Polymeric microsphere-loaded palladium-iminodiacetic acid complex as an efficient and easily recycled catalyst for Suzuki reaction in ionic liquid 机翻标题: 暂无翻译,请尝试点击翻译按钮。

来源
Research on Chemical Intermediates
年/卷/期
2019 / 45 / 5
页码
2503-2514
ISSN号
0922-6168
作者单位
Northwestern Polytech Univ, Sch Sci, Dept Appl Chem, Xian 710072, Shaanxi, Peoples R China;Anhui Univ, Coll Chem & Chem Engn, Hefei 230601, Anhui, Peoples R China;Northwestern Polytech Univ, Sch Sci, Dept Appl Chem, Xian 710072, Shaanxi, Peoples R China;Northwestern Polytech Univ, Sch Sci, Dept Appl Chem, Xian 710072, Shaanxi, Peoples R China;AECC Beijing Inst Aeronaut Mat, Beijing 100095, Peoples R China;
作者
Zhang, Jianzheng;Chen, Jingshuai;Zhang, Qiuyu;Wang, Rumin;Wu, Songhua;
摘要
Core-crosslinked shelled-core microspheres of poly(styrene-co-methyl acrylic acid) (PS-co-PMAA), with cores rich in PS and the shell rich in PMAA, were synthesized by one-stage soap-free emulsion polymerization. A palladium (Pd)-iminodiacetic acid (IDA) complex catalyst is loaded on the shell of the PS-co-PMAA microsphere, which results in the advantage of high dispersion degree and, therefore, high activity. The resultant polymeric microspheres catalyst systems are then applied to catalyze the Suzuki reaction of aryl halides with phenylboronic acid in an ionic liquid of 1-butyl-3-methylimidazolium tetrafluoroborate ([bmim][BF4]). Our catalyst systems are proved to be efficient and active for both aryl bromides and aryl iodides. Compared to traditional Pd(Ph3)(4) catalyst, the PS-co-PMAA-IDA-Pd catalyst used here affords higher yield of Suzuki reaction at even lower catalyst concentration. In addition, our polymeric-microsphere based catalytic system can be easily recycled at least four times with high activity in ionic [bmim][BF4] liquid.
机翻摘要
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关键词/主题词
Iminodiacetic acid;Ionic liquid;Microsphere;Palladium;Suzuki reaction;
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