s)
Signal Word Danger Hazard(s) H228 Flammable solid H316 Causes mild skin irritation H320 Causes eye irritation H360 May damage fertility or the unborn child H372 Causes damage to organs through prolonged or repeated exposure Prevention P210 Keep away from heat/sparks/open flames/hot surfaces. - No smoking P240 Ground/Bond container and receiving equipment P241 Use explosion-proof electrical/ventilating/lighting equipment P280 Wear protective gloves/protective clothing/eye protection/face protection P260 Do not breathe dust/fume/gas/mist/vapours/spray P264 Wash thoroughly after handling P201 Obtain special instructions before use P202 Do not handle until all safety precautions have been read and understood P270 Do not eat, drink or smoke when using this product Response P308+P313 IF exposed or concerned: Get medical advice/attention P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing P337+P313 If eye irritation persists: Get medical advice/attention P303+P361+P353 IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower P332+P313 If skin irritation occurs: Get medical advice/attention P370+P378 In case of fire: Use appropriate media for extinction Storage P405 Store locked up Disposal P501 Dispose of contents/container in accordance with local/regional/national/international regulations LEAD (7439-92-1) Symbol(s)
Signal Word Danger Hazard(s) H351 Suspected of causing cancer H360 May damage fertility or the unborn child Prevention P280 Wear protective gloves/protective clothing/eye protection/face protection P201 Obtain special instructions before use P202 Do not handle until all safety precautions have been read and understood Response P308+P313 IF exposed or concerned: Get medical advice/attention Storage P405 Store locked up Disposal P501 Dispose of contents/container in accordance with local/regional/national/international regulations ALUMINUM, METALLIC, POWDER (7429-90-5) Symbol(s)
Signal Word Danger Hazard(s) H261 In contact with water releases flammable gases Prevention P223 Keep away from any possible contact with water, because of violent reaction and possible flash fire P231+P232 Handle under inert gas. Protect from moisture P280 Wear protective gloves/protective clothing/eye protection/face protection Response P335+P334 Brush off loose particles from skin. Immerse in cool water/wrap in wet bandages P370+P378 In case of fire: Use appropriate media for extinction Storage P402+P404 Store in a dry place. Store in a closed container Disposal P501 Dispose of contents/container in accordance with local/regional/national/international regulations NICKEL (7440-02-0) Symbol(s)
Signal Word Danger Hazard(s) H319 Causes serious eye irritation H334 May cause allergic or asthmatic symptoms or breathing difficulties if inhaled H317 May cause allergic skin reaction H351 Suspected of causing cancer H412 Harmful to aquatic life with long lasting effects Prevention P272 Contaminated work clothing should not be allowed out of the workplace P280 Wear protective gloves/protective clothing/eye protection/face protection P284 Wear respiratory protection P261 Avoid breathing dust/fume/gas/mist/vapours/spray P264 Wash thoroughly after handling P201 Obtain special instructions before use P202 Do not handle until all safety precautions have been read and understood P273 Avoid release to the environment Response P308+P313 IF exposed or concerned: Get medical advice/attention P304+P340 IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing P342+P311 If experiencing respiratory symptoms: Call a POISON CENTER or doctor/physician P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing P337+P313 If eye irritation persists: Get medical advice/attention P302+P352 IF ON SKIN: Wash with plenty of soap and water P362+P364 Take off contaminated clothing and wash it before reuse P333+P313 If skin irritation or rash occurs: Get medical advice/attention P321 Specific treatment (see label) Storage P405 Store locked up Disposal P501 Dispose of contents/container in accordance with local/regional/national/international regulations SILVER (7440-22-4) Hazard(s) H402 Harmful to aquatic life Prevention P273 Avoid release to the environment Disposal P501 Dispose of contents/container in accordance with local/regional/national/international regulations ANTIMONY (7440-36-0) Symbol(s)
Signal Word Warning Hazard(s) H316 Causes mild skin irritation H320 Causes eye irritation H373 May cause damage to organs through prolonged or repeated exposure Prevention P260 Do not breathe dust/fume/gas/mist/vapours/spray P264 Wash thoroughly after handling Response P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing P337+P313 If eye irritation persists: Get medical advice/attention P332+P313 If skin irritation occurs: Get medical advice/attention P314 Get medical advice/attention if you feel unwell Disposal P501 Dispose of contents/container in accordance with local/regional/national/international regulations ARSENIC (7440-38-2) Symbol(s)
Signal Word Danger Hazard(s) H302 Harmful if swallowed H331 Toxic if inhaled H341 Suspected of causing genetic defects H350 May cause cancer H372 Causes damage to organs through prolonged or repeated exposure H411 Toxic to aquatic life with long lasting effects Prevention P271 Use only outdoors or in a well-ventilated area P280 Wear protective gloves/protective clothing/eye protection/face protection P260 Do not breathe dust/fume/gas/mist/vapours/spray P264 Wash thoroughly after handling P201 Obtain special instructions before use P202 Do not handle until all safety precautions have been read and understood P270 Do not eat, drink or smoke when using this product P273 Avoid release to the environment Response P308+P313 IF exposed or concerned: Get medical advice/attention P304+P340 IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing P311 Call a POISON CENTER or doctor/physician P301+P312 IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell P321 Specific treatment (see label) P330 Rinse mouth P391 Collect spillage Storage P403+P233 Store in a well-ventilated place. Keep container tightly closed P405 Store locked up Disposal P501 Dispose of contents/container in accordance with local/regional/national/international regulations
Classification 
No classification assigned. 

* * * Section 16 - OTHER INFORMATION  * * *


Key / Legend 
ACGIH - American Conference of Governmental Industrial Hygienists; ADR - European Road Transport; AU - Australia; BOD - Biochemical Oxygen Demand; C - Celsius; CA - Canada; CAS - Chemical Abstracts Service; CERCLA - Comprehensive Environmental Response, Compensation, and Liability Act; CN - China; CPR - Controlled Products Regulations; DFG - Deutsche Forschungsgemeinschaft; DOT - Department of Transportation; DSL - Domestic Substances List; EEC - European Economic Community; EINECS - European Inventory of Existing Commercial Chemical Substances; EPA - Environmental Protection Agency; EU - European Union; F - Fahrenheit; IARC - International Agency for Research on Cancer; IATA - International Air Transport Association; ICAO - International Civil Aviation Organization; IDL - Ingredient Disclosure List; IDLH - Immediately Dangerous to Life and Health; IMDG - International Maritime Dangerous Goods; JP - Japan; Kow - Octanol/water partition coefficient; KR - Korea; LEL - Lower Explosive Limit; LOLI - List Of LIsts™ - ChemADVISOR’s Regulatory Database; MAK - Maximum Concentration Value in the Workplace; MEL - Maximum Exposure Limits; NFPA - National Fire Protection Agency; NIOSH - National Institute for Occupational Safety and Health; NJTSR - New Jersey Trade Secret Registry; NTP - National Toxicology Program; NZ - New Zealand; OSHA - Occupational Safety and Health Administration; PH - Philippines; RCRA - Resource Conservation and Recovery Act; RID - European Rail Transport; RTECS - Registry of Toxic Effects of Chemical Substances®; SARA - Superfund Amendments and Reauthorization Act; STEL - Short-term Exposure Limit; TDG - Transportation of Dangerous Goods; TSCA - Toxic Substances Control Act; TWA - Time Weighted Average; UEL - Upper Explosive Limit; US - United States 
Other Information 
Reasonable care has been taken in the preparation of this information; however, the manufacturer makes no warranty whatsoever including the warranty of merchantability, expressed or implied, with respect to this information. The manufacturer makes no representations and assumes no liability for any direct, incidental, consequential, or other such damages resulting from its use or misuse. 
Disclaimer: 
Supplier gives no warranty whatsoever, including the warranties of merchantability or of fitness for a particular purpose. Any product purchased is sold on the assumption the purchaser shall determine the quality and suitability of the product. Supplier expressly disclaims any and all liability for incidental, consequential or any other damages arising out of the use or misuse of this product. No information provided shall be deemed to be a recommendation to use any product in conflict with any existing patent rights. THIS SDS IS TO BE UTILIZED SOLELY AS A REFERENCE DOCUMENT AND IT IS NOT TO BE USED TO SATISFY THE DISTRIBUTION REQUIREMENTS OF OSHA'S HAZARD COMMUNICATION STANDARD (HCS) NOR CANADA'S CONTROLLED PRODUCT REGULATION (CPR). Read the Safety Data Sheet before handling product. Use of any information contained herein is provided at the reader's own risk and thus independent judgment by trained professionals must be utilized at all times. 
Copyright 
Copyright 1984-2016 ChemADVISOR, Inc 'RTECS®' is a United States trademark owned and licensed under authority of the U.S. Government, by and through Accelrys/Biovia. Portions ©Copyright 2016, U.S. Government. All rights reserved 

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