(DE19710760) The invention relates to a fungicide mixture with synergistic effect, containing a) a fungicide active compound of formula IA or IB wherein <u>- - -</u> represents a single or double bond and the index and substituents have the following meanings: R' -C[CO2CH3] =CHOCH3, -C[CO2CH3] =NOCH3, -C[CONHCH3] =NOCH3, -C[CO2CH3] =CHCH3, -C[CO2CH3] =CHCH2CH3, -C[COCH3] =NOCH3, -C[COCH2CH3] =NOCH3, -N(OCH3) -CO2CH3, -N(CH3) -CO2CH3, -N(CH2CH3) -CO2CH3; R'' a C-organic radical which is bonded directly or via an oxy-, mercapto-, amino- or alkylamino group; together with a group X and the ring Q or T to which they are bonded, an optionally substituted bicyclic, partially or completely unsaturated system; R<x> -OC[CO2CH3] =CHOCH3, -OC[CO2CH3] =CHCH3, -OC[CO2CH3] =CHCH2CH3, -SC[CO2CH3] =CHOCH3, -SC[CO2CH3] =CHCH3, -SC[CO2CH3] =CHCH2CH3, -N(CH3)C[CO2CH3] =CHOCH3, -N(CH3)C[CO2CH3] =NOCH3, -CH2C[CO2CH3] =CHOCH3, -CH2C[CO2CH3] =NOCH3, -CH2C[CONHCH3] =NOCH3; R<y> oxygen, sulfur, =CH- or =N-; n 0, 1, 2 or 3; X cyano, nitro, halogen, alkyl, halogenalkyl, alkoxy, halogenalkoxy, alkylthio; if n>1, an optionally substituted alkylene, alkenylene, oxyalkylene, oxyalkylenoxy, oxyalkenylene, oxyalkenylenoxy or butadiendiyl group bonded to two adjoining C-atoms of the phenyl ring; Y C- or -N-; Q cyclopentenyl, cyclohexenyl, phenyl, pyrrolyl, thienyl, furyl, pyrazolyl, imidazolyl, oxazolyl, isoxazolyl, thiazolyl, thiadiazolyl, triazolyl, pyridinyl, 2-pyridonyl, pyrimidinyl and triazinyl; T phenyl, oxazolyl, thiazolyl, thiadiazolyl, oxadiazolyl, pyridinyl, pyrimidinyl and triazinyl, and b) the herbicide active agent II and/or b2) the herbicide active agent III. The invention also relates to methods for producing mixtures of that type and the use of such mixtures for combatting harmful fungi in the area of plant and material protection.
(DE19710760) 1. Fungicidal mixtures, comprising a) for preparing compound of formula IA or IB in which a single or double bond and the Ÿ for Index and the substituents have the following meaning: C R′ ¢ co2 ch3 ! =choh3, C co- ¢2 ch3 ! =nor3, C-conhch ¢3 ! =nor3, C co- ¢2 ch3 ! ═ch3, C co- ¢2 ch3 ! ═CH2 CH3, C- ¢ cochimin3 ! =nor3, C- ¢ cochimin2 ch3 ! =nor3, N-(OCH3) -CO2 CH3, N-(CH3) -CO2 CH3, N-(CH2 CH3) -CO2 CH3 ; R" C-organic radical a, directly or via an Oxy group, Mercapto, Amino, alkyl Amino group is bonded or; X and ring Q together with a group T or, to which they are attached, an optionally substituted bicyclic a, partially or fully unsaturated System, which in addition to carbon ring heteroatoms such as oxygen, sulfur and nitrogen may; Rx -Oc ¢ CO2 CH3 ! =choh3, -OC ¢ CO2 CH3 ! ═CH3, -OC ¢ CO2 CH3 ! ═CH2 CH3, CO-SC ¢2 CH3 ! =choh3, CO-SC ¢2 CH3 ! ═CH3, CO-SC ¢2 CH3 ! ═CH2 CH3, N-(CH3) C ¢ co2 CH3 ! =choh3, N-(CH3) C ¢ co2 CH3 ! =nor3, -CH2 ¢ co C2 CH3 ! =choh3, -CH2 ¢ co C2 CH3 ! =nor3, -CH2 ¢ CONNCH C3 ! Still=3 ; Ry oxygen, sulfur, ═CH-or N--; 0 N, 1, 2 or 3, wherein the groups X may be different, if N is greater than 1; X cyano, nitro, Halogen, C1 -C4 Alkyl, C1 -C4 haloalkyl, C1 -C4 Alkoxy, C1 -C4 - haloalkoxy, C1 -C4 alkylthio; if, when N > is 1, a C atoms of the Phenyl ring bonded to two adjacent C3 -C5 alkylene, C3 -C5 alkenylene, Oxy-C2 -C4 alkylene -, Oxy-C1 -C3 - alkylenoxy -, Oxy-C2 -C4 keny -, Oxy-C2 -C4 - alkenyleneoxy or butadiene diyl group, which in turn can carry from one to three of the following chain: Halogen, C1 -C4 Alkyl, C1 -C4 haloalkyl, C1 -C4 Alkoxy, C1 -C4 - haloalkoxy or C1 -C4 alkylthio, Y=C or N-; Q cyclopentenyl, cyclohexenyl, Phenyl, Pyrrolyl, thienyl, Furyl, Pyrazolyl, Imidazolyl, Oxazolyl, Isoxazolyl, thiazolyl, thiadiazolyl, triazolyl, Pyridinyl, 2-Pyridonyl, Pyrimidinyl and triazinyl; T Phenyl, Oxazolyl, thiazolyl, thiadiazolyl, Oxadiazolyl, Pyridinyl, Pyrimidinyl and triazinyl, and b1) the herbicidally active compound II and/or b2) the herbicidally active compound III in a synergistically effective amount. 2. Fungicidal mixtures according to claim 1, characterized in, that the weight ratio of II or III 10 to the compound IA or IB compounds: 1 to 0.1: 1 and the ratio of the compounds to the compound II and compound IA or IB III 10:1: 0.4 to 0.1: 1: 0.4 is. 3. Method for controlling harmful fungi, characterized in, that the harmful fungi, their habitat or the plants to be kept free from them, seeds, soils, surfaces, materials or spaces with a compound of formula IA or IB and the compound of formula II according to claim 1 and/or the compound according to claim 1 III according to claim 1 treated. 4. Method according to claim 3, characterized in, that compound IA or IB and the compound according to claim 1 II and/or the compound according to claim 1 III simultaneously according to claim 1, together or separately and, or sequentially applying. 5. Method for protecting crops from fungi according to claim 3, characterized in, that the parasitic fungi, plant habitat or to be kept free from them, 0.01 to 1 seeds or soils with a compound IA or IB kg/ha treated according to claim 1. 6. Method according to claim 5, characterized in, that compound II in an amount of 0.01 to 1 according to claim 1 applies kg/ha. 7. Method according to claim 5, characterized in, that compound III in an amount of 0.001 to 0.3 according to claim 1 applies kg/ha. 8. Method for the protection of materials or rooms against fungi according to claim 3, characterized in, that the materials or spaces to be kept free from 0.01 to 20 with fungi g/m3 a compound IA or IB according to claim 1 treated. 9. Method according to claim 8, characterized in, that compound II in an amount of 0.01 to 20 according to claim 1 g/m3 uses. 10. Method according to claim 8, characterized in, that compound III in an amount of 0.01 to 20 according to claim 1 g/m3 uses. 11. Use of a compound IA or IB to produce a fungicidal synergistic mixture according to claim 1 according to claim 1. 12. II use of a compound according to claim 1 for producing a fungicidal synergistic mixture according to claim 1. 13. III use of a compound according to claim 1 for producing a fungicidal synergistic mixture according to claim 1.
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