(JP2591743) 1. Formula (i): (In formula, as for W R (1) O [2] C-C=CH-ZR (2) (however, R (1) and R as for (2) it is identical So it is possible to differ and respective alkyl or [huruoru] To display the alkyl group, as for Z the oxygen or sulfur atom the chart [wa] It does) displaying; As for A oxygen or sulfur atom, or - NR (3)- Displaying basis; X, Y and Z (1) being identical, even when is possible and to differ, The respective hydrogen or halogen atom, or hydroxy, Non substitution or substitution alkyl, non substitution or substitution [shikuroaruki] [ru], non substitution or substitution [shikuroarukiruarukiru], non substitution and Substitution phenyl alkyl, non substitution or substitution [heteroari] [ruarukiru], non substitution or substitution phenoxy alkyl, non position Exchanging or substitution hetero aryl oxy alkyl, non substitution or Substitution [arukeniru], non substitution or substitution [arukiniru], non substitution and Substitution phenyl, non substitution or substitution hetero aryl, non position Exchanging or substitution alkoxy, non substitution or substitution [hueniruaruko] [kishi], non substitution or substitution phenoxy, non substitution or substitution [hete] Lower reel oxy and acetyl oxy, [benzoiruoki] [shi], - NR ' R ", - NHCOR ', non substitution or substitution phenyl Azo, nitro, cyano, - CO [2] R (6), - CONR (7) R (8), - COR (9), - CR =NR (10), - CR=NOR (10) or - N=CR (11) R (12) the basis is displayed or, or the basis As for X and Y, when those is contiguity position with respect to ring, when Connecting mutually depending upon, it forms condensation benzene ring; R ' And R " the respective hydrogen atom, C [1-4] alkyl, C [1-4] Al [kokishi], C [1-4] alkyl thio, C [3-6] [shikuroarukiru], C [3-6] [shikuroarukiru] (C [1-4]) alkyl, phenyl or [benji] To be the [ru] basis, as for the said phenyl group and the benzyl basis halogen, Being substituted with C [1-4] alkyl or C [1-4] alkoxy group Good; R, R (3), R (6), R (7), R (8), R (9), R (10), R (11) and R (12) it is identical So it is possible to differ and the respective hydrogen atom, non substitution or Substitution alkyl, non substitution or substitution [shikuroarukiru], non substitution Or substitution [shikuroarukiruarukiru], non substitution or substitution [hue] [niruarukiru], non substitution or substitution [heteroariruaruki] [ru], non substitution or substitution phenoxy alkyl, non substitution or position Exchanging hetero aryl oxy alkyl, non substitution or substitution Al [keniru], non substitution or substitution [arukiniru], non substitution or substitution [hu] [eniru] or non substitution or substitution hetero aryl basis chart [wa] It does; However, hetero aryl alkyl group and hetero ant As for hetero aryl part of [ruokishiarukiru] [pirijini] [ru], [pirimijiniru] and [chieniru], frill or in pyro rill basis To be, as for the hetero aryl part of the hetero aryl oxy basis To be the [pirijiniru] or [pirimijiniru] basis, hetero aryl As for basis [pirijiniru], [pirimijiniru], [pirajiniru] and [piridaji] [niru], [toriajiniru], [tetorajiniru], [chieniru] and [kinori] [niru], [isokinoriniru], [kinokisariniru] or benzo thio It is phenyl group; As for substituent of substitution alkyl group [hidoroki] The group which consists of [shi], halogen and the alkoxy carbonyl group? And others it is something which is chosen; Substitution alkoxy group, substitution [shikuro] Substituent of alkyl group and substitution [shikuroarukiruarukiru] Halogen, it consists of hydroxy and C [1-4] alkoxy group It is something which is chosen from the group; Substituent of substitution [arukiniru] basis It is phenyl group; As for substituent of substitution [arukeniru] basis [hue] [niru], frill, it is the [chieniru] or [pirijiniru] basis; It substitutes Phenyl alkyl group and substitution phenoxy alkyl group, substitution Phenyl group and substitution phenyl alkoxy group, substitution [huenoki] Like substituent of phenyl part of [shi] basis and substitution phenyl azo basis In [bi] substitution hetero aryl alkyl group, substitution [heteroari] [ruokishiarukiru] , substitution hetero aryl basis and substitution [he] As for substituent of hetero aryl part of terrorist aryl oxy basis The respective halogen, hydroxy and C [1-4] alkyl, C [1-4] [a] [rukokishi] and halo (C [1-4]) alkyl, halo (C [1-4]) [aruko] [kishi], C [1-4] alkyl thio, C [1-4] alkoxy (C [1-4]) Al To kill, C [3-6] [shikuroarukiru] and C [3-6] [shikuroarukiru] (C [1-4]) alkyl, phenyl and phenoxy, phenyl (C [1-4]) alkyl and phenyl (C [1-4]) alkoxy, [hue] [nokishi] (C [1-4]) alkyl and acetyl oxy, benzoyl Oxy, cyano and thio cyanate and nitro, - NR ' R ", - NHCOR ', - NHCONR ' R ", - CONR ' R ", - C OOR ", - OSO [2] R ', - SO [2] R ', - COR ', - CR ' =NR " and [bi] - N=CR ' R & basis (R in formula ' and R " the aforementioned meaning It possesses) to be something which is chosen from the group which consists of; In addition R (1) And R (2) both to be the methyl group together, A with the sulfur atom a At the same time the [ri], W has adjoined to A, when Z is the oxygen atom, X, Y or as for Z (1) there are no times when everything is the hydrogen atom, In addition the next formula: (In formula, R is the hydrogen atom or the methyl group) chemical compound It excludes} with the chemical compound which is displayed and that solid Isomer. 2. X, Y and Z as for (1) hydrogen and halogen, C [1-4] Al To kill, phenyl (C [1-4]) alkyl and hetero aryl (C [1-4]) Alkyl and hetero aryl oxy (C [1-4]) [aruki] [ru], hetero aryl oxy, phenoxy (C [1-4]) [aruki] [ru], C [1-4] alkoxy and phenyl (C [1-4]) alkoxy, [hu] [enokishi], phenyl (C [2-4]) [arukeniru], [heteroari] [ru] (C [2-4]) [arukeniru], phenyl (C [2-4]) [arukiniru], Hetero aryl (C [2-4]) [arukiniru], cyano, (C [1-4]) From alkoxy carbonyl and phenoxy carbonyl To be the atom or the basis which is chosen from the group which becomes, at that time X, Y and Z (1) one to be the atom or the basis other than hydrogen and with respect to complex ring Example of the patent claim which is something which exists in the position where it adjoins to the basis W Chemical compound of surrounding 1st section statement. 3. R (1) and R the patent claim to which (2) together is the methyl group Chemical compound of range 1st section statement. 4. Formula: (In formula, as for X there is a position where it adjoins to the acrylate basis and Halogen, C [1-4] alkyl, halo (C [1-4]) alkyl, [hue] [niru] (C [1-4]) alkyl, phenoxy (C [1-4]) alkyl, Phenyl (C [2-4]) [arukeniru], phenoxy or acyl basis You display) with the range of the patent claim which is the chemical compound which is displayed Chemical compound of 1 section statements. 5. Formula: (In formula, R as for (3) hydrogen atom, C [1-4] alkyl or aryl (C [1-4]) To display the alkyl group, as for X the hydrogen atom, C [1-4] [aruki] [ru], phenyl (C [1-4]) alkyl and phenyl (C [2-4]) Al To display the [keniru] or acyl basis, and Y and Z as for (1) that [re] hydrogen is displayed, or when or X displays hydrogen, Y And Z (1) forms condensation benzene ring together) with displaying The chemical compound of range 1st section statement of the patent claim which is [ru] chemical compound. 6. Formula: Keto ester in solvent PH [3] P (+<HAN>, </HAN>-) CH (ZR (2)) (in formula, as for PH Phenyl group is displayed, Z and R (2) has the below-mentioned meaning) - phospho run with process do thing from become, system (i): (In formula, as for W R (1) O [2] C-C=CH-ZR (2) (however, R (1) and R as for (2) it is identical So it is possible to differ and respective alkyl or [huruoru] To display the alkyl group, as for Z the oxygen or sulfur atom the chart [wa] It does) displaying; As for A oxygen or sulfur atom, or - NR (3)- Displaying basis; X, Y and Z (1) being identical, even when is possible and to differ, The respective hydrogen or halogen atom, or hydroxy, Non substitution or substitution alkyl, non substitution or substitution [shikuroaruki] [ru], non substitution or substitution [shikuroarukiruarukiru], non substitution and Substitution phenyl alkyl, non substitution or substitution [heteroari] [ruarukiru], non substitution or substitution phenoxy alkyl, non position Exchanging or substitution hetero aryl oxy alkyl, non substitution or Substitution [arukeniru], non substitution or substitution [arukiniru], non substitution and Substitution phenyl, non substitution or substitution hetero aryl, non position Exchanging or substitution alkoxy, non substitution or substitution [hueniruaruko] [kishi], non substitution or substitution phenoxy, non substitution or substitution [hete] Lower reel oxy and acetyl oxy, [benzoiruoki] [shi], - NR ' R ", - NHCOR ' -, non substitution or substitution [hueni] [ruazo], nitro, cyano, - CO [2] R (6), - CONR (7) R (8), - COR (9), - CR=NR (10), - CR=NOR (10) or - N=CR (11) R (12) the basis is displayed or, or As for the basis X and Y, when those is contiguity position with respect to ring, the place Connecting mutually depending upon combination, it forms condensation benzene ring; R ' and R " the respective hydrogen atom, C [1-4] alkyl, C [1-4] Alkoxy, C [1-4] alkyl thio, C [3-6] [shikuroarukiru], C [3-6] [shikuroarukiru] (C [1-4]) alkyl, phenyl or [be] To be the [njiru] basis, as for the said phenyl group and the benzyl basis [haroge] [n], it is substituted with C [1-4] alkyl or C [1-4] alkoxy group, [te] good; R, R (3), R (6), R (7), R (8), R (9), R (10), R (11) and R (12) Being identical, even when it is possible and the respective hydrogen atom, non substitution to differ, Or substitution alkyl, non substitution or substitution [shikuroarukiru], fault Substitution or substitution [shikuroarukiruarukiru], non substitution or substitution Phenyl alkyl, non substitution or substitution hetero aryl Al To kill, non substitution or substitution phenoxy alkyl, non substitution or Substitution hetero aryl oxy alkyl, non substitution or substitution [a] [rukeniru], non substitution or substitution [arukiniru], non substitution or substitution Phenyl or non substitution or substitution hetero aryl basis chart The [wa] it does; However, hetero aryl alkyl group and [heteroa] As for hetero aryl part of reel oxy alkyl group [piriji] [niru], [pirimijiniru] and [chieniru], frill or pyro rill basis So to be, the hetero aryl part of the hetero aryl oxy basis To be the [pirijiniru] or [pirimijiniru] basis, [heteroari] As for [ru] basis [pirijiniru], [pirimijiniru], [pirajiniru] and [pirida] [jiniru], [toriajiniru], [tetorajiniru], [chieniru] and [kino] [riniru], [isokinoriniru], [kinokisariniru] or [benzochi] It is [ohueniru] ; As for substituent of substitution alkyl group hydro The group which consists of [kishi], halogen and the alkoxy carbonyl group From it is something which is chosen; Substitution alkoxy group, substitution [shiku] Substitution of [roarukiru] and substitution [shikuroarukiruarukiru] As for basis halogen, from hydroxy and C [1-4] alkoxy group It is something which is chosen from the [ru] group; Substitution of substitution [arukiniru] basis The basis is phenyl group; As for substituent of substitution [arukeniru] basis [hu] [eniru], frill, it is the [chieniru] or [pirijiniru] basis; Position Exchanging phenyl alkyl group and substitution phenoxy alkyl group, position Exchanging phenyl group and substitution phenyl alkoxy group, substitution [hueno] Substituent of phenyl part of [kishi] basis and substitution phenyl azo basis And substitution hetero aryl alkyl group, substitution hetero ant [ruokishiarukiru] , substitution hetero aryl basis and substitution Substituent of hetero aryl part of hetero aryl oxy basis The respective halogen, hydroxy and C [1-4] alkyl, C [1-4] Alkoxy and halo (C [1-4]) alkyl, halo (C [1-4]) Al [kokishi], C [1-4] alkyl thio, C [1-4] alkoxy (C [1-4]) [a] [rukiru], C [3-6] [shikuroarukiru] and C [3-6] [shikuroarukiru] (C [1-4]) Alkyl, phenyl and phenoxy, phenyl (C [1-4]) Alkyl and phenyl (C [1-4]) alkoxy, [hueno] [kishi] (C [1-4]) alkyl and acetyl oxy, [benzoiruo] [kishi], cyano and thio cyanate and nitro, - NR ' R ", - NHCOR ', - NHCONR ' R ", - CONR ' R ", - COO R ", - OSO [2] R ', - SO [2] R ', - COR ', - CR ' =NR " and - N=CR ' R & basis (R in formula ' and R " the aforementioned meaning It possesses) to be something which is chosen from the group which consists of; In addition R (1) and [bi] R (2) both to be the methyl group together, A with the sulfur atom a At the same time the [ri], W has adjoined to A, when Z is the oxygen atom, X, Y or as for Z (1) there are no times when everything is the hydrogen atom, In addition the next formula: (In formula, R is the hydrogen atom or the methyl group) chemical compound It excludes} with the chemical compound which is displayed and that solid Manufacturing method of isomer. 7. Formula: Processing the acetal under acidic or basic condition, said [ase] From tar that alcohol R (2) ZH (in formula, Z and R as for (2) description below It possesses meaning) it consists of the fact that it is disconnected the part, formula (i): (In formula, as for W R (1) O [2] C-C=CH-ZR (2) (however, R (1) and R as for (2) it is identical So it is possible to differ and respective alkyl or [huruoru] To display the alkyl group, as for Z the oxygen or sulfur atom the chart [wa] It does) displaying; As for A oxygen or sulfur atom, or - NR (3)- Displaying basis; X, Y and Z (1) being identical, even when is possible and to differ, The respective hydrogen or halogen atom, or hydroxy, Non substitution or substitution alkyl, non substitution or substitution [shikuroaruki] [ru], non substitution or substitution [shikuroarukiruarukiru], non substitution and Substitution phenyl alkyl, non substitution or substitution [heteroari] [ruarukiru], non substitution or substitution phenoxy alkyl, non position Exchanging or substitution hetero aryl oxy alkyl, non substitution or Substitution [arukeniru], non substitution or substitution [arukiniru], non substitution and Substitution phenyl, non substitution or substitution hetero aryl, non position Exchanging or substitution alkoxy, non substitution or substitution [hueniruaruko] [kishi], non substitution or substitution phenoxy, non substitution or substitution [hete] Lower reel oxy and acetyl oxy, [benzoiruoki] [shi], - NR ' R ", - NHCOR ', non substitution or substitution phenyl Azo, nitro, cyano, - CO [2] R (6), - CONR (7) R (8), - COR (9), - CR =NR (10), - CR=NOR (10) or - N=CR (11) R (12) the basis is displayed or, or the basis As for X and Y, when those is contiguity position with respect to ring, when Connecting mutually depending upon, it forms condensation benzene ring; R ' And R " the respective hydrogen atom, C [1-4] alkyl, C [1-4] Al [kokishi], C [1-4] alkyl thio, C [3-6] [shikuroarukiru], C [3-6] [shikuroarukiru] (C [1-4]) alkyl, phenyl or [benji] To be the [ru] basis, as for the said phenyl group and the benzyl basis halogen, Being substituted with C [1-4] alkyl or C [1-4] alkoxy group Good; R, R (3), R (6), R (7), R (8), R (9), R (10), R (11) and R (12) it is identical So it is possible to differ and the respective hydrogen atom, non substitution or Substitution alkyl, non substitution or substitution [shikuroarukiru], non substitution Or substitution [shikuroarukiruarukiru], non substitution or substitution [hue] [niruarukiru], non substitution or substitution [heteroariruaruki] [ru], non substitution or substitution phenoxy alkyl, non substitution or position Exchanging hetero aryl oxy alkyl, non substitution or substitution Al [keniru], non substitution or substitution [arukiniru], non substitution or substitution [hu] [eniru] or non substitution or substitution hetero aryl basis chart [wa] It does; However, hetero aryl alkyl group and hetero ant As for hetero aryl part of [ruokishiarukiru] [pirijini] [ru], [pirimijiniru] and [chieniru], frill or in pyro rill basis To be, as for the hetero aryl part of the hetero aryl oxy basis To be the [pirijiniru] or [pirimijiniru] basis, hetero aryl As for basis [pirijiniru], [pirimijiniru], [pirajiniru] and [piridaji] [niru], [toriajiniru], [tetorajiniru], [chieniru] and [kinori] [niru], [isokinoriniru], [kinokisariniru] or benzo thio It is phenyl group; As for substituent of substitution alkyl group [hidoroki] The group which consists of [shi], halogen and the alkoxy carbonyl group? And others it is something which is chosen; Substitution alkoxy group, substitution [shikuro] Substituent of alkyl group and substitution [shikuroarukiruarukiru] Halogen, it consists of hydroxy and C [1-4] alkoxy group It is something which is chosen from the group; Substituent of substitution [arukiniru] basis It is phenyl group; As for substituent of substitution [arukeniru] basis [hue] [niru], frill, it is the [chieniru] or [pirijiniru] basis; It substitutes Phenyl alkyl group and substitution phenoxy alkyl group, substitution Phenyl group and substitution phenyl alkoxy group, substitution [huenoki] Like substituent of phenyl part of [shi] basis and substitution phenyl azo basis In [bi] substitution hetero aryl alkyl group, substitution [heteroari] [ruokishiarukiru] , substitution hetero aryl basis and substitution [he] As for substituent of hetero aryl part of terrorist aryl oxy basis The respective halogen, hydroxy and C [1-4] alkyl, C [1-4] [a] [rukokishi] and halo (C [1-4]) alkyl, halo (C [1-4]) [aruko] [kishi], C [1-4] alkyl thio, C [1-4] alkoxy (C [1-4]) Al To kill, C [3-6] [shikuroarukiru] and C [3-6] [shikuroarukiru] (C [1-4]) alkyl, phenyl and phenoxy, phenyl (C [1-4]) alkyl and phenyl (C [1-4]) alkoxy, [hue] [nokishi] (C [1-4]) alkyl and acetyl oxy, benzoyl Oxy, cyano and thio cyanate and nitro, - NR ' R ", - NHCOR ', - NHCONR ' R ", - CONR ' R ", - C OOR ", - OSO [2] R ', - SO [2] R ', - COR ', - CR ' =NR " and [bi] - N=CR ' R & basis (R in formula ' and R " the aforementioned meaning It possesses) to be something which is chosen from the group which consists of; In addition R (1) And R (2) both to be the methyl group together, A with the sulfur atom a At the same time the [ri], W has adjoined to A, when Z is the oxygen atom, X, Y or as for Z (1) there are no times when everything is the hydrogen atom, In addition the next formula: (In formula, R is the hydrogen atom or the methyl group) chemical compound It excludes} with the chemical compound which is displayed and that solid Manufacturing method of isomer. 8. Formula: (In formula, R (13) the hydrogen atom or the metal atom is displayed) chemical combination When the thing, R (13) it is the metal atom, R (2) Q (in formula, R as for (2) under It possesses the meaning of description, the disconnection basis it is displayed) processes Q in chemical kind It does, when R (13) it is the hydrogen atom, the base and chemical kind R (2) with Q It consists of the fact that it processes consecutively, formula (i): (In formula, as for W R (1) O [2] C-C=CH-ZR (2) (however, R (1) and R as for (2) it is identical So it is possible to differ and respective alkyl or [huruoru] To display the alkyl group, as for Z the oxygen or sulfur atom the chart [wa] It does) displaying; As for A oxygen or sulfur atom, or - NR (3)- Displaying basis; X, Y and Z (1) being identical, even when is possible and to differ, The respective hydrogen or halogen atom, or hydroxy, Non substitution or substitution alkyl, non substitution or substitution [shikuroaruki] [ru], non substitution or substitution [shikuroarukiruarukiru], non substitution and Substitution phenyl alkyl, non substitution or substitution [heteroari] [ruarukiru], non substitution or substitution phenoxy alkyl, non position Exchanging or substitution hetero aryl oxy alkyl, non substitution or Substitution [arukeniru], non substitution or substitution [arukiniru], non substitution and Substitution phenyl, non substitution or substitution hetero aryl, non position Exchanging or substitution alkoxy, non substitution or substitution [hueniruaruko] [kishi], non substitution or substitution phenoxy, non substitution or substitution [hete] Lower reel oxy and acetyl oxy, [benzoiruoki] [shi], - NR ' R ", - NHCOR ', non substitution or substitution phenyl Azo, nitro, cyano, - CO [2] R (6), - CONR (7) R (8), - COR (9), - CR =NR (10), - CR=NOR (10) or - N=CR (11) R (12) the basis is displayed or, or the basis As for X and Y, when those is contiguity position with respect to ring, when Connecting mutually depending upon, it forms condensation benzene ring; R ' And R " the respective hydrogen atom, C [1-4] alkyl, C [1-4] Al [kokishi], C [1-4] alkyl thio, C [3-6] [shikuroarukiru], C [3-6] [shikuroarukiru] (C [1-4]) alkyl, phenyl or [benji] To be the [ru] basis, as for the said phenyl group and the benzyl basis halogen, Being substituted with C [1-4] alkyl or C [1-4] alkoxy group Good; R, R (3), R (6), R (7), R (8), R (9), R (10), R (11) and R (12) it is identical So it is possible to differ and the respective hydrogen atom, non substitution or Substitution alkyl, non substitution or substitution [shikuroarukiru], non substitution Or substitution [shikuroarukiruarukiru], non substitution or substitution [hue] [niruarukiru], non substitution or substitution [heteroariruaruki] [ru], non substitution or substitution phenoxy alkyl, non substitution or position Exchanging hetero aryl oxy alkyl, non substitution or substitution Al [keniru], non substitution or substitution [arukiniru], non substitution or substitution [hu] [eniru] or non substitution or substitution hetero aryl basis chart [wa] It does; However, hetero aryl alkyl group and hetero ant As for hetero aryl part of [ruokishiarukiru] [pirijini] [ru], [pirimijiniru] and [chieniru], frill or in pyro rill basis To be, as for the hetero aryl part of the hetero aryl oxy basis To be the [pirijiniru] or [pirimijiniru] basis, hetero aryl As for basis [pirijiniru], [pirimijiniru], [pirajiniru] and [piridaji] [niru], [toriajiniru], [tetorajiniru], [chieniru] and [kinori] [niru], [isokinoriniru], [kinokisariniru] or benzo thio To be phenyl group, as for the substituent of the substitution alkyl group [hidoroki] The group which consists of [shi], halogen and the alkoxy carbonyl group? And others it is something which is chosen; Substitution alkoxy group, substitution [shikuro] Substituent of alkyl group and substitution [shikuroarukiruarukiru] Halogen, it consists of hydroxy and C [1-4] alkoxy group It is something which is chosen from the group; Substituent of substitution [arukiniru] basis It is phenyl group; As for substituent of substitution [arukeniru] basis [hue] [niru], frill, it is the [chieniru] or [pirijiniru] basis; It substitutes Phenyl alkyl group and substitution phenoxy alkyl group, substitution Phenyl group and substitution phenyl alkoxy group, substitution [huenoki] Like substituent of phenyl part of [shi] basis and substitution phenyl azo basis In [bi] substitution hetero aryl alkyl group, substitution [heteroari] [ruokishiarukiru] , substitution hetero aryl basis and substitution [he] As for substituent of hetero aryl part of terrorist aryl oxy basis The respective halogen, hydroxy and C [1-4] alkyl, C [1-4] [a] [rukokishi] and halo (C [1-4]) alkyl, halo (C [1-4]) [aruko] [kishi], C [1-4] alkyl thio, C [1-4] alkoxy (C [1-4]) Al To kill, C [3-6] [shikuroarukiru] and C [3-6] [shikuroarukiru] (C [1-4]) alkyl, phenyl and phenoxy, phenyl (C [1-4]) alkyl and phenyl (C [1-4]) alkoxy, [hue] [nokishi] (C [1-4]) alkyl and acetyl oxy, benzoyl Oxy, cyano and thio cyanate and nitro, - NR ' R ", - NHCOR ', - NHCONR ' R ", - CONR ' R ", - C OOR ", - OSO [2] R ', - SO [2] R ', - COR ', - CR ' =NR " and [bi] - N=CR ' R & basis (R in formula ' and R " the aforementioned meaning It possesses) to be something which is chosen from the group which consists of; In addition R (1) And R (2) both to be the methyl group together, A with the sulfur atom a At the same time the [ri], W has adjoined to A, when Z is the oxygen atom, X, Y or as for Z (1) there are no times when everything is the hydrogen atom, In addition the next formula: (In formula, R is the hydrogen atom or the methyl group) chemical compound It excludes} with the chemical compound which is displayed and that solid Manufacturing method of isomer. 9. As a active ingredient, formula (i): (In formula, as for W R (1) O [2] C-C=CH-ZR (2) (however, R (1) and R as for (2) it is identical So it is possible to differ and respective alkyl or [huruoru] To display the alkyl group, as for Z the oxygen or sulfur atom the chart [wa] It does) displaying; As for A oxygen or sulfur atom, or - NR (3)- Displaying basis; X, Y and Z (1) being identical, even when is possible and to differ, The respective hydrogen or halogen atom, or hydroxy, Non substitution or substitution alkyl, non substitution or substitution [shikuroaruki] [ru], non substitution or substitution [shikuroarukiruarukiru], non substitution and Substitution phenyl alkyl, non substitution or substitution [heteroari] [ruarukiru], non substitution or substitution phenoxy alkyl, non position Exchanging or substitution hetero aryl oxy alkyl, non substitution or Substitution [arukeniru], non substitution or substitution [arukiniru], non substitution and Substitution phenyl, non substitution or substitution hetero aryl, non position Exchanging or substitution alkoxy, non substitution or substitution [hueniruaruko] [kishi], non substitution or substitution phenoxy, non substitution or substitution [hete] Lower reel oxy and acetyl oxy, [benzoiruoki] [shi], - NR ' R ", - NHCOR ', non substitution or substitution phenyl Azo, nitro, cyano, - CO [2] R (6), - CONR (7) R (8), - COR (9), - CR =NR (10), - CR=NOR (10) or - N=CR (11) R (12) the basis is displayed or, or the basis As for X and Y, when those is contiguity position with respect to ring, when Connecting mutually depending upon, it forms condensation benzene ring; R ' And R " the respective hydrogen atom, C [1-4] alkyl, C [1-4] Al [kokishi], C [1-4] alkyl thio, C [3-6] [shikuroarukiru], C [3-6] [shikuroarukiru] (C [1-4]) alkyl, phenyl or [benji] To be the [ru] basis, as for the said phenyl group and the benzyl basis halogen, Being substituted with C [1-4] alkyl or C [1-4] alkoxy group Good; R, R (3), R (6), R (7), R (8), R (9), R (10), R (11) and R (12) it is identical So it is possible to differ and the respective hydrogen atom, non substitution or Substitution alkyl, non substitution or substitution [shikuroarukiru], non substitution Or substitution [shikuroarukiruarukiru], non substitution or substitution [hue] [niruarukiru], non substitution or substitution [heteroariruaruki] [ru], non substitution or substitution phenoxy alkyl, non substitution or position Exchanging hetero aryl oxy alkyl, non substitution or substitution Al [keniru], non substitution or substitution [arukiniru], non substitution or substitution [hu] [eniru] or non substitution or substitution hetero aryl basis chart [wa] It does; However, hetero aryl alkyl group and hetero ant As for hetero aryl part of [ruokishiarukiru] [pirijini] [ru], [pirimijiniru] and [chieniru], frill or in pyro rill basis To be, as for the hetero aryl part of the hetero aryl oxy basis To be the [pirijiniru] or [pirimijiniru] basis, hetero aryl As for basis [pirijiniru], [pirimijiniru], [pirajiniru] and [piridaji] [niru], [toriajiniru], [tetorajiniru], [chieniru] and [kinori] [niru], [isokinoriniru], [kinokisariniru] or benzo thio It is phenyl group; As for substituent of substitution alkyl group [hidoroki] The group which consists of [shi], halogen and the alkoxy carbonyl group? And others it is something which is chosen; Substitution alkoxy group, substitution [shikuro] Substituent of alkyl group and substitution [shikuroarukiruarukiru] Halogen, it consists of hydroxy and C [1-4] alkoxy group It is something which is chosen from the group; Substituent of substitution [arukiniru] basis It is phenyl group; As for substituent of substitution [arukeniru] basis [hue] [niru], frill, it is the [chieniru] or [pirijiniru] basis; It substitutes Phenyl alkyl group and substitution phenoxy alkyl group, substitution Phenyl group and substitution phenyl alkoxy group, substitution [huenoki] Like substituent of phenyl part of [shi] basis and substitution phenyl azo basis In [bi] substitution hetero aryl alkyl group, substitution [heteroari] [ruokishiarukiru] , substitution hetero aryl basis and substitution [he] As for substituent of hetero aryl part of terrorist aryl oxy basis The respective halogen, hydroxy and C [1-4] alkyl, C [1-4] [a] [rukokishi] and halo (C [1-4]) alkyl, halo (C [1-4]) [aruko] [kishi], C [1-4] alkyl thio, C [1-4] alkoxy (C [1-4]) Al To kill, C [3-6] [shikuroarukiru] and C [3-6] [shikuroarukiru] (C [1-4]) alkyl, phenyl and phenoxy, phenyl (C [1-4]) alkyl and phenyl (C [1-4]) alkoxy, [hue] [nokishi] (C [1-4]) alkyl and acetyl oxy, benzoyl Oxy, cyano and thio cyanate and nitro, - NR ' R ", - NHCOR ', - NHCONR ' R ", - CONR ' R ", - C OOR ", - OSO [2] R ', - SO [2] R ', - COR ', - CR ' =NR " and [bi] - N=CR ' R & basis (R in formula ' and R " the aforementioned meaning It possesses) to be something which is chosen from the group which consists of; In addition R (1) And R (2) both to be the methyl group together, A with the sulfur atom a At the same time the [ri], W has adjoined to A, when Z is the oxygen atom, X, Y or as for Z (1) there are no times when everything is the hydrogen atom, In addition the next formula: (In formula, R is the hydrogen atom or the methyl group) chemical compound It excludes} with the chemical compound which is displayed or the stand Containing the effective quantity of body isomer, the bactericide composition which becomes.
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