3-keto or 3-oximoether substituted benzoylcyclohexanediones 机翻标题: 暂无翻译,请尝试点击翻译按钮。

公开号/公开日
WO03084912 A1 2003-10-16 [WO200384912] / 2003-10-16
申请号/申请日
2003WO-EP03250 / 2003-03-28
发明人
SEITZ THOMAS;VAN ALMSICK ANDREAS;WILLMS LOTHAR;SCHMITT MONIKA H;AULER THOMAS;BIERINGER HERMANN;MENNE HUBERT;
申请人
BAYER CROPSCIENCE;
主分类号
IPC分类号
A01N-035/06A01N-035/10A01N-041/10A01N-043/80C07C-045/54C07C-049/84C07C-205/45C07C-251/38C07C-251/40C07C-317/24C07C-323/65C07D-261/08
摘要
(WO200384912) Benzoylcyclohexanedione derivatives of formula (I) and use thereof as herbicides are disclosed.  In said general formula (I) R<1a>, R<1b>, R<1c>, R<2>, R<3>, R<4> and R<5> = various groups, X<1> = a bridging atom, X<2> = a hydrocarbon chain and X<3> = a chalcogen atom or an oximino group.
机翻摘要
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地址
代理人
代理机构
;
优先权号
2002DE-1015723 2002-04-10
主权利要求
(WO200384912) Claims: 1. Compounds of the formula (I) or salts thereof wherein the radicals and indices have the following meanings: X1means a divalent unit from the group consisting of O, S (0)n, N-H, N-R2; X2means a straight-chain or branched, by w radicals from the group consisting of halogen, cyano and N02and by v radicals R2substituted (crc 6) - alkylene -, (C2- C6) - alkenylene - or (C2- C6) - alkynylene; X3means oxygen, sulfur or NOR3; R1a, R1band R1cindependently H meant, Mercapto, N02, halogen, cyano, Thiocyanato, (C O - - co - alkyl CeJ, (C - C ι6) - alkyl - S (0)n-0, (- C C ι6) - alkyl - S (0)n, (crc6) - haloalkyl - S (0)n, (C3- C7) - cycloalkyl - S (0)n, di - (C C6) - alkyl - N - S02, (C C6) - alkyl - b12- nh, (C C6) - nh - - co-alkyl, di - (C C6) - N - - co alkyl, (C - C ι6) - alkyl - S - θ 2 (crc6) - alkyl - nh, (C C6) - alkyl - - co (C C6) - nh - alkyl, (crc6) - 0 - CH2 - alkyl, (C C6) - alkyl - S (0)n- ch2, (crc6) - alkyl - - nh ch2, 1, 2.4 - Triazol - 1 - yl, 1, 2.4 - Triazol - l - yl - ch2, by v radicals from the group cn in each case, N02and halo-substituted (C cr6) - alkyl - (D)P, (C2- C6) - alkenyl - (D)P, (C2- C6) - alkynyl - (D)P, (C3- C9) - cycloalkyl - (D)p, (C3- C9) - - Cyloalkenyl(D)p, (C C6) - alkyl - cycloalkyl - (D) p, (crc6) - alkyl - - cycloalkenyl (D)p; D means oxygen or sulfur; R2, R3independently of one another are hydrogen, in each case by v radicals from the group consisting of CN, N02and halo-substituted (C - C ι6) - alkyl, (C2- C6) - alkenyl, (C2- C6) - alkynyl, (C3- C9) - cycloalkyl, (C3- C9) - cycloalkenyl, (C C6) - alkyl - (C3- C9) - cycloalkyl, (crc6) - alkyl - (C3- C9) - cycloalkenyl, (C2- C6) - alkenyl - (C3- C9) - cycloalkyl, (C2- C6) - alkenyl - (C3- C9) - cycloalkenyl, (C2- C6) - alkynyl - (C3- C9) - cycloalkyl, (C2- C6) - alkynyl - (C3- cg) - cycloalkenyl or straight-chain or branched [C (R6)2] z - [Oc (R6) 2] w - [0 - C (R6)2] - R χ6, in each case by v radicals from the group consisting of CN, N02, halogen, (C - C ι6) - alkyl - (D)Pand halogen - (C - C ι6) - alkyl - (D)psubstituted aryl, (C C6) - alkyl - aryl, (C2- C6) - alkenyl - aryl, (C2- C6) - alkynyl - aryl, Heterocyclyl or heteroaryl; R4means Or7, (C1- C4) - Alkylthio, halo - (C C4) - Alkylthio, (C2- C4) - Alkenylthio, halo - (C2- C4) - Alkenylthio, (C2- C4) - alkynylthio, halo - (C2- C4) - alkynylthio, (Cι-C4) - alkyl-SO, halo - (C C4) - alkyl-SO, (C2- C4) - alkenyl-SO, halo - (C2- C4) - alkenyl-SO, (C2- C4) - alkynyl-SO, halo - (C2- C4) - alkynyl-SO, (C C4) - alkyl-S02, halo - (crc4) - alkyl-Sθ2, (C2- C4) - alkenyl-S02, halogen - (C2- C4) - alkenyl-S02](C2- C4) - alkynyl-S02, halogen - (C2- C4) - alkynyl-S02, halogen, cn, cyanato, Thiocyanato Or Phenylthio; R5represents hydrogen, in each case by means of halogen v, (crc4) - Alkylthio and (d-C4) - alkoxy substituted Tetrahydropyranyl 3, Tetrahydropyranyl-4, Tetrahydrothiopyranyl-3, (Cι-C4) - alkyl, (Cι-C8) - cycloalkyl, (C C4) - alkoxy, (crc4) - alkoxy - (crc4) - alkyl, (C C4) - alkoxy-co, (C C4) - Alkylthio or phenyl, or two C atom R bonded residues on a common5form a chain of the Group OCH2CH20, OCH2CH2CH2O, sch2CH2S and sch2CH2CH2S, is substituted by w methylene groups being, or two adjacent C atoms bonded directly to R residues5form with the C atoms carrying them by w radicals from the group halogen a, (Cι-C4) - alkyl, (Crc4) - Alkylthio and (C C4) - alkoxy-substituted, 3 - bis 6-membered ring; R6means H, halogen, CN, N02, (C C4) - alkyl or halo - (Cι-C4) - alkyl; R7means H, (d-C4) - alkyl, halo - (C C4) - alkyI, (Cι-C4) - alkoxy - (C C4) - alkyl, cho, (Cι-C4) - alkyl-co, (C C4) alkoxy-co -, (d-C4) - alkyl-nh-co, Di - (C C4) - alkyl-N-co, (crc4) - alkyl-S02, halogen - (C C4) - alkyl-S02, in each case by v radicals from the group of (C C4) - alkyl, halo - (C C4) - alkyl, (C C4) - alkoxy, halo - (C C4) - alkoxy, halogen, CN and N02substituted Benzoyl or phenyl-S02; Represents Y a divalent unit from the group consisting of O, S, N-H, (crc6) ~- alkyl N, CHR5and C (R5)2; Z represents a direct bond or a divalent unit from the group consisting of O, S, so, S02, N-H, d-C6) - alkyl-N, chr6or C (R6)2; m and n each represents an integer of 0, 1 or 2; p is independently 0 or 1; v represents 0, 1, 2 or 3; w and x each independently 0.1, 2, 3 or 4, z is 1, 2, 3 or 4 wherein w and x shall not simultaneously be zero. 2. Compounds according to claim 1, wherein R2, R3independently of one another hydrogen, in each case by v radicals from the group consisting of CN, N02and halo-substituted (d-d) - Alkyl, (C2- C6) - alkenyl, (C2- C6) - alkynyl, (C3- C9) - cycloalkyl, (C3- C9) - cycloalkenyl, (C C6) - alkyl - (C3- C9) - cycloalkyl, (Cι-C6) - alkyl - (C3- C9) - cycloalkenyl, (C2- C6) - alkenyl - (C3- C9) - cycloalkyl, (C2- C6) - alkenyl - (C3- C9) - cycloalkenyl, (C2- C6) - alkynyl - (C3- C9) - cycloalkyl, (C2- C6) - alkynyl - (C3- cg) - cycloalkenyl or straight-chain or branched [C (R6)2] z - [Oc (R6)2]w- [0-C(R6)2] χ-R6, by v radicals from the group cn in each case, N02, halogen, (D-C6) - alkyl - (D)pand Halogen - (Cι-C6) - alkyl - (D)psubstituted aryl, (D-C6) - alkyl-aιNI, (C2- C6) - alkenyl-aryl, or (C2-C6) - alkynyl-aryl; X3oxygen or NOR3, and R1care hydrogen. 3. Compounds according to claim 1 or 2, wherein X1n;oxygen or S (0) R1a, R1bindependently of one another are F, Cl, Br, N02, Cf3, CH3, CH3S, CH30, CH3S02, EtS02, Cf3CH2S02or Cyclopropyl-S02, and R2, R3independently of one another are hydrogen, in each case by v radicals from the group consisting of CN, N0 and halo-substituted (crc6) - Alkyl, (C2- C6) - alkenyl, (C2- C6) - alkynyl, (C3- C9) - cycloalkyl, (d-C6) - alkyl - (C3- C9) - Cycloalkyl, straight-chain or branched [C (R6) 2] z - [Oc (R6) 2] w - [0-C(R6)2] χ-R6, in each case by v radicals from the group consisting of cn, N02, halogen, (Cι-C6) - alkyl - (D)Pand Halo - (D-C6) - alkyl - (D)psubstituted aryl or (D-C6) - alkyl-aryl, mean. 4. Compounds according to any one of claims 1 to 3, wherein X1oxygen and R4Or7, (d-C4) - Alkylthio, (C2- C4) - Alkenylthio, (C C4) - alkyl-S02, halogen, cn, cyanato, Thiocyanato Or Phenylthio mean. 5. Compounds according to any one of claims 1 to 4, wherein R5hydrogen or (Cι-C4) - Alkylthio. 6. Compounds according to any one of claims 1 to 5, wherein R4Or7; Oxygen D; Y, Z are each CH2; v, w and x are each independently 0, 1 or 2; Z is 1 or 2 signify. 7. Compounds according to any one of claims 1 to 6, wherein said compounds are present as the salt is not. 8. Herbicidal compositions, characterized by a herbicidally effective content of at least one compound of the general formula (I) according to any one of claims 1 to 7. 9. Herbicidal compositions according to claim 8 in a mixture with formulation auxiliaries. 10. Method for controlling undesirable plants, characterized in, that an effective amount of at least one compound of the general formula (I) according to any one of claims 1 to 7 or of a herbicidal composition according to claim 8 or 9 to the plants or to the locus of the undesired plant growth to be applied. 11. Use of compounds of the general formula (I) according to any one of claims 1 to 7 or of herbicidal compositions according to claim 8 or 9 for controlling unwanted plants. 12. Use according to claim 11, characterized in, that the compounds of the general formula (I) are used for controlling unwanted plants in crops of useful plants. 13. Use according to claim 12, characterized in, that the useful plants are transgenic crop plants are.
法律状态
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专利类型码
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