Acrylic acid derivatives, manufacture and fungicidal, insecticidal or plant growth regulator 机翻标题: 暂无翻译,请尝试点击翻译按钮。

源语言标题
(JP2591743) アクリル​酸​誘導体、その​製造​法​及び​それ​を​含有​する​殺菌​剤​組成​物
公开号/公开日
JPS62258344 A 1987-11-10 [JP62258344]JP2591743 B2 1997-03-19 [JP2591743] / 1987-11-101997-03-19
申请号/申请日
1987JP-0093477 / 1987-04-17
发明人
BIIBIIAN MAAGARETSUTO ANTONII;JON MAACHIN KURO;HOORU DEFUREIN;KEBIN BYUUTOMENTO;KURISUTOFUAA RICHAADO AIRISU GOTSUDOFUREI;
申请人
ICI - IMPERIAL CHEMICAL INDUSTRIES;
主分类号
IPC分类号
A01N-037/36A01N-037/42A01N-037/44A01N-037/48A01N-043/06A01N-043/08A01N-043/10A01N-043/36A01N-043/38A01N-043/58C07C-067/00C07C-069/734C07C-201/00C07C-205/56C07C-229/64C07C-233/58C07C-239/00C07C-241/00C07C-245/06C07C-251/02C07C-251/44C0
摘要
(JP2591743) Compounds of formula (1): <CHEM> and stereoisomers thereof, wherein W is R<1>O2-C=CH-ZR<2>, wherein R<1> and R<2>, which are the same or different, are alkyl or fluoroalkyl groups, and Z is either an oxygen or sulphur atom; A is an oxygen or sulphur atom, -NR<3>-, or -CR<4>R<5>-; X, Y and Z<1>, which are the same or different, are hydrogen or halogen atoms, or hydroxy, optionally substituted alkyl, optionally substituted cycloalkyl, optionally substituted cycloalkylalkyl, optionally substituted aralkyl, optionally substituted heteroarylalkyl, optionally substituted aryloxyalkyl, optionally substituted heteroaryloxyalkyl, optionally substituted alkenyl, optionally substituted alkynyl, optionally substituted aryl, optionally substituted heteroaryl, optionally substituted alkoxy, optionally substituted arylalkoxy, optionally substituted aryloxy, optionally substituted heteraryloxy, optionally substituted acyloxy, optionally substituted amino, optionally substituted acylamino, optionally substituted arylazo, nitro, cyano, -CO2R<6>, -CONR<7>R<8>, -COR<9> -CR=NR<1><0>, -CR=NOR<1><0> or -N=CR<1><1>R<1><2> groups; or the groups X and Y, when they are in adjacent positions on the ring, optionally join to form a fused ring, either aromatic or aliphatic, optionally containing one or more heteroatoms; and R, R<3>, R<4>, R<5>, R<6>, R<7>, R<8>, R<9>, R<1><0>, R<1><1> and R<1><2>, which are the same or different, are hydrogen atoms (provided that R<4> and R<5> are not hydrogen) or optionally substituted alkyl, optionally substituted cycloalkyl, optionally substituted cycloalkylalkyl, optionally substituted aralkyl, optionally substituted heterarylalkyl, optionally substituted aryloxyalkyl, optionally substituted heteroaryloxyalkyl, optionally substituted alkenyl, optionally substituted alkynyl, optionally substituted aryl or optionally substituted heteroaryl groups; and metal complexes thereof.  The compounds are useful in agriculture, especially as fungicides but also as insecticides and plant growth regulators.  (From EP0243014 A1)
机翻摘要
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地址
代理人
代理机构
;
优先权号
1986GB-0009452 1986-04-17
主权利要求
(JP2591743)   1. Formula (i): (In formula, as for W R (1) O [2] C-C=CH-ZR (2) (however, R (1) and R as for (2) it is identical So it is possible to differ and respective alkyl or [huruoru] To display the alkyl group, as for Z the oxygen or sulfur atom the chart [wa] It does) displaying;  As for A oxygen or sulfur atom, or - NR (3)- Displaying basis;  X, Y and Z (1) being identical, even when is possible and to differ, The respective hydrogen or halogen atom, or hydroxy, Non substitution or substitution alkyl, non substitution or substitution [shikuroaruki] [ru], non substitution or substitution [shikuroarukiruarukiru], non substitution and Substitution phenyl alkyl, non substitution or substitution [heteroari] [ruarukiru], non substitution or substitution phenoxy alkyl, non position Exchanging or substitution hetero aryl oxy alkyl, non substitution or Substitution [arukeniru], non substitution or substitution [arukiniru], non substitution and Substitution phenyl, non substitution or substitution hetero aryl, non position Exchanging or substitution alkoxy, non substitution or substitution [hueniruaruko] [kishi], non substitution or substitution phenoxy, non substitution or substitution [hete] Lower reel oxy and acetyl oxy, [benzoiruoki] [shi], - NR ' R ", - NHCOR ', non substitution or substitution phenyl Azo, nitro, cyano, - CO [2] R (6), - CONR (7) R (8), - COR (9), - CR =NR (10), - CR=NOR (10) or - N=CR (11) R (12) the basis is displayed or, or the basis As for X and Y, when those is contiguity position with respect to ring, when Connecting mutually depending upon, it forms condensation benzene ring;  R ' And R " the respective hydrogen atom, C [1-4] alkyl, C [1-4] Al [kokishi], C [1-4] alkyl thio, C [3-6] [shikuroarukiru], C [3-6] [shikuroarukiru] (C [1-4]) alkyl, phenyl or [benji] To be the [ru] basis, as for the said phenyl group and the benzyl basis halogen, Being substituted with C [1-4] alkyl or C [1-4] alkoxy group Good;  R, R (3), R (6), R (7), R (8), R (9), R (10), R (11) and R (12) it is identical So it is possible to differ and the respective hydrogen atom, non substitution or Substitution alkyl, non substitution or substitution [shikuroarukiru], non substitution Or substitution [shikuroarukiruarukiru], non substitution or substitution [hue] [niruarukiru], non substitution or substitution [heteroariruaruki] [ru], non substitution or substitution phenoxy alkyl, non substitution or position Exchanging hetero aryl oxy alkyl, non substitution or substitution Al [keniru], non substitution or substitution [arukiniru], non substitution or substitution [hu] [eniru] or non substitution or substitution hetero aryl basis chart [wa] It does;  However, hetero aryl alkyl group and hetero ant As for hetero aryl part of [ruokishiarukiru] [pirijini] [ru], [pirimijiniru] and [chieniru], frill or in pyro rill basis To be, as for the hetero aryl part of the hetero aryl oxy basis To be the [pirijiniru] or [pirimijiniru] basis, hetero aryl As for basis [pirijiniru], [pirimijiniru], [pirajiniru] and [piridaji] [niru], [toriajiniru], [tetorajiniru], [chieniru] and [kinori] [niru], [isokinoriniru], [kinokisariniru] or benzo thio It is phenyl group;  As for substituent of substitution alkyl group [hidoroki] The group which consists of [shi], halogen and the alkoxy carbonyl group? And others it is something which is chosen;  Substitution alkoxy group, substitution [shikuro] Substituent of alkyl group and substitution [shikuroarukiruarukiru]  Halogen, it consists of hydroxy and C [1-4] alkoxy group It is something which is chosen from the group;  Substituent of substitution [arukiniru] basis It is phenyl group;  As for substituent of substitution [arukeniru] basis [hue] [niru], frill, it is the [chieniru] or [pirijiniru] basis;  It substitutes Phenyl alkyl group and substitution phenoxy alkyl group, substitution Phenyl group and substitution phenyl alkoxy group, substitution [huenoki] Like substituent of phenyl part of [shi] basis and substitution phenyl azo basis In [bi] substitution hetero aryl alkyl group, substitution [heteroari] [ruokishiarukiru] , substitution hetero aryl basis and substitution [he] As for substituent of hetero aryl part of terrorist aryl oxy basis The respective halogen, hydroxy and C [1-4] alkyl, C [1-4] [a] [rukokishi] and halo (C [1-4]) alkyl, halo (C [1-4]) [aruko] [kishi], C [1-4] alkyl thio, C [1-4] alkoxy (C [1-4]) Al To kill, C [3-6] [shikuroarukiru] and C [3-6] [shikuroarukiru] (C [1-4]) alkyl, phenyl and phenoxy, phenyl (C [1-4]) alkyl and phenyl (C [1-4]) alkoxy, [hue] [nokishi] (C [1-4]) alkyl and acetyl oxy, benzoyl Oxy, cyano and thio cyanate and nitro, - NR ' R ", - NHCOR ', - NHCONR ' R ", - CONR ' R ", - C OOR ", - OSO [2] R ', - SO [2] R ', - COR ', - CR ' =NR " and [bi] - N=CR ' R &amp; basis (R in formula ' and R " the aforementioned meaning It possesses) to be something which is chosen from the group which consists of;  In addition R (1) And R (2) both to be the methyl group together, A with the sulfur atom a At the same time the [ri], W has adjoined to A, when Z is the oxygen atom, X, Y or as for Z (1) there are no times when everything is the hydrogen atom, In addition the next formula: (In formula, R is the hydrogen atom or the methyl group) chemical compound It excludes} with the chemical compound which is displayed and that solid Isomer.  2. X, Y and Z as for (1) hydrogen and halogen, C [1-4] Al To kill, phenyl (C [1-4]) alkyl and hetero aryl (C [1-4]) Alkyl and hetero aryl oxy (C [1-4]) [aruki] [ru], hetero aryl oxy, phenoxy (C [1-4]) [aruki] [ru], C [1-4] alkoxy and phenyl (C [1-4]) alkoxy, [hu] [enokishi], phenyl (C [2-4]) [arukeniru], [heteroari] [ru] (C [2-4]) [arukeniru], phenyl (C [2-4]) [arukiniru], Hetero aryl (C [2-4]) [arukiniru], cyano, (C [1-4]) From alkoxy carbonyl and phenoxy carbonyl To be the atom or the basis which is chosen from the group which becomes, at that time X, Y and Z (1) one to be the atom or the basis other than hydrogen and with respect to complex ring Example of the patent claim which is something which exists in the position where it adjoins to the basis W Chemical compound of surrounding 1st section statement.  3. R (1) and R the patent claim to which (2) together is the methyl group Chemical compound of range 1st section statement.  4. Formula: (In formula, as for X there is a position where it adjoins to the acrylate basis and Halogen, C [1-4] alkyl, halo (C [1-4]) alkyl, [hue] [niru] (C [1-4]) alkyl, phenoxy (C [1-4]) alkyl, Phenyl (C [2-4]) [arukeniru], phenoxy or acyl basis You display) with the range of the patent claim which is the chemical compound which is displayed Chemical compound of 1 section statements.  5. Formula: (In formula, R as for (3) hydrogen atom, C [1-4] alkyl or aryl (C [1-4]) To display the alkyl group, as for X the hydrogen atom, C [1-4] [aruki] [ru], phenyl (C [1-4]) alkyl and phenyl (C [2-4]) Al To display the [keniru] or acyl basis, and Y and Z as for (1) that [re] hydrogen is displayed, or when or X displays hydrogen, Y And Z (1) forms condensation benzene ring together) with displaying The chemical compound of range 1st section statement of the patent claim which is [ru] chemical compound.  6. Formula: Keto ester in solvent PH [3] P (+&lt;HAN&gt;, &lt;/HAN&gt;-) CH (ZR (2)) (in formula, as for PH Phenyl group is displayed, Z and R (2) has the below-mentioned meaning) - phospho run with process do thing from become, system (i): (In formula, as for W R (1) O [2] C-C=CH-ZR (2) (however, R (1) and R as for (2) it is identical So it is possible to differ and respective alkyl or [huruoru] To display the alkyl group, as for Z the oxygen or sulfur atom the chart [wa] It does) displaying;  As for A oxygen or sulfur atom, or - NR (3)- Displaying basis;  X, Y and Z (1) being identical, even when is possible and to differ, The respective hydrogen or halogen atom, or hydroxy, Non substitution or substitution alkyl, non substitution or substitution [shikuroaruki] [ru], non substitution or substitution [shikuroarukiruarukiru], non substitution and Substitution phenyl alkyl, non substitution or substitution [heteroari] [ruarukiru], non substitution or substitution phenoxy alkyl, non position Exchanging or substitution hetero aryl oxy alkyl, non substitution or Substitution [arukeniru], non substitution or substitution [arukiniru], non substitution and Substitution phenyl, non substitution or substitution hetero aryl, non position Exchanging or substitution alkoxy, non substitution or substitution [hueniruaruko] [kishi], non substitution or substitution phenoxy, non substitution or substitution [hete] Lower reel oxy and acetyl oxy, [benzoiruoki] [shi], - NR ' R ", - NHCOR ' -, non substitution or substitution [hueni] [ruazo], nitro, cyano, - CO [2] R (6), - CONR (7) R (8), - COR (9), - CR=NR (10), - CR=NOR (10) or - N=CR (11) R (12) the basis is displayed or, or As for the basis X and Y, when those is contiguity position with respect to ring, the place Connecting mutually depending upon combination, it forms condensation benzene ring; R ' and R " the respective hydrogen atom, C [1-4] alkyl, C [1-4] Alkoxy, C [1-4] alkyl thio, C [3-6] [shikuroarukiru], C [3-6] [shikuroarukiru] (C [1-4]) alkyl, phenyl or [be] To be the [njiru] basis, as for the said phenyl group and the benzyl basis [haroge] [n], it is substituted with C [1-4] alkyl or C [1-4] alkoxy group, [te] good;  R, R (3), R (6), R (7), R (8), R (9), R (10), R (11) and R (12) Being identical, even when it is possible and the respective hydrogen atom, non substitution to differ, Or substitution alkyl, non substitution or substitution [shikuroarukiru], fault Substitution or substitution [shikuroarukiruarukiru], non substitution or substitution Phenyl alkyl, non substitution or substitution hetero aryl Al To kill, non substitution or substitution phenoxy alkyl, non substitution or Substitution hetero aryl oxy alkyl, non substitution or substitution [a] [rukeniru], non substitution or substitution [arukiniru], non substitution or substitution Phenyl or non substitution or substitution hetero aryl basis chart The [wa] it does;  However, hetero aryl alkyl group and [heteroa] As for hetero aryl part of reel oxy alkyl group [piriji] [niru], [pirimijiniru] and [chieniru], frill or pyro rill basis So to be, the hetero aryl part of the hetero aryl oxy basis To be the [pirijiniru] or [pirimijiniru] basis, [heteroari] As for [ru] basis [pirijiniru], [pirimijiniru], [pirajiniru] and [pirida] [jiniru], [toriajiniru], [tetorajiniru], [chieniru] and [kino] [riniru], [isokinoriniru], [kinokisariniru] or [benzochi] It is [ohueniru] ;  As for substituent of substitution alkyl group hydro The group which consists of [kishi], halogen and the alkoxy carbonyl group From it is something which is chosen;  Substitution alkoxy group, substitution [shiku] Substitution of [roarukiru] and substitution [shikuroarukiruarukiru]  As for basis halogen, from hydroxy and C [1-4] alkoxy group It is something which is chosen from the [ru] group;  Substitution of substitution [arukiniru] basis The basis is phenyl group;  As for substituent of substitution [arukeniru] basis [hu] [eniru], frill, it is the [chieniru] or [pirijiniru] basis;  Position Exchanging phenyl alkyl group and substitution phenoxy alkyl group, position Exchanging phenyl group and substitution phenyl alkoxy group, substitution [hueno] Substituent of phenyl part of [kishi] basis and substitution phenyl azo basis And substitution hetero aryl alkyl group, substitution hetero ant [ruokishiarukiru] , substitution hetero aryl basis and substitution Substituent of hetero aryl part of hetero aryl oxy basis The respective halogen, hydroxy and C [1-4] alkyl, C [1-4] Alkoxy and halo (C [1-4]) alkyl, halo (C [1-4]) Al [kokishi], C [1-4] alkyl thio, C [1-4] alkoxy (C [1-4]) [a] [rukiru], C [3-6] [shikuroarukiru] and C [3-6] [shikuroarukiru] (C [1-4]) Alkyl, phenyl and phenoxy, phenyl (C [1-4]) Alkyl and phenyl (C [1-4]) alkoxy, [hueno] [kishi] (C [1-4]) alkyl and acetyl oxy, [benzoiruo] [kishi], cyano and thio cyanate and nitro, - NR ' R ", - NHCOR ', - NHCONR ' R ", - CONR ' R ", - COO R ", - OSO [2] R ', - SO [2] R ', - COR ', - CR ' =NR " and - N=CR ' R &amp; basis (R in formula ' and R " the aforementioned meaning It possesses) to be something which is chosen from the group which consists of;  In addition R (1) and [bi] R (2) both to be the methyl group together, A with the sulfur atom a At the same time the [ri], W has adjoined to A, when Z is the oxygen atom, X, Y or as for Z (1) there are no times when everything is the hydrogen atom, In addition the next formula: (In formula, R is the hydrogen atom or the methyl group) chemical compound It excludes} with the chemical compound which is displayed and that solid Manufacturing method of isomer.  7. Formula: Processing the acetal under acidic or basic condition, said [ase] From tar that alcohol R (2) ZH (in formula, Z and R as for (2) description below It possesses meaning) it consists of the fact that it is disconnected the part, formula (i): (In formula, as for W R (1) O [2] C-C=CH-ZR (2) (however, R (1) and R as for (2) it is identical So it is possible to differ and respective alkyl or [huruoru] To display the alkyl group, as for Z the oxygen or sulfur atom the chart [wa] It does) displaying;  As for A oxygen or sulfur atom, or - NR (3)- Displaying basis;  X, Y and Z (1) being identical, even when is possible and to differ, The respective hydrogen or halogen atom, or hydroxy, Non substitution or substitution alkyl, non substitution or substitution [shikuroaruki] [ru], non substitution or substitution [shikuroarukiruarukiru], non substitution and Substitution phenyl alkyl, non substitution or substitution [heteroari] [ruarukiru], non substitution or substitution phenoxy alkyl, non position Exchanging or substitution hetero aryl oxy alkyl, non substitution or Substitution [arukeniru], non substitution or substitution [arukiniru], non substitution and Substitution phenyl, non substitution or substitution hetero aryl, non position Exchanging or substitution alkoxy, non substitution or substitution [hueniruaruko] [kishi], non substitution or substitution phenoxy, non substitution or substitution [hete] Lower reel oxy and acetyl oxy, [benzoiruoki] [shi], - NR ' R ", - NHCOR ', non substitution or substitution phenyl Azo, nitro, cyano, - CO [2] R (6), - CONR (7) R (8), - COR (9), - CR =NR (10), - CR=NOR (10) or - N=CR (11) R (12) the basis is displayed or, or the basis As for X and Y, when those is contiguity position with respect to ring, when Connecting mutually depending upon, it forms condensation benzene ring;  R ' And R " the respective hydrogen atom, C [1-4] alkyl, C [1-4] Al [kokishi], C [1-4] alkyl thio, C [3-6] [shikuroarukiru], C [3-6] [shikuroarukiru] (C [1-4]) alkyl, phenyl or [benji] To be the [ru] basis, as for the said phenyl group and the benzyl basis halogen, Being substituted with C [1-4] alkyl or C [1-4] alkoxy group Good;  R, R (3), R (6), R (7), R (8), R (9), R (10), R (11) and R (12) it is identical So it is possible to differ and the respective hydrogen atom, non substitution or Substitution alkyl, non substitution or substitution [shikuroarukiru], non substitution Or substitution [shikuroarukiruarukiru], non substitution or substitution [hue] [niruarukiru], non substitution or substitution [heteroariruaruki] [ru], non substitution or substitution phenoxy alkyl, non substitution or position Exchanging hetero aryl oxy alkyl, non substitution or substitution Al [keniru], non substitution or substitution [arukiniru], non substitution or substitution [hu] [eniru] or non substitution or substitution hetero aryl basis chart [wa] It does;  However, hetero aryl alkyl group and hetero ant As for hetero aryl part of [ruokishiarukiru] [pirijini] [ru], [pirimijiniru] and [chieniru], frill or in pyro rill basis To be, as for the hetero aryl part of the hetero aryl oxy basis To be the [pirijiniru] or [pirimijiniru] basis, hetero aryl As for basis [pirijiniru], [pirimijiniru], [pirajiniru] and [piridaji] [niru], [toriajiniru], [tetorajiniru], [chieniru] and [kinori] [niru], [isokinoriniru], [kinokisariniru] or benzo thio It is phenyl group;  As for substituent of substitution alkyl group [hidoroki] The group which consists of [shi], halogen and the alkoxy carbonyl group? And others it is something which is chosen;  Substitution alkoxy group, substitution [shikuro] Substituent of alkyl group and substitution [shikuroarukiruarukiru]  Halogen, it consists of hydroxy and C [1-4] alkoxy group It is something which is chosen from the group;  Substituent of substitution [arukiniru] basis It is phenyl group;  As for substituent of substitution [arukeniru] basis [hue] [niru], frill, it is the [chieniru] or [pirijiniru] basis;  It substitutes Phenyl alkyl group and substitution phenoxy alkyl group, substitution Phenyl group and substitution phenyl alkoxy group, substitution [huenoki] Like substituent of phenyl part of [shi] basis and substitution phenyl azo basis In [bi] substitution hetero aryl alkyl group, substitution [heteroari] [ruokishiarukiru] , substitution hetero aryl basis and substitution [he] As for substituent of hetero aryl part of terrorist aryl oxy basis The respective halogen, hydroxy and C [1-4] alkyl, C [1-4] [a] [rukokishi] and halo (C [1-4]) alkyl, halo (C [1-4]) [aruko] [kishi], C [1-4] alkyl thio, C [1-4] alkoxy (C [1-4]) Al To kill, C [3-6] [shikuroarukiru] and C [3-6] [shikuroarukiru] (C [1-4]) alkyl, phenyl and phenoxy, phenyl (C [1-4]) alkyl and phenyl (C [1-4]) alkoxy, [hue] [nokishi] (C [1-4]) alkyl and acetyl oxy, benzoyl Oxy, cyano and thio cyanate and nitro, - NR ' R ", - NHCOR ', - NHCONR ' R ", - CONR ' R ", - C OOR ", - OSO [2] R ', - SO [2] R ', - COR ', - CR ' =NR " and [bi] - N=CR ' R &amp; basis (R in formula ' and R " the aforementioned meaning It possesses) to be something which is chosen from the group which consists of;  In addition R (1) And R (2) both to be the methyl group together, A with the sulfur atom a At the same time the [ri], W has adjoined to A, when Z is the oxygen atom, X, Y or as for Z (1) there are no times when everything is the hydrogen atom, In addition the next formula: (In formula, R is the hydrogen atom or the methyl group) chemical compound It excludes} with the chemical compound which is displayed and that solid Manufacturing method of isomer.  8. Formula: (In formula, R (13) the hydrogen atom or the metal atom is displayed) chemical combination When the thing, R (13) it is the metal atom, R (2) Q (in formula, R as for (2) under It possesses the meaning of description, the disconnection basis it is displayed) processes Q in chemical kind It does, when R (13) it is the hydrogen atom, the base and chemical kind R (2) with Q It consists of the fact that it processes consecutively, formula (i): (In formula, as for W R (1) O [2] C-C=CH-ZR (2) (however, R (1) and R as for (2) it is identical So it is possible to differ and respective alkyl or [huruoru] To display the alkyl group, as for Z the oxygen or sulfur atom the chart [wa] It does) displaying;  As for A oxygen or sulfur atom, or - NR (3)- Displaying basis;  X, Y and Z (1) being identical, even when is possible and to differ, The respective hydrogen or halogen atom, or hydroxy, Non substitution or substitution alkyl, non substitution or substitution [shikuroaruki] [ru], non substitution or substitution [shikuroarukiruarukiru], non substitution and Substitution phenyl alkyl, non substitution or substitution [heteroari] [ruarukiru], non substitution or substitution phenoxy alkyl, non position Exchanging or substitution hetero aryl oxy alkyl, non substitution or Substitution [arukeniru], non substitution or substitution [arukiniru], non substitution and Substitution phenyl, non substitution or substitution hetero aryl, non position Exchanging or substitution alkoxy, non substitution or substitution [hueniruaruko] [kishi], non substitution or substitution phenoxy, non substitution or substitution [hete] Lower reel oxy and acetyl oxy, [benzoiruoki] [shi], - NR ' R ", - NHCOR ', non substitution or substitution phenyl Azo, nitro, cyano, - CO [2] R (6), - CONR (7) R (8), - COR (9), - CR =NR (10), - CR=NOR (10) or - N=CR (11) R (12) the basis is displayed or, or the basis As for X and Y, when those is contiguity position with respect to ring, when Connecting mutually depending upon, it forms condensation benzene ring;  R ' And R " the respective hydrogen atom, C [1-4] alkyl, C [1-4] Al [kokishi], C [1-4] alkyl thio, C [3-6] [shikuroarukiru], C [3-6] [shikuroarukiru] (C [1-4]) alkyl, phenyl or [benji] To be the [ru] basis, as for the said phenyl group and the benzyl basis halogen, Being substituted with C [1-4] alkyl or C [1-4] alkoxy group Good;  R, R (3), R (6), R (7), R (8), R (9), R (10), R (11) and R (12) it is identical So it is possible to differ and the respective hydrogen atom, non substitution or Substitution alkyl, non substitution or substitution [shikuroarukiru], non substitution Or substitution [shikuroarukiruarukiru], non substitution or substitution [hue] [niruarukiru], non substitution or substitution [heteroariruaruki] [ru], non substitution or substitution phenoxy alkyl, non substitution or position Exchanging hetero aryl oxy alkyl, non substitution or substitution Al [keniru], non substitution or substitution [arukiniru], non substitution or substitution [hu] [eniru] or non substitution or substitution hetero aryl basis chart [wa] It does;  However, hetero aryl alkyl group and hetero ant As for hetero aryl part of [ruokishiarukiru] [pirijini] [ru], [pirimijiniru] and [chieniru], frill or in pyro rill basis To be, as for the hetero aryl part of the hetero aryl oxy basis To be the [pirijiniru] or [pirimijiniru] basis, hetero aryl As for basis [pirijiniru], [pirimijiniru], [pirajiniru] and [piridaji] [niru], [toriajiniru], [tetorajiniru], [chieniru] and [kinori] [niru], [isokinoriniru], [kinokisariniru] or benzo thio To be phenyl group, as for the substituent of the substitution alkyl group [hidoroki] The group which consists of [shi], halogen and the alkoxy carbonyl group? And others it is something which is chosen;  Substitution alkoxy group, substitution [shikuro] Substituent of alkyl group and substitution [shikuroarukiruarukiru]  Halogen, it consists of hydroxy and C [1-4] alkoxy group It is something which is chosen from the group;  Substituent of substitution [arukiniru] basis It is phenyl group;  As for substituent of substitution [arukeniru] basis [hue] [niru], frill, it is the [chieniru] or [pirijiniru] basis;  It substitutes Phenyl alkyl group and substitution phenoxy alkyl group, substitution Phenyl group and substitution phenyl alkoxy group, substitution [huenoki] Like substituent of phenyl part of [shi] basis and substitution phenyl azo basis In [bi] substitution hetero aryl alkyl group, substitution [heteroari] [ruokishiarukiru] , substitution hetero aryl basis and substitution [he] As for substituent of hetero aryl part of terrorist aryl oxy basis The respective halogen, hydroxy and C [1-4] alkyl, C [1-4] [a] [rukokishi] and halo (C [1-4]) alkyl, halo (C [1-4]) [aruko] [kishi], C [1-4] alkyl thio, C [1-4] alkoxy (C [1-4]) Al To kill, C [3-6] [shikuroarukiru] and C [3-6] [shikuroarukiru] (C [1-4]) alkyl, phenyl and phenoxy, phenyl (C [1-4]) alkyl and phenyl (C [1-4]) alkoxy, [hue] [nokishi] (C [1-4]) alkyl and acetyl oxy, benzoyl Oxy, cyano and thio cyanate and nitro, - NR ' R ", - NHCOR ', - NHCONR ' R ", - CONR ' R ", - C OOR ", - OSO [2] R ', - SO [2] R ', - COR ', - CR ' =NR " and [bi] - N=CR ' R &amp; basis (R in formula ' and R " the aforementioned meaning It possesses) to be something which is chosen from the group which consists of;  In addition R (1) And R (2) both to be the methyl group together, A with the sulfur atom a At the same time the [ri], W has adjoined to A, when Z is the oxygen atom, X, Y or as for Z (1) there are no times when everything is the hydrogen atom, In addition the next formula: (In formula, R is the hydrogen atom or the methyl group) chemical compound It excludes} with the chemical compound which is displayed and that solid Manufacturing method of isomer.  9. As a active ingredient, formula (i):  (In formula, as for W R (1) O [2] C-C=CH-ZR (2) (however, R (1) and R as for (2) it is identical So it is possible to differ and respective alkyl or [huruoru] To display the alkyl group, as for Z the oxygen or sulfur atom the chart [wa] It does) displaying;  As for A oxygen or sulfur atom, or - NR (3)- Displaying basis;  X, Y and Z (1) being identical, even when is possible and to differ, The respective hydrogen or halogen atom, or hydroxy, Non substitution or substitution alkyl, non substitution or substitution [shikuroaruki] [ru], non substitution or substitution [shikuroarukiruarukiru], non substitution and Substitution phenyl alkyl, non substitution or substitution [heteroari] [ruarukiru], non substitution or substitution phenoxy alkyl, non position Exchanging or substitution hetero aryl oxy alkyl, non substitution or Substitution [arukeniru], non substitution or substitution [arukiniru], non substitution and Substitution phenyl, non substitution or substitution hetero aryl, non position Exchanging or substitution alkoxy, non substitution or substitution [hueniruaruko] [kishi], non substitution or substitution phenoxy, non substitution or substitution [hete] Lower reel oxy and acetyl oxy, [benzoiruoki] [shi], - NR ' R ", - NHCOR ', non substitution or substitution phenyl Azo, nitro, cyano, - CO [2] R (6), - CONR (7) R (8), - COR (9), - CR =NR (10), - CR=NOR (10) or - N=CR (11) R (12) the basis is displayed or, or the basis As for X and Y, when those is contiguity position with respect to ring, when Connecting mutually depending upon, it forms condensation benzene ring;  R ' And R " the respective hydrogen atom, C [1-4] alkyl, C [1-4] Al [kokishi], C [1-4] alkyl thio, C [3-6] [shikuroarukiru], C [3-6] [shikuroarukiru] (C [1-4]) alkyl, phenyl or [benji] To be the [ru] basis, as for the said phenyl group and the benzyl basis halogen, Being substituted with C [1-4] alkyl or C [1-4] alkoxy group Good;  R, R (3), R (6), R (7), R (8), R (9), R (10), R (11) and R (12) it is identical So it is possible to differ and the respective hydrogen atom, non substitution or Substitution alkyl, non substitution or substitution [shikuroarukiru], non substitution Or substitution [shikuroarukiruarukiru], non substitution or substitution [hue] [niruarukiru], non substitution or substitution [heteroariruaruki] [ru], non substitution or substitution phenoxy alkyl, non substitution or position Exchanging hetero aryl oxy alkyl, non substitution or substitution Al [keniru], non substitution or substitution [arukiniru], non substitution or substitution [hu] [eniru] or non substitution or substitution hetero aryl basis chart [wa] It does;  However, hetero aryl alkyl group and hetero ant As for hetero aryl part of [ruokishiarukiru] [pirijini] [ru], [pirimijiniru] and [chieniru], frill or in pyro rill basis To be, as for the hetero aryl part of the hetero aryl oxy basis To be the [pirijiniru] or [pirimijiniru] basis, hetero aryl As for basis [pirijiniru], [pirimijiniru], [pirajiniru] and [piridaji] [niru], [toriajiniru], [tetorajiniru], [chieniru] and [kinori] [niru], [isokinoriniru], [kinokisariniru] or benzo thio It is phenyl group;  As for substituent of substitution alkyl group [hidoroki] The group which consists of [shi], halogen and the alkoxy carbonyl group? And others it is something which is chosen;  Substitution alkoxy group, substitution [shikuro] Substituent of alkyl group and substitution [shikuroarukiruarukiru]  Halogen, it consists of hydroxy and C [1-4] alkoxy group It is something which is chosen from the group;  Substituent of substitution [arukiniru] basis It is phenyl group;  As for substituent of substitution [arukeniru] basis [hue] [niru], frill, it is the [chieniru] or [pirijiniru] basis;  It substitutes Phenyl alkyl group and substitution phenoxy alkyl group, substitution Phenyl group and substitution phenyl alkoxy group, substitution [huenoki] Like substituent of phenyl part of [shi] basis and substitution phenyl azo basis In [bi] substitution hetero aryl alkyl group, substitution [heteroari] [ruokishiarukiru] , substitution hetero aryl basis and substitution [he] As for substituent of hetero aryl part of terrorist aryl oxy basis The respective halogen, hydroxy and C [1-4] alkyl, C [1-4] [a] [rukokishi] and halo (C [1-4]) alkyl, halo (C [1-4]) [aruko] [kishi], C [1-4] alkyl thio, C [1-4] alkoxy (C [1-4]) Al To kill, C [3-6] [shikuroarukiru] and C [3-6] [shikuroarukiru] (C [1-4]) alkyl, phenyl and phenoxy, phenyl (C [1-4]) alkyl and phenyl (C [1-4]) alkoxy, [hue] [nokishi] (C [1-4]) alkyl and acetyl oxy, benzoyl Oxy, cyano and thio cyanate and nitro, - NR ' R ", - NHCOR ', - NHCONR ' R ", - CONR ' R ", - C OOR ", - OSO [2] R ', - SO [2] R ', - COR ', - CR ' =NR " and [bi] - N=CR ' R &amp; basis (R in formula ' and R " the aforementioned meaning It possesses) to be something which is chosen from the group which consists of;  In addition R (1) And R (2) both to be the methyl group together, A with the sulfur atom a At the same time the [ri], W has adjoined to A, when Z is the oxygen atom, X, Y or as for Z (1) there are no times when everything is the hydrogen atom, In addition the next formula:  (In formula, R is the hydrogen atom or the methyl group) chemical compound It excludes} with the chemical compound which is displayed or the stand Containing the effective quantity of body isomer, the bactericide composition which becomes.
法律状态
(JP2591743) LEGAL DETAILS FOR JPS62258344  Actual or expected expiration date=2007-04-17    Legal state=DEAD    Status=EXPIRED     Event publication date=1987-04-17  Event code=JP/APP  Event indicator=Pos  Event type=Examination events  Application details  Application country=JP JP9347787  Application date=1987-04-17  Standardized application number=1987JP-0093477     Event publication date=1987-11-10  Event code=JP/A  Event indicator=Pos  Event type=Examination events  Published application  Publication country=JP  Publication number=JPS62258344  Publication stage Code=A  Publication date=1987-11-10  Standardized publication number=JP62258344     Event publication date=1997-03-19  Event code=JP/B2  Event indicator=Pos  Event type=Event indicating In Force  Published granted patent (Second level)  from 01-03-1996 onwards (Published examined patent application (Second level) 1971-1996)  Publication country=JP  Publication number=JP2591743  Publication stage Code=B2  Publication date=1997-03-19  Standardized publication number=JP2591743     Event publication date=2007-04-17  Event code=JP/EEDX  Event indicator=Neg  Event type=Event indicating Not In Force  Patent has expired
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AB2
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