Substituted cyclopropane carboxylic acid esters of alpha-cyanated alcohols, a process for their preparation, pesticidal compositions containing them, as well as their use as veterinary medicaments 机翻标题: 暂无翻译,请尝试点击翻译按钮。

公开号/公开日
EP0007255 A1 1980-01-23 [EP---7255]EP0007255 B1 1983-07-06 [EP---7255] / 1980-01-231983-07-06
申请号/申请日
1979EP-0400322 / 1979-05-22
发明人
MARTEL, JACQUES;TESSIER, JEAN;
申请人
ROUSSEL UCLAF;
主分类号
IPC分类号
A01N-053/00A01N-053/08A01N-053/14A01P-007/04A61K-031/275A61P-033/00C07C-067/00C07C-253/00C07C-253/30C07C-255/39C07C-255/53
摘要
(EP---7255) Abstract in publication language, translation not available  Composés de formule dans laquelle n est égal à 1, 2 ou 3, la configuration de la copule acide, étant (1R, trans) ou (1R, cis) et celle de la copule alcoolique étant (RS) ou (S), préparés par estérification de l'acide correspondant avec l'alcool alpha -cyano3- phénoxybenzylique.  Compositions pesticides renfermant ces esters; leur application à titre de médicaments vétérinaires.
机翻摘要
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地址
代理人
代理机构
;
优先权号
1978FR-0016858 1978-06-06
主权利要求
(EP---7255)  1. : 1) The compounds of formula (I) wherein CD :/ n is an integer of 1, 2 or 3 of the configuration is the acid copula (1E, trans) or (1E, cis) and that of the alcoholic copula is (ES) or (S). 2. The compounds of formula I as defined in claim 1, wherein the alcohol copula is (S) configuration. 10. 3) ie 1E, trans 2,2-dimethyl 3 - (cyclopentylidene methyl) cyclo-propane-l-cartoxylate of (ES)-cyano-3-phenoxybenzyl tenzyle, 4) 1E, trans 2,2-dimethyl 3 - <cyclopentylidene methyl ) cyclo-propane-1-carboxylate de (S) a-cyano 3-phenoxy \"benzyle,, 5) le 1E, cis 2,2-dimethyl 3-(cyclopentylidene methyl) cyclo-15 propane-1-carboxylate de (ES) a-cyano 3-phenoxy tenzyle, 6) le 1E, cis 2,2-dimethyl 3-(cyclopentylidene methyl) cyclo-propane-l-carboxylate de (S) a-cyano 3-phenoxy \"benzyle, \" 7)le 1E, cis 2,2-dimethyl 3-(cyclobutylidene methyl) cyclopropane-1-car\"boacylate de (ES) a-cyano 3-phenoxy \"benzyle, 8) le 1E, cis 2,2-dimethyl 3-(cyclo\"butylidene methyl) cyclopropane-l-carbosylate de (S) a-cyano 3-phenoxy \"benzyle, 9) le 1E, trans 2,2-dimethyl 3-(cyclo'butylidene methyl) cyclo-propane-1-carbo3tylate de (S) a-cyano 3-phenoxy \"benzyle, 10) le 1E, cis 2,2-dimethyl 3-(cyclopropylidene methyl) cyclo-25 propane-1-carboxylate de (ES) a-cyano 3-phenoxy \"benzyle, 11) le 1E, cis 2,2-dimethyl 3-(cyclopropylidene methyl) cyclo-propane-1-car\"boxylate de (S) a-cyano 3-phenoxy \"benzyle, 12) le 1E, trans 2,2-dimethyl 3-(cyclopropylidene methyl) cyclo-propane-1-car\"boxylate de (ES) a-cyano 3-?henoxy \"benzyle, 13) le.  E, trans 2,2-dimethyl 5-(cyclopropylidene dethyl) cyclo-propane-l-cartoxylate de (S) a-cjano 3-phenoxy \"benzyle.  L'aliment utilise correspond a 82 unites fourrageres pour 100 kilos et contient, pour 100 kilos : 910.000 U. I. de vitamine A, 91.000 U. I. de vitamine D,, 156 mg de vitamine E et 150 mg de vitamine C. Is incorporated into the food, 0.04 kg (1B, trans) 2,2-dimethyl 3-cyclopentylidene-1-methyl cyclopropane carboaylate of (ES)-3-cyano pfcenoxy "benzyl. 17) Insecticidal compositions, characterized in that they contain, as active principle, at least one of compounds of formula I, as defined in claim 1. 18) Insecticidal compositions, characterized in that they contain 5, as active ingredient, at least one compounds of formula I, as defined in claim 2. 19) Insecticidal compositions, characterized in that they contain, as active principle, at least one of the compounds of formula I as defined in claim 3 May, 7 10 were 12. 20) Insecticidal compositions, characterized in that they contain, as active principle, at least one of the compounds of formula I as defined in claim 4, 6, 8.9, 11 or 13. 21) nematicide compositions, characterized in that they contain, as active principle, at least one of the compounds of formula 15 I, as defined in any one of claims 1 to 13. 22. Acaricidal compositions, for the fight against plant parasitic mites, characterized in that they contain, as active principle, at least one of the compounds of formula 20 I, as defined in any one of claims 1 to 13. 23) Use of the products of formula I as defined in any one of claims 1 to 13. the fight against parasitic mites of anf-ma-mr. 24) By way of veterinary drugs for the fight against the parasitic acaridae of animals, the compounds of formula I, as defined in any one of claims 1 to 13. 25) Compositions containing, as active principle, 1 to 30 unless the products of formula I, as defined in any one of claims 1 to 13, and for the fight against the parasitic acaridae of animals. 26. Pharmaceutical compositions veterinary, containing as active principle, at least one of the products of formula I as defined in any one of claims 1 to 13, and for the fight against parasitic mites of rM-man r, 27) Compositions intended for animal feed, characterized in that they are constituted by a food animal and RUDP balanced understood that they contain, in addition, the tannin compounds of formula I, as defined in the any one of claims 1 to 13. 14. Process for preparing the products of formula I as defined in claim 1, characterized in that one reacting an acid of formula II of structure (1E, cis) or (1B, trans): e O-OH wherein n is defined as in claim 1, or a functional derivative thereof, with the alcohol (S)-cyano-3-phenoxybenzyl alcohol or with (ES)-cyano-3-phenoxybenzyl, to obtain the corresponding ester of (S) or (ES)-cyano-phenoxy benzyl 10. I, and subjected, if necessary, the ester of (ES)-cyano-3-phenoxy benzyl action of a basic agent in a solvent in which the corresponding ester of alcohol (S) configuration is insoluble and wherein the corresponding alcohol ester of (E) configuration is soluble, for 15 the ester of (S)-cyano-3-benzyl pnenoxy. 15) A method according to claim 14, characterized in that in the ester of (ES)-cyano-3-benzyl pnenoxy to the action of a basic agent in a solvent in which the corresponding alcohol ester of (S) configuration and is insoluble in 20 wherein the ester corresponding alcohol (E) configuration is soluble, and obtain the ester of (S)-cyano-3-benzyl pnenoxy. 16. The method of claims 14 or 15 characterized in that the basic agent used for the transformation of the ester Alool (ES) alcohol ester (S) is selected from the group consisting 1ammoniaque, triethylamine, diethylamine, morpholine, pyrrolidine, piperidine, and utilized in catalytic quantity, sodium hydroxide, potassium hydroxide, alkali metal alcoholates, alkali metal amides, alkaline hydrides, and in that the solvent or solvent mixture used for insoluble- 30 lubiliser the alcohol ester (S) is selected from the group consisting of aceto nitrile, the alkanols and the mixtures of alkanol and petroleum ether, the notasnnent oelanges alkanol and pentane, to hexane or heptane.
法律状态
(EP---7255) LEGAL DETAILS FOR EP0007255  Actual or expected expiration date=1999-05-22    Legal state=DEAD    Status=EXPIRED     Event publication date=1979-05-22  Event code=EP/APP  Event indicator=Pos  Event type=Examination events  Application details  Application country=EP EP79400322  Application date=1979-05-22  Standardized application number=1979EP-0400322     Event publication date=1980-01-23  Event code=EP/A1  Event type=Examination events  Application published with search report  Publication country=EP  Publication number=EP0007255  Publication stage Code=A1  Publication date=1980-01-23  Standardized publication number=EP---7255     Event publication date=1980-01-23  Event code=EP/AK  Event indicator=Pos  Event type=Designated states  Designated contracting states: Benannte vertragsstaaten BE CH DE FR GB IT NL    Event publication date=1980-06-25  Event code=EP/17P  Event indicator=Pos  Event type=Examination events  Request for examination filed Pruefungsantrag gestellt    Event publication date=1983-07-06  Event code=EP/B1  Event indicator=Pos  Event type=Event indicating In Force  Patent specification  Publication country=EP  Publication number=EP0007255  Publication stage Code=B1  Publication date=1983-07-06  Standardized publication number=EP---7255     Event publication date=1983-07-06  Event code=EP/AK  Event indicator=Pos  Event type=Designated states  Designated contracting states: Benannte vertragsstaaten BE CH DE FR GB IT NL    Event publication date=1984-07-18  Event code=EP/26N  Event indicator=Pos  Event type=No opposition filed  Event type=Event indicating In Force  No opposition filed Kein einspruch eingelegt    Event publication date=1999-05-22  Event code=EP/EEDX  Event indicator=Neg  Event type=Event indicating Not In Force  Patent has expired MEMBER STATE LEGAL DETAILS FOR BE  Actual or expected expiration date=1995-05-31    Legal state=DEAD    Status=LAPSED   Corresponding cc:  Designated or member state=BE     Event publication date=1994-04-29  Event code=EP/PGFP  Event indicator=Pos  Event type=Event indicating In Force  Event type=Payment or non-payment notifications  Postgrant: annual fees paid to national office   Annual fees payment date=1994-04-29     Year of payment of annual fees=16  Corresponding cc:  Designated or member state=BE     Event publication date=1995-05-31  Event code=EP/PG25  Event indicator=Neg  Event type=Event indicating Not In Force  Event type=Payment or non-payment notifications  Lapsed in a contracting state announced via postgrant inform. from nat. office to EPO Corresponding cc:  Designated or member state=BE   Effective date of the event=1995-05-31     Event publication date=1995-11-30  Event code=EP/BERE  Event indicator=Neg  Event type=Event indicating Not In Force  BE: Lapsed BE: Dechu Corresponding cc:  Designated or member state=BE   Effective date of the event=1995-05-31  MEMBER STATE LEGAL DETAILS FOR CH  Actual or expected expiration date=1995-05-31    Legal state=DEAD    Status=EXPIRED   Corresponding cc:  Designated or member state=CH     Event publication date=1994-04-26  Event code=EP/PGFP  Event indicator=Pos  Event type=Event indicating In Force  Event type=Payment or non-payment notifications  Postgrant: annual fees paid to national office   Annual fees payment date=1994-04-26     Year of payment of annual fees=16  Corresponding cc:  Designated or member state=CH     Event publication date=1995-05-31  Event code=EP/PG25  Event indicator=Neg  Event type=Event indicating Not In Force  Event type=Payment or non-payment notifications  Lapsed in a contracting state announced via postgrant inform. from nat. office to EPO Corresponding cc:  Designated or member state=CH   Effective date of the event=1995-05-31     Event publication date=1996-01-31  Event code=EP/REG  Event code=CH/PL  Event indicator=Neg  Event type=Event indicating Not In Force  Reference to a national code Patent ceased Loeschung/radiation/radiazion Corresponding cc:  Designated or member state=CH  MEMBER STATE LEGAL DETAILS FOR DE2965815  Actual or expected expiration date=1996-02-01    Legal state=DEAD    Status=LAPSED   Corresponding cc:  Designated or member state=DE Corresponding appl: DE2965815  Application date in the designated or member state=1979-05-22   Application number in the designated or member state=1979DE-2965815 Corresponding cc:  Designated or member state=DE Corresponding pat: DE2965815  Publication stage code in the designated or member state=D1  Publication date in the designated or member state=1983-08-11   Publication number in the designated or member state=DE2965815    Event publication date=1983-08-11  Event code=EP/REF  Event type=Entry into national phase  Corresponds to: Corresponding cc:  Designated or member state=DE     Event publication date=1994-07-25  Event code=EP/PGFP  Event indicator=Pos  Event type=Event indicating In Force  Event type=Payment or non-payment notifications  Postgrant: annual fees paid to national office   Annual fees payment date=1994-07-25     Year of payment of annual fees=16  Corresponding cc:  Designated or member state=DE     Event publication date=1996-02-01  Event code=EP/PG25  Event indicator=Neg  Event type=Event indicating Not In Force  Event type=Payment or non-payment notifications  Lapsed in a contracting state announced via postgrant inform. from nat. office to EPO Corresponding cc:  Designated or member state=DE   Effective date of the event=1996-02-01  MEMBER STATE LEGAL DETAILS FOR FR  Actual or expected expiration date=1996-02-29    Legal state=DEAD    Status=LAPSED   Corresponding cc:  Designated or member state=FR     Event publication date=1994-05-24  Event code=EP/PGFP  Event indicator=Pos  Event type=Event indicating In Force  Event type=Payment or non-payment notifications  Postgrant: annual fees paid to national office   Annual fees payment date=1994-05-24     Year of payment of annual fees=16  Corresponding cc:  Designated or member state=FR     Event publication date=1996-02-29  Event code=EP/PG25  Event indicator=Neg  Event type=Event indicating Not In Force  Event type=Payment or non-payment notifications  Lapsed in a contracting state announced via postgrant inform. from nat. office to EPO Corresponding cc:  Designated or member state=FR   Effective date of the event=1996-02-29     Event publication date=1996-04-05  Event code=EP/REG  Event code=FR/ST  Event indicator=Neg  Event type=Event indicating Not In Force  Event type=Payment or non-payment notifications  Reference to a national code Notification of lapse Constatation de decheances Corresponding cc:  Designated or member state=FR     Event publication date=1996-04-19  Event code=EP/REG  Event code=FR/ST  Event indicator=Neg  Event type=Event indicating Not In Force  Event type=Payment or non-payment notifications  Reference to a national code Notification of lapse Constatation de decheances Corresponding cc:  Designated or member state=FR  MEMBER STATE LEGAL DETAILS FOR GB  Actual or expected expiration date=1995-05-22    Legal state=DEAD    Status=LAPSED   Corresponding cc:  Designated or member state=GB     Event publication date=1994-05-20  Event code=EP/PGFP  Event indicator=Pos  Event type=Event indicating In Force  Event type=Payment or non-payment notifications  Postgrant: annual fees paid to national office   Annual fees payment date=1994-05-20     Year of payment of annual fees=16  Corresponding cc:  Designated or member state=GB     Event publication date=1995-05-22  Event code=EP/GBPC  Event indicator=Neg  Event type=Event indicating Not In Force  Event type=Payment or non-payment notifications  GB: European patent ceased through non-payment of renewal fee Corresponding cc:  Designated or member state=GB   Effective date of the event=1995-05-22     Event publication date=1995-05-22  Event code=EP/PG25  Event indicator=Neg  Event type=Event indicating Not In Force  Event type=Payment or non-payment notifications  Lapsed in a contracting state announced via postgrant inform. from nat. office to EPO Corresponding cc:  Designated or member state=GB   Effective date of the event=1995-05-22  MEMBER STATE LEGAL DETAILS FOR IT  Actual or expected expiration date=1999-05-22    Legal state=DEAD    Status=EXPIRED   Corresponding cc:  Designated or member state=IT     Event publication date=1982-12-13  Event code=EP/ITF  Event indicator=Pos  Event type=Examination events  IT: Translation for a EP patent filed IT: Deposito traduzione di brevetto europeo Corresponding cc:  Designated or member state=IT     Event publication date=1994-05-31  Event code=EP/ITTA  Event type=Event indicating In Force  Event type=Payment or non-payment notifications  IT: Last paid annual fee IT: Tassa annuale ultimo pagamento Corresponding cc:  Designated or member state=IT  MEMBER STATE LEGAL DETAILS FOR NL  Actual or expected expiration date=1995-12-01    Legal state=DEAD    Status=LAPSED   Corresponding cc:  Designated or member state=NL     Event publication date=1994-05-31  Event code=EP/PGFP  Event indicator=Pos  Event type=Event indicating In Force  Event type=Payment or non-payment notifications  Postgrant: annual fees paid to national office   Annual fees payment date=1994-05-31     Year of payment of annual fees=16  Corresponding cc:  Designated or member state=NL     Event publication date=1995-12-01  Event code=EP/PG25  Event indicator=Neg  Event type=Event indicating Not In Force  Event type=Payment or non-payment notifications  Lapsed in a contracting state announced via postgrant inform. from nat. office to EPO Corresponding cc:  Designated or member state=NL   Effective date of the event=1995-12-01     Event publication date=1995-12-01  Event code=EP/NLV4  Event indicator=Neg  Event type=Event indicating Not In Force  Event type=Payment or non-payment notifications  NL: Lapsed or anulled due to non-payment of the annual fee NL: Vervallen wegens niet betalen van een jaarcijns Corresponding cc:  Designated or member state=NL   Effective date of the event=1995-12-01
专利类型码
A1B1
国别省市代码
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