Insecticidal composition having improved efficacy 机翻标题: 暂无翻译,请尝试点击翻译按钮。

源语言标题
(JP2009519278) 改善​さ​れ​た​効果​を​有する​殺虫​組成​物
公开号/公开日
JP2009519278 A 2009-05-14 [JP2009519278] / 2009-05-14
申请号/申请日
2008JP-0544847 / 2006-12-11
发明人
Fuitsushiya liner;Lohr Shiyutefuan;Marutsuotsuku Peter;Retsukuman oud;Arunoruto Ian Christe;Hempel Bal trout;Sanbaruto Eritsuhi;Pontsuen Rolf;
申请人
BAYER CROPSCIENCE;
主分类号
IPC分类号
A01N-043/08A01N-043/16A01N-043/36A01N-043/40A01N-043/86A01N-043/90A01N-059/02A01P-007/04
摘要
(JP2009519278) The present invention concerns boosting the activity of crop protection materials comprising active ingredients from the class of the phenyl-substituted cyclic ketoenols through the addition of ammonium salts and/or phosphonium salts or through the addition of ammonium salts and/or phosphonium salts and penetrants, the corresponding materials, processes for preparing them, and their use in crop protection.  (From US8247351 B2)
机翻摘要
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地址
代理人
代理机构
;
优先权号
2005DE-10059469 2005-12-13 2006WO-EP11912 2006-12-11
主权利要求
(JP2009519278) 1. 1 At least one of a phenyl-substituted cyclic Ketoenols Frce arylaminotriazoles and/or acaricidally active component, at least one of the following formula (II) 1 salt  (xLxWx, is nitrogen or phosphorus and D, R26 、R27 、R28 and R29 are independently, hydrogen, or optionally substituted in either of the cases in which C1 -C8 -alkyl, or optionally mono-substituted or multi-unsaturated substituted C1 -C8 -alkylene, the substituents are halogen, which is selected from nitro and cyano, n is 4 or is 1, 2, 3, R30 is an organic or inorganic anion.) Composition comprising.  2. Wherein the active ingredient, according to the following formula (I) a phenyl-substituted cyclic Ketoenols  [xLxWx, W is hydrogen, alkyl, alkenyl, alkynyl, halogen, alkoxy, haloalkyl, haloalkoxy or cyano and, X is halogen, alkyl, alkenyl, alkynyl, alkoxy, alkoxy - alkoxy, haloalkyl, haloalkoxy or cyano and, Y is hydrogen, halogen, alkyl, alkenyl, alkynyl, alkoxy, cyano, haloalkyl, haloalkoxy or, in each case optionally substituted phenyl or hetaryl and, Z hydrogen, halogen, alkyl, haloalkyl, cyano, alkoxy or haloalkoxy and, 1 is one of a group CKE is  (˜C, A is hydrogen, in each case optionally halogen-substituted alkyl, alkenyl, alkoxyalkyl, alkylthioalkyl and, the at least one ring atom is optionally substituted with 1 when the heteroatom is substituted by a saturated or unsaturated cycloalkyl, or in each case optionally halogen, alkyl, haloalkyl, alkoxy, haloalkoxy, cyano or nitro substituted aryl, arylalkyl or hetaryl and, B is hydrogen, alkyl, or alkoxyalkyl which is, or is A B and, together with the carbon atoms to which they are attached, including 1 at least one hetero atom and optionally a saturated or unsaturated unsubstituted or substituted ring, and is preferably a hydrogen D, or a 1 - membered heterocycle optionally substituted with one or more of the hetero atoms of the series alkyl, alkenyl, alkynyl, alkoxyalkyl, saturated or unsaturated cycloalkyl which is substituted by a group from which the case, or an arylalkyl, aryl, or hetaryl and Hetarylalkyl, or A D and is, together with the atoms to which they are attached, 1 optionally at least one hetero atom and (in the case of CKE=8), A, which is saturated or unsaturated D in a portion of the ring that is saturated or unsaturated, and A or Q1 together, optionally a hydroxyl, or optionally substituted by in each case alkyl, alkoxy, alkylthio, cycloalkyl, benzyloxy or aryl or alkanediyl and alkenediyl substituted, or D and Q1 may, together with the atoms to which they are bonded, comprises at least one hetero atom and optionally 1, D, Q1 portion is saturated or unsaturated ring that is saturated or unsaturated, Q1 is hydrogen, alkyl, alkoxyalkyl, optionally substituted cycloalkyl (where one methylene group is optionally 1 substituted by an oxygen or sulfur.), Or is phenyl optionally substituted, Q2 、Q4 、Q5 and Q6 independently of one another are hydrogen or alkyl, Q3 is hydrogen, optionally substituted alkyl, alkoxyalkyl, alkylthioalkyl, cycloalkyl optionally substituted by (optionally one methylene group is 1 substituted with an oxygen or sulfur.), Or optionally substituted phenyl, or Q1 and Q2 may, together with the carbon atoms to which they are attached, a saturated or unsaturated and optionally containing a hetero atom in the ring, or Q3 and Q4 may, together with the carbon atoms to which they are bonded, and optionally containing a heteroatom of the saturated or unsaturated, unsubstituted or substituted ring, g (a) hydrogen, or one of the following radicals 1  (˜C, 1 is a metal ion equivalent or one E ammonium ions, and L denotes oxygen or sulfur, oxygen or sulfur and M, R1 is, in each case optionally halogen-substituted alkyl, alkenyl, alkoxyalkyl, alkylthioalkyl, polyalkoxyalkyl or is interrupted by at least 1 heteroatoms and optionally can be halogen, alkyl or alkoxy-substituted cycloalkyl, or an optionally substituted in each case phenyl, phenylalkyl, hetaryl, or Hetaryloxyalkyl and Phenoxyalkyl, R2 is, in each case optionally halogen-substituted alkyl, alkenyl, alkoxyalkyl, polyalkoxyalkyl and, or in each case optionally substituted cycloalkyl, phenyl or benzyl, R3 、R4 and R5 independently of one another are, in each case optionally halogen-substituted alkyl, alkoxy, alkylamino, dialkylamino, alkylthio, alkenylthio, cycloalkylthio and, or an optionally substituted in each case the phenyl, benzyl, phenoxy or phenylthio and, R6 and R7 is, independently of one another are hydrogen, in each case optionally halogen-substituted alkyl, cycloalkyl, alkenyl, alkoxy, alkoxyalkyl, optionally substituted phenyl, and benzyl optionally substituted, or R6 and R7 N together with the atoms to which they are attached, and optionally interrupted by oxygen or sulfur ring.). ). ] Wherein the, composition according to claim 1. 3. (I) in the formula as defined in the following substituents, namely, hydrogen W, C1 -C6 -alkyl, C2 -C6 -alkenyl, C2 -C6 -alkynyl, halogen, C1 -C6 -alkoxy, C1 -C4 -haloalkyl, C1 -C4 -haloalkoxy or cyano, a halogen X, C1 -C6 -alkyl, C2 -C6 -alkenyl, C2 -C6 -alkynyl, C1 -C6 -alkoxy, C1 -C6 -alkoxy -C1 -C4 -alkoxy, C1 -C4 -haloalkyl, C1 -C4 -haloalkoxy or cyano, Y is hydrogen, halogen, C1 -C6 -alkyl, C2 -C6 -alkenyl, C2 -C6 -alkynyl, C1 -C6 -alkoxy, cyano, C1 -C4 -haloalkyl, haloalkoxy, or V1 -and V2 -is phenyl or pyridyl which is substituted, V1 halogen, C1 -C12 -alkyl, C1 -C6 -alkoxy, C1 -C4 -haloalkyl, C1 -C4 -haloalkoxy, cyano or nitro, V2 is hydrogen, halogen, C1 -C6 -alkyl, C1 -C6 -alkoxy or C1 -C4 -haloalkyl, V1 and V2 jointly, and/or the optionally halogen C1 -C2 -alkyl can be substituted by, 1 or 2 oxygen atoms and optionally can be interrupted C3 -C4 -is alkanediyl, Z hydrogen, halogen, C1 -C6 -alkyl, C1 -C4 -haloalkyl, cyano, C1 -C6 -alkoxy or C1 -C4 -haloalkoxy, 1 CKE is a group of one  [Ais hydrogen, halogen or in each case optionally substituted C1 -C12 -alkyl, C3 -C8 -alkenyl, C1 -C10 -alkoxy -C1 -C8 -alkyl, C1 -C10 -alkylthio -C1 -C6 -alkyl and, one or two not directly adjacent ring members of 1 oxygen and 2 is optionally substituted nitrogen and/or, optionally halogen, C1 -C6 -or alkyl C1 -C6 -alkoxy substituted C3 -C8 -cycloalkyl, halogen or in each case optionally, C1 -C6 -alkyl, C1 -C6 -haloalkylinclude, C1 -C6 -alkoxy, C1 -C6 -haloalkoxy, cyano or nitro-substituted phenyl, naphthyl, one of 5 6 ring atoms or hetaryl from (for example, furanyl, pyridyl, imidazolyl, triazolyl, pyrazolyl, pyrimidyl, thiazolyl or thienyl), phenyl -C1 -C6 -alkyl or naphthyl -C1 -C6 -alkyl, B hydrogen, C1 -C12 -alkyl or C1 -C8 -alkOXy -C1 -C6 -alkyl, A or, B and the carbon atom to which they are attached may, optionally one oxygen or sulfur 1 is substituted with a heteroring, optionally C1 -C8 -alkyl, C1 -C6 -alkOXy -C1 -C6 -alkyl, C3 -C6 -cycloalkyl -C1 -C2 -alkoxy, C3 -C10 -cycloalkyl, C1 -C8 -haloalkyl, C1 -C8 -alkoxy, C1 -C6 -alkOXy -C1 -C4 -alkoxy, C1 -C8 -alkylthio, halogen or phenyl mono-substituted or substituted saturated double C3 -C10 -cycloalkyl or unsaturated C5 -C10 -cycloalkyl, A or, wherein the carbon atom to which they are attached and B is, optionally C1 -C4 -alkyl optionally substituted with one or two not directly adjacent oxygen and/or one of 1 2 Alkylenediyl group containing sulfur atom, or a Alkylenedioxy Lumpur group, or together with the carbon atom bonded to 8 - membered ring formed from 5 and further substituted with a group Alkylene Ji oil C3 -C6 -cycloalkyl, A or, B and the carbon atom to which they are attached is, in which one substituent of 2, together with the carbon atoms to which they are attached, in each case, optionally C1 -C6 -alkyl, C1 -C6 -alkoxy or halogen substituted C2 -C6 -alkanediyl, C2 -C6 -alkenediyl or C4 -C6 -Alkane diene diyl and, 1 is oxygen or sulfur or a methylene group of the substituted C3 -C8 -cycloalkyl or C5 -C8 -is cycloalkenyl, D hydrogen, in each case optionally halogen-substituted C1 -C12 -alkyl, C3 -C8 -alkenyl, C3 -C8 -alkynyl, C1 -C10 -alkOXy -C2 -C8 -alkyl and, wherein the two rings 1 optionally replaced by oxygen or sulfur Otis halogen when, C1 -C4 -alkyl, C1 -C4 -alkoxy or C1 -C4 -haloalkyl substituted C3 -C8 -cycloalkyl, or optionally in each case halogen, C1 -C6 -alkyl, C1 -C6 -haloalkyl, C1 -C6 -alkoxy, C1 -C6 -haloalkoxy, phenyl substituted with a cyano or nitro, having 5 ring atoms or hetaryl from one 6 (for example, furanyl, imidazolyl, pyridyl, thiazolyl, pyrazolyl, pyrimidyl, Pyrrolyl, thienyl or triazolyl), phenyl C1 -C6 -from 6 5 alkyl or the two ring atoms hetaryl -C1 -C6 -alkyl (for example, furanyl, imidazolyl, pyridyl, thiazolyl, pyrazolyl, pyrimidyl, Pyrrolyl, thienyl or triazolyl) which, together or A D and, optionally one methylene group is a carbonyl group 1, oxygen or sulfur and is substituted in each case optionally substituted C3 -C6 -alkanediyl or C3 -C6 -is alkenediyl, suitable substituents, in each case halogen, hydroxyl, and mercapto, or in each case optionally halogen-substituted C1 -C10 -alkyl, C1 -C6 -alkoxy, C1 -C6 -alkylthio, C3 -C7 -cycloalkyl, phenyl or benzyloxy which is, or optionally C1 -C6 -which is substituted with an alkyl, or optionally two adjacent 2 substituents, together with the carbon atoms to which they are attached, a 6 5 ring atoms one or two additional ring is a ring formed of a saturated or unsaturated (in the case of the formula (I - 1), A D and is, together with the atoms to which they are bonded, define a group equal to or less than AD - 10 after a from AD - 1.), Which can be oxygen or sulfur, or two 1 groups optionally in the presence of, further C3 -C6 -alkanediyl portion, C3 -C6 -alkenediyl or butadienyl moiety,  or A and Q1 together C4 -C6 -alkenediyl or C3 -C6 -is alkanediyl, these, halogen, hydroxyl, in each case optionally halogen-substituted group 1 of the same or different from the 3-substituted RAMRn C3 -C7 -cycloalkyl, C1 -C6 -alkylthio, C1 -C6 -alkoxy or C1 -C10 -and is substituted with an alkyl, and in each case be the same or a different halogen than, C1 -C6 -alkyl or C1 -C6 -3 1 alkoxy substituted with phenyl substituted once or twice by identical or different substituents selected from the benzyloxy group at the 1 - or in each case optionally-substituted and 2, are, further optionally includes one of a group 1, or C1 -C2 -alkanediyl group or oxygen atom is crosslinked and,  Dand Q1 together, in any of these cases optionally C1 -C4 -alkyl and C1 -C4 -alkoxy selected from the substituents of the same or different 2 or 1 times substituted RAMRn C3 -C6 -is alkanediyl, Q1 is, hydrogen, C1 -C6 -alkyl, C1 -C6 -alkOXy -C1 -C2 -alkyl, 1 is optionally one methylene group is replaced by sulfur or oxygen and in the case where the fluorine, chlorine, C1 -C4 -alkyl, C1 -C2 -haloalkylinclude or C1 -C4 -alkoxy substituted C3 -C8 -cycloalkyl, or optionally halogen, C1 -C4 -alkyl, C1 -C4 -alkoxy, C1 -C2 -haloalkylinclude, C1 -C2 -haloalkoxy, cyano or nitro substituted phenyl, Q2 、Q4 、Q5 and Q6 independently of one another are hydrogen or1 -C4 -alkyl, Q3 is, hydrogen, C1 -C6 -alkyl, C1 -C6 -alkOXy -C1 -C2 -alkyl, C1 -C6 -alkylthio -C1 -C2 -alkyl, 1 is optionally one methylene group is replaced by oxygen or sulfur and optionally C1 -C4 -or alkyl C1 -C4 -alkoxy substituted C3 -C8 -cycloalkyl, halogen or optionally, C1 -C4 -alkyl, C1 -C4 -alkoxy, C1 -C2 -haloalkyl, C1 -C2 -haloalkoxy, cyano or nitro-substituted phenyl, Q1 and Q2 are, together with the carbon atoms to which they are attached, 1 optionally substituted with two of the ring members are oxygen or sulfur and optionally C1 -C6 -alkyl, C1 -C6 -alkoxy or C1 -C2 -haloalkyl substituted C3 -C7 -ring, Q3 and Q4 may, together with the carbon atoms to which they are attached, or 1 ring members and optionally one oxygen and optionally is replaced by sulfur C1 -C4 -alkyl, C1 -C4 -alkoxy or C1 -C2 -haloalkyl substituted C3 -C7 -ring, g is hydrogen or one of the following radicals (a) 1 is one, in particular (a), (b), and (c) or (g),  E1 is one metal ion equivalent or an ammonium ion, and L denotes oxygen or sulfur, oxygen or sulfur and M, R1 is, which is optionally substituted with halogen C1 -C20 -alkyl, C2 -C20 -alkenyl, C1 -C8 -alkOXy -C1 -C8 -alkyl, C1 -C8 -alkylthio -C1 -C8 -alkyl, poly -C1 -C8 -alkOXy -C1 -C8 -alkyl, or optionally 1 and one or more not directly adjacent (more preferably at most one 2) oxygen and/or sulfur ring members are optionally substituted by halogen, C1 -C6 -or alkyl C1 -C6 -alkoxy substituted C3 -C8 -cycloalkyl which, in the case of halogen, cyano, nitro, C1 -C6 -alkyl, C1 -C6 -alkOXy, C1 -C6 -haloalkyl, C1 -C6 -haloalkoxy, C1 -C6 -alkylthio or C1 -C6 -Examptes-substituted phenyl, optionally halogen, nitro, cyano, C1 -C6 -alkyl, C1 -C6 -alkoxy, C1 -C6 -or haloalkyl C1 -C6 -haloalkoxy-substituted phenyl -C1 -C6 -alkyl, halogen or optionally C1 -C6 -6 or 5 which is substituted with an alkyl - or hetaryl - (e.g., pyrazolyl, thiazolyl, pyridyl, pyrimidyl, furanyl, or thienyl) and, halogen or optionally C1 -C6 -alkyl substituted phenoxy -C1 -C6 -alkyl, or optionally halogen, amino or C1 -C6 -SOzZ Hetaryloxy - 5 has been substituted with a 6 - membered -C1 -C6 -alkyl (for example, pyridyloxy -C1 -C6 -alkyl, pyrimidinyoxy -C1 -C6 -alkyl or thiazolyloxy -C1 -C6 -alkyl) and, R2 is, in each case optionally halogen-substituted C1 -C20 -alkyl, C2 -C20 -alkenyl, C1 -C8 -alkOXy -C2 -C8 -alkyl, poly -C1 -C8 -alkOXy -C2 -C8 -alkyl, optionally halogen, C1 -C6 -or alkyl C1 -C6 -alkoxy substituted C3 -C8 -cycloalkyl, or in each case optionally halogen, cyano, nitro, C1 -C6 -alkyl, C1 -C6 -alkoxy, C1 -C6 -or haloalkyl C1 -C6 -haloalkoxy substituted phenyl or benzyl, R3 is, optionally halogen-substituted C1 -C8 -alkyl, halogen or in each case optionally, C1 -C6 -alkyl, C1 -C6 -alkoxy, C1 -C4 -haloalkyl, C1 -C4 -haloalkoxy, cyano or nitro or a phenyl or substituted benzyl, R4 and R5 independently of one another are, in each case optionally halogen-substituted C1 -C8 -alkyl, C1 -C8 -alkoxy, C1 -C8 --alkylamino, di - (C1 -C8 -alkyl) amino, C1 -C8 -alkylthio, C2 -C8 -alkenylthio, C3 -C7 -and cycloalkylthio, or in each case optionally halogen, nitro, cyano, C1 -C4 -alkoxy, C1 -C4 -haloalkoxy, C1 -C4 -alkylthio, C1 -C4 -haloalkthio, C1 -C4 -or alkyl C1 -C4 -haloalkyl-substituted phenyl, phenoxy or phenylthio and, R6 and R7 is, independently of one another are hydrogen, in each case optionally halogen-substituted C1 -C8 -alkyl, C3 -C8 -Cycloalkjd, C1 -C8 -alkoxy, C3 -C8 -alkenyl, C1 -C8 -alkOXy -C1 -C8 -alkyl, optionally halogen, C1 -C8 -haloalkylinclude, C1 -C8 -or alkyl C1 -C8 -alkoxy substituted phenyl, optionally halogen, C1 -C8 -alkyl, C1 -C8 -haloalkylinclude or C1 -C8 -alkoxy substituted benzyl, or together, 1 and optionally one carbon atom is replaced by oxygen or sulfur and optionally C1 -C4 -alkyl substituted C3 -C6 -alkylene groups and, R13 hydrogen, in each case optionally halogen-substituted C1 -C8 -or alkyl C1 -C8 -alkoxy and, in the case where 1 is oxygen or sulfur by one methylene group is substituted by halogen when, C1 -C4 -or alkyl C1 -C4 -alkoxy substituted C3 -C8 -cycloalkyl, or optionally in each case halogen, C1 -C6 -alkyl, C1 -C6 -alkoxy, C1 -C4 -haloalkyl, C1 -C4 -haloalkoxy, nitro or cyano-substituted phenyl, phenyl -C1 -C4 -alkyl or a phenyl -C1 -C4 -alkoxy, R14a hydrogen or C1 -C8 -alkyl, or R13 and R14a together C4 -C6 -is alkanediyl, R15a and R16a are the same or different C1 -C6 -alkyl, or R15a and R16a together C2 -C4 -alkanediyl (this C2 -C4 -is an alkanediyl group, C1 -C6 -alkyl, C1 -C6 -haloalkyl, or optionally halogen, C1 -C6 -alkyl, C1 -C4 -haloalkylinclude, C1 -C6 -alkoxy, C1 -C4 -haloalkoxy, phenyl substituted with nitro or cyano and optionally substituted.) And, R17a and R18a independently of one another are hydrogen, optionally halogen-substituted C1 -C8 -alkyl, or optionally halogen, C1 -C6 -alkyl, C1 -C6 -alkoxy, C1 -C4 -haloalkylinclude, C1 -C4 -haloalkoxy, nitro or cyano-substituted phenyl, or R17a and R18a may, together with the carbon atoms to which they are attached, a carbonyl group, or optionally 1 one methylene group is replaced by oxygen or sulfur when the halogen by, C1 -C4 -or alkyl C1 -C4 -alkoxy substituted C5 -C7 -cycloalkyl, R19a and R20a independently of one another are C1 -C10 -alkyl, C2 -C10 -alkenyl, C1 -C10 -alkoxy, C1 -C10 -alkylamino, C3 -C10 -Alkenylamino, amino or di - (C1 -C10 -alkyl) di - (C3 -C10 -alkenyl) amino. ] Wherein the, composition according to claim 1.  4. (I) a substituent of the formula as defined in the following, namely, W is, hydrogen, fluorine, chlorine, bromine, C1 -C4 -alkyl, C2 -C4 -alkenyl, C2 -C4 -alkynyl, C1 -C4 -alkoxy, C1 -C2 -haloalkyl or C1 -C2 -haloalkoxy, where X, chlorine, bromine, iodine, C1 -C4 -alkyl, C2 -C4 -alkenyl, C2 -C4 -alkynyl, C1 -C4 -alkoxy, C1 -C4 -alkOXy -C1 -C3 -alkoxy, C1 -C2 -haloalkylinclude, C1 -C2 -haloalkoxy or cyano, Y is, in position 4, the hydrogen, C2 -C4 -alkenyl, C2 -C4 -alkynyl, fluorine, chlorine, bromine, iodine, methoxy, ethoxy, cyano, trifluoromethyl, difluoromethoxy or trifluoromethoxy, hydrogen Z, also W, hydrogen, fluorine, chlorine, bromine or C1 -C4 -alkyl, also X, chlorine, bromine, C1 -C4 -alkyl, C1 -C4 -alkoxy, C1 -C2 -haloalkylinclude, C1 -C2 -haloalkoxy or cyano, Y also, in position 4 is a group of the following,  Zalso, hydrogen, V1 also, fluorine, SOCb, C1 -C4 -alkyl, C1 -C4 -alkoxy, C1 -C2 -haloalkyl or C1 -C2 -haloalkoxy, cyano or nitro, V2 also, hydrogen, fluorine, chlorine, C1 -C4 -alkyl, C1 -C4 -alkoxy or C1 -C2 -haloalkyl, V1 and V2 can also, together with -O- CH2 -O-and -O- CF2 -O-and, similarly W, hydrogen, fluorine, chlorine, bromine or C1 -C4 -alkyl, similarly X, chlorine, bromine, C1 -C4 -alkyl, C1 -C4 -alkoxy, C1 -C2 -haloalkylinclude, C1 -C2 -haloalkoxy or cyano, Y likewise, in position 5, C2 -C4 -alkenyl, C2 -C4 -alkynyl, or is a group of the following,  Zas is, in position 4, the hydrogen, C1 -C4 -alkyl or chlorine, V1 similarly, fluorine, chlorine, C1 -C4 -alkyl, C1 -C4 -alkoxy, C1 -C2 -haloalkyl or C1 -C2 -haloalkoxy, cyano or nitro, V2 similarly, hydrogen, fluorine, chlorine, C1 -C4 -alkyl, C1 -C4 -alkoxy or C1 -C2 -haloalkyl, V1 and V2 similarly, together with the -O- CH2 -O-and -O- CF2 -O-in, further W, hydrogen, C1 -C4 -alkyl, C2 -C4 -alkenyl, C2 -C4 -alkynyl, C1 -C4 -alkoxy, fluorine, chlorine, bromine or trifluoromethyl, more X, fluorine, chlorine, bromine, iodine, C1 -C4 -alkyl, C2 -C4 -alkenyl, C2 -C4 -alkynyl, C1 -C4 -alkoxy, C1 -C4 -alkOXy -C1 -C3 -alkoxy, C1 -C2 -haloalkyl, C1 -C2 -haloalkoxy or cyano, more Y, in position 4, C1 -C4 -alkyl, further Z, is hydrogen, the added W, hydrogen, fluorine, chlorine, bromine, C1 -C4 -alkyl or C1 -C4 -alkoxy, added by X, chlorine, bromine, iodine, C1 -C4 -alkyl, C1 -C4 -alkoxy, C1 -C2 -haloalkylinclude, C1 -C2 -haloalkoxy or cyano, where the addition Y, in position 4, a hydrogen, chlorine, bromine, iodine, C1 -C4 -alkyl, C1 -C2 -haloalkyl or C1 -C2 -haloalkoxy, Z is added, in the 3 position or 5 position, a fluorine, chlorine, bromine, iodine, C1 -C4 -alkyl, C1 -C2 -haloalkylinclude, C1 -C4 -alkoxy or C1 -C2 -haloalkoxy, the group CKE represents one of the following 1  [Ais hydrogen, fluorine or chlorine and optionally in each case substituted by from 1 in 3 C1 -C6 -alkyl, C1 -C4 -alkOXy -C1 -C2 -alkyl, optionally C1 -C2 -or alkyl C1 -C2 -alkoxy which is substituted by a single or double substituted C3 -C6 -cycloalkyl, or (formula (I - 3), (I - 4), (I - 6) and (I - 7) except in the case of the compounds is a) in the case where in each case fluorine, chlorine, bromine, C1 -C4 -alkyl, C1 -C2 -haloalkylinclude, C1 -C4 -alkoxy, C1 -C2 -haloalkoxy, cyano or nitro-substituted phenyl or mono - or di-benzyl DIALYTIKAc, B hydrogen, C1 -C4 -or alkyl C1 -C2 -alkOXy -C1 -C2 -alkyl, A or, and the carbon atom to which they are attached B is, Q3 condition is hydrogen or methyl, one of the two rings Otis 1 optionally replaced by oxygen or sulfur, optionally C1 -C6 -alkyl, C1 -C4 -alkOXy -C1 -C2 -alkyl, trifluoromethyl, C1 -C6 -alkoxy, C1 -C3 -alkOXy -C1 -C3 -alkoxy or C3 -C6 -Cycloalkyl methoxy which is substituted by a single unsubstituted or saturated or unsaturated double C3 -C7 -cycloalkyl, A or, wherein the carbon atom to which they bond and B is, Q3 condition is hydrogen or methyl, Alkylene thiol group, or a Alkylenedioxy Lumpur group, or optionally substituted methyl or ethyl, in the case where 1 is one or two not directly adjacent oxygen or sulfur atom and the two 2, together with the carbon atom bound to 6 - membered ring to form a further 5 or which is substituted by a group Alkylenediyl C5 -C6 -cycloalkyl, A or, wherein the carbon atom to which they bond and B is, Q3 condition is hydrogen or methyl, in each case optionally substituted C3 -C6 -cycloalkyl or C5 -C6 -cycloalkyl, 2 is two substituents, together with the carbon atoms to which they are attached, in either case optionally C1 -C2 -alkyl or C1 -C2 -alkoxy substituted C2 -C4 -alkanediyl, C2 -C4 -Butadiene-diyl and alkenediyl or, D is hydrogen, in each case optionally substituted by 3 fluoro 1 from C1 -C6 -alkyl, C3 -C6 -alkenyl, C1 -C4 -alkOXy -C2 -C3 -alkyl, optionally C1 -C4 -alkyl, C1 -C4 -alkoxy or C1 -C2 -haloalkyl substituted double or mono-substituted, 1 optionally one methylene group is replaced with an oxygen C3 -C6 -cycloalkyl, or (formula (I - 1) except in the case of compounds where the) in each case optionally fluorine, chlorine, bromine, C1 -C4 -alkyl, C1 -C4 -haloalkyl, C1 -C4 -alkoxy or C1 -C4 -aminopropyladenine or mono-substituted haloalkoxy or phenyl and substituted pyridyl, or A D and together, a carbonyl group and a methylene group is one of 1 (formula (I - 1) except in the case of compounds of a), oxygen or sulfur and optionally be substituted with a single or double substituted with a substituted C3 -C5 -is alkanediyl, suitable substituents include C1 -C2 -alkyl or C1 -C2 -alkoxy, or is A D and (in the case of the compounds of the formula (I - 1)), together with the carbon atoms to which they are attached, a group AD - 1 one of 1 and AD - 10 from,  Aand Q1 is in accordance with, in either case optionally C1 -C2 -alkyl or C1 -C2 -alkOXy of the same or different selected from the substituent group is substituted by a single or double substituted C3 -C4 -is alkanediyl, or D and Q1 together C3 -C4 -is alkanediyl, or Q1 is hydrogen, C1 -C4 -alkyl, C1 -C4 -alkOXy -C1 -C2 -alkyl, or optionally 1 one methylene group is optionally substituted oxygen and substituted by a methyl or methoxy C3 -C6 -cycloalkyl, Q2 is hydrogen, methyl or ethyl, Q4 、Q5 and Q6 independently of one another are hydrogen or C1 -C3 -alkyl, Q3 is hydrogen and, C1 -C4 -alkyl, or optionally substituted methyl or methoxy which is substituted by a single dual C3 -C6 -cycloalkyl, or Q1 and Q2 is hydrogen, C1 -C4 -alkyl, C1 -C4 -alkOXy -C1 -C2 -alkyl, or optionally 1 one methylene group is substituted with a methyl or methoxy if substituted by C3 -C6 -cycloalkyl, Q3 and Q4 may, together with the carbon to which they are bonded, is a hydrogen or a methyl A condition, and optionally one oxygen or sulfur at the 1 - membered heterocycle which is optionally substituted C1 -C2 -or alkyl C1 -C2 -alkoxy substituted saturated C5 -C6 ring, g (a) hydrogen, or one of the following radicals in 1, in particular (a), (b) or (c) and,  E1 is one metal ion equivalent or an ammonium ion, and L denotes oxygen or sulfur, M denotes oxygen or sulfur and, R1 is, in each case optionally fluorine or chlorine substituted 1 3 from C1 -C8 -alkyl, C2 -C18 -alkenyl, C1 -C4 -alkOXy -C1 -C2 -alkyl, C1 -C4 -alkylthio -C1 -C2 -alkyl, or optionally 2 one or two not directly adjacent ring members of 1 is optionally substituted with oxygen and a fluorine, chlorine, C1 -C2 -or alkyl C1 -C2 -alkoxy mono-substituted or substituted double C3 -C6 -cycloalkyl which, in the case of fluorine, chlorine, bromine, cyano, nitro, C1 -C4 -alkyl, C1 -C4 -alkoxy, C1 -C2 -or haloalkyl C1 -C2 -haloalkoxy-substituted phenyl or mono-substituted and double, R2 is, in each case optionally fluorine-substituted 1 3 from C1 -C8 -alkyl, C2 -C8 -alkenyl or C1 -C4 -alkOXy -C2 -C4 -alkyl, optionally C1 -C2 -or alkyl C1 -C2 -substituted 1 alkoxy C3 -C6 -cycloalkyl which, when in either of the cases or by a fluorine, chlorine, bromine, cyano, nitro, C1 -C4 -alkyl, C1 -C3 -alkoxy, trifluoromethyl or trifluoromethoxy-substituted benzyl or mono-substituted phenyl or double and, R3 is, optionally fluorine-substituted 1 3 times a C1 -C6 -alkyl, or optionally fluorine, chlorine, bromine, C1 -C4 -alkyl, C1 -C4 -alkoxy, trifluoromethyl, trifluoromethoxy, cyano or nitro-substituted phenyl and 1, R4 is, C1 -C6 -alkyl, C1 -C6 -alkoxy, C1 -C6 --alkylamino, di - (C1 -C6 -alkyl) amino, C1 -C6 -alkylthio, C3 -C4 -alkenylthio, C3 -C6 -and cycloalkylthio, or in any case in the case of fluorine, chlorine, bromine, nitro, cyano, C1 -C3 -alkoxy, C1 -C3 -haloalkoxy, C1 -C3 -alkylthio, C1 -C3 -haloalkthio, C1 -C3 -alkyl, or trifluoromethyl phenylthio substituted with 1, phenoxy or phenyl, R5 is C1 -C6 -alkoxy or C1 -C6 -and alkylthio, R6 is, hydrogen, C1 -C6 -alkyl, C3 -C6 -cycloalkyl, C1 -C6 -alkoxy, C3 -C6 -alkenyl, C1 -C6 -alkOXy -C1 -C4 -alkyl, optionally fluorine, chlorine, bromine, trifluoromethyl, C1 -C4 -or alkyl C1 -C4 -1 alkoxy-substituted phenyl, or optionally fluorine, chlorine, bromine, C1 -C4 -alkyl, trifluoromethyl or C1 -C4 -1 alkoxy-substituted benzyl, R7 is C1 -C6 -alkyl, C3 -C6 -alkenyl or C1 -C6 -alkOXy -C1 -C4 -alkyl, R6 and R7 is in accordance with, and optionally one methylene group is an oxygen or sulfur 1 is substituted by methyl or ethyl when substituted C4 -C5 -alkylene group. ] Wherein the, composition according to claim 1.   5. Wherein the active ingredient is selected from the following list with, a composition according to claim 1.           6. Wherein the weight % of the active ingredient is contained in an amount 0.5% by weight is from 50 to, one or more of claims 5 to claim 1 from the composition.  7. 0.5 An ammonium salt or phosphonium salt in the amount of said 80mmol/l from, one or more of claims 6 to claim 1 from the composition.  8. D is nitrogen characterized in that, one of the claim 1 from the composition of claim 7.  9. R30 bicarbonate ions, borate ions, fluoride ions, and bromide ions, iodide ions, chloride ions, hydrogen phosphate ion, dihydrogen phosphate ion, hydrogen sulfate ion, tartrate ion, sulfate ion, nitrate ion, thiosulfate ion, thiocyanate ion, formate ion, lactic acid ion, acetate ion, propionate ion, the ion-butyric acid, pentanoic acid ions, citrate ions or an oxalic acid ion and, the composition according to claim 8.  10. R30 is carbonate, pentaborate ions, sulfite ions, acid ions, hydrogen ions and oxalic acid, citric acid ion, a tetrafluoroborate ion or a Methyl ion sulfate characterized in that, the composition according to claim 8.  11. R30 lactic acid ion, sulfate ion, nitrate ion, thiosulfate ion, thiocyanate ion, citrate ion, formate ion or oxalate ion and characterized in that, the composition according to claim 8.  12. R30 is thiocyanate ion, dihydrogen phosphate ion, hydrogen ion or a sulfate ion in the phosphate can be one characterized in that, the composition according to claim 8.  13. 1 At least one osmotic agent and characterized in that it comprises, in any one of claims 12 to claim 1 from the composition.  14. Wherein the osmolality agent, fatty alcohol alkoxylate of the following formula (III) (- AO) R FixedDocument_add O-v -R' (III) [xLxWx, having a carbon number of from 4 20 R straight-chain or branched alkyl, R ' is hydrogen, methyl, ethyl, n- propyl, isopropyl, n- butyl, isobutyl, tert - butyl, n- pentyl or n- hexyl, AO is ethylene oxide groups, propylene oxide groups, butylene oxide and of propylene oxide groups and an ethylene oxide group or a butylene group and the ethylene oxide groups or a mixture of organic and and, 2 is 30 v is a number from. ] A, or a mineral or vegetable or mineral oils or vegetable oils and esters, a composition according to claim 13.  15. Wherein the penetrant is an ester of a vegetable oil characterized in that, the composition according to claim 13.  16. Wherein the penetrant is rapeseed oil methyl esters and characterized in that, the composition according to claim 13.  17. Wherein the amount of penetrant 95% 1% by weight from the weight and characterized in that, in any one of claims 16 to claim 13 from the composition.  18. Claim 1 from one or more of claims 17 to composition, the effective amount of the active ingredient contained in the insect and/or spider mites or their habitat an amount acts, said spider mites or insects and/or the habitat or applied directly to said diluting, and/or a method of combating a parasitic spider mites.  19. (I) according to claim 2 Ketoenols Eqs polyvinyloenechloride phenyl substituted cyclic crop protection active ingredient that comprises a method of increasing the activity of the material, the material immediately sprayed (spray), a salt of formula (II) according to claim 1 prepared using said, method.  20. Wherein the spray, characterized in that the osmotic agent and used to prepare the, method according to claim 18.  21. (II) the salt of the formula, 80mmol 0.5 is present in a final concentration from said, method according to claim 19 or 20.  22. Wherein the osmolality agent, in a final concentration of from 0.1 to 10 g/l and is present in the, method according to claim 20.  23. 10 g/l 0.1 From the penetrant is present in final concentration, to a final concentration of salt of formula (II) from 0.5 to 80mmol and is present in the, method according to claim 20.  24. A phenyl-substituted cyclic Ketoenols as crop protection active ingredient for enhancing the activity of the target material, wherein the salt of according to claim 1 use (II), can be Dispersement stockroom (spray) crop protection material the salt used during the preparation and use.  25. Wherein the crop protection material can be Dispersem(...)
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(JP2009519278) LEGAL DETAILS FOR JP2009519278  Actual or expected expiration date=2012-09-25    Legal state=DEAD    Status=REVOKED     Event publication date=2006-12-11  Event code=JP/APP  Event indicator=Pos  Event type=Examination events  Application details  Application country=JP JP2008544847  Application date=2006-12-11  Standardized application number=2008JP-0544847     Event publication date=2009-05-14  Event code=JP/A  Event indicator=Pos  Event type=Examination events  Published application  Publication country=JP  Publication number=JP2009519278  Publication stage Code=A  Publication date=2009-05-14  Standardized publication number=JP2009519278     Event publication date=2009-12-11  Event code=JP/A621  Event indicator=Pos  Event type=Examination events  Written request for application examination  Effective date of the event=2009-12-10  JAPANESE INTERMEDIATE CODE: A621     Event publication date=2012-02-02  Event code=JP/A977  Event type=Examination events  Report on retrieval  Effective date of the event=2012-02-02  JAPANESE INTERMEDIATE CODE: A971007     Event publication date=2012-02-08  Event code=JP/A131  Event indicator=Neg  Event type=Examination events  Notification of reasons for refusal  Effective date of the event=2012-02-07  JAPANESE INTERMEDIATE CODE: A131     Event publication date=2012-05-03  Event code=JP/A601  Event type=Examination events  Written request for extension of term  Effective date of the event=2012-05-02  JAPANESE INTERMEDIATE CODE: A601     Event publication date=2012-05-16  Event code=JP/A602  Event type=Examination events  Written permission of extension of term  Effective date of the event=2012-05-15  JAPANESE INTERMEDIATE CODE: A602     Event publication date=2012-06-01  Event code=JP/A521  Event type=Restitution or restoration  Written amendment  Effective date of the event=2012-05-31  JAPANESE INTERMEDIATE CODE: A523     Event publication date=2012-09-26  Event code=JP/A02  Event indicator=Neg  Event type=Event indicating Not In Force  Decision of refusal  Effective date of the event=2012-09-25  JAPANESE INTERMEDIATE CODE: A02
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