(JP2019183160) Perfluoro (poly) ether group-containing silane compound 机翻标题: 暂无翻译,请尝试点击翻译按钮。

源语言标题
(JP2019183160) Perfluoro (poly) ether group-containing silane compound
公开号/公开日
JP2019183160JP6575721 / 2019-10-242019-09-18
申请号/申请日
JP2019102899 / 2019-05-31
发明人
MITSUHASHI HISASHITAKANO MAYUKONAMIKAWA TAKASHINOMURA TAKASHI;
申请人
DAIKIN INDUSTRIES;
主分类号
IPC分类号
C07F-007/18 C08G-065/336 C09D-171/02 C09K-003/00 C09K-003/18
摘要
(JP6575721) The present invention provides a perfluoro(poly)ether group containing silane compound of €ƒ€ƒ€ƒ€ƒ€ƒ€ƒ€ƒ€ƒ (Rf-PFPE) ² -X-(CR a k R b l R c m) ± ··· €ƒ€ƒ€ƒ€ƒ€ƒ (1a) €ƒ€ƒ€ƒ€ƒ€ƒ€ƒ€ƒ€ƒ (R c m R b l R a k C) ± -X-PFPE-X-(CR a k R b l R c m ) ± ··· €ƒ€ƒ€ƒ€ƒ€ƒ (1b) wherein the symbols are as defined in the description.  (From EP3333172 A1)
机翻摘要
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地址
代理人
(JP2019183160) Yamada Takuzi Reg. Nb: 100101454 Yoshida Ring Reg. Nb: 100132252
代理机构
;
优先权号
2015JP-0152468 2015JP-0181146 2015JP-0215019
主权利要求
(JP6575721) 1. (1a ") Of the formula: [wherein: Rf is a, represents a perfluoroalkyl group of 1-3 carbon atoms; PFPE is, of the formula: formula -(OC4F8) a-(OC3F6) b-(OC2F4) c-(OCF2) d-(, a and b are, each independently, is an integer of 30 or 0, c and d are, independently, is an integer of 200 or more 5, a, b, c and d 10 greater than or equal to the sum of the portions, the ratio of c to d is, equal to or less than 0.9, the subscript a, b, c or d are denoted by the order of the repeating units within the parentheses to which in the formula may be in any order.) Is a group represented by the formula; X is, represented by the following formula: - Xd-R31-R31-Xc-R31-or [wherein: R31 is, independently, -s' - (CH2) (in the formula, s'is, an integer of 1-3.) Represents; Xc is, or is - O-CONR34-, Xd is, - CONR34-and, R34 is, independently at each occurrence, represents a hydrogen atom or methyl group. ] Represents a group represented by the formula; Rb is, independently at each occurrence, represents - Y-SiR53; is Y, C1-6 alkylene group; R5 is, - OR and, R is applied, a methyl group or ethyl group. ] (Poly) ether group represented by the compound perfluoro silane containing. 2. PFPE is, of the formula: formula -(OCF2CF2CF2CF2) a-(OCF2CF2CF2) b-(OCF2CF2) c-(OCF2) d-(, and b is a, independently, an integer of 30 or more and 0, c and d are, independently, an integer of 200 or more and 5, a, b, c and d is 10 or more and the sum, the ratio of c to d, less than or equal to 0.9, subscript a, b, c or d are denoted by the order of the repeating units within the parentheses to which in the formula may be in any order.) Is a group represented by the formula, according to claim 1 perfluoro (poly) ether group-containing silane compound. 3. PFPE is, of the formula: formula -(OCF2CF2) c-(OCF2) d-(, c and d are, independently, is an integer of 200 or more 5, 10 or more and the sum of c and d, the ratio of c to d, less than or equal to 0.9, c or d are denoted by the subscript within the parentheses to which the order of the repeating units is arbitrary in the formula.) Is a group represented by the formula, according to claim 1 or 2 perfluoro (poly) ether group-containing silane compound. 4. The ratio of c to d, less than or equal to 0.9 or 0.2, any one of claims 1-3 (poly) ether is perfluoro group-containing silane compound. 5. The ratio of c to d, less than or equal to 0.9 or 0.3, wherein the perfluoro (poly) ether of any one of claims 1-4 group-containing silane compound.  6. (1a ") Of the formula:  [wherein: Rf is a, represents a perfluoroalkyl group of 1-3 carbon atoms; PFPE is, of the formula :-(OCF2CF2CF2) b- (wherein, b is an integer of 200 or 5) a group represented by the formula; X is, represented by the following formula: - Xd-R31-R31-Xc-R31-or [wherein: R31 is, independently, -s' - (CH2) (in the formula, s'is, is an integer of 1-3.) Represents; Xc is, or is - O-CONR34-, Xd is, - CONR34-and, R34 is, independently at each occurrence, represents a hydrogen atom or methyl group. ] Represents a group represented by the formula; Rb is, independently at each occurrence, represents - Y-SiR53; is Y, C1-6 alkylene group; R5 is, - OR and, R is applied, a methyl group or ethyl group. ] (Poly) ether group represented by the compound perfluoro silane containing. 7. Rf is, - CF3 in, any one of claims 1-6 (poly) ether is a perfluoro group-containing silane compound. 8. X is, represented by the following formula: - Xd-R31-[in which: R31 is-s' - (CH2) (in the formula, s'is, an integer of 1-3.) Represents; Xd is, - CONR34-and, R34 is, independently at each occurrence, represents a hydrogen atom or methyl group. ] Is a group represented by the formula, (poly) ether of any one of claims 1-7 perfluoro group-containing silane compound. 9. S'is 1 in, any one of claims 1-8 (poly) ether comprises a perfluoro group-containing silane compound. 10. R34 Is, a hydrogen atom, any one of claims 1-9 (poly) ether is perfluoro group-containing silane compound. 11. Y is, at a - CH2CH2CH2-, any one of claims 1-10 (poly) ether is a perfluoro group-containing silane compound. 12. R5 Is, - OCH3 in, any one of claims 1-11 (poly) ether comprises a perfluoro group-containing silane compound. 13. 2,500-12,000 has a number average molecular weight of, any one of claims 1-12 (poly) ether is perfluoro group-containing silane compound. 14. (1a ") Of any one of claims 1-13 represented by the formula 1 (poly) ether and at least one perfluoro-alkyl group containing silane compound, and the surface treatment agent. 15. The fluorine-containing oil, silicone oil, and the catalyst is selected from one or more of 1 further comprising a component of the other, and the surface treatment agent according to claim 14. 16. The fluorine-containing oil, the formula (3): formula R21-(OC4F8) a'-(OC3F6) b'-(OC2F4) c'-(OCF2) d'-R22, (3) [: is R21, a fluorine atom and 1 is optionally substituted by one or more of the carbon atoms which may have a 1-16 alkyl group; R22 may, be substituted by one or more of a fluorine atom and 1 is an alkyl group of 1-16 carbon atoms which may have, represents a hydrogen atom or a fluorine atom; a ', b', c'and d'are, to obtain a perfluorinated polymer to constitute the main skeleton of the (poly) ethers of the number of repeating units represents 4, 0 independently of one another an integer of 300 or more, a ', b', c'and d'1 and the sum of the at least one, and the subscript a', b ', c'and d'or parentheses given order of the repeating units, optionally in the formula. ] 1 Is represented by one or more of the compounds, and the surface treatment agent according to claim 15. 17. The fluorine-containing oil, (3a) or formula (3b): formula R21-(OCF2CF2CF2) b''-R22, (3a) R21-(OCF2CF2CF2CF2) a''-(OCF2CF2CF2) b''-(OCF2CF2) c''-(OCF2) d''-R22, (3b) [: is R21, 1 or more fluorine atoms may be substituted by an alkyl group having a carbon number of 1-16; R22 is, one or more fluorine atoms and 1 is substituted by an alkyl group of 1-16 carbon atoms and may or may not, represents a hydrogen atom or a fluorine atom; in formula (3a), b "is an integer of 100 or more is 1; (3b) in the formula, a" and b "are, each independently represent 0 or an integer less than or equal to 30, c" and d "are, each independently is an integer of 300 or more 1; Z_x a", b ", c" d or " by the same reference numerals within the parentheses to which the order of the repeating units, optionally in the formula. ] 1 Is represented by one or more of the compounds, and the surface treatment agent according to claim 15 or 16. 18. Which further comprises a solvent, and the surface treatment agent according to any one of claims 14-17 of. 19. A waterproof coating agent or an anti-staining property is used as a coating agent, wherein the surface treatment agent of any one of claims 14-18. 20. In a carrier for vacuum vapor deposition, and the surface treatment agent according to any one of claims 14-19. 21. Wherein the surface treatment agent of any one of claims 14-20 pellets containing. 22. And the substrate, the surface of the substrate, wherein the compound of any one of claims 1-13 surface treating agent according to any one of claims 14-20 or formed by the layer of the article. 23. Wherein said article is an optical member, the article according to claim 22. 24. Wherein said article is a display, the article according to claim 22.
法律状态
GRANTED
专利类型码
AB1
国别省市代码
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