一种​防霉​型​智能​调温​聚氨酯​泡沫​的​制备​方法

源语言标题
(CN105131246) 一种​防霉​型​智能​调温​聚氨酯​泡沫​的​制备​方法
公开号/公开日
CN105131246 A 2015-12-09 [CN105131246] / 2015-12-09
申请号/申请日
2015CN-0609532 / 2015-09-23
发明人
CAI LIFENG;XU MINGHONG;
申请人
FUJIAN YUETE NEW MATERIAL TECHNOLOGY;UNIVERSITY PUTIAN;
主分类号
IPC分类号
C08G-018/48C08G-018/76C08G-101/00C08K-005/01C08K-005/05C08K-007/24C08K-009/02C08K-009/04C08K-009/12
摘要
(CN105131246) 本​发明​公开​了​一种​防霉​型​智能​调温​聚氨酯​泡沫​的​制备​方法,先​将​埃洛​石​纳米​管​活化,然后​将​有机​相变​材料​浸渍​进去,再用​8-羟基​喹啉​把​埃洛​石​纳米​管​端口​包覆,再利用​8-羟基​喹啉​和​铜​离子​的​络合​反应​得到​端口​包覆​8-羟基​喹啉​铜​的​塑料​调温​材料,然后​将​塑料​调温​材料​的​表面​修饰​氨基,最后​将​修饰​后的​塑料​调温​材料​添加​入​聚氨酯​泡沫​的​聚合反应,从而​制备​得​防霉​型​智能​调温​聚氨酯​泡沫。本​发明​的​有益​效果:(1)埃洛​石​纳米​管​既可以​作为​相变​材料​的​装载​容器,同时​可作​为​聚氨酯​泡沫​的​增强​材料;(2)埃洛​石​纳米​管​端口​反应​形成​8-羟基​喹啉​铜​络合物​既可以​防止​相变​材料​流出​埃洛​石​纳米​管,同时​可以​作为​防霉剂;(3)塑料​调温​材料​表面的​氨基​使得​该​材料​与​泡沫​紧密结合。
地址
代理人
代理机构
;
优先权号
2015CN-0609532 2015-09-23
主权利要求
(CN105131246) 1. One mildew type intelligent temperature control method for producing a polyurethane foam, characterized in: preparing method comprises the following steps: Will(1) halioysite nanotube at a temperature of 25-80 Ć, immersed in dilute hydrochloric acid 5-20% of mass fraction of from 30-60 minutes, washed sequentially filtering, washing, drying, is activated halioysite nanotubes; A weight ratio of 1:3 in terms of organic(2) phase change material and an organic solvent, the organic low-temperature phase-change material is dissolved in an organic solvent, to give the phase change material solution; nanotube and a phase-change material again in accordance with activation halioysite 1:2 weight ratio of solution, the step(1) resulting activated halioysite nanotubes are added to the phase change material solution, vacuum impregnation 1-3 hours, after drying, by vacuum impregnation and drying 2nd repetitions, load of phase change material to obtain a nanotube halioysite lumen; According to(3) 8-solvent weight ratio of 1:3 with quinolinal, will 8-hydroxyquinoline dissolved in a solvent, to give 8-hydroxyquinoline solution; is further depressed to take care of phase change material halioysite nanotubes with a load chamber 8-hydroxyquinoline solution weight ratio of 1:2, phase change material will be obtained in Step(2) halioysite nanotubes are added to the load vessel lumen 8-hydroxyquinoline solution, vacuum impregnation 20-60 minutes, after drying, by vacuum impregnation and drying 2nd iteration, to give the port covering 8-load phase change material and the lumens quinolinal nanotube halioysite a solid powder; A solution of a solid or powder will be(4) obtained in Step(3) 0.1-0.8 mol/L solution of cupric ion compound, solid or powder with a solution of cupric ion compound weight ratio of 1:5, vogorously, complexation reaction 20-200 hs, sequentially filtering, washing, drying, tempering to obtain plastic material; A diluent and(5) an aminosilane in a weight ratio 3:1 mixed to obtain a mixed solution, and the temperature regulating material and the resulting mixed solution to give the(4) plastic a weight ratio of 1: 0.1-1: 0.5 mixed, and then stirred in a homomixer 20-40 minutes, temperature-regulating additives to obtain plastic; The step(6)(5) of a plastic temperature regulating additive is added butter PPG autoclave, agitated by a homomixer 20-70 minutes, wherein each of the cast material in parts by weight ratio of: Plastic tempering additive 10-35 parts; Butter PPG10-50 parts; Continues to butter PPG 1.0-3.5 parts by weight of water were added sequentially the kettle to, 2.0-5.5 parts by weight of a cell opener, 1.0-2.0 parts by weight of liquid ammonia, 35-80 parts by weight of silicone oil and 0.25-0.5 parts by weight of catalyst, was stirred in a homomixer 15-40 hs; in the vessel was continuously added 50-100 parts by weight of MDI, stirring by a homomixer 15-40 hs, and then directly into a polyurethane reaction tank; After 2 hours at room temperature(8) environments where natural aging placed, polyurethane foam obtained tempered.
法律状态
(CN105131246) LEGAL DETAILS FOR CN105131246  Actual or expected expiration date=2035-09-23    Legal state=ALIVE    Status=PENDING     Event publication date=2015-09-23  Event code=CN/APP  Event indicator=Pos  Event type=Examination events  Application details  Application country=CN CN201510609532  Application date=2015-09-23  Standardized application number=2015CN-0609532     Event publication date=2015-12-09  Event code=CN/A  Event type=Examination events  Published application  Publication country=CN  Publication number=CN105131246  Publication stage Code=A  Publication date=2015-12-09  Standardized publication number=CN105131246     Event publication date=2015-12-09  Event code=CN/C06  Event indicator=Pos  Event type=Examination events  Publication    Event publication date=2016-01-06  Event code=CN/C10  Event type=Examination events  Request of examination as to substance
专利类型码
A
国别省市代码
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