Halogenalkylmethylenoxy-phenyl-substituted ketoenols 机翻标题: 暂无翻译,请尝试点击翻译按钮。

公开号/公开日
WO2010102758 A2 2010-09-16 [WO2010102758]WO2010102758 A3 2011-01-20 [WO2010102758] / 2010-09-162011-01-20
申请号/申请日
2010WO-EP01392 / 2010-03-05
发明人
FISCHER REINER;BRETSCHNEIDER THOMAS;LEHR STEFAN;FRANKEN EVA-MARIA;MALSAM OLGA;VOERSTE ARND;GOERGENS ULRICH;DITTGEN JAN;FEUCHT DIETER;HAEUSER-HAHN ISOLDE;ROSINGER CHRISTOPHER HUGH;ANGERMANN ALFRED;
申请人
BAYER CROPSCIENCE;
主分类号
IPC分类号
A01N-043/12A01N-043/16A01N-043/36A01N-043/38C07C-053/134C07D-209/54C07D-307/94C07D-487/04C07D-491/10C07D-493/10
摘要
(WO2010102758) The invention relates to novel compounds of formula (I), wherein W, X, Y, Z and CKE are defined as indicated above, to several methods and intermediates for producing the same and to their use as pest control agents and/or herbicides.  The invention further relates to selectively herbicidal products which contain halogenalkylmethylenoxy-phenyl-substituted ketoenols and a compound that improves crop plant compatibility.  The invention further relates to increasing the effect of plant protection agents which contain halogenalkylmethylenoxy-phenyl-substituted ketoenols by adding ammonium or phosphonium salts and optionally penetration enhancers, to the corresponding products, to methods for producing the same and to their use in plant protection as insecticides and/or acaricides and/or for preventing undesired plant growth.
机翻摘要
暂无翻译结果,您可以尝试点击头部的翻译按钮。
地址
代理人
代理机构
;
优先权号
2009EP-0154888 2009-03-11
主权利要求
(WO2010102758) 1. Claims 1. Compounds of the formula (I)  in which W is hydrogen, alkyl, halogen, haloalkyl, alkoxy or haloalkoxy, X is alkyl, alkenyl, alkynyl, halogen, alkoxy, haloalkyl, haloalkoxy or Cyano, Y is hydrogen, alkyl, alkoxy or halogen A group Z in which J1and J2each independently represent hydrogen or halogen and J3is halogen or a haloalkyl group CKE represents one of the groups  is (11),  wherein - S - U for, - S (O) -, - S (O)2-, - O -, or represents optionally Q3and Q4substituted CrC4- alkylene, which may optionally be interrupted by oxygen, represents hydrogen, represents in each case optionally halogen-substituted alkyl, alkenyl, Alkoxyalkyl, Alkylthioalkyl, represents saturated or unsaturated, optionally substituted Cycloalkyl, in which optionally at least one ring atom is replaced by a Heteroatom, or in each case optionally halogen, alkyl, haloalkyl, alkoxy, haloalkoxy, Cyano or Nitro-substituted aryl, Arylalkyl or Hetaryl, B is hydrogen, alkyl or Alkoxyalkyl, or And A B together with the carbon atom to which they are attached represent a saturated or unsaturated, optionally at least one Heteroatom unsubstituted or substituted cycle which holds de - stand, Is hydrogen D or represents an optionally substituted radical from the series alkyl, alkenyl, alkynyl, Alkoxyalkyl, saturated or unsaturated Cycloalkyl, in which optionally one or more ring members are replaced by heteroatoms, represents in each case optionally substituted Arylalkyl, aryl, Hetarylalkyl or Hetaryl or And A D together with the atoms to which they are attached represent a saturated or unsaturated and optionally at least one (in the case of CKE=8 and 11 further) Heteroatom-containing, in the A, D-member unsubstituted or substituted cycle are, or And A Q! together are in each case optionally substituted alkanediyl or alkenediyl, which is optionally substituted by at least one Heteroatom, a ^co- or substituted "c = N- group or may be interrupted And B Q2together with the atoms, to which they are attached, a saturated or unsaturated and optionally contains at least one Heteroatom, in the B, Q - ^ are part of unsubstituted or substituted cycle, or And D Q! together with the atoms, to which they are attached, a saturated or unsaturated and optionally contains at least one Heteroatom, in the D, Q 1 - part are unsubstituted or substituted cycle, Q! is hydrogen, alkyl, Alkoxyalkyl, optionally substituted Cycloalkyl, wherein optionally one methylene group is replaced by oxygen or sulphur or represents optionally substituted phenyl, ^ Q, Q4, Q5und Q6 are independently hydrogen or alkyl, ^ Q represents hydrogen, represents in each case optionally substituted alkyl, alkoxy, Alkylthio, Alkoxyalkyl, alkylthioalkyl, optionally substituted Cycloalkyl, wherein optionally one or two methylene groups are replaced by oxygen or sulphur or represents optionally substituted phenyl, or Q! and Q ^ together with the carbon atom, to which they are attached, is an optionally hetero atom-containing unsubstituted or substituted cycle are, or And Q Q ^ ^ together with the carbon atom, to which they are attached, a saturated or unsaturated, optionally at least one Heteroatom are unsubstituted or substituted cycle, or And A - Q * together with the carbon atom, to which they are attached, for a subsaturated n_ge - or unsaturated, optionally at least one Heteroatom are unsubstituted or substituted cycle, or And A Q5 together with the carbon atom, to which they are attached, a saturated or unsaturated, optionally at least one Heteroatom are unsubstituted or substituted cycle, G is hydrogen (a) one of the groups or is, wherein A metal ion equivalent or an ammonium ion is E, L represents oxygen or sulphur, M represents oxygen or sulphur, R. 1 is in each case optionally halogen-substituted alkyl, alkenyl, Alkoxyalkyl, Alkylthioalkyl, Polyalkoxyalkyl or represents optionally by halogen, alkyl or alkoxy-substituted Cycloalkyl, may be interrupted by at least one Heteroatom, represents in each case optionally substituted phenyl, Phenylalkyl, Hetaryl, Phenoxyalkyl or hetaryloxy-alkyl, In each case optionally halogen-substituted alkyl or R ^, alkenyl, Alkoxyalkyl, Polyalkoxyalkyl or represents in each case optionally sub - stituiertesCycloalkyl, phenyl or benzyl, R. 3, and R R ^ ^ are independently in each case optionally halogen-substituted alkyl, alkoxy, Alkylamino, Dialkylamino, Alkylthio, - Alke nylthio, Cycloalkylthio or represents in each case optionally substituted phenyl, benzyl, Phenoxy or Phenylthio are, R " and R′ are independently hydrogen, represents in each case optionally halogen-substituted alkyl, Cycloalkyl, alkenyl, alkoxy, Alkoxyalkyl, optionally substituted phenyl, represent optionally substituted benzyl, or together with the N atom, to which they are bonded, are an optionally interrupted by oxygen or sulphur ring. 2. Compounds of the formula (I) according to claim 1, in which W is hydrogen, C ι - coe-alkyl, halogen, C - cg-alkoxy-j, C i - C4- 1 alkyl or cj-C4-haloalkoxy halogen, X is halogen, ci-cg-alkyl, C2- C6-alkenyl, C2 - C6 - alkynyl, ci-cg-alkoxy, C \ - C4-haloalkyl, Cj- C4-haloalkoxy or cyano, Y is hydrogen, halogen, Cj- cg-alkyl, or C i - cg-alkoxy, A group Z  in which J1and J2each independently represent hydrogen, fluorine or chlorine and J3is halogen or Q-Gj-haloalkyl, CKE represents one of the groups is, - S - U for, - S (O) -, - S (O)2-, - O -, N-R S=13, S (O) N-R=13or is, in which n represents the number 0, 1 or 2 is, Each A is hydrogen or optionally halogen-substituted cj-C - ^ alkyl, C3- cg-alkenyl, Cj Cio-alkoxy-cj-cg-alkyl -, C jo-Alkylthio-ci-coe-alkyl ^, optionally substituted by halogen, Cj- cg-alkyl or Cj- cg-alkoxy-substituted C3- cg - Cycloalkyl, in which optionally one or two not directly adjacent ring members are replaced by oxygen and/or sulphur or represents in each case optionally Halogen, cj-cg Alkvl, Cj- cg haloalkyl, Cj- cg-alkoxy, ci-cg-haloalkoxy, cyano or Nitro-substituted phenyl, Naphthyl, Hetaryl having 5 to 6 ring atoms, phenyl - Ci-Cg-alkyl or Naphthyl-Ci-Cg-alkyl, B is hydrogen, C12-alkyl or C j - C - cj8- alkoxy-C j - C6-alkyl or A, B and the carbon atom to which they are attached, represents saturated C3- cjQ- cycloalkyl or unsaturated C5-Cj Q- cycloalkyl, wherein optionally one ring member nitrogen, oxygen or sulfur and which is optionally substituted once or twice by ci - cg-alkyl, Cj- cg-alkoxy, C3-cg Alkenyloxy, Cj- cg-alkoxy-Cj- C6-alkyl, C3- cg- CyClOaIlCyI-C i-C2-alkoxy, C3-Cjo-cycloalkyl, Cj- cg-haloalkyl, C2 - C6 - haloalkoxy, Cj- cg-alkoxy-ci - ^ alkoxy substituted by C, the aforementioned radicals also referred to as N-substituents in question, or A, B and the carbon atom, to which they are attached, for C3- C6-cycloalkyl, which is one or two not directly adjacent oxygen by an optionally - and/or sulphur atoms optionally substituted by cj-C ^ alkyl substituted alkylene containing - or by an alkylenedioxy or by - diyl a Alkylendithioylgroup is substituted, the carbon atom, it is attached to, forms a further five - to eight-membered ring or A, B and the carbon atom, to which they are attached, for C3-cg cycloalkyl or C5-cg-cycloalkenyl are, in which two substituents together with the carbon atoms, to which they are attached, represents in each case optionally C ^ to cg-alkyl, C1- cg-alkoxy or halogen substituted C2-cg-alkylene, or C4 - C6 - alkane C2-cg-alkenediyl diene diyl, wherein optionally a methylene group by oxygen or Is replaced with sulfur, D is hydrogen, in each case optionally halogen-substituted C - γ C12 - alkyl, C3-cg-alkenyl, C3 - C8 - alkynyl, C ci ^Q- alkoxy-Cj- cg-alkyl, optionally substituted by halogen, cj-C ^ alkyl, cj-C4-alkoxy or C1C3 - cg-cycloalkyl - substituted C4-haloalkyl, in which optionally one ring member is replaced by oxygen or sulphur or in each case optionally halogen, cj-cg alkyl, cj-cg-haloalkyl, C1- cg--alkoxy, C cg haloalkoxy ^, cyano or Nitro-substituted phenyl, Hetaryl having 5 or 6 ring atoms, phenyl-C to cg-alkyl or Hetaryl-C ^j- 5 or 6 ring atoms or with cg-alkyl Together D and A in each case optionally substituted C3-Cg alkanediyl or C3-Cg-alkenediyl, wherein optionally one methylene group by a carbonyl group, oxygen or sulfur and wherein the substituents in question is replaced in each case: Halogen, hydroxy, Mercapto or in each case optionally halogen-substituted C1- C1Q- AIlCyI, C1- cg--alkoxy, C cg Alkylthio ^, C3-C7- cycloalkyl, phenyl or Benzyloxy, or another C3-C(j- alkanediyl grouping, or a butadienyl grouping C3-cg-alkenediyl group, optionally substituted by Cj Css-alkyl - or optionally two adjacent substituents together with the carbon atoms in, to which they are bonded, a further saturated or unsaturated cycle having 5 or 6 ring atoms (in the case of the compound of formula (I - 1) are A and D then together with the atoms, to which they are attached for example for the below-mentioned groups Ad I to Ad 10), oxygen or sulfur, or wherein optionally one of the following groups is present, or And A Q1 together with the carbon atoms, to which they are bonded, represents in each case optionally mono-or disubstituted, identically or differently by halogen, hydroxy, each of which is optionally trisubstituted by, identical or different halogen-substituted Cj- Cio-alkyl, cj-cg-alkenyl, ci-cg-alkoxy, ci - cg-Alkylthio, C3 - C7 - Cycloalkyl which is optionally monosubstituted to trisubstituted or respectively, the same or different by halogen, Cj-Cg-alkyl or Ci-Cg-alkoxy substituted Benzyloxy or phenyl substituted C3 - C6 - alkylene or Czj- Cg-alkenediyl, further comprising appropriate gegebe- one of the following groups  or a Cj-C2 alkanediyl group contains or is bridged by an oxygen atom or And B Q2together are optionally substituted by CrC2- alkyl-substituted C] - C3- alkanediyl stand, which may optionally be interrupted by oxygen, or And D Q! together are optionally singly or doubly, identically or differently by ci - C4-alkyl, cj-C ^ - alkoxy-substituted C3 - C6 alkanediyl are, or Q1is hydrogen, C cg alkyl ^, C1- cg-alkoxy-C i-C2-alkyl, optionally substituted by fluorine, chlorine, C - ^ - C alkyl \, Cj- C - 1 or C2-haloalkyl - substituted C3 - C8 C4-alkoxy Cycloalkyl, wherein optionally one methylene group is replaced by oxygen or sulphur or optionally halogen, ci - C4-alkyl, CJ-C4-alkoxy, CJ-C2 - haloalkyl, CjC2-haloalkoxy -, cyano or Nitro-substituted phenyl, ^ Q, Q ^, QJund QOare independently hydrogen or Ci - C4-alkyl, Q3is hydrogen, ci-cg-alkyl, C1- cg--alkoxy, cj-cg Alkylthio, cj-cg-alkoxy - Cj-C2-alkyl, ci-C6-Alkylthio-ci-C2-alkyl, optionally substituted by cj - ^ alkyl or C1C3-cg cycloalkyl substituted with - C4-alkoxy, wherein optionally one or two methylene groups are replaced by oxygen or sulphur or optionally halogen, C1- C4-alkyl, C1C4-alkoxy -, C1C2-haloalkyl -, C1C2-haloalkoxy -, cyano or Nitro-substituted phenyl, or Q1and Q2with the carbon atom, to which they are attached, are optionally substituted by ci - cg-alkyl for, CjC5-alkoxy or - C1- C2-haloalkyl substituted C3-Cγ-ring, in which optionally one ring member is replaced by oxygen or sulphur, And Q Q ^ ^ together with the carbon atom, to which they are attached, form an optionally by ci-C4-alkyl for, CjC4-alkoxy or ci-C2-haloalkyl - - sub stituted saturated or unsaturated C3-Cγ-ring, in which optionally one or two ring members are replaced by oxygen or sulphur, And A - Q * together with the carbon atoms, to which they are attached, a saturated or unsaturated, optionally substituted by ci-C4-alkyl, ci-C4-alkoxy or C] - C3 - C7 - ring substituted C2-haloalkyl, in which optionally one or two ring members are replaced by oxygen or sulphur, Together with the carbon atoms A and cr, to which they are attached, a saturated or unsaturated, optionally substituted by cj-C4-alkyl, C1- C4-alkoxy or ci-C2-haloalkyl-substituted C3 - C7 - ring, in which optionally one ring member is replaced by oxygen or sulphur, G is hydrogen (a) one of the groups or is, in which A metal ion equivalent or an ammonium ion is E, L represents oxygen or sulphur and M is oxygen or sulfur. R! represents in each case optionally halogen-substituted ci-C20-alkyl, C2 - C20 - alkenyl, C1- C8-alkoxy-C -1- C8- alkyl, C cg-Alkylthio-ci-cg-alkyl ^, ^ C ^ - cg-alkoxy poly-C or cg-alkyl optionally substituted by halogen, C1- cg- AIlCyIor C1C3-cg-cycloalkyl - cg--alkoxy substituted, in which optionally one or more not directly adjacent ring members are replaced by oxygen and/or sulfur, optionally substituted by halogen fiir, cyano, Nitro, cj-cg-alkyl, C1- cg--alkoxy, C1- cg haloalkyl -, CpCg-haloalkoxy, C or cj-cg-Alkylsulfonyl cg Alkylthio ^ substituted phenyl, optionally substituted by halogen, Nitro, cyano, C1- cg- AIlCyI, C1- cg--alkoxy, C1- cg alkyl or C 1 - halogenj- cg-haloalkoxy-substituted phenyl-C - \ to cg-alkyl, optionally substituted by halogen or C1- 5 - cg AIlCyI6-membered Hetaryl or substituted, optionally substituted by halogen or C1- cg- AIlCyIsubstituted Phenoxy-cj-cg-alkyl or optionally substituted by halogen, amino or C1- 5 - or 6 - membered substituted cg AhCyIHetaryloxy-Cj- cg-alkyl, ^ Represents in each case optionally halogen-substituted R ci C2() - alkyl, - C2 - C20 alkenyl, cj-cg-alkoxy - cg-alkyl ^, poly-C j-cg alkoxy - cg-alkyl ^, optionally substituted by halogen, C1- cg-a·hrs1cyi or C1C3-cg cycloalkyl - - cg--alkoxy substituted or represents in each case optionally halogen, cyano, Nitro, C] - cg alkyl, cj-cg alkoxy, cj - cg-haloalkyl or ci-cg-haloalkoxy-substituted phenyl or benzyl, ^ R optionally halogen-substituted Cj-Cg-alkyl for or for in each case optionally halogen, Cj-Cg alkyl, Cj-Cg-alkoxy, Ci-C4-haloalkyl, C1 - C4 - haloalkoxy, Cyano or Nitro-substituted phenyl or benzyl, And R R ^ -> independently of one another represent in each case optionally halogen-substituted cj-C8- alkyl, C1- cg--alkoxy, ci-cg-Alkylamino, Di - (C j-cg alkyOamino, C1- cg Alkylthio -, thio C2-cg alkenyl, or represents in each case optionally halogen - C3 - C7 Cycloalkylthio, Nitro, cyano, CjC - ^ alkoxy, C1C4-haloalkoxy -, C - \ C4-Alkylthio, C1- C4-haloalkylthio, C1C4-alkyl or C -1- C4-haloalkyl-substituted phenyl, Are Phenoxy or Phenylthio, R " and R′ are independently hydrogen, represents in each case optionally Halogen-substituted cj-cg alkyl, C3-cg-cycloalkyl, C1- cg--alkoxy, C3-cg-alkenyl, Cj-cg-alkoxy-C ^ to cg-alkyl, optionally substituted by halogen, Cj- cg haloalkyl, C1- cg-alkyl or C1- cg--alkoxy substituted phenyl, optionally substituted by halogen, C1cg-alkyl, ci-cg-haloalkyl or cj-cg-alkoxy-substituted benzyl or together represent an optionally alkyl-substituted cj-C ^ C3-cg-alkylene are, in which optionally one carbon atom is replaced by oxygen or sulphur, R. 13 represents hydrogen, represents in each case optionally halogen-substituted Cj- alkyl or C - cgj- cg-alkoxy (only in the case of C N-R=13- group), optionally substituted with Halogen, CjC - ^ alkyl or ci-czjC3-cg-cycloalkyl - alkoxy-substituted, in which optionally one methylene group is replaced by oxygen or sulphur, or represents in each case optionally substituted by halogen, cj - cg-alkyl, ci-cg-alkoxy, C -|C4-haloalkyl, Cj-C4-haloalkoxy, nitro or cyano-substituted phenyl, phenyl-ci-C4-alkyl, Hetaryl-C - \ C4-alkyl, or only in the case of C N-R=13- phenyl-C - group or C4 alkoxy j Hetaryl-ci-C4-alkoxy, R14aC \ - cg-alkyl or hydrogen or R13 ^ And R optionally substituted with Ci-Q-alkyl together a substituted alkanediyl - C4-Cg stand, which optionally may be interrupted by oxygen or sulphur, Rl5aUNd Rl6a giejcnor different and are C - cg-alkyl or \ ^ Raand R! "atogether for a C2 - C4 - alkanediyl or represent C4-alkanediyl, optionally substituted by C \ - cg alkyl, cj-cg-haloalkyl or by optionally substituted by halogen, C \ - cg-alkyl, C]C4-haloalkyl -, C - cg-alkoxy-j, C j - - oxy C4- Halogenalk, Nitro or cyano-substituted phenyl is substituted, R! 'aand R' °aare independently hydrogen, optionally halogen-substituted C - \ to cg alkyl or optionally substituted by halogen, C \ - cg-alkyl, C]- cg-alkoxy, cj-C4-haloalkyl, ci-C4-haloalkoxy, Nitro or cyano-substituted phenyl or ^ RaUnd R ^atogether with the carbon atom, to which they are attached, for a Carbonyl group or optionally substituted by halogen, Cj- C4-alkyl or cj-C4-alkoxy-substituted C5 - C7 - cycloalkyl, in which optionally one methylene group is replaced by oxygen or sulphur, Rl ^a^ Oa and R is independently Cj Cio-alkyl -, C2-C]Q-alkenyl, cj-ck) - alkoxy, Cj- Cio-Alkylamino, amino C3- Cio-alkenyl, Di - (Cj- Cjo-alkyl) amino or Di - (C3-jo- aIkenyl) are amino. 3. Compounds of the formula (I) according to claim 1, in which W is hydrogen, fluorine, chlorine, bromine, C1- C4 AIlCyI-, cj-C4- alkoxy, C1- C2- haloalkyl or ci-C2- haloalkoxy, X represents chlorine, bromine, iodine, C1- C4- AIl ^ yi, C2- C4 alkenyl, C2-C4- alkynyl, C1- C4- alkoxy, C1- C2 HaIOgCHaIlCyI-, ^ C ^ haloalkoxy or cyano C, Y is hydrogen, methyl, ethyl, fluorine, chlorine, bromine, iodine, represents methoxy or ethoxy, The group Z  in which f i are each independently hydrogen jl, fluorine or chlorine and fi represents fluorine, chlorine, trichloromethyl, difluoromethyl, difluorochloromethyl, dichlorofluoromethyl or trifluoromethyl, CKE represents one of the groups   - CH U for2-, - CH2- CH2-, - O - or  A is hydrogen, each of which is optionally trisubstituted by fluorine or chlorine substituted C1- C6- Ailcyi, C1- C4-alkoxy-C ^ C ^ - alkyl, which is optionally monosubstituted to disubstituted by Cj- C2- alkyl or C1- C2-alkoxy substituted and optionally interrupted by an oxygen atom - C3-C6- cycloalkyl or (but not in the case of the compounds of the formulae (1 - 3), (1 - 4), (1 - 6), (1 - 7), (1 - 9), (I - 10) and (M l) ) in each case optionally substituted once or twice by fluorine, chlorine, bromine, C1- C4- Ailcyi, C1- C2- haloalkyl, C1- C4-alkoxy -, ci-C2- haloalkoxy, cyano or Nitro-substituted phenyl, Pyridyl or benzyl and, B is hydrogen, C i - C4- alkyl or C 1 - C2- alkoxy-C i - C2- alkyl or A, B and the carbon atom to which they are attached, saturated or unsaturated C3 - C7 - cycloalkyl for, wherein optionally one ring member nitrogen, oxygen or sulfur and which is optionally substituted once or twice by C replacing1- C6- AIlCyI, C1- C4-alkoxy-C -1- C2^ IlCyI, trifluoromethyl, C1- C6- -alkoxy, C3- C6Alkenyloxy, trifluoroethoxy, ci - C3-alkoxy-C] - C3 - C6 - cycloalkyl is substituted with methoxy or C3-alkoxy, wherein the aforementioned radicals may also be considered as a N - substituent, with the proviso, that if Q is hydrogen or methyl or ^ A, B and the carbon atom, to which they are attached, for C5-C(j- cycloalkyl, optionally containing one or two not directly adjacent by an oxygen - or sulphur atoms optionally substituted by methyl or ethyl substituted alkylene containing or by an alkylenedioxy or - - diyl - dithiol group is substituted by an alkylene, with the carbon atom, it is attached to, a five - or six - membered ring is further provided, that then Q ^ is hydrogen or methyl, or A, B and the carbon atom, to which they are attached, for C3-cg cycloalkyl or C5-cg-cycloalkenyl are, in which two substituents together with the carbon atoms, to which they are attached, represents in each case optionally CjC2 - - alkyl or cj-C2-alkoxy-substituted C2 - C4 - alkylene, C2 - C4 - alkenediyl or Butadiene diyl, with the proviso, that Q * is hydrogen or methyl then -, D represents hydrogen, represents in each case optionally fluorine-substituted to trisubstituted by simple ci-cg-alkyl, C3-cg-alkenyl, Cj- alkoxy-C C ^j^ - alkyl, optionally substituted once or twice by ci-C ^ for alkyl, ci-C4-alkoxy or CjC2 C3-cg cycloalkyl substituted with - - haloalkyl, in which optionally one methylene group is replaced by oxygen or (only in the case of compounds of the formula (1 - 4) ) represents in each case optionally substituted once or twice by fluorine, chloro, bromo, ci - C4-alkyl, cj-C4-haloalkyl, ci - or cj-C4-haloalkoxy-substituted C4-alkoxy phenyl or Pyridyl, or And A D together are optionally substituted once or twice substituted C3 - C5 - Are alkylene, in which a methylene group by a carbonyl group (but not in the case of the compounds of the formula (I - 11)), oxygen or sulfur may be substituted, is substituted with Cj-C2-alkyl or wherein said Cj-C2-alkoxy or A and D in question (in the case of the compounds of the formula (I - 1) ) together with the atoms, to which they are bonded, one of the groups Ad I to Ad-io are:  or And A D are taken together - C3 - C5 alkanediyl, optionally substituted by two not directly adjacent oxygen atoms and optionally containing one to four times by C1- C4 AIlCyI- or ci-C3- alkoxy-ci-C2- alkyl-substituted alkylenedioxy - group is substituted, wherein a further 5 - or 6-ring is formed, or And A Q! together are optionally mono-or disubstituted, same or different or Ci - Ci-C2 alkyl by~C3 - C4 - alkoxy-substituted alkanediyl C2 stand, which optionally contains the following group:  in which  RlSaun(j Rl6a are the same or different represent methyl or ethyl, or R.15auncj C2 - C4 alkanediyl - or - Rl6a together for a stand C4-alkenediyl, optionally substituted by methyl or ethyl, or And B Q2together are - CH2-, - CH2- CH2- - CH2- CH2- CH2-, or - CH2- O-CH2are - or And D Q! C3 - C4 are together - alkanediyl, or Q1is hydrogen, Cj- ^ alkyl, ci-C4-alkoxy-ci-C2-alkyl, or optionally substituted by methyl or methoxy C3-cg-cycloalkyl, wherein optionally one methylene group is replaced by oxygen, Q2is hydrogen, methyl or ethyl, Q4, Q5 And Q ^ are independently hydrogen or Ci-C3-alkyl, ^ Q is hydrogen, C]- C4-alkyl, ci-C4-alkoxy, or optionally substituted once or twice by methyl or methoxy substituted optionally by a Oxygen atom interrupted Css-Cg-Cycloalkyl is, or Q! and Q2with the carbon, to which they are bonded, optionally substituted with methyl or methoxy substituted C3-Cg-Cycloalkyl, wherein optionally one methylene group is replaced by oxygen, with the proviso, that A and B are independently hydrogen or methyl then stand, or And Q together with the carbon ^ Q-3, to which they are attached, C represents an optionally byjC2-alkyl or cj-C2-alkoxy - substituted saturated C5 - C6 - ring, in which optionally one or two ring members are replaced by oxygen or sulfur, with the proviso, that if A is hydrogen or methyl, or Together with the carbon A and cp, to which they are attached, C represents an optionally byjC2-alkyl or cj-C2-alkoxy - substituted saturated C5 - C6 - ring, in which optionally a ring member is replaced by oxygen or sulfur, with the proviso, that then B, Q ^, ^ Q ^ are independently hydrogen or methyl and Q, or And A Q ^ together with the carbon atoms, to which they are attached, an optionally substituted Cj-C2-alkyl or for Ci - C2-alkoxy-substituted saturated or unsaturated C5-Cg ring, with the proviso, that B then, Q ^, ^ and Q Q6 are independently hydrogen or methyl voneinenander, G is hydrogen (a) one of the groups or is, in which A metal ion equivalent or an ammonium ion is E, L represents oxygen or sulphur and M represents oxygen or sulphur, R. 1 each of which is optionally trisubstituted by fluorine or chlorine for substituted ci-cg-alkyl, C2-cg-alkenyl, ci-C4-alkoxy-ci-C2-alkyl, C] - alkyl or - - C2 C4-Alkylthio-ci optionally substituted once or twice by fluorine, chlorine, ci - or C C2 alkylj- C3 - C6 Cycloalkyl - substituted C2-alkoxy, in which optionally one or two not directly adjacent ring members are replaced by oxygen, is optionally substituted once or twice by fluorine, chlorine, bromine, cyano, Nitro, C1 - C4 - alkyl, C] - C4-alkoxy, ci-C2-haloalkyl or cj-C2-haloalkoxy-substituted phenyl, ^ R each of which is optionally substituted to trisubstituted by fluorine C forj- cg - alkyl, C2- cg-alkenyl or C1- C4- alkoxy-C2- C4-alkyl, which is optionally monosubstituted by C forjC2-alkyl or ci-C2-alkoxy - C3 - C6 - cycloalkyl each of which is optionally substituted or disubstituted by fluorine, chlorine, bromine, cyano, Nitro, CjC - ^ alkyl, ci-C3-alkoxy, trifluoromethyl or trifluoromethoxy-substituted phenyl or benzyl, R. 3 which is optionally monosubstituted to trisubstituted by fluorine C for1- cg-a·hrs1or cyi is optionally monosubstituted by fluorine, chlorine, bromine, cj- Czt-alkyl, CjC - ^ alkoxy, Trifluoromethyl, trifluoromethoxy, Cyano or Nitro-substituted phenyl, R4C i - cg-alkyl for, C ι - cg-alkoxy, C i - cg-Alkylamino, Di - (C \ - C6- alkyl) amino, C \ - cg-Alkylthio, C3 - C4 - Alkenylthio, C3-cg cycloalkylthio or represents in each case optionally monosubstituted by fluorine, chlorine, bromine, Nitro, cyano, cj-C3-alkoxy, C1C3-haloalkoxy -, Cj- ^ Alkylthio, cj-C3-haloalkylthio, ci-C3-alkyl or trifluoromethyl-substituted phenyl, Phenoxy or Phenylthio is, R5for Cj- cg-alkoxy or ci-C6- Alkylthio, R6is hydrogen, C1- cg- AIlCyI, C3-C6- cycloalkyl, C1- cg--alkoxy, C3- cg-alkenyl, C1C6-alkoxy-C -1- C4-alkyl, optionally monosubstituted by fluorine, chlorine, bromine, trifluoromethyl, C1C4-alkyl or C -1- C4-alkoxy substituted phenyl, optionally monosubstituted by fluorine, chlorine, bromine, C1C4-alkyl -, trifluoromethyl or C1- C4-alkoxy substituted benzyl, R7for C1- cg-alkyl, C3 - cg-alkenyl or C 1 - cg-alkoxy-C 1 - is C4-alkyl, R " and R ' together represent an optionally substituted by methyl or ethyl are C4 C5-alkylene -, in which optionally one methylene group is replaced by oxygen or sulfur. 4. Compounds of the formula (I) according to claim 1, in which W is hydrogen, chlorine, methyl or ethyl, X represents chlorine, methyl, ethyl, methoxy or is ethoxy, Y is hydrogen, methyl or chlorine, The group Z is, in which each independently are hydrogen or Fluor jl and fi and J ^ represents fluorine, chlorine or trifluoromethyl, CKE represents one of the groups is, - CH U for2-, - CH2- CH2-, - O - or  A is hydrogen, each of which is optionally substituted C \ - to trisubstituted by fluorine or C \ - C alkyl - C42- alkoxy-C \ - C2- alkyl, cyclopropyl, cyclopentyl or cyclohexyl and in the case of the compounds of the formula (1 - 5) is optionally substituted once or twice by fluorine, chlorine, bromine, methyl, ethyl, n-propyl, iso-propyl, methoxy, ethoxy, trifluoromethyl, trifluoromethoxy, cyano or Nitro-substituted phenyl, B is hydrogen, methyl or ethyl or A, B and the carbon atom to which they are attached, - C5 - C6 saturated Cycloalkyl, in which optionally one ring member nitrogen, oxygen or sulfur and which is optionally substituted once or twice by methyl, ethyl, Methoxymethyl, Ethoxymethyl, Methoxyethyl, Ethoxyethyl, trifluoromethyl, methoxy, ethoxy, Propoxy, Butoxy, Methoxyethoxy, Ethoxyethoxy, Allyloxy, Cyclopropylmethoxy or trifluoroethoxy-substituted, wherein the aforementioned radicals also as N-substituents are possible, with the proviso, then Q is hydrogen or ^ A, B and the carbon atom, to which they are attached for Cg-Cycloalkyl, which may be optionally interrupted by an oxygen atom by an optionally alkylidene diyl group or by an alkylenedioxy group containing two not directly adjacent oxygen atoms is substituted by, a further 5 - or 6 ring being formed (which may be substituted once or twice by methyl the) with the proviso, then Q * is hydrogen or - so A, B and the carbon atom, to which they are attached, or C5 - C5 - Cycloalkenyl C5-Cg-Cycloalkyl for stand, wherein two substituents together with the Carbon atoms, to which they are attached, or C C2 - C4 - alkanediyl for2C4-alkenediyl or butadiene - diyl, with the proviso, that Q is hydrogen then ^, D is hydrogen, each of which is optionally substituted to trisubstituted by fluorine for cj-C4-alkyl, C3 - C4 - alkenyl, ci-C4-alkoxy-Cj- C3-alkyl, cyclopropyl, cyclopentyl or cyclohexyl or (in the case of the compounds of the formula (1 - 4) ) represents in each case optionally monosubstituted by fluorine, chlorine, methyl, ethyl, n-propyl, iso-propyl, methoxy, Ethoxy or trifluoromethyl substituted phenyl or Pyridyl, or Together D and A is optionally monosubstituted by methyl or methoxy substituted C3 - C5 - for are alkanediyl, wherein optionally one carbon atom through a carbonyl group (but not in the case of the compounds of the formula (I - H)), oxygen or sulfur or for the group Ad I is substituted, or And A D C3 - C5 - together are alkanediyl, which is optionally substituted with two not directly adjacent oxygen atoms containing a optionally substituted once or twice by ci-C2- alkyl-substituted alkylenedioxy group as the substituent, wherein a further 5 - membered ring is formed, or And A Q! once or twice by methyl or together form optionally C3 - C4 - Alkandiyl are methoxy-substituted, which optionally contains the following group: wherein R ^aand R ^atogether for a C2 - C4 - alkanediyl - or C4-alkenediyl are, or And B Q2together - CH2- CH2- CH2-, or - CH2- O-CH2are - or And D Q1- alkanediyl or together stand for C3 - C4 Q! is hydrogen, methyl, ethyl, propyl, iso-propyl, Cyclopropyl, Cyclopentyl or cyclohexyl, Q2is hydrogen, methyl or ethyl, Q5 And Cj6 are each independently CA hydrogen or methyl, Q3is hydrogen, methyl, ethyl, propyl, methoxy or ethoxy, or represents optionally monosubstituted by methyl or methoxy substituted by C3 - C6 - Cycloalkyl optionally interrupted by an oxygen atom, or Q! and Q ^ with the carbon atom, to which they are attached, an optionally substituted C5 - C6 - Cycloalkyl substituted by methyl or methoxy, wherein optionally one methylene group is replaced by oxygen, with the proviso, that A and B for Hydrogen, or Q3and Q together with the carbon ^, to which they are attached, which is optionally monosubstituted by methyl or methoxy substituted for by an oxygen atom optionally interrupted, saturated Cs-Cg ring, with the proviso, that then A, B, Q5and Q6are hydrogen, G is hydrogen (a) one of the groups or in which L represents oxygen or sulphur, M represents oxygen or sulphur and A metal ion equivalent or an ammonium ion is E, R! each of which is optionally substituted by chlor(...)
法律状态
(WO2010102758) LEGAL DETAILS FOR WO2010102758  Actual or expected expiration date=2012-09-11    Legal state=DEAD    Status=LAPSED     Event publication date=2010-03-05  Event code=WO/APP  Event indicator=Pos  Event type=Examination events  Application details  Application country=WO WOEP2010001392  Application date=2010-03-05  Standardized application number=2010WO-EP01392     Event publication date=2010-09-16  Event code=WO/A2  Event type=Examination events  International application published with declaration under Article 17 (2) (a)  Publication country=WO  Publication number=WO2010102758  Publication stage Code=A2  Publication date=2010-09-16  Standardized publication number=WO2010102758     Event publication date=2011-01-20  Event code=WO/A3  Event indicator=Pos  Event type=Examination events  Later publication of ISR with revised front page  Publication country=WO  Publication number=WO2010102758  Publication stage Code=A3  Publication date=2011-01-20  Standardized publication number=WO2010102758     Event publication date=2012-09-11  Event code=WO/EETL  Event type=Event indicating Not In Force  PCT Application validity period expired. LEGAL DETAILS FOR DESIGNATED STATE AU2010223535  Actual or expected expiration date=2030-03-05    Legal state=ALIVE    Status=GRANTED   Corresponding cc:  Designated or member state=AU Corresponding appl: AU2010223535  Application date in the designated or member state=2010-03-05   Application number in the designated or member state=2010AU-0223535 Corresponding cc:  Designated or member state=AU Corresponding pat: AU2010223535  Publication stage code in the designated or member state=A1  Publication date in the designated or member state=2011-09-22   Publication number in the designated or member state=AU2010223535    Event publication date=2011-08-30  Event code=WO/WWE  Event indicator=Pos  Event type=Entry into national phase  Wipo information: entry into national phase Corresponding cc:  Designated or member state=AU     Event publication date=2011-09-22  Event code=WO/ENP  Event type=Entry into national phase  Entry into the national phase in: Corresponding cc:  Designated or member state=AU     Event publication date=2016-01-14  Event code=AU/STCHG  Patent Status changed by the national office Corresponding cc:  Designated or member state=AU  LEGAL DETAILS FOR DESIGNATED STATE BRPI1008949  Actual or expected expiration date=2030-03-05    Legal state=ALIVE    Status=PENDING   Corresponding cc:  Designated or member state=BR Corresponding appl: BRPI1008949  Application date in the designated or member state=2010-03-05   Application number in the designated or member state=2010BR-0008949 Corresponding cc:  Designated or member state=BR Corresponding pat: BRPI1008949  Publication stage code in the designated or member state=A1  Publication date in the designated or member state=2012-11-27   Publication number in the designated or member state=BR201008949    Event publication date=2012-11-27  Event code=WO/REG  Event code=BR/B01A  Event type=Examination events  Reference to a national code Pct publication - request for entry into the national phase Comunicacao da publicacao internacional pct. apresentacao de peticao de requerimento de entrada na fase nacional Corresponding cc:  Designated or member state=BR     Event publication date=2015-09-01  Event code=WO/ENP  Event type=Entry into national phase  Entry into the national phase in: Corresponding cc:  Designated or member state=BR   Effective date of the event=2011-09-12  LEGAL DETAILS FOR DESIGNATED STATE CA2754847  Actual or expected expiration date=2030-03-05    Legal state=ALIVE    Status=GRANTED   Corresponding cc:  Designated or member state=CA Corresponding appl: CA2754847  Application date in the designated or member state=2010-03-05   Application number in the designated or member state=2010CA-2754847 Corresponding cc:  Designated or member state=CA Corresponding pat: CA2754847  Publication stage code in the designated or member state=A1  Publication date in the designated or member state=2010-09-16   Publication number in the designated or member state=CA2754847    Event publication date=2011-09-08  Event code=WO/WWE  Event indicator=Pos  Event type=Entry into national phase  Wipo information: entry into national phase Corresponding cc:  Designated or member state=CA     Event publication date=2017-07-11  Event code=CA/STCHG  Patent Status changed by the national office Corresponding cc:  Designated or member state=CA  LEGAL DETAILS FOR DESIGNATED STATE CN102348684  Actual or expected expiration date=2030-03-05    Legal state=ALIVE    Status=GRANTED   Corresponding cc:  Designated or member state=CN Corresponding appl: CN201080011864  Application date in the designated or member state=2010-03-05   Application number in the designated or member state=2010CN-80011864 Corresponding cc:  Designated or member state=CN Corresponding pat: CN102348684  Publication stage code in the designated or member state=A  Publication date in the designated or member state=2012-02-08   Publication number in the designated or member state=CN102348684    Event publication date=2015-08-05  Event code=CN/STCHG  Patent Status changed by the national office Corresponding cc:  Designated or member state=CN  LEGAL DETAILS FOR DESIGNATED STATE DE  Actual or expected expiration date=2011-09-12    Legal state=DEAD    Status=LAPSED   Corresponding cc:  Designated or member state=DE     Event publication date=2011-09-12  Event code=WO/NENP  Event type=Event indicating Not In Force  Non-entry into the national phase in: Corresponding cc:  Designated or member state=DE  LEGAL DETAILS FOR DESIGNATED STATE EA201190190  Actual or expected expiration date=2017-11-30    Legal state=DEAD    Status=LAPSED   Corresponding cc:  Designated or member state=EA Corresponding appl: EA201190190  Application date in the designated or member state=2010-03-05   Application number in the designated or member state=2011EA-0090190 Corresponding cc:  Designated or member state=EA Corresponding pat: EA201190190  Publication stage code in the designated or member state=A1  Publication date in the designated or member state=2012-02-28   Publication number in the designated or member state=EA201190190    Event publication date=2017-11-30  Event code=EA/STCHG  Patent Status changed by the national office Corresponding cc:  Designated or member state=EA  LEGAL DETAILS FOR DESIGNATED STATE IN7021/DELNP/2011  Actual or expected expiration date=2030-03-05    Legal state=ALIVE    Status=PENDING   Corresponding cc:  Designated or member state=IN Corresponding appl: IN7021/DELNP/2011  Application date in the designated or member state=2011-09-14   Application number in the designated or member state=2011IN-DN07021 Corresponding cc:  Designated or member state=IN Corresponding pat: IN7021/DELNP/2011  Publication stage code in the designated or member state=A  Publication date in the designated or member state=2012-11-16   Publication number in the designated or member state=IN2011DN07021 LEGAL DETAILS FOR DESIGNATED STATE JP  Actual or expected expiration date=2030-03-05    Legal state=ALIVE    Status=PENDING   Corresponding cc:  Designated or member state=JP Corresponding appl: JP2011553331    Event publication date=2011-09-09  Event code=WO/WWE  Event indicator=Pos  Event type=Entry into national phase  Wipo information: entry into national phase Corresponding cc:  Designated or member state=JP     Event publication date=2016-01-06  Event code=JP/STCHG  Patent Status changed by the national office Corresponding cc:  Designated or member state=JP  LEGAL DETAILS FOR DESIGNATED STATE KR20110132591  Actual or expected expiration date=2030-03-05    Legal state=ALIVE    Status=GRANTED   Corresponding cc:  Designated or member state=KR Corresponding appl: KR20117023789  Application date in the designated or member state=2010-03-05   Application number in the designated or member state=2011KR-7023789 Corresponding cc:  Designated or member state=KR Corresponding pat: KR20110132591  Publication stage code in the designated or member state=A  Publication date in the designated or member state=2011-12-08   Publication number in the designated or member state=KR20110132591    Event publication date=2011-10-10  Event code=WO/ENP  Event type=Entry into national phase  Entry into the national phase in: Corresponding cc:  Designated or member state=KR     Event publication date=2017-02-07  Event code=KR/STCHG  Patent Status changed by the national office Corresponding cc:  Designated or member state=KR  LEGAL DETAILS FOR DESIGNATED STATE MX338802  Actual or expected expiration date=2030-03-05    Legal state=ALIVE    Status=GRANTED   Corresponding cc:  Designated or member state=MX Corresponding appl: MX2013011965  Application date in the designated or member state=2010-03-05   Application number in the designated or member state=2013MX-PA11965 Corresponding cc:  Designated or member state=MX Corresponding pat: MX338802  Publication stage code in the designated or member state=B  Publication date in the designated or member state=2016-05-02   Publication number in the designated or member state=MX-338802    Event publication date=2014-01-31  Event code=MX/STCHG  Patent Status changed by the national office Corresponding cc:  Designated or member state=MX
专利类型码
A2A3
国别省市代码
若您需要申请原文,请登录。

最新评论

暂无评论。

登录后可以发表评论

意见反馈
返回顶部