A 3D metal-organic framework with isophthalic acid linker for photocatalytic properties 机翻标题: 暂无翻译,请尝试点击翻译按钮。

来源
Inorganic Chemistry Communications
年/卷/期
2019 / 100 /
页码
92-96
ISSN号
1387-7003
作者单位
Shenzhen Huachuang Biopharmaceut Technol Co Ltd, Shenzhen, Peoples R China;Guangdong Med Univ, Sch Pharm, Key Lab Res & Dev New Med Mat, Dongguan Key Lab Drug Design & Formulat Technol, Dongguan 523808, Peoples R China;Guangdong Med Univ, Sch Pharm, Key Lab Res & Dev New Med Mat, Dongguan Key Lab Drug Design & Formulat Technol, Dongguan 523808, Peoples R China;Guangdong Med Univ, Sch Pharm, Key Lab Res & Dev New Med Mat, Dongguan Key Lab Drug Design & Formulat Technol, Dongguan 523808, Peoples R China;Guangdong Med Univ, Sch Pharm, Key Lab Res & Dev New Med Mat, Dongguan Key Lab Drug Design & Formulat Technol, Dongguan 523808, Peoples R China;Guangdong Med Univ, Sch Pharm, Key Lab Res & Dev New Med Mat, Dongguan Key Lab Drug Design & Formulat Technol, Dongguan 523808, Peoples R China;Univ Delhi, Dept Chem, Delhi, India;Univ Lucknow, Dept Chem, Fac Sci, Lucknow 226007, Uttar Pradesh, India;
作者
Liu, Dong;Pan, Ying;Liu, Weicong;Ding, Qiongjie;Liu, Jianqiang;Xu, Hongjia;Trivedi, Manoj;Kumar, Abhinav;
摘要
The efficient removal of organic pollutants from wastewater is a hot research topic due to its ecological and environmental importance. Herein, by using the ligand-truncation and functionalization strategy, a Cu(II)-based 3D metal-organic framework (MOF), [Cu-2(L1)center dot 5DMF](n) (1) (H(4)L1 = 3,5-di(3,5-dicarboxyphenyl)nitrobenzene), has been designed, prepared and characterized. The single crystal X-ray diffraction results indicates that MOF 1 possess a 3D framework with 1D hexangular channels. The MOF 1 has been used as photocatalyst for the photodegradation of organic dyes viz. methyl violet (MV) and Rhodamine B (Rh B). The photocatalytic results indicated that 1 offered better photocatalysis towards the photodegradation of MV in comparison to Rh B. The probable mechanism for the photocatalytic activity of 1 has been addressed using density of states (DOS) and partial DOS calculations.
机翻摘要
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关键词/主题词
MOF;Dye;Photocatalysis;Density of states;
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