Fungicide, insecticide and miticide relations approach to its production, agents containing them and method for use thereof 机翻标题: 暂无翻译,请尝试点击翻译按钮。

源语言标题
(DK-174963) Fungicide, insekticide og miticide forbindelser, fremgangsmåde til fremstilling deraf, midler indeholdende dem og fremgangsmåde til anvendelse heraf
公开号/公开日
DK584789 D0 1989-11-21 [DK8905847] DK584789 A 1990-05-22 [DK8905847] DK174963 B1 2004-04-05 [DK-174963] / 1989-11-21 1990-05-22 2004-04-05
申请号/申请日
1989DK-0005847 / 1989-11-21
发明人
FRAINE PAUL JOHN DE; MARTIN ANNE
申请人
SYNGENTA
主分类号
IPC分类号
A01N-037/36;A01N-037/38;A01N-037/40;A01N-037/50;A01N-041/02;A01N-041/10;A01N-043/08;A01N-043/10;A01N-043/16;A01N-043/18;A01N-043/36;A01N-043/40;A01N-043/42;A01N-043/54;A01N-043/58;A01N-043/60;A01N-043/653;A01N-043/707;A01N-043/74;A01N-043/76;A01N-043/78;A01N-043/80;A01N-047/34;C07C-249/04;C07C-251/40;C07C-251/60;C07C-253/30;C07C-255/62;C07C-255/64;C07C-317/28;C07C-317/32;C07C-323/24;C07C-327/58;C07D-207/32;C07D-207/335;C07D-213/53;C07D-213/55;C07D-213/57;C07D-213/61;C07D-213/84;C07D-213/85;C07D-213/89;C07D-215/12;C07D-215/18;C07D-215/20;C07D-215/48;C07D-215/50;C07D-237/08;C07D-239/26;C07D-239/28;C07D-239/30;C07D-239/34;C07D-239/52;C07D-239/74;C07D-241/12;C07D-241/16;C07D-241/18;C07D-241/24;C07D-241/42;C07D-241/52;C07D-249/08;C07D-249/12;C07D-253/06;C07D-261/10;C07D-261/12;C07D-263/56;C07D-277/28;C07D-277/32;C07D-277/58;C07D-307/14;C07D-307/52;C07D-307/66;C07D-311/68;C07D-333/22;C07D-333/28
摘要
(DK-174963)
Compounds having the formula (I) : <CHEM> and stereoisomers thereof, wherein A is hydrogen, halo, hydroxy, C1-4 alkyl, C1-4 alkoxy, C1-4 haloalkyl, C1-4 haloalkoxy, C1-4 alkylcarbonyl, C1-4 alkoxycarbonyl, phenoxy, nitro or cyano; R<1> and R<2>, which may be the same or different, are hydrogen, optionally substituted alkyl, optionally substituted cycloalkyl, optionally substituted heterocyclylalkyl, optionally substituted cycloalkylalkyl, optionally substituted aralkyl, optionally substituted heteroarylalkyl, optionally substituted aryloxyalkyl, optionally substituted heteroaryloxyalkyl, optionally substituted alkenyl, optionally substituted alkynyl, optionally substituted alkoxy, optionally substituted aryl, optionally substituted heteroaryl, optionally substituted aryloxy, optionally substituted heteroaryloxy, nitro, halo, cyano, -NR<3>R<4>, -CO2R<3>, -CONR<3>R<4>, -COR<3>, -S(O)nR<3> wherein n is 0, 1 or 2, (CH2)mPO(OR<3>)2 wherein m is O or 1, or R<1> and R<2> join to form a carbocyclic or heterocyclic ring system; and R<3> and R<4>, which may be the same or different, are hydrogen, optionally substituted alkyl, optionally substituted aralkyl, optionally substituted alkenyl, optionally substituted alkynyl, optionally substituted aryl or optionally substituted heteroaryl. 
The compounds are useful as fungicides, insecticides and miticides.
 (From EP0370629 A1)
机翻摘要
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地址
代理人
代理机构
优先权号
1988GB-0027149 1988-11-21 1989GB-0005383 1989-03-09
主权利要求
(DK-174963)
1. Compounds of the formula (I):
R 2
C = N / 0
CH
RC
CH 3 0 2 0 CH.00H 3
And stereoisomers thereof, where A is hydrogen, halogen, hydroxy, C 1-C 4 alkoxy, C 1-C 4-halogenallcyl, C 1-C 4-halogenalkoxy, C,-C 4-alkylcarbonyl, CI-C 4 alkoxycarbonyl, phenoxy, nitro or cyano; R 'and R 2, which may be similar or different is hydrogen, C 1-C 6-alkyl, C 3-C 6-cycloalkyl, hetero cyclyl-C 1-C 4-allcyl, C 3-C 6-cycloalkyl -C 1-C 4 alkyl, aryloxy-C 1-C 4-alkyl, heteroaryloxyalkyl, C 2-C 6-alkenyl, C2-C6alkynyl, C 1-C 6-alkoxy, aryl, heteroaryl, aryloxy, heteroaryloxy, nitro, halogen, cyano,
-NR 3 R 4,-CO 2 R 3,-CONR 3 R 4,-COR 3,-S (0), R 3 or (CH2), P0 (0R 3) 2, where n is 0, 1 or 2, m is 0 or 1 and R 3 and R 4 which are similar or different is hydrogen, C 1-C 6-alkyl, aryl C 1 - C 6 - alkyl, C 2-C 6-alkenyl, C 2 -C 6-alkynyl, aryl or heteroaryl, or R 'and R 2 are joined to form a Cyclopentyl, cyclohexyl or cyclohexadienonylgruppe which may involve a condensed benzene ring and / or a methylsubstituent, or R' and R 2 are united the formation of a tetrahydropyranylringsystem; with any of the above alkyldele possibly being substituted with halogen, hydroxy or C,-C 4-alkoxy, since any of the aforementioned alkenyl or alkynyldele possibly being substituted with phenyl, and since any of the above aryldele as phenyl or naphthyl, and any of the aforementioned heterocyclyl or heteroaryldele chosen among the group consisting of thienyl, furyl, pyrrolyl, triazolyl, thiazolyl, pyridyl, pyrimidinyl, pyrazinyl, pyridazinyl, triazinyl, quinolinyl and QUINOXALINYL and N-oxides thereof, may be substituted with one or more of halogen, hydroxy, mercapto, C 1-C 4-alkyl, C 2-C 4-alkenyl, C 2-C 4-alkynyl, C, -- C 4 - alkoxy, C 2 - C 4 - alkenyloxy,
C 2-C 4-alkynyloxy, halogen-C 1-C 4-alkyl, halogen-C 1-C 4-alkoxy, C,-C 4-alkylthio, hydroxy-C 1-C 4-alkyl, CL-C 4 -alkoxy-C 1-C 4-alkyl, C 3-C 6-cycloalkyl, C 3-C 6-cycloalkyl-C 1-C 4-alkyl, phenyl, pyridyl, pyrimidinyl, phenoxy, pyridyloxy, pyrimidinyloxy, phenyl-C 1-C 4-alkyl where alkyldelen possibly being substituted with hydroxy, pyridyl or pyrimidinyl-C 1-C 4 alkyl, phenyl-C 2-C 4-alkenyl, pyridyl or pyrimidinyl-C 2-C 4-alkenyl, phenyl-C 1-C4alkoxy, pyridyl or pyrimidinyl-C 1-C 4-alkoxy, phenoxy-C 1-C 4-alkyl, pyridyloxy or pyrimidinyloxy-C 1-C 4-alkyl, C 1-C 4-alkanoyloxy, benzoyloxy, cyano, thiocyanato, nitro,
-NR 'R ",-NHCOR',-NHCONR 'R',-CONR 'R"-Coors',-OSO 2 R',-SO 2 R ',-COR',
-CR = NR "or-N = CR'R" where R 'and R "independently is hydrogen, CI-C4
1. 0 alkyl, C 1-C 4-alkoxy, C 1-C 4-alkylthio, C 3-C 6-cycloalkyl, C 3-C 6-cycloalkyl-C 1-C 4-alkyl, phenyl or benzyl, the phenyl - and benzylgrupperne possibly being substituted with halogen, C 1-C 4-alkyl or C 1-C 4-alkoxy, and any of the above phenyl, pyridyl or pyrimidinylsubstituenter in itself may be substituted with one or more of halogen, hydroxy, mercapto, C 1-C 4-alkyl, C 2-C 4-alkenyl, C 2-C 4-alkynyl, C 1-C4-alkoxy, C 2-C 4-alkenyloxy, C2-C4 alicYnYloxy, halogen-C1-C4 alkyl, halogen-C 1-C 4 alkoxy, C 1-C 4-alkylthio, hydroxy-C 1-C 4-alkyl, C 3-C 6-cycloalkyl, C 3-C 6 -- cycloalkyl-C I-C 4-allcyl, alkanoyloxy, benzoyloxy, cyano, thiocyanato, nitro,
-NR 'R ",-NHCOR',-NHCONR 'R',-CONR 'R"-Coors',-SO 2 R',-OSO 2 R ',-COR',
-CR '= NR "or-N = CR'R" where R' and R "have the above meanings.
2. Connection according to claim 1, where A is hydrogen, halogen, hydroxy, methyl, methoxy, trifluoromethyl, trifluorrnethoxy, C 1-C 2-alkylcarbonyl, C 1-C 2-alkoxycarbonyl, phenoxy, nitro or cyano; and R 'is C 1-C 4-alkyl, halogen-C,-C 4-alkyl, C 1-C 4-alkoxy, halogenated CI-C 4-alkoxy, C 1-C 4 allcylearbonyl, C 1-C 4-alkoxycarbonyl, cyano, phenyl-C I-C 4-alkyl, phenyl or an aromatic hetero ring chosen from the group consisting of thienyl, furyl, pyrrolyl, triazolyl, thiazolyl, pyridyl, pyrimidinyl, pyrazinyl, pyridazinyl, triazinyl, quinolinyl and QUINOXALINYL; with phenyl-and hetero-aromatic part of any of the above may be substituted with one or more of halogen, hydroxy, C1-C4a lkyl, h al anda-C 1-C 4-allcyl, C 1-C 4-alkox y, hal ogen-C 1-C 4-allwxy, C 1-C 4-carbon yl allcyl, C 1-C 4-alkoxycarbonyl, nitro, cyano, phenyl, phenoxy, benzyl or benzyloxy; and R 2 is hydrogen, halogen, C,-C 4 allcyl, halogen-C,-C 4-alkyl, C 1-C 4-allcylcarbonyl, CI-C c alkoxycarbonyl, cyano or phenyl.
3. Connection according to claim 1, characterized in that A is hydrogen or halogen, R 1 is C1-C4 alkyl, benzyl, C1-C4alkylcarbonyl, C1-C4 alkoxycarbonyl, cyano, phenyl, thienyl, triazolyl, thiazolyl, pyridyl, pyrimidinyl, pyrazinyl, pyridazinyl, triazinyl, quinolinyl or QUINOXALINYL since the aromatic or heteroaromatic molecule of any of the foregoing may be substituted with one or more of halogen, C1-C4 alkyl, trifluoromethyl, C1-C4 alkoxy, trifluoromethoxy, nitro, cyano, phenyl or benzyloxy, and R 2 is hydrogen, C1-C4 alkyl, C1-C4 alkylcarbonyl, C1-C4 alkoxycarbonyl, cyano or phenyl, or R 1 and R 2 are linked to the formation of a cyklopentyl or cyklohexylring which possibly a condensed benzene ring..
4. Method for making a connection according to claim 1, characterized by a reaction of the formula (II):
CH 2 X
'CH.00H 3
CH 0
3. 2
Where A is the claim of 1 meaning and X is an off-service group, with a salt of an oxime of the formula (III):
R 2
HO. N = C
R 1
Where R 1 and R 2 have the claim of 1 meaning under alkaline conditions.
5. Method for making a connection according to claim 1, characterized by
(a) the processing of the formula (IX):
R2. N
C = N
(IX)
RI
CH 3 0 2 C / / CHOR 5
With the formula CH3L; or
(b) elimination of the elements of methanol from a connection with formula (IV):
R 2 0
'.,. / N
(IV)
C = N CH
R 1, CH
CH 3 0 2 C CH (0Ch 3) 2
Under acidic or alkaline conditions; or
(c) treatment of a ketoester of formula (XI):
IA
R 2
C = t4 / / o CH2
(XI)
R 1 W
CH 3 0 2 C 0
With a methoxymethyleneringsreagens; where A, R 1 and R 2 have the claim of 1 meaning, L is an off-service group, and R 5 is a metal atom.
6. Fungicides, insecticides or miticidt means comprehensive as active ingredient a connection according to claim 1 and a fungicide, insecticide or miticidt acceptable carrier or diluent therefore.
7. Approach to combat fungi, a characteristic of that in a plant seed, a plant or grow instead of one plant is applied to a fungicidal effective amount of a connection according to claims 1
8. Tion approach to kill or control insects or mites, characterized by, by administering to the insect or mite or its habitat of an insecticide or miticidt effective quantity of a connection according to claim
法律状态
(DK-174963)
LEGAL DETAILS FOR DK584789

Actual or expected expiration date=2009-11-21   
Legal state=DEAD   
Status=EXPIRED 



Event publication date=1989-11-21 
Event code=DK/APP 
Event indicator=Pos 
Event type=Examination events 
Application details

Application country=DK DK584789 
Application date=1989-11-21 
Standardized application number=1989DK-0005847 



Event publication date=1989-11-21 
Event code=DK/D0 
Event indicator=Pos 
Event type=Examination events 
Patent application filed

Publication country=DK 
Publication number=DK584789 
Publication stage Code=D0 
Publication date=1989-11-21 
Standardized publication number=DK8905847 



Event publication date=1990-05-22 
Event code=DK/A 
Event type=Examination events 
Published application

Publication country=DK 
Publication number=DK584789 
Publication stage Code=A 
Publication date=1990-05-22 
Standardized publication number=DK8905847 



Event publication date=2004-04-05 
Event code=DK/B1 
Event indicator=Pos 
Event type=Event indicating In Force 
Patent granted (law 1993)

Publication country=DK 
Publication number=DK174963 
Publication stage Code=B1 
Publication date=2004-04-05 
Standardized publication number=DK-174963 



Event publication date=2009-12-07 
Event code=DK/PUP 
Event indicator=Neg 
Event type=Event indicating Not In Force 
Patent expired
Patentet udloebet
专利类型码
D0 A B1
国别省市代码
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