Recent Advances in Application of Pyridinium Chlorochromate (PCC) in Organic Synthesis 机翻标题: 暂无翻译,请尝试点击翻译按钮。

来源
Current Organic Synthesis
年/卷/期
2016 / 13 / 2
页码
220-254
ISSN号
1570-1794
作者单位
Alzahra Univ, Sch Sci, Dept Chem, Tehran 1993891176, Iran;Alzahra Univ, Sch Sci, Dept Chem, Tehran 1993891176, Iran;Alzahra Univ, Sch Sci, Dept Chem, Tehran 1993891176, Iran;
作者
Heravi, Majid M.;Fazeli, Azadeh;Faghihi, Zeinab;
摘要
Pyridinium chlorochromate (PCC) is an important reagent in organic synthesis used primarily for the selective oxidation of alcohols to give carbonyl compounds. Although a variety of related compounds are known with similar reactivity, PCC offers exclusively the advantage of the selective oxidation of alcohols to aldehydes, whereas many other reagents were less selective. Disadvantages of using PCC are the tedious reaction workup and its toxicity, very well compensated by selective oxidation, observed using this reagent as an oxidant. This useful oxidant was first synthesized and used by E. J. Corey and J. William Suggs in 1972.
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关键词/主题词
Pyridinium chlorochromate (PCC);organic synthesis;alcohol;oxidation;carbonyl compounds;selective oxidation;
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