AGENTS SUPPORTING THE GROWTH OF THE PLANTS AND PHYTOPROTECTEURS CONTAINING OXIMETHERS AND OXIMESTERS 机翻标题: 暂无翻译,请尝试点击翻译按钮。

公开号/公开日
FR2387945 A1 1978-11-17 [FR2387945]FR2387945 B1 1981-11-27 [FR2387945] / 1978-11-171981-11-27
申请号/申请日
1978FR-0005716 / 1978-02-28
发明人
;
申请人
CIBA GEIGY;
主分类号
IPC分类号
A01N-025/32A01N-035/08A01N-035/10A01N-037/26A01N-037/34A01N-037/36A01N-037/44A01N-037/50A01N-037/52A01N-041/04A01N-041/06A01N-043/06A01N-043/08A01N-051/00C07C-067/00C07C-251/32C07C-259/02C07C-301/00C07C-303/30C07C-303/40C07C-309/63C07
摘要
(FR2387945) Novel compositions which are suitable in agriculture for crop protection contain, together with suitable carrier material, at least one active ingredient from the series comprising oxime ethers, oxime esters or oxime carbamates, the active substance having the formula I <IMAGE> in which the substituents are as defined in Claim 1.  The compositions can be used advantageously for crop protection.  Such compositions have antidote properties for protecting plants against aggressive agrochemicals and, besides, have other plant-regulating and pesticidal properties.  (From GB1601752 A)
机翻摘要
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地址
代理人
代理机构
;
优先权号
1977CH-0002606 1977-03-02
主权利要求
(FR2387945) REVEKDICATIOUS - 1. A compound of formula Ar - C - N-0-Q (IY where the substituents have them - following significances: Ar represents - a radical phenyl of formula 1. 0 - a radical has or p-naphtyl, or - a heterocyclic core of formula R 5 X - ONE, -10 2, a halogen, a alcanoyle infarieUr L unrac.?.calester, of carboxylic acid, a hydrogen, a radical amide of acidecarboxylic, lower alkyl, - a lower alkyl, being able with right or ramified chain, or stopped by heteroatoms, or to be substituted by halogens, - a lower alcenyle or a halogen-alcenyle, - a lower alcynyle, - a cycloalcoyle in 0 3 with O 7 possibly substituted by halogens, lower cyanalcoyle, - an ester group of lower acid alcanecarboxylic, - an amide group of lower acid alcanecarboxylic, - a radical aliphatic acyle, - a radical acyle araliphatic, cycloaliphatic, aromatic possibly substituted or heterocyclic, - an acid alcoylsulfonic or - F a radical amide of sulfonic acid, = - a hydrogen, a halogen, a lower alkyl, a lower alcoxy or a radical phenoxy in para position possibly substituted to the maximum twice by a halogen, ONE, NO 2 ' CF R 2 one and R 3 = independently one of other U hydrogen, a halogen, 1T0 2, a lower alkyl, an halogen-alkyl, a lower alcoxy, R 4 and R 5 = - independently one of the other a hydrogen, a halogen, NO 2 a lower alkyl, Z = an oxygen or a sulfur, with the precision that if Ar represents a radical nonsubstitue phenyl and Q the radical - CH 2 CN, X - NO 2 represents, a halogen, a lower alcanoyle, a radical ester of acid - carboxylicue, a hydrogen, a friendly radical of carboxylic acid or a lower alkyl. 2. Compounds according to claim 1 where Macaw the significance given above and or the others substituents has the following meanings: X = - a cyano, a nitro, a halogen, a lower alcanoyle, a radical ester of carboxylic acid of a lower aliphatic alcohol, a radical amide of carboxylic acid or - a lower alkyl, Q - a lower alkyl, with right chain D 6u ramified, drunk which can be stopped by a heteroatom or substituted by a halogen, - a lower alcenyle, - a lower alcenyle, - a lower cyanoalcoyle, - an ester group of lower acid alcanecarboxylic, - an amide group of lower acid alcanecarboxylic, - a radical aliphatic acyle inff, laugher, - a radical cycloaliphatic acyle having from 4 to 6 carbon atoms, or - a radical amide of sulfonic acid not-substituted or ponoou disubstituted by a lower aliphatic radical, R = a hydrogen or a radical phenoxy in para position, R 2 and R 3 - independently one of the other a hydrogen, a halogen or a lower alkyl, R.et R 5 -. a hydrogen Z = an oxygen or a sulfur. 3. Compounds according to claim 1 of formula 4. C - X (Ia) where the substituents have the following meaning: X = - a cyano, a nitro, a halogen, a lower alcanoyle, a radical ester of acid carboxylicue of a lower aliphatic alcohol, a radical amide of carboxylic acid or a lower alkyl, Q = - a chain alkyl inf e right rieure stopped by an oxygen, - a lower alcenyle, - a lower alcynyle, - a cyanalcoyle infrior, - an ester group of acid alcanecarboxylicue infrior, “c0 - an amide group of acid alcanecarboxylicue infrior, - a radical acyle aliphatioue infrior, - a radical amide of disubstituted acid sulfoniciun not-substituted or monoou by a radical aliphaticue infirior, R I = - a hydrogen, 5. R. = - a hydrogen. a halogen, a lower alkyl or a alcoxy inr: laugher, R, = - a H: drogene, a halorYene, an alkyl infrior or a lower alcoxy. 4. Compounds according to claim 3 where subs- -30 tituants of formula have it if: 7nificatien following: X = - un' cyano, a nitro, a halation - ene, a alcanoy1, inrrior, a radical ester of acid carboxyli:: EU of a alcanol inf (; laugher, a radical amide of acid carb=ylicue, Q. = a alcynyle infrior, - 55. A cyanalcoyle infrior, - an ester group of lower acid alcanecarboxylicue, - a grouu alcanecarbœr: Lower Tlicue, R 1 = - a hydrogen, R = - a hydrogen, a halogen or a lower alkyl, R 3 = - a hydrogen, a halogen or a lower alkyl. - Compounds according to the claim 4 where the substituents of formula have it the following significance: 5. X = - a cyano, a chlorine, a bromine, an acetyl, a propionyl -000CH 3 ' - COGC-H - COCO-NHCH - IDIOT (CH) E 5 ' CONE 2,3,3 2 ' Q = a propynyle or a butynyle, - a cyanomethyle or cyanethyle, - a methoxycarbonylmethyle, a ethoxycarbonylmethyle, a methoxycarbonylethyle, a ethoxycarbonylethyle, - a radical acetamide or propionamide possibly substituted on the nitrogen atom by one or two lower aliphatic groups, R 1 = - a hydrogen, R 2 = a hydrogen, a halogen or a methyl, R, D = - a hydrogen, a halogen or a methyl. 6. The compounds according to claim 5 where X is a cyano group and where Q, R 1, R 2 and R 3 have the meaning mentioned. 7. Compounds according to claim 1 of formula II R 1 - 04C - N-0 (CH) - R N 10 R 9 where 5 0 R 1, R 2 and R 3 represent independently one of the other a hydrogen, a halogen, NO 2, a lower alkyl, a halogenealcoyle, a lower alcoxy, and X = - CN, NO 2, a halogen, the acetyl group, a radical ester of carboxylic acid of an alcohol aliphatique.infeior or a radical amide of carboxylic acid, however that N is worth 1.2 or 3, R O is a hydrogen or a lower alkyl, R 10 - CONE 2 ' - CO-NH ((radical aliphatic inferior) I -00-NHcycloalcoyle, - CONH- (C 6:5 m) (halogenous, lower alkyl) m or - CN, and m accounts for an integer, 0,1,2 or 3. 8. Compounds according to claim 7 of formula III . X' lt N-0-0H--R 2 where 10 X' represents it, NG 2 a chlorine, an acetyl, a alcoxycarbo' - L lower nyle, a allyloxycarbonyle, a carbamoyle or an di-alkyl inferior-carbamoyle, and R 10 represents it, 00-2, - lower Co-TE-alkyl or - CONE (C 6:5 - m) (Cl, Br, CH 3) m and 15. M is an integer, 0.1 or 2. 9. The a-cyanobenzylidene-amino-oxacetamide of formula C-GN N-0-GE -00-7H 2 2 10. A method of preparation of composed of formula I of the claim 1 by etherification or acylation of an oxime of formula V 5. Ar - C - X (V) N-OH or of its salt with a halide of Halg-Q formula, where Ar, X and Q have the meaning given for formula I and where Halg represents a halogen, preferably chlorine or bromine. 3. C it - Proc (: die according to claim IO of preparation of composed according to one of claims 4 to 9 by etherification of an alkaline salt or of ammonium of formula V with a Halg-Q halide where Ar, X and Q correspond has one of the definitions given in one of the claims 4 9 and where Hal represents a halogen, preferably chlorine or bromine. 12. An agent supporting the growth of the plants and also phytoprotector, which contains like substance activates 0,01-90 in weight of a compound of formula I of claim 1, with dei suitable supports and/or of the surface-active additives. 13. An agent according to claim 12, where the active substance corresponds to a compound according to claim 2. 14. An agent according to claim 12, where the active substance corresponds to a compound selon.la claim 3. 15. - An agent according to claim 12, where the active substance corresponds to Comtose according to claim 4. 16. An agent, according to claim 12, where the subs- 10 scolds active corresponds to a compound according to claim 5. 17. An agent according to claim 12, where the active substance corresponds to a compound according to claim 6. 18. An agent according to claim 12, where the subs- scolds active corresponds to a compound according to claim 7. 15. 19 - An agent according to claim 12, where the subs- scolds active corresponds to a compound according to claim 8. - An agent according to claim 12, where the subs- scolds active corresponds to a compound according to claim 9. 21. A process of favorisation of the growth of the 20 plants by treatment of the plants or of parts of them or their nutritive grounds with a compound of formula I according to one of claims 1 to 9. 22. A process according to claim 21, where the pregermees seeds or seeds are treated. 23. A process according to the claim 22 allowing to treat the sorghum. 24. A process according to the claim 22 allowing to treat rice. 25. A process according to the claim 22 allowing 0 to treat the mals. 26. A process according to the claim 22 allowing to treat wheat, rye, the barley or the oats. 27. - A process according to the claim 22 Allowing to treat soya. 28. A process according to the claim 22 allowing to treat cotton. 29. A process according to the claim 22 allowing to treat sugar beet. - A process of protection of the crop plants of the undesirable action of the chemical products employed in agriculture by application of one compoae according to one of claims 1 to 9 on the plants, its various parts or its ground nutri- 5. In an unspecified order, front, during or after the application of these chemical products. 31. A-Process according to claim 30, where the chemical product used in agriculture is a herbicide. - A process according to claim 31, where the her- 10. Bicide is an active substance of the series of the chloracetanilides. 33. A process according to claim 32, where one uses as herbicide N [3 1 - methoxy-propyl- (2 ')]- N-chloracetyl- 2-methyl-6-ethyl aniline. 34. A process according to claim 31, where the herbi- 15 cide is an active substance of the series of the thiolcarbamates. 35. - A process according to claim 31, where the herbicide is an active substance of the series of esters and Dropionesters substituted of the phenoxyphnoxy-acetic acid or esters and propionoesters of the substituted pyridinoxyphenox7-acetic acid 20.
法律状态
(FR2387945) LEGAL DETAILS FOR FR2387945  Actual or expected expiration date=1995-12-29    Legal state=DEAD    Status=LAPSED     Event publication date=1978-02-28  Event code=FR/APP  Event indicator=Pos  Event type=Examination events  Application details  Application country=FR FR7805716  Application date=1978-02-28  Standardized application number=1978FR-0005716     Event publication date=1978-11-17  Event code=FR/A1  Event type=Examination events  Application for patent of invention, (first publ.)  Publication country=FR  Publication number=FR2387945  Publication stage Code=A1  Publication date=1978-11-17  Standardized publication number=FR2387945     Event publication date=1981-11-27  Event code=FR/B1  Event indicator=Pos  Event type=Event indicating In Force  Patent of invention (second publication)  Publication country=FR  Publication number=FR2387945  Publication stage Code=B1  Publication date=1981-11-27  Standardized publication number=FR2387945     Event publication date=1995-12-29  Event code=FR/ST  Event indicator=Neg  Event type=Event indicating Not In Force  Event type=Payment or non-payment notifications  Notification of lapse Constatation de decheances
专利类型码
A1B1
国别省市代码
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