substitution annular keto enol 机翻标题: 暂无翻译,请尝试点击翻译按钮。

源语言标题
(JP5268657) シクロアルキルフェニル​置換​環状​ケトエノール
公开号/公开日
JP2009527513 A 2009-07-30 [JP2009527513]JP5268657 B2 2013-08-21 [JP5268657] / 2009-07-302013-08-21
申请号/申请日
2008JP-0555662 / 2007-02-08
发明人
Toshi shake Yunai Darling Thomas;Lohr Shiyutefuan;Fuoihito Deita;Franken Eva-Maria;Marusamu Olga;Angelman Arufuretsudo;Boyatsuku Gido;Arunoruto Ian Christe;Hills Matein-Jiefuri;Kene Heinz;Rosinger Christoph Ah Hiyu;
申请人
BAYER CROPSCIENCE;
主分类号
IPC分类号
A01N-025/32A01N-035/06A01N-043/12A01N-043/36A01N-043/38A01N-043/90A01P-007/02A01P-007/04A01P-013/02C07B-061/00C07C-049/747C07C-057/46C07C-057/62C07C-062/22C07C-069/616C07C-069/65C07C-069/757C07C-233/51C07C-233/52C07D-207/40C07D-207/408
摘要
(JP5268657) Cyclic keto enol derivatives (I) are new.  Cyclic keto enol derivatives of formula (I) are new.  In (I): J = optionally substituted (OS) (hetero)cycloalkyl; X, Y' = H, alkyl, halo, haloalkyl, alkoxy or haloalkoxy; m = 1-3; CKE = a cyclic keto enol group of formula (1)-(10).  A = e.g.  H; alkyl, alkenyl or alkoxyalkyl; B' = e.g.  H, alkyl or alkoxyalkyl; or D' = H or OS alkyl, alkenyl or alkynyl; Q 1> = e.g.  H, alkyl or alkoxyalkyl; Q 2>, Q 4>, Q 5>, Q 6> = H or alkyl; Q 3> = e.g.  H, alkyl, alkoxyalkyl, alkylthioalkyl, cycloalkyl or phenyl; G = e.g.  H, COR 1> or E; E = a metal ion or ammonium; R 1> = e.g. alkyl, alkenyl, alkoxyalkyl or alkylthioalkyl.  Provided that at least 1 of J, X or Y' = is in the 2-position of the phenyl moiety and is not H.  Full definitions are given in the Definitions field.  Independent claims are also included for: (1) a process for preparing (I); (2) composition comprising at least one compound (I) and at least one safener comprising a compound for formula (IIa-e), or one of 57 specific compounds listed in the specification; and (3) starting materials and intermediates of formulae (II), (III), (IV), (VI), (VIII), (IX), (XII), (XIII), (XIV), (XXVIII), (XXVII), (XXXII), (XXXIV), (XXXVI), (XI), (XXXVII), (XXXVIII), (XLI), (XLII) and (LXVI).  In the safeners (IIa-e): m = 0-5; A 1> = a group of formula (a)-(d); n = 0-5; A 2> = OS 1-2C alkanediyl; R 14>, R 15> = e.g.  OH or SH; R 16> = OS 1-4C alkyl; R 17>, R 18> = e.g.  H or OS 1-6C alkyl, 2-6C alkenyl or 2-6C alkynyl; R 19> = e.g.  H, CN or halo; R 20> = e.g.  H or OS 1-6C alkyl; R 21> = e.g.  H, CN or halo; X 1> = e.g. nitro, CN or halo; X 2>, X 3> = H or as for X 1>; t = 0-5; v = 0-5 (sic); R 22>, R 23> = H or 1-4C alkyl R 24> = e.g.  H or OS 1-6C alkyl or 1-6C alkoxy; R 25> = e.g.  H or OS 1-4C alkyl; R 26> = as for R 25>; or OS phenyl; and X 4>, X 5> = e.g. nitro, CN or COOH.  Full definitions are included in the Definitions field.  In the claimed starting materials and intermediates: Ar = phenyl substituted with X, Y' and (J) m; R 8> = alkyl; Ar' = phenyl optionally monosubstituted with halo, alkyl or alkoxy; Hal = halo; Z = a leaving group; U' = OR 8>, V'=H, halo, alkyl or alkoxy; and all other groups are as listed for (I). [Image] [Image] [Image] [Image] [Image] [Image] [Image] [Image] [Image] [Image] [Image] ACTIVITY : Herbicide; Insecticide; Arachnicide; Molluscicide; Anthelmintic; Protozoacide; Nematocide.  In a post-emergence test, 3-(4-cyclopropyl-2-ethyl-6-methyl-phenyl)-8-methoxy-2-oxo-1-aza-spiro[4.5]dec-3-en-4-yl carbonate ethyl ester gave at least 90% control of Lolium multiflorum and Setaria viridis at an application rate of 320 g/ha.  MECHANISM OF ACTION : None given.  (From DE102006007882 A1)
机翻摘要
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地址
代理人
代理机构
;
优先权号
2006DE-10007882 2006-02-21 2007WO-EP01075 2007-02-08
主权利要求
(JP5268657)   1. The chemical compound which is displayed with formula (i) [In formula, As for J, displaying [shikuropuropiru];  As for X, chlorine, displaying methyl or ethyl;  As for Y, chlorine, displaying methyl, ethyl or hydrogen;  As for m, number 1 or 2 displaying;  However, at the same time the basis J, X or among Y one has been categorized to 2 rank of phenyl group at least, is not hydrogen;  At that time, basis J, as for X and Y, phenyl substitution pattern below So we are arranged;  As for CKE, the below-mentioned basis One inside displaying;  Here, As for A, displaying [C] -C -ARUKIRU or [shikuropuropiru];  As for B, displaying hydrogen or methyl;  Or, A and B and the carbon atom which those have connected may be replaced, saturation [C] -C -SHIKUROARUKIRU (as for the ring member 1, with oxygen, in addition, methoxy, ethoxy, with [butokishi] or methoxy methyl 1 to be substituted are possible.)Displaying;  A and B and the carbon atom which those have connected, [C] -shikuroarukiru (may be substituted with the [C] -C -ARUKIRENJIOKISHIRU basis which possesses the oxygen atom which 2 have not adjoined directly.)Displaying;  D, displaying hydrogen;  Or, A and D together, displaying [C] -C -ARUKANJIIRU;  A and Q1 together, displaying [C] -C -ARUKANJIIRU;  Q2, displaying hydrogen;  Hydrogen (a) you display G, or, or, the below-mentioned basis One inside displaying, Here, R1, displays [C] -C -ARUKIRU, or, phenyl (1 is substituted with chlorine.)Displaying;  R2, displaying [C] -C -ARUKIRU;  R3, displays [C] -C -ARUKIRU. ].  2. Being the method of manufacturing the chemical compound which in claim 1 is displayed with formula (i) of statement, (A) formula (I-1-a) [In formula, A, B, D and J, m, X and Y is, as defined with claim 1. ] So in order to obtain the chemical compound which is displayed, formula (ii) [In formula, A, B, D and J, m, X and Y to be, as defined at description above, and R8 displays alkyl. ] So the chemical compound which is displayed, under existing of the rare explanation/releasing medicine, and under existing of the base, it features that inside the molecule it makes condense, the aforementioned method.  3. Being the method of manufacturing the chemical compound which in claim 1 is displayed with formula (i) of statement, (K) Formula (I-1-b) [In formula, A, B, D and J, m, R1, X and Y is, as defined with claim 1. ] With in order to obtain the chemical compound which is displayed, the formula which is shown with claim 2 (I-1-a) with the chemical compound which is displayed, (I) Formula (XV) [In formula, R1 to be, as defined at description above, and Hal displays halogen. ] So it reacts with the acid halide which is displayed or, or, (I) In appropriate case under, and in appropriate case existing of rare explanation/releasing medicine under existing of acid binder, formula (XVI) [In formula, R1 is, as defined at description above. ] So it makes the thing feature which it reacts with the carboxylic acid anhydride which is displayed, the aforementioned method.  4. Being the method of manufacturing the chemical compound which in claim 1 is displayed with formula (i) of statement, (L) Formula (I-1-c) [In formula, A, B, D and J, m, R2, X and Y is, as defined with claim 1, L displays oxygen, and M displays oxygen. ] With in order to obtain the chemical compound which is displayed, the formula which is shown with claim 2 (I-1-a) with the chemical compound which is displayed, in appropriate case under, and in appropriate case existing of the rare explanation/releasing medicine under existing of the acid binder, formula (XVII) [In formula, R2 and M are, as defined at description above. ] So it features that it reacts with [kurorogi] esuteru which is displayed, the aforementioned method.  5. Being the method of manufacturing the chemical compound which in claim 1 is displayed with formula (i) of statement, (N) Formula (I-1-d) [In formula, A, B, D and J, m, R3, X and Y is, as defined with claim 1. ] With in order to obtain the chemical compound which is displayed, the formula which is shown with claim 2 (I-1-a) with the chemical compound which is displayed, in appropriate case under, and in appropriate case existing of the rare explanation/releasing medicine under existing of the acid binder, formula (XIX) [In formula, R3 is, as defined at description above. ] So it features that it reacts with the chloridation sulfonyl which is displayed, the aforementioned method.  6. Being the method of manufacturing the chemical compound which in claim 1 is displayed with formula (i) of statement, (R) The formula which from claim 2 is shown with 5 (I-1-a) from formula (I-1-d) with in order to obtain the chemical compound which is displayed, formula (I-1') [In formula, A, B, D and G, m, X and Y is, as defined with claim 1, and J' displays bromine or iodine. ] For example so the chemical compound which is displayed, under existing of the solvent, under existing of the catalyst, and under existing of the base, the coupling possible [shikuroarukiruboron] acid derivative (, formula (XXV) So [shikuroarukiruboron] acid or that ester which is displayed) with the coupling it can point;  It features, the aforementioned method.  7. The pest (pest) and/or being the composition in order to prevent the desirable vegetation, The said composition, to include the active chemical compound combination of the effective quantity, the said combination, as a component, (A') at least in claim 1 of 1 types the substitution annular keto enol formula (i) of statement;  And, (B') it is selected from the group of the chemical compound below, at least the herbicide chemical injury reduction medicine of 1 types (herbicide sofener);  The aforementioned composition which is included: 4 - [jikuroroasechiru] - 1 - [okisa] - 4 - [azasupiro] [4.5] Deccan (AD-67 and MON-4660), 1 - [jikuroroasechiruhekisahidoro] - *** , , a-torimechirupiroro [1,2-a] pyrimidine - 6 (2H) - on ([jishikuronon] (dicyclonon) and BAS-145138), 4 - [jikuroroasechiru] - 3,4 - [jihidoro] - 3 - methyl - *** H- , -benzo oxazine ([benokisakoru]), 1 - methyl hexyl 5 - [kurorokinorin] - 8 - oxy acetate (clo child set - [mekishiru]), 3- (2 - [kurorobenjiru]) - 1- (1 - methyl - 1 - phenyl ethyl) urea ([kumiruron]), .alpha.- (cyano methoxy imino) phenyl acetonitrile ([shiometoriniru] (cyometrinil))2,4 - [jikurorohuenokishi] acetic acid (2,4-D), 4- (2,4 - [jikurorohuenokishi]) butyric acid (2,4-DB), 1- (1 - methyl - 1 - phenyl ethyl) - 3- (4 - methylphenyl) urea (dime remaining overnight (daimuron and dymron))3,6 - [jikuroro] - 2 - methoxy benzoic acid ([jikanba]), [S]- -mechiru - 1 - phenyl ethyl piperidine - 1 - [chiokarubokishireto] ([jimepireto]), 2,2 - [jikuroro] - N- (2 - oxo - 2- (2 - propenyl amino) ethyl) - N- (2 - propenyl) acetamide (DKA-24), 2,2 - [jikuroro] - N and [N]-ji - 2 - propenyl acetamide ([jikurorumido]), 4,6 - [jikuroro] - 2 - phenyl pyrimidine (foehn clo rim), 1- (2,4 - [jikurorohueniru]) - 5 - trichlororo methyl - *** H- , , -toriazoru - 3 - carboxylic acid ethyl ([huenkurorazoru] - ethyl), 2 - [kuroro] - 4 - trifluoromethylThiazole - 5 - carboxylic acid phenyl methyl ([hururazoru]), 4 - [kuroro] - N- (1,3 - [jiokisoran] - 2 - [irumetokishi]) - ***.alpha.-torihuruoroasetohuenonokishimu ([hurukisohuenimu]), 3 - [jikuroroasechiru] - 5- (2 - [huraniru]) - 2,2 - [jimechiruokisazorijin] ([hurirazoru] and MON-13900), 4,5 - [jihidoro] - 5,5 - diphenyl - 3 - isoxazole carboxylic acid ethyl ([isokisajihuen] - ethyl), 1- (ethoxy carbonyl) ethyl 3,6 - [jikuroro] - 2 - methoxy benzoate ([rakuchijikuroru]), (4 - [kuroro] - [o]-toriru oxy) acetic acid (MCPA), 2- (4 - [kuroro] - [o]-toriru oxy) propionic acid ([mekopurotsupu]), 1- (2,4 -[jikurorohueniru]) - 4,5 - [jihidoro] - 5 - methyl - *** H-pirazoru - 3,5 - di-carboxylic acid diethyl ([mehuenpiru] - diethyl), 2 - [jikuroromechiru] - 2 - methyl - 1,3 - [jiokisoran] (MG-191), 2 - propenyl - 1 - [okisa] - 4 - [azasupiro] [4.5] Deccan - 4 - [karubojichioeto] (MG-838), 1,8 - naphthalic acid anhydride, .alpha.- (1,3 - [jiokisoran] - 2 - [irumetokishiimino]) phenyl acetonitrile ([okisabetoriniru]), 2,2 - [jikuroro] - N- (1,3 - [jiokisoran] - 2 - [irumechiru]) - N- (2 - propenyl) acetamide (PPG-1292), 3 - [jikuroroasechiru] - 2,2 - [jimechiruokisazorijin] (R-28725),3 - [jikuroroasechiru] - 2,2,5 - [torimechiruokisazorijin] (R-29148), 4- (4 - [kuroro] - [o]-toriru) butyric acid, 4- (4 - [kurorohuenokishi]) butyric acid, diphenyl methoxy acetic acid, diphenyl methoxy methyl acetate and diphenyl methoxy ethyl acetate, 1- (2 - [kurorohueniru]) - 5 - phenyl - *** H-pirazoru - 3 - carboxylic acid methyl, 1- (2,4 - [jikurorohueniru]) - 5 - methyl - *** H-pirazoru - 3 - carboxylic acid ethyl, 1- (2,4 - [jikurorohueniru]) - 5 - isopropyl - *** H-pirazoru - 3 - carboxylic acid ethyl, 1- (2,4 - [jikurorohueniru]) - 5- (1,1 - dimethyl ethyl) - *** H-pirazoru - 3 - carboxylic acid ethyl, 1-(2,4 - [jikurorohueniru]) - 5 - phenyl - *** H-pirazoru - 3 - carboxylic acid ethyl, 5- (2,4 - [jikurorobenjiru]) - 2 - [isookisazorin] - 3 - carboxylic acid ethyl, 5 - phenyl - 2 - [isookisazorin] - 3 - carboxylic acid ethyl, 5- (4 - fluoro phenyl) - 5 - phenyl - 2 - [isookisazorin] - 3 - carboxylic acid ethyl, 1,3 - dimethyl cover - 1 - [iru] 5 - [kurorokinorin] - 8 - oxy acetate, 4 - allyl oxy butyl 5 - [kurorokinorin] - 8 - oxy acetate, 1 - [ariruokishipuropa] - 2 - [iru] 5 - [kurorokinorin] - 8 - oxy acetate and methyl 5 - [kurorokinokisarin] - 8- Oxy acetate and ethyl 5 - [kurorokinorin] - 8 - oxy acetate and allyl 5 - [kurorokinokisarin] - 8 - oxy acetate, 2 - [okisopuropa] - 1 - [iru] 5 - [kurorokinorin] - 8 - oxy acetate, diethyl 5 - [kurorokinorin] - 8 - [okishimaroneto], diallyl 5 - [kurorokinokisarin] - 8 - [okishimaroneto] and diethyl 5 - [kurorokinorin] - 8 - [okishimaroneto], 4 - [karubokishikuroman] - 4 - [iru] acetic acid (AC-304415), 4 - [kurorohuenokishi] acetic acid, 3,3' - dimethyl - 4 - methoxy benzophenone, 1 - [buromo] - 4 - chloromethyl sulfonyl benzene, 1- [4- ([N]- -metokishibenzoirusuruhuamoiru) phenyl] - 3 - methylurea ("N-(2 - The methoxy benzoyl) - 4- [(methyl amino carbonyl) amino] as benzene sulfonamide," being known, it is.)1- [4- ([N]- -metokishibenzoirusuruhuamoiru) phenyl] - 3,3 - dimethyl urea, 1- [4- ([N]- , -jimechirubenzoirusuruhuamoiru) phenyl] - 3 - methylurea, 1- [4- ([N]-nahuchirusuruhuamoiru) phenyl] - 3,3 - dimethyl urea, N- (2 - methoxy - 5 - methyl benzoyl) - 4- ([shikuropuropiruaminokaruboniru]) benzene sulfonamide, And/or, below being defined with general formula, 1 types inside chemical compound: General system (IIa) So the chemical compound which is displayed, or, General system (IIb) So the chemical compound which is displayed, or, General system (IIc) So the chemical compound which is displayed [In the above-mentioned formula, As for m, number 0, 1, 2, 3, 4 or 5 displaying;  As for A1, two value hetero cyclic bases which are shown below One inside displaying;  As for n, number 0, 1, 2, 3, 4 or 5 displaying;  Displaying [arukanjiiru] A2 may be substituted [C] -C -ARUKIRU- BI/or [C] -C -ARUKOKISHI carbonyl - and/or [C] -C -ARUKENIRUOKISHIKARUBONIRU-DE, 1 or 2 carbon atoms possesses;  As for R14, hydroxyl and [merukaputo], amino and [C] -C -ARUKOKISHI, [C] -C -ARUKIRU thio, [C] -C -ARUKIRU amino or [ji] ([C] -C -ARUKIRU) displaying amino;  As for R15, hydroxyl and [merukaputo], amino, [C] -C -ARUKOKISHI, [C] -C -ARUKENIRUOKISHI and [C] -C -ARUKENIRUOKISHI-C -C -arukokishi, [C] -C -ARUKIRU thio, [C] -C -ARUKIRU amino or [ji] ([C] -C -ARUKIRU) - displaying amino;  As for R16, in case of in each case fluorine -, chlorine - and/or bromine - with displaying [C] -C -ARUKIRU which is possible to be substituted;  R17 may be substituted, hydrogen, in case of in each case fluorine -, chlorine - and/or bromine - with [C] -C -ARUKIRU, [C] -C -ARUKENIRU or [C] -C -ARUKINIRU, [C] -C -ARUKOKISHI-C -C -arukiru and [jiokisoraniru] which are possible to be substituted - [C] -C -ARUKIRU, the frill and the frill - [C] -C -ARUKIRU, [chieniru], [chiazoriru] and [piperijiniru], or, fluorine -, chlorine - and/or bromine - or [C] -C -ARUKIRU-DE, displaying phenyl;  R18 may be substituted, hydrogen, in case of in each case fluorine -, chlorine - and/or bromine - with [C] -C -ARUKIRU, [C] -C -ARUKENIRU or [C] -C -ARUKINIRU, [C] -C -ARUKOKISHI-C -C -arukiru and [jiokisoraniru] which are possible to be substituted - [C] -C -ARUKIRU, the frill and the frill - [C] -C -ARUKIRU, [chieniru], [chiazoriru] and [piperijiniru], or, fluorine -, chlorine - and/or bromine - or [C] -C -ARUKIRU-DE, displaying phenyl;  R17 and R18 may be substituted, furthermore and, becoming simultaneous, [C] -C -ARUKANJIIRU or [C] -C -OKISAARUKANJIIRU (respectively, [C] -C -ARUKIRU, phenyl, with the frill and condensation benzene ring, or, with two substituents, at that time, the said two substituents C atom which those have connected and form the carbon ring of 5 members or 6 members together.)Displaying;  Displaying [C] -C -ARUKIRU, [C] -C -SHIKUROARUKIRU or the phenyl where R19, hydrogen, displays cyano, halogen, or, in case of in each case fluorine -, chlorine - and/or bromine - with is possible to be substituted;  As for R20, hydrogen and hydroxyl -, cyano -, halogen - or [C] -C -ARUKOKISHI-DE [C] -C -ARUKIRU, [C] -C -SHIKUROARUKIRU or [tori] which are possible to be substituted - ( [C] -C -ARUKIRU) displaying [shiriru];  Displaying [C] -C -ARUKIRU, [C] -C -SHIKUROARUKIRU or the phenyl where R21, hydrogen, displays cyano, halogen, or, in case of in each case fluorine -, chlorine - and/or bromine - with is possible to be substituted;  As for X1, nitro, cyano, halogen, [C] -C -ARUKIRU, [C] -C -HARO alkyl, displaying [C] -C -ARUKOKISHI or [C] -C -HARO alkoxy;  As for X2, hydrogen, cyano, nitro, halogen and [C] -C -ARUKIRU, [C] -C -HARO alkyl, displaying [C] -C -ARUKOKISHI or [C] -C -HARO alkoxy;  X3, hydrogen, cyano, nitro, halogen and [C] -C -ARUKIRU, [C] -C -HARO alkyl, displays the [C] -C -ARUKOKISHI or [C] -C -HARO alkoxy. ] And/or, below being defined with general formula, chemical compound: General system (IId) So the chemical compound which is displayed, or, General system (IIe) So the chemical compound which is displayed [In the above-mentioned formula, As for t, number 0, 1, 2, 3, 4 or 5 displaying;  As for v, number 0, 1, 2, 3, 4 or 5 displaying;  As for R22, displaying hydrogen or [C] -C -ARUKIRU;  As for R23, displaying hydrogen or [C] -C -ARUKIRU;  As for R24, hydrogen, in case of in each case cyano -, halogen - or [C] -C -ARUKIRU and [C] -C -ARUKOKISHI which [C] -C -ARUKOKISHI-DE are possible to be substituted, [C] -C -ARUKIRU thio, [C] -C -ARUKIRU amino or [ji] ([C] -C -ARUKIRU) amino, or, in case of in each case cyano -, halogen - or [C] -C -ARUKIRU-DE displaying [C] -C -SHIKUROARUKIRU, [C] -C -SHIKUROARUKIRUOKISHI, [C] -C -SHIKUROARUKIRUCHIO or [C] -C -SHIKUROARUKIRUAMINO which are possible to be substituted;  As for R25, hydrogen, cyano -, hydroxyl -, halogen - or [C] -C -ARUKIRU which [C] -C -ARUKOKISHI-DE is possible to be substituted, in case of in each case cyano - or halogen - with [C] -C -ARUKENIRU or [C] -C -ARUKINIRU which are possible to be substituted, or, cyano -, halogen - or [C] -C -ARUKIRU-DE [C] -C -SHIKUROARUKIRU which is possible to be substituted, Or, displaying [C] -C -ARUKANJIIRU or [C] -C -OKISAARUKANJIIRU where [C] -C -SHIKUROARUKIRU which is substituted with [C] -C -ARUKIRU, or, nitro -, cyano -, halogen -, [C] -C -ARUKIRU -, [C] -C -HARO alkyl -, the [C] -C -ARUKOKISHI- SHIKUHA C -C -HARO alkoxy - with you display the phenyl which is possible to be substituted, or, R25 and become simultaneous, in case of in each case are possible to be substituted with [C] -C -ARUKIRU;  As for X4, nitro and cyano, carboxyl, [karubamoiru], formyl, [suruhuamoiru] and hydroxyl, amino, halogen and [C] -C -ARUKIRU, [C] -C -HARO alkyl, displaying [C] -C -ARUKOKISHI or [C] -C -HARO alkoxy;  And X5, nitro and cyano, carboxyl, [karubamoiru], the formyl, [suruhuamoiru] and hydroxyl, amino, halogen and [C] -C -ARUKIRU, [C] -C -HARO alkyl, displays the [C] -C -ARUKOKISHI or [C] -C -HARO alkoxy. ].  8. Herbicide chemical injury reduction medicine, group of chemical compound below: Clo child set - [mekishiru] and [huenkurorazoru] - ethyl and [isokisajihuen] - ethyl and [mehuenpiru] - diethyl, [hurirazoru], foehn clo rim, [kumiruron] and dime remaining overnight, or, chemical compound The empty it is selected, in claim 7 the composition of statement.  9. The herbicide chemical injury reduction medicine, clo child set - is [mekishiru], in claim 7 and 8 the composition of statement.  10. The herbicide chemical injury reduction medicine, [mehuenpiru] - is diethyl, in claim 7 and 8 the composition of statement.  11. The pest (pest) and/or being the composition in order to prevent the desirable vegetation, it features that it includes the chemical compound formula (i) of statement in claim 1 of 1 types at least, the aforementioned composition.  12. The pest (pest) and/or being the method of preventing the desirable vegetation, the chemical compound which in claim 1 is displayed with formula (i) of statement the pest (pest), it features that it operates those habitat environments the desirable vegetation and/or, the aforementioned method.  13. The pest (pest) and/or use of the chemical compound which, in claim 1 in order to prevent the desirable vegetation is displayed with formula (i) of statement.  14. The pest (pest) and/or being the method of manufacturing the composition in order to prevent the desirable vegetation, the chemical compound which in claim 1 is displayed with formula (i) of statement it features that it makes mix with the surface active agent the dust diluent and/or, the aforementioned method.  15. The pest (pest) and/or use of the chemical compound which, in claim 1 in order to manufacture the composition in order to prevent the desirable vegetation is displayed with formula (i) of statement.  16. Being the method of preventing the desirable vegetation, the composition of statement the plant or it features that it operates those habitat environments in claim 7, the aforementioned method.  17. In claim 7 in order to prevent the desirable vegetation use of the composition of statement.  18. Being the method of preventing the desirable vegetation, the plant or in those habitat environments, in chemical compound and the claim 7 which in claim 1 are displayed with formula (i) of statement continuing the herbicide chemical injury reduction medicine of statement, between brief, it features that it operates separately, the aforementioned method.  19. The pest (pest) and/or being the composition in order to prevent the desirable vegetation, At least in claim 1 of 1 types in the chemical compound or claim 7 formula (i) of statement the composition of statement, and, At least formula of 1 types (III') [In formula, As for D, displaying nitrogen or phosphorus;  As for R26, R27, R28 and R29, becoming independent mutually, hydrogen, or, in case of in each case [C] -C -ARUKIRU which is possible to be substituted or mono unsaturation or poly- unsaturated [C] -C -ARUKIREN which is possible to be substituted (as for the substituent, halogen, nitro and cyano it can be selected from the group which consists of.)Displaying;  As for n, 1, 2, 3 or 4 displaying;  R30 displays the inorganic or organic anion. ] Salt;  It includes, the aforementioned composition.  20. At least, it features that the penetrant of 1 types is included, in claim 19 the composition of statement.  21. The shooting harmful biological agent which includes the composition of statement in the active chemical compound or claim 7 formula (i) of statement in claim 1 and/or being the method of improving the activity of the herbicide, immediately the active composition (the spray) it features that it manufactures formula of statement (making use of III') salt to claim 19, the aforementioned method.  22. It features that the spray is manufactured making use of the penetrant, in claim 21 method of statement.
法律状态
(JP5268657) LEGAL DETAILS FOR JP2009527513  Actual or expected expiration date=2027-02-08    Legal state=ALIVE    Status=GRANTED     Event publication date=2007-02-08  Event code=JP/APP  Event indicator=Pos  Event type=Examination events  Application details  Application country=JP JP2008555662  Application date=2007-02-08  Standardized application number=2008JP-0555662     Event publication date=2009-07-30  Event code=JP/A  Event indicator=Pos  Event type=Examination events  Published application  Publication country=JP  Publication number=JP2009527513  Publication stage Code=A  Publication date=2009-07-30  Standardized publication number=JP2009527513     Event publication date=2010-02-06  Event code=JP/A621  Event indicator=Pos  Event type=Examination events  Written request for application examination  Effective date of the event=2010-02-05  JAPANESE INTERMEDIATE CODE: A621     Event publication date=2012-09-26  Event code=JP/A977  Event type=Examination events  Report on retrieval  Effective date of the event=2012-09-25  JAPANESE INTERMEDIATE CODE: A971007     Event publication date=2012-10-03  Event code=JP/A131  Event indicator=Neg  Event type=Examination events  Notification of reasons for refusal  Effective date of the event=2012-10-02  JAPANESE INTERMEDIATE CODE: A131     Event publication date=2012-11-03  Event code=JP/RD02  Event type=Change of name or address  Event type=Administrative notifications  Notification of acceptance of power of attorney  Effective date of the event=2012-11-02  JAPANESE INTERMEDIATE CODE: A7422     Event publication date=2012-12-29  Event code=JP/A524  Event type=Corrections  Written submission of copy of amendment under section 19 (pct)  Effective date of the event=2012-12-28  JAPANESE INTERMEDIATE CODE: A524     Event publication date=2013-01-29  Event code=JP/RD04  Event type=Change of name or address  Event type=Administrative notifications  Notification of resignation of power of attorney  Effective date of the event=2013-01-28  JAPANESE INTERMEDIATE CODE: A7424     Event publication date=2013-04-23  Event code=JP/TRDD  Event indicator=Pos  Event type=Administrative notifications  Trial decision date    Event publication date=2013-05-01  Event code=JP/A01  Event indicator=Pos  Event type=Event indicating In Force  Written decision to grant a patent or to grant a registration (utility model)  Effective date of the event=2013-04-30  JAPANESE INTERMEDIATE CODE: A01     Event publication date=2013-05-16  Event code=JP/A61  Event indicator=Pos  Event type=Event indicating In Force  First payment of annual fees (during grant procedure)  Effective date of the event=2013-05-07  JAPANESE INTERMEDIATE CODE: A61     Event publication date=2013-05-17  Event code=JP/R150  Event indicator=Pos  Event type=Event indicating In Force   Certificate of patent (=grant) or registration of utility model JAPANESE INTERMEDIATE CODE: R150     Event publication date=2013-08-21  Event code=JP/B2  Event indicator=Pos  Event type=Event indicating In Force  Published granted patent (Second level)  from 01-03-1996 onwards (Published examined patent application (Second level) 1971-1996)  Publication country=JP  Publication number=JP5268657  Publication stage Code=B2  Publication date=2013-08-21  Standardized publication number=JP5268657     Event publication date=2015-02-19  Event code=JP/S111  Event type=Change of name or address  Event type=Reassignment  Request for change of ownership or part of ownership JAPANESE INTERMEDIATE CODE: R313113     Event publication date=2015-03-11  Event code=JP/R350  Event type=Change of name or address  Event type=Reassignment  Written notification of registration of transfer JAPANESE INTERMEDIATE CODE: R350     Event publication date=2016-05-10  Event code=JP/R250  Event indicator=Pos  Event type=Payment or non-payment notifications  Receipt of annual fees JAPANESE INTERMEDIATE CODE: R250     Event publication date=2017-05-09  Event code=JP/R250  Event indicator=Pos  Event type=Payment or non-payment notifications  Receipt of annual fees JAPANESE INTERMEDIATE CODE: R250
专利类型码
AB2
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