Halogen alkyl methylene oxy phenyl substitution keto enol 机翻标题: 暂无翻译,请尝试点击翻译按钮。

源语言标题
(JP5840955) ハロゲンアルキルメチレンオキシフェニル​置換​ケトエノール​類
公开号/公开日
JP2012520242 A 2012-09-06 [JP2012520242]JP5840955 B2 2016-01-06 [JP5840955] / 2012-09-062016-01-06
申请号/申请日
2011JP-0553331 / 2010-03-05
发明人
Toshi shake Yunai Darling Thomas;Lohr Shiyutefuan;Franken Efua-Maria;Marusamu Olga;Fuerusute Arndt;Gerugensu Ulrich;Deitsugen Yang;Fuoihito Deita;Heuser-Hahn Isolde;Rosinger Christoph Ah Hiyu;Angelman Arufuretsudo;
申请人
BAYER CROPSCIENCE;
主分类号
IPC分类号
A01N-025/32A01N-035/06A01N-043/12A01N-043/36A01N-043/38A01N-043/90A01N-047/06A01P-007/04A01P-013/02C07C-049/733C07C-057/58C07C-059/64C07C-069/96C07C-235/36C07D-209/54C07D-307/94C07D-309/08C07D-309/14C07D-487/04C07D-491/107C07D-493/10C
摘要
(JP5840955) The invention relates to novel compounds of the formula (I), in which W, X, Y, Z and CKE are each as defined above, to several methods and intermediates for preparation thereof and to the use thereof as pesticides and/or herbicides.  The invention also relates to selective herbicidal compositions which comprise firstly haloalkylmethyleneoxyphenyl-substituted ketoenols and secondly a compound which improves crop plant compatibility.  The present invention further relates to the enhancement of the action of crop protection compositions comprising especially haloalkylmethyleneoxyphenyl-substituted ketoenols, by the addition of ammonium or phosphonium salts and optionally penetration enhancers, to the corresponding compositions, to methods for production thereof and to the use thereof in crop protection as insecticides and/or acaricides and/or for preventing undesired plant growth.  (From US8518985 B2)
机翻摘要
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地址
代理人
代理机构
;
优先权号
2009EP-0154888 2009-03-11 2010WO-EP01392 2010-03-05
主权利要求
(JP5840955)  1. Formula (i): (In the above-mentioned formula, W, hydrogen and chlorine, is methyl or ethyl;  X, chlorine, is methyl, ethyl, the methoxy or the ethoxy;  Y, hydrogen, is methyl or chlorine;  Z, basis [In formula, J1 and J2, becoming independent respectively, are hydrogen or fluorine, and, J3, is fluorine, chlorine or trifluoromethyl] So it is;  CKE, the below-mentioned basis It is one inside;  U, - CH2-, - CH2-CH2-, - [O]- ha So it is;  A, is hydrogen, or, in case of in each case one substitution - three is [C] -C -ARUKIRU or [C] -C -ARUKOKISHI-C -C -arukiru which are substituted with fluorine with when whether, or, when [shikuropuropiru], is cyclopentyl or [shikurohekishiru], and, formula (I-5) is chemical compound, fluorine -, chlorine -, bromine -, methyl -, ethyl -, [n]-puropiru -, isopropyl -, the methoxy -, the ethoxy -, trifluoromethyl -, one substitution - two it is the phenyl which is substituted [torihuruorometokishi] -, cyano - or with nitro with when;  B, hydrogen, is methyl or ethyl;  Or, A and B and the carbon atom which those have connected, [C] -C -SHIKUROARUKIRU of saturation (here, as for the ring member 1, are replaced with nitrogen, oxygen or the sulfur by when, in addition, said [shikuroarukiru], methyl -, ethyl -, methoxy methyl -, ethoxy methyl -, methoxy ethyl -, ethoxy ethyl -, trifluoromethyl -, the methoxy -, the ethoxy -, [puropokishi] -, [butokishi] -, the methoxy ethoxy -, the ethoxy ethoxy -, the allyl oxy -, one substitution or two is substituted [torihuruoroetokishi] - or with [shikuropuropirumetokishi] by when) to be, (here, as for the above-mentioned basis,Also it is possible) to be the nitrogen substituent;  Or, A and B and the carbon atom which those have connected, [C] -shikuroarukiru (here, as for said [shikuroarukiru], the [arukiridenjiiru] basis (here, as for the said [arukiridenjiiru] basis, are discontinued with 1 oxygen atoms by when) with, or, the alkylene dioxy basis (here, as for the said alkylene dioxy basis, 2 oxygen atoms which it has not adjoined directly are included due to when) with, with when being substituted, further ring of 5 members or 6 members (here, as for the said ring, one substitution or two it is possible to be substituted) forming with methylIt is) to be;  Or, A and B and the carbon atom which those have connected, [C] -C -SHIKUROARUKIRU or [C] -C -SHIKUROARUKENIRU (here, as for two substituents, the carbon atom which those have connected and together, are [C] -C -ARUKANJIIRU or [C] -C -ARUKENJIIRU or [butajienjiiru]) to be;  D, is hydrogen, or, in case of in each case one substitution - three it is [C] -C -ARUKIRU, [C] -C -ARUKENIRU or [C] -C -ARUKOKISHI-C -C -arukiru which are substituted with when whether, or, [shikuropuropiru], is cyclopentyl or [shikurohekishiru] with fluorine whether, or, when (formula (1-4) it is chemical compound,) in case of in each case fluorine -, chlorine -, methyl -, ethyl -, [n]-puropiru -, isopropyl -, the methoxy -, one it is phenyl or [pirijiru] which are substituted the ethoxy - or with trifluoromethyl with when;  Or, A and D together, methyl - or with the methoxy with when one [C] -C -ARUKANJIIRU which is substituted (here, as for 1 carbon atoms, when the carbonyl group (formula (I-11) it is not chemical compound only,), are replaced) are with oxygen or the sulfur with when or, or, the AD-1 basis: So it is;  Or, Being substituted with the alkylene dioxy basis which includes 2 oxygen atoms where A and D together, [C] -C -ARUKANJIIRU (here, as for said [arukanjiiru], one substitution - two are substituted with [C] -C -ARUKIRU by when and have not adjoined directly by when, it forms the further ring of 5 members) to be;  Or, A and Q1 together, methyl - or with the methoxy with when one substitution or two [C] -C -ARUKANJIIRU which is substituted (here, as for said [arukanjiiru], the basis below [Inside, R15a and R16a of formula together, are the [C] -C -ARUKANJIIRU basis or the [C] -arukenjiiru basis] include due to when) to be;  Or B and Q2 together, - is [CH] -CH -CH - HA-CH -O-CH -de;  Or, D and Q1 together, are [C] -C -ARUKANJIIRU;  Or, Q1, hydrogen, methyl, ethyl, propyl, isopropyl and [shikuropuropiru], is cyclopentyl or [shikurohekishiru];  Q2, hydrogen, is methyl or ethyl;  Q5 and Q6 becoming independent, respectively, it is hydrogen or methyl;  Or, Q1 and Q2, the carbon atom which those have connected and together, methyl - or with the methoxy [C] -C -SHIKUROARUKIRU which is substituted by when (here, as for the methylene basis 1, are replaced with oxygen by when) to be, (however, A and B, respectively, are hydrogen);  G is, hydrogen (a) or, or, the below-mentioned basis It is one inside, In formula, L, is oxygen or the sulfur;  M, is oxygen or the sulfur;  E, is one metal ion equivalent ones or 1 ammonium ions;  R1, in case of in each case with chlorine one [C] -C -ARUKIRU, [C] -C -ARUKENIRU and [C] -C -ARUKOKISHI-C 1 which are substituted - alkyl or [C] -C -ARUKIRU thio - it is [C] -arukiru with when whether, or, in case of in each case fluorine -, chlorine -, one it is [shikuropuropiru] or [shikurohekishiru] which are substituted methyl - or with the methoxy with when whether, or, fluorine -, chlorine -, bromine -, cyano -, nitro -, methyl -, the methoxy -, one it is the phenyl which is substituted trifluoromethyl - or with [torihuruorometokishi] with when;  R2, in case of in each case one [C] -C -ARUKIRU, [C] -C -ARUKENIRU or [C] -C -ARUKOKISHI-C -C -arukiru which are substituted, it is phenyl or the benzyl with fluorine with when;  R3 is, [C] -C -ARUKIRU] chemical compound.  2. W, hydrogen, is methyl or ethyl;  X, chlorine, is methyl or ethyl;  Y, is hydrogen;  Z, it is OCH2-CF3 in 3 rank;  Or, Z, it is OCH2-CF3 in 4 rank;  Or, Z, it is OCH2-CF3 in 5 rank;  CKE, the below-mentioned basis It is one inside;  A, is methyl or ethyl;  B, is hydrogen or methyl;  A and B and the carbon atom which those have connected, [C] -C -SHIKUROARUKIRU of saturation (here, as for the ring member 1, are replaced with oxygen by when, in addition, said [shikuroarukiru], methyl -, ethyl -, methoxy methyl -, the methoxy -, the ethoxy -, [puropokishi] -, [butokishi] - or one substitution or two is substituted with [torihuruoroetokishi] by when) to be;  Or, A and B and the carbon atom which those have connected, [C] -shikuroarukiru (here, as for said [shikuroarukiru], being substituted with the alkylene dioxy basis which includes 2 oxygen atoms which it has not adjoined directly by when, further ring of 5 members or 6 members (here, as for the said ring, one substitution or two are substituted) form with methyl) to be;  D, is hydrogen;  Or, A and D together, [C] -C -ARUKANJIIRU (here, as for 1 carbon atoms, are replaced with oxygen by when) to be;  Or, Being substituted with the alkylene dioxy basis which includes 2 oxygen atoms where A and D together, [C] -C -ARUKANJIIRU (here, as for said [arukanjiiru], one substitution - two are substituted with methyl by when and have not adjoined directly due to when by when, it forms the further ring of 5 members) to be;  Or, A and Q1 together, are [C] -C -ARUKANJIIRU;  Q2, is hydrogen;  G is, hydrogen (a) or, or, the below-mentioned basis It is one inside, In formula, L, is oxygen;  M, is oxygen;  R1, is [C] -C -ARUKIRU;  R2, is [C] -C -ARUKIRU;  In claim 1 the chemical compound formula (i) of statement.  3. In order to prevent the noxious insect and/and being the composition in order to control the growth where the plant is not desirable, it features that formula (i) of statement includes one chemical compound in claim 1 at least, the aforementioned composition.  4. In order to prevent the noxious insect and/or being method in order to control the growth where the plant is not desirable, the chemical compound formula (i) of statement it features that it operates those habitat environments the growth where the noxious insect and the plant are not desirable and/or in claim 1, the aforementioned method.  5. In order to prevent the noxious insect and/or, in claim 1 in order to control the growth where the plant is not desirable use of the chemical compound formula (i) of statement.  6. In order to prevent the noxious insect and/and being the method of producing the composition in order to control the growth where the plant is not desirable, the chemical compound formula (i) of statement it features that it makes mix with the surface active agent the dust diluent and/or in claim 1, the aforementioned method.  7. In order to prevent the noxious insect and/and, in claim 1 in order to produce the composition in order to control the growth where the plant is not desirable use of the chemical compound formula (i) of statement.  8. Being the composition which includes the active ingredient combination of the effective quantity, the said combination, as a component, (A') formula (i) [in formula, W, X, Y, Z and CKE are, as respectively, defined with claim 1 or 2,] at least one chemical compound;  And, The aforementioned composition which includes one which (b') is selected from group S1 of chemical compound, S2, S3, S4, S5, S6, S7, S8, S9, S10, S11, S12, S13, S14 and S15 improves the compatibility of the crop plant chemical compound at least, each chemical compound as follows is. (S1) formula (S1) (In formula, the sign and the subscript are defined, respectively, like below: nA is natural number of the 0-5;  RA1, halogen, (C1-C4) - alkyl, (C1-C4) - the alkoxy and nitro or (C1-C4) - is halo alkyl;  WA the 1-3 which is selected from the group of N and O part has the hetero ring atom the unsaturation or is selected is not substituted from 5 member hetero rings of aromatic or or two value hetero cyclic bases which are substituted (here, at least 1 nitrogen atoms and being maximum, 1 oxygen atoms exist in the said ring) to be;  RA2, is ORA3, SRA3 or NRA3RA4 or, or, at least 1 The nitrogen atom and being maximum, the saturation which possesses up to 3 hetero atoms or hetero ring of the unsaturated 3-7 member (here, (S1) through the nitrogen atom in inside, we connect the said hetero ring, to the carbonyl group, and, are not substituted, or we are substituted with the basis which is selected from the group of the phenyl which is substituted, (C1-C4) - alkyl, (C1-C4) - by the alkoxy and case) to be;  RA3 is hydrogen, or or, it is not substituted or or it is the aliphatic hydrocarbon radical which is substituted;  RA4, hydrogen, (C1-C6) - alkyl, (C1-C6) - is the alkoxy, or or, it is substituted, or or the phenyl which is not substituted it is) chemical compound;  (S2) formula (S2) (In formula, the sign and the subscript are defined, respectively, like below: RB1, halogen, (C1-C4) - alkyl, (C1-C4) - the alkoxy and nitro or (C1-C4) - is halo alkyl;  nB is natural number of the 0-5;  RB2, is ORB3, SRB3 or NRB3RB4 or, or, at least 1 The nitrogen atom and being maximum, the saturation which possesses up to 3 hetero atoms or hetero ring of the unsaturated 3-7 member (here, (S2) through the nitrogen atom in inside, we connect the said hetero ring, to the carbonyl group, and, are not substituted, or we are substituted with the basis which is selected from the group of the phenyl which is substituted, (C1-C4) - alkyl, (C1-C4) - by the alkoxy and case) to be;  RB3 is hydrogen, or or, it is not substituted or or it is the aliphatic hydrocarbon radical which is substituted;  RB4, hydrogen, (C1-C6) - alkyl, (C1-C6) - is the alkoxy, or or, it is substituted or or it is the phenyl which is not substituted;  As for TB, (C1-, or, C2) - the [arukanjiiru] chain (here, as for the said [arukanjiiru] chain, it is not substituted, or, 1 or 2 (C1-C4) - is substituted with the alkyl group, or, [(C1-C3) - the alkoxy] it is substituted) is with carbonyl) the quinoline derivative;  (S3) formula (S3) (In formula, the sign and the subscript are defined, respectively, like below: RC1, (C1-C4) - alkyl, (C1-C4) - halo alkyl, (C2-C4) - [arukeniru], (C2-C4) - [haroarukeniru], (C3-C7) - is [shikuroarukiru];  RC2 and RC3 are identical or or it differs, and, hydrogen, (C1-C4) - alkyl, (C2-C4) - [arukeniru], (C2-C4) [arukiniru], (C1-C4) - halo alkyl, (C2-C4) - [haroarukeniru], (C1-C4) - [arukirukarubamoiru] - (C1-C4) - alkyl, (C2-C4) - [arukenirukarubamoiru] - (C1-C4) - alkyl, (C1-C4) - the alkoxy - (C1-C4) - alkyl and [jiokisoraniru] - (C1-C4) - alkyl and [chiazoriru], the frill and frill alkyl, it is [chieniru] and [piperijiru], or or, it is substituted or or it is the phenyl which is not substituted?,Or, RC2 and RC3 are substituted, or together, or form the hetero cyclic ring which is not substituted) chemical compound;  (S4) formula (S4) (In formula, the sign and the subscript are defined, respectively, like below: XD is CH or N;  RD1 is CO-NRD5RD6 or NHCO-RD7;  RD2, halogen, (C1-C4) - halo alkyl, (C1-C4) - the halo alkoxy and nitro, (C1-C4) - alkyl, (C1-C4) - the alkoxy, (C1-C4) - alkyl sulfonyl, (C1-C4) - alkoxy carbonyl or (C1-C4) - is alkyl carbonyl;  RD3, hydrogen, (C1-C4) - alkyl, (C2-C4) - [arukeniru] or (C2-C4) - is [arukiniru];  RD4, halogen, nitro, (C1-C4) - alkyl, (C1-C4) - halo alkyl, (C1-C4) - the halo alkoxy, (C3-C6) - [shikuroarukiru], phenyl, (C1-C4) - the alkoxy, cyano, (C1-C4) - alkyl thio, (C1-C4) - alkyl sulfinyl, (C1-C4) - alkyl sulfonyl, (C1-C4) - alkoxy carbonyl or (C1-C4) - is alkyl carbonyl;  As for RD5, hydrogen, (C1-C6) - alkyl, (C3-C6) - [shikuroarukiru], (C2-C6) - [arukeniru], (C2-C6) - [arukiniru], (C5-C6) - [shikuroarukeniru], hetero ring of the phenyl or 3-6 member (here, as for the said hetero ring, vD which is selected from the group of nitrogen, oxygen and the sulfur the hetero atom is included) to be, (here, as for the last seven bases, halogen, (C1-C6) - the alkoxy, (C1-C6) - the halo alkoxy, (C1-C2) - alkyl sulfinyl, (C1-C2) - alkyl sulfonyl, (C3-C6) - [shikuroarukiru], (C1-C4) - Alkoxy carbonyl, (C1-C4) - it is selected from the group of alkyl carbonyl and phenyl, in addition, when it is the cyclic basis, furthermore, (C1-C4) - alkyl and (C1-C4) - it is selected even from the group of halo alkyl, it is substituted with the substituent of vD);  RD6, hydrogen, (C1-C6) - alkyl, (C2-C6) - [arukeniru] or (C2-C6) - is [arukiniru] and (here, the last three bases, halogen, hydroxy, (C1-C4) - alkyl, (C1-C4) - the alkoxy and (C1-C4) - are substituted with the basis of vD which is selected from the alkyl thio group);  Or, RD5 and RD6, the nitrogen atom which has possessed those and together, form the [pirorijiniru] basis or the [piperijiniru] basis;  RD7, hydrogen, (C1-C4) - alkyl amino, [ji] - (C1-C4) - alkyl amino, (C1-C6) - alkyl or (C3-C6) - is [shikuroarukiru] and (here, the last two bases, halogen, (C1-C4) - the alkoxy and the halo - (C1-C6) - the alkoxy and (C1-C4) - are selected from the alkyl thio group, in addition, when it is the cyclic basis, furthermore, (C1-C4) - alkyl and (C1-C4) - it is selected even from the group of halo alkyl, it is substituted with the substituent of vD);  ND is, 0, 1 or 2;  mD is 1 or 2;  vD is, 0, 1, 2 or 3) [N]-ashiru sulfonamide and those salts;  * (S5) 3,4,5 - [toriasetokishi] benzoic acid ethyl, 3,5 - dimethoxy - 4 - hydroxy benzoic acid, 3,5 - [jihidorokishi] benzoic acid, 4 - hydroxy salicylic acid, 4 - fluoro salicylic acid, 2 - hydroxy cinnamic acid, 1,2 - [jihidoro] - 2 - oxo - 6 - trifluoromethyl pyridine - 3 - [karubokisamido] and 2,4 - [jikurorokei] ;  (S6) 1 - methyl - 3- (2 - [chieniru]) - 1,2 - [jihidorokinokisarin] - 2 - on, 1 - methyl - 3- (2 - [chieniru]) - 1,2 - [jihidorokinokisarin] - 2 - thion, 1- (2 - amino ethyl) - 3- (2 - [chieniru]) - 1,2 - [jihidorokinokisarin] - 2 - on hydrochloride, 1- [2- (diethyl amino) ethyl] - 6,7 - dimethyl - 3 - thiophene - 2 - [irukinokisarin] - 2 (1H) - on and 1- (2 - methyl sulfonyl amino ethyl) - 3- (2 - [chieniru]) - 1,2 - [jihidorokinokisarin] - 2 - on;  (S7) formula (S7) (In formula, the sign and the subscript are defined, respectively, like below: RE1 and RE2, becoming independent respectively, halogen, (C1-C4) - alkyl, (C1-C4) - the alkoxy, (C1-C4) - halo alkyl, (C1-C4) - alkyl amino, [ji] - (C1-C4) - are alkyl amino or nitro;  AE is COORE3 or COSRE4;  RE3 and RE4, becoming independent respectively, hydrogen, (C1-C4) - alkyl, (C2-C6) - [arukeniru], (C2-C4) - [arukiniru], cyano alkyl, (C1-C4) - halo alkyl, phenyl and nitro phenyl, the benzyl and the halo benzyl, are [pirijiniruarukiru] or alkyl ammonium;  nE1 is 0 or 1;  nE2 and nE3 are, becoming independent respectively, 0, 1 or 2) chemical compound;  (S8) formula (S8) (In formula, XF is CH or N;  nF, when it is XF=N, is integer of the 0-4;  And, nF, when it is XF=CH, is integer of the 0-5;  RF1 is the phenoxy which is substituted by phenyl or the case where it is substituted halogen, (C1-C4) - alkyl, (C1-C4) - halo alkyl, (C1-C4) - the alkoxy, (C1-C4) - the halo alkoxy and nitro, (C1-C4) - alkyl thio, (C1-C4) - alkyl  sulfonyl, (C1-C4) - alkoxy carbonyl, by when;  RF2 hydrogen or (C1-C4) - is alkyl;  As for RF3, hydrogen, (C1-C8) - alkyl, (C2-C4) - [arukeniru], (C2-C4) - [arukiniru] or aryl (here, as for the above-mentioned carbon content basis, respectively, it is not substituted, or or, 1 or more where it is selected from the group which consists of halogen and the alkoxy it is identical, or it is substituted) it is in the basis which differs) chemical compound or that salt;  (S9) 1,2 - [jihidoro] - 4 - hydroxy - 1 - ethyl - 3- (5 - [tetorazorirukaruboniru]) - 2 - [kinoron] and 1,2 - [jihidoro] - 4 - hydroxy - 1 - methyl - 3- (5 - [tetorazorirukaruboniru]) - 2 - [kinoron];  (S10) formula (S10a) or formula (S10b) (In formula, RG1, halogen, (C1-C4) - alkyl, the methoxy and nitro, is cyano, CF3 or OCF3;  YG and ZG, becoming independent respectively, are O or S;  nG is integer of the 0-4;  RG2, (C1-C16) - alkyl, (C2-C6) - [arukeniru], (C3-C6) - [shikuroarukiru], is aryl, the benzyl or the halo benzyl;  RG3 is hydrogen or (C1-C6) - alkyl) chemical compound. (S11) "[okisabetoriniru]" ((Z) - 1,3 - [jiokisoran] - 2 - [irumetokishiimino] (phenyl) acetonitrile) (S11-1);  "[hurukisohuenimu]" (1- (4 - [kurorohueniru]) - 2,2,2 - [torihuruoro] - 1 - eta non O- (1,3 - [jiokisoran] - 2 - [irumechiru]) oxime) (S11-2);  And "[shiometoriniru]" or "CGA-43089" ((Z) - cyano methoxy imino (phenyl) acetonitrile) (S11-3);  (S12) [(3 - oxo - *** H- -benzo thiopyran - 4 (3H) - [iriden]) methoxy] methyl acetate) (S12-1);  (S13) the chemical compound of 1 types or more which are selected from the group below (S13): "Naphthalic acid anhydride" (1,8 - naphthalene di-carboxylic acid anhydride) (S13-1);  "Foehn clo rim" (4,6 - [jikuroro] - 2 - phenyl pyrimidine) (S13-2);  "[hururazoru]" (2 - [kuroro] - 4 - trifluoromethyl - 1,3 - thiazole - 5 - carboxylic acid benzyl) (S13-3);  "CL-304415" (4 - [karubokishi] - 3,4 - [jihidoro] - *** H- -benzo pyrane - 4 - acetic acid) (S13-4);  "MG-191" (2 - [jikuroromechiru] - 2 - methyl - 1,3 - [jiokisoran]) (S13-5);  "MG-838" (2 - propenyl 1 - [okisa] - 4 - [azasupiro] [4.5] Deccan - 4 - [karubojichioeto]) (S13-6);  "[jisuruhoton]" (O and [O]-jiechiru S- -echiruchioechiruhosuhorojichioeto) (S13-7);  "[jietoreto] (dietholate)" (O and [O]-jiechiru O-hueniruhosuhorochioeto) (S13-8);  And "[mehueneto] (mephenate)" (methyl carbamic acid 4 - [kurorohueniru]) (S13-9);  (S14) "[jimepipereto]" or "MY-93" ([S]- -mechiru - 1 - phenyl ethyl piperidine - 1 - [karubochioeto]);  "Dime remaining overnight" or "SK 23" (1- (1 - methyl - 1 - phenyl ethyl) - *** -p-toriru urea);  "[kumiruron]" = "JC-940" (3- (2 - [kurorohuenirumechiru]) - 1- (1 - methyl - 1 - phenyl ethyl) urea;  "Methoxy phenon" or "NK 049" (3,3' - dimethyl - 4 - methoxy benzophenone);  And "CSB" (1 - [buromo] - 4- (chloromethyl sulfonyl) benzene);  (S15) (2,4 - [jikurorohuenokishi]) acetic acid (2,4-D);  (4 - [kurorohuenokishi]) acetic acid;  (R and S) - 2- (4 - [kuroro] - [o]-toriru oxy) propionic acid ([mekopurotsupu]);  4- (2,4 - [jikurorohuenokishi]) butyric acid (2,4-DB);  (4 - [kuroro] - [o]-toriru oxy) acetic acid (MCPA);  4- (4 - [kuroro] - [o]-toriru oxy) butyric acid;  4- (4 - [kurorohuenokishi]) butyric acid;  3,6 - [jikuroro] - 2 - methoxy benzoic acid ([jikanba]);  And 3,6 - [jikuroro] - 2 - methoxy benzoic acid 1- (ethoxy carbonyl) ethyl ([rakuchijikuroru] - ethyl (lactidichlor-ethyl))  9. The aforementioned chemical compound which improves the compatibility of the crop plant, is [shipurosuruhuamido], in claim 8 the composition of statement.  10. The aforementioned chemical compound which improves the compatibility of the crop plant, [mehuenpiru] - is diethyl, in claim 8 the composition of statement.  11. Being the method of controlling the growth where the plant is not desirable, the composition of statement it features that it operates the said plant or the environment in claim 8, the aforementioned method.  12. In claim 8 in order to control the growth where the plant is not desirable use of the composition of statement.  13. Being the method of controlling the growth where the plant is not desirable, continuing the chemical compound which in claim 1 improves the compatibility of the crop plant of statement in the chemical compound and claim 8 formula (i) of statement vis-a-vis the said plant or the environment, between brief, it features that it operates separately, the aforementioned method.  14. Being the composition, At least in claim 1 in one chemical compound or claim 8 formula (i) of statement the composition of statement And, Formula (III') [In formula, D is nitrogen or phosphorus;  R26, R27, R28 and R29, becoming independent respectively, are hydrogen, or, in case of in each case are [C] -C -ARUKIRU which is substituted by when whether, or, it is [C] -C -ARUKIREN which is substituted mono the unsaturation or poly- by when it is unsaturated and (here, the said substituent can be selected, halogen, nitro and the cyano empty);  n is, 1, 2, 3 or 4;  R30 is the inorganic anion or the organic anion] At least one salt;  It includes, the aforementioned composition.  15. At least, it features that one permeation reinforcement medicine is included, in claim 14 the composition of statement.  16. The murder insect medicine which includes the composition of statement in the active ingredient or claim 8 formula (i) of statement in claim 1 and/or being the method of reinforcing the action of the herbicide, immediately the active composition (the spray) it features that it manufactures formula of statement (making use of III') salt to claim 14, the aforementioned method.  17. It features that the aforementioned spray is manufactured making use of the permeation reinforcement medicine, in claim 16 method of statement.
法律状态
(JP5840955) LEGAL DETAILS FOR JP2012520242  Actual or expected expiration date=2030-03-05    Legal state=ALIVE    Status=GRANTED     Event publication date=2010-03-05  Event code=JP/APP  Event indicator=Pos  Event type=Examination events  Application details  Application country=JP JP2011553331  Application date=2010-03-05  Standardized application number=2011JP-0553331     Event publication date=2012-09-06  Event code=JP/A  Event indicator=Pos  Event type=Examination events  Published application  Publication country=JP  Publication number=JP2012520242  Publication stage Code=A  Publication date=2012-09-06  Standardized publication number=JP2012520242     Event publication date=2013-03-05  Event code=JP/A621  Event indicator=Pos  Event type=Examination events  Written request for application examination  Effective date of the event=2013-03-04  JAPANESE INTERMEDIATE CODE: A621     Event publication date=2014-03-14  Event code=JP/A977  Event type=Examination events  Report on retrieval  Effective date of the event=2014-03-13  JAPANESE INTERMEDIATE CODE: A971007     Event publication date=2014-04-16  Event code=JP/A131  Event indicator=Neg  Event type=Examination events  Notification of reasons for refusal  Effective date of the event=2014-04-15  JAPANESE INTERMEDIATE CODE: A131     Event publication date=2014-07-15  Event code=JP/A521  Event type=Restitution or restoration  Written amendment  Effective date of the event=2014-07-14  JAPANESE INTERMEDIATE CODE: A523     Event publication date=2015-02-13  Event code=JP/A711  Event type=Change of name or address  Event type=Reassignment  Event type=Administrative notifications  Notification of change in applicant  Effective date of the event=2015-02-13  JAPANESE INTERMEDIATE CODE: A711     Event publication date=2015-04-01  Event code=JP/A02  Event indicator=Neg  Event type=Event indicating Not In Force  Decision of refusal  Effective date of the event=2015-03-31  JAPANESE INTERMEDIATE CODE: A02     Event publication date=2015-04-03  Event code=JP/RD03  Event type=Change of name or address  Event type=Administrative notifications  Notification of appointment of power of attorney  Effective date of the event=2015-04-03  JAPANESE INTERMEDIATE CODE: A7423     Event publication date=2015-07-30  Event code=JP/A521  Event type=Restitution or restoration  Written amendment  Effective date of the event=2015-07-30  JAPANESE INTERMEDIATE CODE: A523     Event publication date=2015-08-10  Event code=JP/A911  Event type=APL  Transfer of reconsideration by examiner before appeal (zenchi)  Effective date of the event=2015-08-07  JAPANESE INTERMEDIATE CODE: A911     Event publication date=2015-08-18  Event code=JP/RD04  Event type=Change of name or address  Event type=Administrative notifications  Notification of resignation of power of attorney  Effective date of the event=2015-08-18  JAPANESE INTERMEDIATE CODE: A7424     Event publication date=2015-10-29  Event code=JP/TRDD  Event indicator=Pos  Event type=Administrative notifications  Trial decision date    Event publication date=2015-11-05  Event code=JP/A01  Event indicator=Pos  Event type=Event indicating In Force  Written decision to grant a patent or to grant a registration (utility model)  Effective date of the event=2015-11-04  JAPANESE INTERMEDIATE CODE: A01     Event publication date=2015-11-19  Event code=JP/A61  Event indicator=Pos  Event type=Event indicating In Force  First payment of annual fees (during grant procedure)  Effective date of the event=2015-11-12  JAPANESE INTERMEDIATE CODE: A61     Event publication date=2015-11-20  Event code=JP/R150  Event indicator=Pos  Event type=Event indicating In Force   Certificate of patent (=grant) or registration of utility model JAPANESE INTERMEDIATE CODE: R150     Event publication date=2016-01-06  Event code=JP/B2  Event indicator=Pos  Event type=Event indicating In Force  Published granted patent (Second level)  from 01-03-1996 onwards (Published examined patent application (Second level) 1971-1996)  Publication country=JP  Publication number=JP5840955  Publication stage Code=B2  Publication date=2016-01-06  Standardized publication number=JP5840955
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