Structural and kinetic insights into Pt/CNT catalysts during hydrogen generation from ammonia borane 机翻标题: 暂无翻译,请尝试点击翻译按钮。

来源
Chemical Engineering Science
年/卷/期
2018 / 192 /
页码
1242-1251
ISSN号
0009-2509
作者单位
East China Univ Sci & Technol, State Key Lab Chem Engn, 130 Meilong Rd, Shanghai 200237, Peoples R China;Norwegian Univ Sci & Technol, Dept Chem Engn, N-7491 Trondheim, Norway;East China Univ Sci & Technol, State Key Lab Chem Engn, 130 Meilong Rd, Shanghai 200237, Peoples R China;East China Univ Sci & Technol, State Key Lab Chem Engn, 130 Meilong Rd, Shanghai 200237, Peoples R China;East China Univ Sci & Technol, State Key Lab Chem Engn, 130 Meilong Rd, Shanghai 200237, Peoples R China;East China Univ Sci & Technol, State Key Lab Chem Engn, 130 Meilong Rd, Shanghai 200237, Peoples R China;
作者
Qian, Gang;Chen, De;Zhou, Xinggui;Chen, Wenyao;Wang, Zijun;Duan, Xuezhi;
摘要
Unraveling the structural and kinetic consequences of catalyst properties, which vary with the catalyst preparation methods, on their catalytic behaviors is of prime scientific and industrial importance. Exemplified by Pt/CNT-catalyzed hydrolytic dehydrogenation of ammonia borane (AB), this work examines the origin of the crucial impacts of the catalyst reduction methods (i.e., in situ reduction with AB and ex situ reduction with H-2) on the surface and electronic properties of the catalyst as well as the consequent hydrogen generation activity and durability. Kinetic and isotopic analyses reveal that the Pt/CNT-ex situ catalyst has low activation energy and a strong ability to activate water. The relationship between the catalyst structure and performance is established, and the unique surface (e.g., fewer Pt-O bonds) and electronic properties (e.g., higher Pt binding energy) of the Pt/CNT-ex situ catalyst are deemed to be responsible for the high activity and durability. The insights reported in this work highlight the importance of understanding the preparation-structure-performance relationship to guide the rational design of catalysts. (C) 2017 Elsevier Ltd. All rights reserved.
机翻摘要
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关键词/主题词
Structure-activity relationship;Kinetic and isotopic analyses;Catalyst surface and electronic properties;Hydrogen generation;Catalyst durability;
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