Antisapstain compositions comprising a haloalkynyl compound, an azole and an unsaturated acid 机翻标题: 暂无翻译,请尝试点击翻译按钮。

公开号/公开日
WO2009133374 A2 2009-11-05 [WO2009133374]WO2009133374 A3 2011-06-23 [WO2009133374] / 2009-11-052011-06-23
申请号/申请日
2009WO-GB01104 / 2009-04-30
发明人
WARBURTON PAUL STUART;MASON LEE;HUGHES ANDREW STEWART;
申请人
ARCH TIMBER PROTECTION;
主分类号
IPC分类号
A01N-037/06A01N-037/08A01N-037/10A01N-037/40A01N-041/04A01N-043/653A01N-047/12A01P-003/00B27K-003/50
摘要
(WO2009133374) The present invention provides antisapstain compositions comprising a haloalkynyl compound, an azole and an unsaturated carboxylic or sulphonic acid.  The compositions of the invention are surprisingly effective at protecting wood and other cellulosic substrates, in particular at providing antisapstain activity.  The invention also provides methods for treating wood and other cellulosic substrates with said compositions.
机翻摘要
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地址
代理人
代理机构
;
优先权号
2008GB-0007905 2008-04-30
主权利要求
(WO2009133374) Claims 1. An antisapstain composition comprising a haloalkynyl compound, an azole and an unsaturated carboxylic or sulphonic acid, salt or precursor thereof. 2. The composition as defined in claim 1, wherein the haloalkynyl compound is of formula (II) : wherein R is selected from the group consisting of hydrogen, substituted and unsubstituted alkyl groups having from 1 to 20 carbon atoms, substituted and unsubstituted aryl, alkyl aryl , and aralkyl groups having from 6 to 20 carbon atoms and from substituted and unsubstituted cycloalkyl and cycloalkenyl groups of 3 to 10 carbon atoms, and m and n are independently integers from 1 to 3. 3. The composition as defined in claim 2, wherein the haloalkynyl compound is a halopropynyl compound of formula (III) :  (III) wherein R is as defined for compound II in claim 2. 4. The composition as defined in claim 3, wherein the halopropynyl compound is selected from 3-iodo-2-propynyl propyl carbamate, 3-iodo-2-propynyl butyl carbamate, 3- iodo-2-propynyl hexyl carbamate, 3-iodo-2-propynyl cyclohexyl carbamate, 3-iodo-2-propynyl phenyl carbamate, and mixtures thereof. 5. The composition as defined in claim 4, wherein the halopropynyl compound is 3-iodo-2-propynyl butyl carbamate (IPBC) . 6. The composition as defined in any preceding claim wherein the unsaturated carboxylic or sulphonic acid, salt or precursor thereof is an unsaturated cyclic carboxylic acid, salt or precursor thereof. 7. The composition as defined in any one of claims 1 to 5, wherein the unsaturated carboxylic or sulphonic acid, salt or precursor thereof is an aromatic acid, salt or precursor thereof. 8. The composition as defined in claim 7 wherein the aromatic acid is of formula (IV) :  (IV) wherein Y denotes CO2M or SO3M; each R independently denotes C1-C4alkyl, OH, OMe, OEt, NH2, NMe2, CO2M or halogen, wherein two R groups may optionally form naphthyl; M denotes H, K or Na; and m denotes 0 to 5. 9. The composition as defined in claim 8, wherein the aromatic acid or salt thereof is selected from benzoic acid and sodium benzoate. 10. The composition as defined in claim 6, wherein the cyclic carboxylic acid is a resin acid or salt thereof. 11. The composition as defined in claim 10, wherein the resin acid or salt thereof is selected from abietic acid, sodium abietate, pimaric acid and sodium pimarate. 12. The composition as defined in any one of claims 1 to 5, wherein the unsaturated carboxylic or sulphonic acid, salt or precursor thereof is a linear unsaturated acid, salt or precursor thereof. 13. The composition as defined in claim 12, wherein the unsaturated acid, salt or precursor thereof has at least 4 carbon atoms . 14. The composition as defined in claim 12, wherein the unsaturated acid, salt or precursor thereof is selected from sorbic acid, sodium sorbate, potassium sorbate, myristoleic acid, palmitoleic acid, oleic acid, elaidic acid, linoleic acid, α-linolenic acid, arachidonic acid, eicosapentaenoic acid, euric acid, docosahexanoic acid, fumaric acid, maleic acid, maleic anhydride, and mixtures thereof. 15. The composition as defined in claim 14, wherein the unsaturated acid, salt or precursor thereof is selected from sorbic acid, sodium sorbate and potassium sorbate. 16. The composition according any preceding claim wherein the azole compound is an imidazole, a 1,2,4- triazole, or mixtures of both. 17. The composition as defined in claim 16, wherein the imidazole is a benzimidazole. 18. The composition as defined in claim 17, wherein the imidazole is selected from thiabendazole, imazalil, carbendazim and prochloraz. 19. The composition as defined in any one of claims 16 to 18, wherein the 1 , 2 , 4-triazole is selected from compounds of formula (VI) :  (VI) wherein R5represents a branched or straight chain C1.5alkyl group and R6represents a phenyl group optionally substituted by one or more substituents selected from halogen, C1-3alkyl, C1-3alkoxy, phenyl or nitro; compounds of formula (VII) :  (VII) wherein R7is as defined for R6above and R8represents a hydrogen atom or a branched or straight chain C1-5alkyl group; or selected from the group comprising triadimefon, triadimenol, triazbutil, cyproconazole, difenoconazole, fluquinconazole, flusilazole, uniconazole, diniconazole, bitertanol, hexaconazole, flutriafol, epoxyconazole, tetraconazole, penconazole, and mixtures thereof 20. The composition as defined in claim 19, wherein the 1 , 2 , 4-triazole is selected from triadimefon, triadimenol, triazbutil, propiconazole, cyproconazole, difenoconazole, fluquinconazole, tebuconazole, flusilazole, uniconazole, diniconazole, bitertanol, hexaconazole, azaconazole, flutriafol, epoxyconazole, tetraconazole, penconazole and mixtures thereof. 21. The composition as defined in claim 19 or claim 20, wherein the 1 , 2 , 4-triazole is selected from propiconazole, azaconazole, hexaconazole, tebuconazole, cyproconazole, triadimefon and mixtures thereof. 22. The composition as defined in any preceding claim, wherein the formulation is in a liquid form. 23. The composition as defined in claim 22, wherein the formulation is an emulsion. 24. A method of protecting a substrate of wood or other cellulosic material which comprises applying to the substrate a composition as claimed in any one of the preceding claims or applying the individual components to the substrate such that the substrate effectively receives a formulation as defined in any of the preceding claims. 25. A substrate made of wood or other cellulosic material treated with a composition as claimed in any one of claims 1 to 23. 26. A substrate of wood or other cellulosic material comprising a haloalkynyl compound, an azole and an unsaturated carboxylic or sulphonic acid, salt or precursor thereof.
法律状态
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专利类型码
A2A3
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