Environmentally benign synthesis of vinyl ester resin from biowaste glycerin 机翻标题: 暂无翻译,请尝试点击翻译按钮。

来源
RSC Advances
年/卷/期
2015 / 5 / 48
页码
38673-38679
作者单位
Univ Massachusetts Lowell, Dept Chem, Lowell, MA 01854 USA;Univ Massachusetts Lowell, Dept Chem Engn, Lowell, MA 01854 USA;Univ Massachusetts Lowell, Dept Chem Engn, Lowell, MA 01854 USA;Univ Massachusetts Lowell, Dept Chem, Lowell, MA 01854 USA;Univ Massachusetts Lowell, Dept Chem, Lowell, MA 01854 USA;Maine Stand Biofuels, Portland, ME 04103 USA;Maine Stand Biofuels, Portland, ME 04103 USA;Univ Massachusetts Lowell, Dept Chem, Lowell, MA 01854 USA;Univ Massachusetts Lowell, Dept Chem, Lowell, MA 01854 USA;Univ Massachusetts Lowell, Dept Chem Engn, Lowell, MA 01854 USA;RF Kovar & Associates, Wrentham, MA 02093 USA;Univ Massachusetts Lowell, Dept Chem, Lowell, MA 01854 USA;
作者
Shah, Priyank N.;Kim, Namjoon;Huang, Zhuangrong;Jayamanna, Mahesh;Kokil, Akshay;Pine, Alex;Kaltsas, Jarmin;Jahngen, Edwin;Ryan, David K.;Yoon, Seongkyu;Kovar, Robert F.;Lee, Yongwoo;
摘要
We present here for the first time a novel environmentally benign protocol for the synthesis of vinyl ester resin (VER). Our synthetic strategy utilizes a commercial waste material, glycerin, from biodiesel manufacturing and converts it into a widely utilized resin. The VER was synthesized using bisphenol A (BPA) and glycidylmethacrylate (GMA) as precursors. GMA was synthesized via a multistep synthetic protocol using glycerin obtained from a biodiesel manufacturing waste stream. The structure of the intermediates was confirmed by H-1 NMR, HPLC and FT-IR spectroscopy.
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