Quinoline derivative and insecticide containing same as active constituent 机翻标题: 暂无翻译,请尝试点击翻译按钮。

公开号/公开日
EP1780202 A1 2007-05-02 [EP1780202]EP1780202 A4 2009-06-17 [EP1780202]EP1780202 B1 2013-02-27 [EP1780202] / 2007-05-022009-06-172013-02-27
申请号/申请日
2005EP-0768511 / 2005-08-03
发明人
YAMAMOTO KAZUMI;HORIKOSHI RYO;OYAMA KAZUHIKO;KURIHARA HIROSHI;SHIMANO SHIZUO;MIYAKE TAKAAKI;HOTTA HIROKI;IWABUCHI JUN;
申请人
MEIJI SEIKA PHARMA;NIPPON KAYAKU;
主分类号
IPC分类号
A01N-025/04A01N-025/12A01N-025/14A01N-043/42C07D-215/22C07D-215/36
摘要
(EP1780202) Disclosed are compounds that have excellent insecticidal activity and are usable as agricultural and horticultural insecticides.  Compounds represented by formula (I) or agriculturally and horticulturally acceptable acid addition salts thereof have excellent insecticidal activity and are usable as agricultural and horticultural insecticides.
机翻摘要
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地址
代理人
代理机构
;
优先权号
2004JP-0228337 2004-08-04 2005WO-JP14217 2005-08-03
主权利要求
(EP1780202)  1. A compound represented by formula (I) or an agriculturally and horticulturally acceptable acid addition salt thereof: (see diagramm) wherein  R 1 represents  a hydrogen atom,  an alkali metal,  an alkaline earth metal,  optionally substituted C 1-18 alkyl,  optionally substituted C 2-18 alkenyl,  optionally substituted C 2-18 alkynyl,  optionally substituted C 3-10 cycloalkyl,  optionally substituted phenyl lower alkyl,  optionally substituted phenoxy lower alkyl,  optionally substituted phenyl,  optionally substituted heterocyclic group,  COR 4 wherein R 4 represents  optionally substituted C 1-18 alkyl,  optionally substituted C 2-18 alkenyl,  optionally substituted C 2-18 alkynyl,  optionally substituted C 3-10 cycloalkyl,  optionally substituted phenyl lower alkyl,  optionally substituted phenoxy lower alkyl,  optionally substituted phenyl,  optionally substituted heterocyclic group,  optionally substituted C 1-4 alkylthio,  OR 5 wherein R 5 represents  optionally substituted C 1-18 alkyl,  optionally substituted C 2-18 alkenyl,  optionally substituted C 2-18 alkynyl,  optionally substituted C 3-10 cycloalkyl,  optionally substituted phenyl lower alkyl,  optionally substituted phenoxy lower alkyl,  optionally substituted phenyl, or  optionally substituted heterocyclic group, or  NR 6R 7 wherein R 6 and R 7 each independently represents  a hydrogen atom,  optionally substituted C 1-18 alkyl, or  optionally substituted phenyl, or  SO 2R 8 wherein R 8 represents  optionally substituted C 1-18 alkyl,  optionally substituted C 2-18 alkenyl,  optionally substituted C 2-18 alkynyl,  optionally substituted C 3-10 cycloalkyl,  optionally substituted phenyl lower alkyl,  optionally substituted phenoxy lower alkyl,  optionally substituted phenyl, or  optionally substituted heterocyclic group,  R 2 represents a hydrogen atom or optionally substituted C 1-4 alkyl,  R 3 represents  a hydrogen atom,  optionally substituted C 1-18 alkyl,  optionally substituted C 2-4 alkenyl, or  optionally substituted C 1-4 alkoxy,  wherein, in R 1, R 2, and R 3, the substituent in each of the optionally substituted groups is selected from the group consisting of halogen atom;  C 1-4 alkyloxy;  C 1-4 alkyloxy-C 1-4 alkyloxy;  C 1-4 alkyloxycarbonyl;  nitro;  cyano;  formyl;  trifluoromethyl;  trifluoromethoxy;  acetyl;  acetyloxy;  C 1-4 alkyl, provided that this C 1-4 alkyl is not a substituent for the alkyl group;  and C 3-6 cycloalkyl optionally substituted by halogen atom,  alternatively R 2 and R 3 together represent -(CH 2) m- wherein m is 3 or 4,  X 1, X 2, and X 3 each independently represent  a hydrogen atom,  a halogen atom,  C 1-4 alkyl optionally substituted by halogen atom,  C 1-4 alkyloxy optionally substituted by halogen atom,  C 1-4 alkylthio optionally substituted by halogen atom,  C 1-4 alkyloxycarbonyl optionally substituted by halogen atom,  nitro, or  cyano,  provided that X 1, X 2, and X 3 do not simultaneously represent a hydrogen atom,  W 1 represents a nitrogen atom or C-Y 1,  W 2 represents a nitrogen atom or C-Y 2,  W 3 represents a nitrogen atom or C-Y 3,  provided that, when W 1 represents a nitrogen atom, W 2 and W 3 represent C-Y 2 and C-Y 3, respectively;  when W 2 represents a nitrogen atom, W 1 and W 3 represent C-Y 1 and C-Y 3, respectively;  and when W 3 represents a nitrogen atom, W 1 and  W 2 represent C-Y 1 and C-Y 2, respectively,  Y 1, Y 2, Y 3, Y 4, and Y 5 each independently represent a hydrogen atom, A, or B,  provided that W 1, W 2, and W 3 respectively represent C-Y 1, C-Y 2, and C-Y 3, and, when Z represents a bond, methylene optionally substituted by one or two methyl groups, or an oxygen atom, at least one of Y 1, Y 2, Y 3, Y 4, and Y 5 represents A,  wherein A represents a group selected from the group consisting of: C 1-8 alkyl which is substituted by one or more groups selected from one or more halogen atoms which may be the same or different, C 1-4 alkyloxy substituted by one or more halogen atoms which may be the same or different, and C 2-4 alkenyloxy substituted by one or more halogen atoms which may be the same or different;  C 2-8 alkenyl which is substituted by one or more groups selected from one or more halogen atoms which may be the same or different, C 1-4 alkyloxy substituted by one or more halogen atoms which may be the same or different, and C 2-4 alkenyloxy substituted by one or more halogen atoms which may be the same or different;  C 1-8 alkyloxy which is substituted by one or more groups selected from one or more halogen atoms which may be the same or different, C 1-4 alkyloxy substituted by one or more halogen atoms which may be the same or different, and C 2-4 alkenyloxy substituted by one or more halogen atoms which may be the same or different;  C 2-8 alkenyloxy which is substituted by one or more groups selected from one or more halogen atoms which may be the same or different, C 1-4 alkyloxy substituted by one or more halogen atoms which may be the same or different, and C 2-4 alkenyloxy substituted by one or more halogen atoms which may be the same or different;  C 1-8 alkyloxycarbonyl which is optionally substituted by one or more halogen atoms which may be the same or different, and/or C 1-4 alkyloxy substituted by one or more halogen atoms which may be the same or different;  C 1-8 alkylthio which is optionally substituted by one or more halogen atoms which may be the same or different, and/or C 1-4 alkyloxy substituted by one or more halogen atoms which may be the same or different;  C 2-8 alkenylthio which is optionally substituted by one or more halogen atoms which may be the same or different, and/or C 1-4 alkyloxy substituted by one or more halogen atoms which may be the same or different;  C 1-8 alkylsulfinyl which is optionally substituted by one or more halogen atoms which may be the same or different, and/or C 1-4 alkyloxy substituted by one or more halogen atoms which may be the same or different;  C 2-8 alkenylsulfinyl which is optionally substituted by one or more halogen atoms which may be the same or different, and/or C 1-4 alkyloxy substituted by one or more halogen atoms which may be the same or different;  C 1-8 alkylsulfonyl which is optionally substituted by one or more halogen atoms which may be the same or different, and/or C 1-4 alkyloxy substituted by one or more halogen atoms which may be the same or different;  C 2-8 alkenylsulfonyl which is optionally substituted by one or more halogen atoms which may be the same or different, and/or C 1-4 alkyloxy substituted by one or more halogen atoms which may be the same or different;   phenyl which is substituted by one or more halogen atoms which may be the same or different, C 1-4 alkyl substituted by one or more halogen atoms which may be the same or different, or C 1-4 alkyloxy substituted by one or more halogen atoms which may be the same or different;  and  phenoxy which is substituted by one or more halogen atoms which may be the same or different, C 1-4 alkyl substituted by one or more halogen atoms which may be the same or different, or C 1-4 alkyloxy substituted by one or more halogen atoms which may be the same or different, B represents a group selected from the group consisting of a halogen atom, C 1-4 alkyl, C 1-4 alkyloxy, nitro, and cyano,  alternatively adjacent two of Y 1, Y 2, Y 3, Y 4, and Y 5 may together represent  -O-(CH 2) n-O- optionally substituted by halogen atom,  -(CH 2) n-O- optionally substituted by halogen atom,  -S-(CH 2) n-S- optionally substituted by halogen atom,  -(CH 2) n-S- optionally substituted by halogen atom, or  -(CH 2) n- optionally substituted by halogen atom,  wherein n is 1, 2, or 3,  Z represents a bond, an oxygen atom, a sulfur atom, SO, SO 2, - Q-, -O-Q-, -O-Q-O-, or CO, and  Q represents C 1-4 alkylene which is optionally substituted by halogen atom, cyano, or C 1-4 alkyl optionally substituted by halogen atom;  -(CH 2) p-CR 10R 11-(CH 2) q- wherein R 10, R 11 and the carbon atom to which they are attached to together represent C 3-6 cycloalkyl which is optionally substituted by halogen atom or C 1-4 alkyl optionally substituted by halogen atom, and p and q each independently are an integer of 0 to 3;  or C 2-4 alkenylene which is optionally substituted by halogen atom, cyano, or C 1-4 alkyl optionally substituted by halogen atom. 2. The compound according to claim 1, wherein  R 1 represents  a hydrogen atom,  an alkali metal,  an alkaline earth metal,  optionally substituted C 1-18 alkyl,  COR 4 wherein R 4 represents optionally substituted C 1-18 alkyl;  optionally substituted C 2-18 alkenyl;  optionally substituted C 3-10 cycloalkyl;  optionally substituted C 1-4 alkylthio;  OR 5  wherein R 5 represents optionally substituted C 1-18 alkyl, optionally substituted C 2-18 alkenyl, or optionally substituted phenyl;  or NR 6R 7 wherein R 6 and R 7 each independently represent a hydrogen atom or optionally substituted C 1-18 alkyl, or  SO 2R 8 wherein R 8 represents optionally substituted C 1-18 alkyl,  R 2 represents a hydrogen atom or optionally substituted C 1-4 alkyl,  R 3 represents optionally substituted C 1-18 alkyl,  alternatively R 2 and R 3 together represent -(CH 2) m- wherein m is 3 or 4,  X 1, X 2, and X 3 each independently represent a hydrogen atom, a halogen atom, C 1-4 alkyl optionally substituted by halogen atom, C 1-4 alkyloxy optionally substituted by halogen atom, C 1-4 alkyloxycarbonyl optionally substituted by halogen atom, nitro, or cyano,  provided that X 1, X 2, and X 3 do not simultaneously represent a hydrogen atom, and  Z represents a bond, an oxygen atom, a sulfur atom, SO, SO 2, CH 2, OCH 2, O(CH 2) 3O, or CO. 3. The compound according to claim 1, wherein  R 1 represents  a hydrogen atom,  an alkali metal,  an alkaline earth metal,  C 1-18 alkyl optionally substituted by C 1-4 alkyloxycarbonyl or C 1-4 alkyloxy-C 1-4 alkyloxy,  COR 4 wherein R 4 represents C 1-18 alkyl optionally substituted by C 1-4 alkyloxy or acetyloxy;  C 2-18 alkenyl;  C 3-10 cycloalkyl;  C 1-4 alkylthio;  OR 5 wherein R 5 represents C 1-18 alkyl optionally substituted by halogen atom or C 1-4 alkyloxy, C 2-18 alkenyl, or phenyl;  or NR 6R 7 wherein R 6 and R 7 each independently represent a hydrogen atom or C 1-18 alkyl, or  SO 2R 8 wherein R 8 represents C 1-18 alkyl,  R 2 represents a hydrogen atom or C 1-4 alkyl,  R 3 represents C 1-18 alkyl optionally substituted by halogen atom or acetyloxy,  alternatively R 2 and R 3 together represent -(CH 2) m- wherein m is 3 or 4,  X 1, X 2, and X 3 each independently represent a hydrogen atom, a halogen atom, C 1-4 alkyl optionally substituted by halogen atom, C 1-4 alkyloxy, C 1-4 alkyloxycarbonyl, nitro, or cyano,  provided that X 1, X 2, and X 3 do not simultaneously represent a hydrogen atom, and  Z represents a bond, an oxygen atom, a sulfur atom, SO, SO 2, CH 2, OCH 2, O(CH 2) 3O, or CO. 4. The compound according to claim 1, wherein  W 1, W 2, and W 3 represent C-Y 1, C-Y 2, and C-Y 3, respectively,  Y 1, Y 2, Y 3, Y 4, and Y 5 each independently represent a hydrogen atom, A', or B',  provided that, when Z represents a bond, methylene optionally substituted by one or two methyl, or an oxygen atom, at least one of Y 1, Y 2, Y 3, Y 4, and Y 5 represents A',  wherein A' represents a group selected from the group consisting of: C 1-8 alkyl which is substituted by one or more halogen atoms which may be the same or different;  C 1-8 alkyloxy which is substituted by one or more halogen atoms which may be the same or different, and/or C 1-4 alkyloxy substituted by one or more halogen atoms which may be the same or different;  C 1-8 alkyloxycarbonyl;  C 1-8 alkylthio which is substituted by one or more halogen atoms which may be the same or different;  C 1-8 alkylsulfonyl which is subsituted by one or more halogen atoms which may be the same or different;   phenyl which is substituted by one or more halogen atoms which may be the same or different, or C 1-4 alkyl substituted by one or more halogen atoms which may be the same or different;  and  phenoxy which is substituted by one or more halogen atoms which may be the same or different, or C 1-4 alkyl substituted by one or more halogen atoms which may be the same or different,  B' represents a group selected from the group consisting of a halogen atom, C 1-4 alkyl, C 1-4 alkyloxy, and cyano,  alternatively adjacent two of Y 1, Y 2, Y 3, Y 4, and Y 5 may together represent -O-(CH 2) n-O- substituted by one or more halogen atoms, wherein n is 1 or 2. 5. The compound according to claim 1, wherein  any one of W 1, W 2, and W 3 represents a nitrogen atom, and the other two groups represent the corresponding C-Y 1, C-Y 2, or C-Y 3, and  Y 1, Y 2, Y 3, Y 4, and Y 5 each independently represent a hydrogen atom;  C 1-8 alkyl substituted by one or more halogen atoms which may be the same or different;  or a halogen atom. 6. The compound according to claim 1, wherein  R 1 represents a hydrogen atom;  or COR 4 wherein R 4 represents C 1-4 alkyl, OR 5 wherein R 5 represents C 1-4 alkyl, or NR 6R 7  wherein R 6 and R 7 each independently represent a hydrogen atom or C 1-18 alkyl,  R 2 represents C 1-4 alkyl,  R 3 represents C 1-4 alkyl,  alternatively R 2 and R 3 together represent -(CH 2) m- wherein m is 3 or 4,  X 1 and X 2 each independently represent a hydrogen atom, a halogen atom, C 1-4 alkyl optionally substituted by halogen atom, C 1-4 alkyloxy, or C 1-4 alkyloxycarbonyl,  provided that X 1 and X 2 do not simultaneously represent a hydrogen atom,  X 3 represents a hydrogen atom, and  Z represents an oxygen atom, OCH 2, or O(CH 2) 3O. 7. The compound according to claim 1, wherein  W 1, W 2, and W 3 represent C-Y 1, C-Y 2, and C-Y 3, respectively, and  Y 1, Y 2, Y 3, Y 4, and Y 5 each independently represent a hydrogen atom;  C 1-8 alkyl which is substituted by one or more halogen atoms which may be the same or different;  C 1-8 alkyloxy which is substituted by one or more halogen atoms which may be the same or different, and/or C 1-4 alkyloxy substituted by one or more halogen atoms which may be the same or different;  C 1-8 alkylthio which is substituted by one or more halogen atoms which may be the same or different;  or a halogen atom,  provided that at least one of Y 1, Y 2, Y 3, Y 4, and Y 5 represents C 1-8 alkyl which is substituted by one or more halogen atoms which may be the same or different;  C 1-8 alkyloxy which is substituted by one or more halogen atoms which may be the same or different, and/or C 1-4 alkyloxy substituted by one or more halogen atoms which may be the same or different;  or C 1-8 alkylthio which is substituted by one or more halogen atoms which may be the same or different,  alternatively adjacent two of Y 1, Y 2, Y 3, Y 4, and Y 5 may together represent -O-(CH 2) n-O- substituted by one or more halogen atoms, wherein n is 1 or 2. 8. The compound according to claim 1, wherein  R 1 represents a hydrogen atom;  or COR 4 wherein R 4 represents C 1-4 alkyl, OR 5 wherein R 5 represents C 1-4 alkyl, or NR 6R 7  wherein R 6 and R 7 each independently represent a hydrogen atom or C 1-18 alkyl,  R 2 represents C 1-4 alkyl,  R 3 represents C 1-4 alkyl,  alternatively R 2 and R 3 together represent -(CH 2) m- wherein m is 3 or 4,  X 1 and X 2 each independently represent a hydrogen atom, a halogen atom, C 1-4 alkyl optionally substituted by halogen atom, C 1-4 alkyloxy, or C 1-4 alkyloxycarbonyl,  provided that X 1 and X 2 do not simultaneously represent a hydrogen atom,  X 3 represents a hydrogen atom,  W 1, W 2, and W 3 represent C-Y 1, C-Y 2, and C-Y 3, respectively, and  Y 1, Y 2, Y 3, Y 4, and Y 5 each independently represent a hydrogen atom;  C 1-8 alkyl which is substituted by one or more halogen atoms which may be the same or different;  C 1-8 alkyloxy which is substituted by one or more halogen atoms which may be the same or different, and/or C 1-4 alkyloxy substituted by one or more halogen atoms which may be the same or different;  C 1-8 alkylthio which is substituted by one or more halogen atoms which may be the same or different;  or a halogen atom,  provided that at least one of Y 1, Y 2, Y 3, Y 4, and Y 5 represents C 1-8 alkyl which is substituted by one or more halogen atoms which may be the same or different;  C 1-8 alkyloxy which is substituted by one or more halogen atoms which may be the same or different, and/or C 1-4 alkyloxy substituted by one or more halogen atoms which may be the same or different;  or C 1-8 alkylthio which is substituted by one or more halogen atoms which may be the same or different,  alternatively adjacent two of Y 1, Y 2, Y 3, Y 4, and Y 5 may together represent -O-(CH 2) n-O- substituted by one or more halogen atoms, wherein n is 1 or 2, and  Z represents an oxygen atom, OCH 2, or O(CH 2) 3O. 9. The compound according to claim 1, wherein  R 1 represents COR 4' or COOR 5 wherein R 4' and R 5 represent C 1-4 alkyl,  R 2 represents C 1-4 alkyl,  R 3 represents C 1-4 alkyl,  X 1 and X 2 each independently represent a hydrogen atom, or C 1-4 alkyl optionally substituted by halogen atom,  provided that X 1 and X 2 do not simultaneously represent a hydrogen atom,  X 3 represents a hydrogen atom,  W 1, W 2, and W 3 represent C-Y 1, C-Y 2, and C-Y 3, respectively,  Y 1, Y 2, Y 3, Y 4, and Y 5 each independently represent a hydrogen atom;  C 1-8 alkyloxy which is substituted by one or more halogen atoms which may be the same or different, and/or C 1-4 alkyloxy substituted by one or more halogen atoms which may be the same or different;  or a halogen atom,  provided that at least one of Y 1, Y 2, Y 3, Y 4, and Y 5 represents C 1-8 alkyloxy which is substituted by one or more halogen atoms which may be the same or different, and/or C 1-4 alkyloxy substituted by one or more halogen atoms which may be the same or different,  alternatively adjacent two of Y 1, Y 2, Y 3, Y 4, and Y 5 may together represent -O-(CH 2) n-O- substituted by one or more halogen atoms, wherein n is 1 or 2, and  Z represents an oxygen atom. 10. An agricultural or horticultural insecticide comprising as an active ingredient a compound according to any one of claims 1 to 9 or an agriculturally and horticulturally acceptable acid addition salt thereof. 11. An agricultural or horticultural insecticide comprising as an active ingredient a compound represented by formula (Ia) or an agriculturally and horticulturally acceptable acid addition salt thereof: (see diagramm) wherein  R 1 represents  a hydrogen atom,  an alkali metal,  an alkaline earth metal,  optionally substituted C 1-18 alkyl,  optionally substituted C 2-18 alkenyl,  optionally substituted C 2-18 alkynyl,  optionally substituted C 3-10 cycloalkyl,  optionally substituted phenyl lower alkyl,  optionally substituted phenoxy lower alkyl,  optionally substituted phenyl,  optionally substituted heterocyclic group,  COR 4 wherein R 4 represents  optionally substituted C 1-18 alkyl,  optionally substituted C 2-18 alkenyl,  optionally substituted C 2-18 alkynyl,  optionally substituted C 3-10 cycloalkyl,  optionally substituted phenyl lower alkyl,  optionally substituted phenoxy lower alkyl,  optionally substituted phenyl,  optionally substituted heterocyclic group,  optionally substituted C 1-4 alkylthio,  OR 5 wherein R 5 represents  optionally substituted C 1-18 alkyl,  optionally substituted C 2-18 alkenyl,  optionally substituted C 2-18 alkynyl,  optionally substituted C 3-10 cycloalkyl,  optionally substituted phenyl lower alkyl,  optionally substituted phenoxy lower alkyl,  optionally substituted phenyl, or  optionally substituted heterocyclic group, or  NR 6R 7 wherein R 6 and R 7 each independently represents  a hydrogen atom,  optionally substituted C 1-18 alkyl, or  optionally substituted phenyl, or  SO 2R 8 wherein R 8 represents  optionally substituted C 1-18 alkyl,  optionally substituted C 2-18 alkenyl,  optionally substituted C 2-18 alkynyl,  optionally substituted C 3-10 cycloalkyl,  optionally substituted phenyl lower alkyl,  optionally substituted phenoxy lower alkyl,  optionally substituted phenyl, or  optionally substituted heterocyclic group,  R 2 represents a hydrogen atom or optionally substituted C 1-4 alkyl,  R 3 represents  a hydrogen atom,  optionally substituted C 1-18 alkyl,  optionally substituted C 2-4 alkenyl, or  optionally substituted C 1-4 alkoxy,  wherein, in R 1, R 2, and R 3, the substituent in each of the optionally substituted groups is selected from the group consisting of halogen atom;  C 1-4 alkyloxy;  C 1-4 alkyloxy-C 1-4 alkyloxy;  C 1-4 alkyloxycarbonyl;  nitro;  cyano;  formyl;  trifluoromethyl;  trifluoromethoxy;  acetyl;  acetyloxy;  C 1-4 alkyl, provided that this C 1-4 alkyl is not a substituent for the alkyl group;  and C 3-6 cycloalkyl optionally substituted by halogen atom,  alternatively R 2 and R 3 together represent -(CH 2) m- wherein m is 3 or 4,  X 1, X 2, and X 3 each independently represent  a hydrogen atom,  a halogen atom,  C 1-4 alkyl optionally substituted by halogen atom,  C 1-4 alkyloxy optionally substituted by halogen atom,  C 1-4 alkylthio optionally substituted by halogen atom,  C 1-4 alkyloxycarbonyl optionally substituted by halogen atom,  nitro, or  cyano,  provided that X 1, X 2, and X 3 do not simultaneously represent a hydrogen atom,  W 11 represents a nitrogen atom or C-Y 11,  W 12 represents a nitrogen atom or C-Y 12,  W 13 represents a nitrogen atom or C-Y 13,  provided that, when W 11 represents a nitrogen atom, W 12 and W 13 represent C-Y 12 and C-Y 13, respectively;  when W 2 represents a nitrogen atom, W 11 and W 13 represent C-Y 11 and C-Y 13, respectively;  and when W 13 represents a nitrogen atom, W 11 and W 12 represent C-Y 11 and C-Y 12, respectively,  Y 11, Y 12, Y 13, Y 14, and Y 15 each independently represent a hydrogen atom, A, or B,  wherein A represents a group selected from the group consisting of: C 1-8 alkyl which is substituted by one or more groups selected from one or more halogen atoms which may be the same or different, C 1-4 alkyloxy substituted by one or more halogen atoms which may be the same or different, and C 2-4 alkenyloxy substituted by one or more halogen atoms which may be the same or different;  C 2-8 alkenyl which is substituted by one or more groups selected from one or more halogen atoms which may be the same or different, C 1-4 alkyloxy substituted by one or more halogen atoms which may be the same or different, and C 2-4 alkenyloxy substituted by one or more halogen atoms which may be the same or different;  C 1-8 alkyloxy which is substituted by one or more groups selected from one or more halogen atoms which may be the same or different, C 1-4 alkyloxy substituted by one or more halogen atoms which may be the same or different, and C 2-4 alkenyloxy substituted by one or more halogen atoms which may be the same or different;  C 2-8 alkenyloxy which is substituted by one or more groups selected from one or more halogen atoms which may be the same or different, C 1-4 alkyloxy substituted by one or more halogen atoms which may be the same or different, and C 2-4 alkenyloxy substituted by one or more halogen atoms which may be the same or different;  C 1-8 alkyloxycarbonyl which is optionally substituted by one or more halogen atoms which may be the same or different, and/or C 1-4 alkyloxy substituted by one or more halogen atoms which may be the same or different;  C 1-8 alkylthio which is optionally substituted by one or more halogen atoms which may be the same or different, and/or C 1-4 alkyloxy substituted by one or more halogen atoms which may be the same or different;  C 2-8 alkenylthio which is optionally substituted by one or more halogen atoms which may be the same or different, and/or C 1-4 alkyloxy substituted by one or more halogen atoms which may be the same or different;  C 1-8 alkylsulfinyl which is optionally substituted by one or more halogen atoms which may be the same or different, and/or C 1-4 alkyloxy substituted by one or more halogen atoms which may be the same or different;  C 2-8 alkenylsulfinyl which is optionally substituted by one or more halogen atoms which may be the same or different, and/or C 1-4 alkyloxy substituted by one or more halogen atoms which may be the same or different;  C 1-8 alkylsulfonyl which is optionally substituted by one or more halogen atoms which may be the same or different, and/or C 1-4 alkyloxy substituted by one or more halogen atoms which may be the same or different;  C 2-8 alkenylsulfonyl which is optionally substituted by one or more halogen atoms which may be the same or different, and/or C 1-4 alkyloxy substituted by one or more halogen atoms which may be the same or different;   phenyl which is substituted by one or more halogen atoms which may be the same or different, C 1-4 alkyl substituted by one or more halogen atoms which may be the same or different, or C 1-4 alkyloxy substituted by one or more halogen atoms which may be the same or different;  and  phenoxy which is substituted by one or more halogen atoms which may be the same or different, C 1-4 alkyl substituted by one or more halogen atoms which may be the same or different, or C 1-4 alkyloxy substituted by one or more halogen atoms which may be the same or different, B represents a group selected from the group consisting of a halogen atom, C 1-4 alkyl, C 1-4 alkyloxy, nitro, and cyano,  alternatively adjacent two of Y 11, Y 12, Y 13, Y 14, and Y 15 may together represent  -O-(CH 2) n-O- optionally substituted by halogen atom,  -(CH 2) n-O- optionally substituted by halogen atom,  -S-(CH 2) n-S- optionally substituted by halogen atom,  -(CH 2) n-S- optionally substituted by halogen atom, or  -(CH 2) n- optionally substituted by halogen atom,  wherein n is 1, 2, or 3,  Z represents a bond, an oxygen atom, a sulfur atom, SO, SO 2, - Q-, -O-Q-, -O-Q-O-, or CO, and  Q represents C 1-4 alkylene which is optionally substituted by halogen atom, cyano, or C 1-4 alkyl optionally substituted by halogen atom;  -(CH 2) p-CR 10R 11-(CH 2) q- wherein R 10, R 11 and the carbon atom to which they are attached together represent C 3-6 cycloalkyl which is optionally substituted by halogen atom or C 1-4 alkyl optionally substituted by halogen atom, and p and q each independently are an integer of 0 to 3;  or C 2-4 alkenylene which is optionally substituted by halogen atom, cyano, or C 1-4 alkyl optionally substituted by halogen atom. 12. A method for controlling an agricultural and horticultural insect pest, comprising the step of applying an effective amount of a compound according to any one of claims 1 to 9 or an agriculturally and horticulturally acceptable acid addition salt thereof to a plant or soil. 13. A method for controlling an agricultural and horticultural insect pest, comprising the step of applying an effective amount of a compound represented by formula (Ia) as defined in claim 11 or an agriculturally and horticulturally acceptable acid addition salt thereof to a plant or soil. 14. The method according to claim 12 or 13, wherein said insect pest is selected from the group consisting of Lepidoptera, Hemiptera, Coleoptera, Acari, Hymenoptera, Orthoptera, Diptera, Thysanoptera, and plant parasitic nematoda. 15. Use of a compound according to any one of claims 1 to 9 or an agriculturally and horticulturally acceptable acid addition salt thereof, as an agricultural and horticultural insecticide. 16. Use of a compound represented by formula (Ia) as defined in claim 11 or an agriculturally and horticulturally acceptable acid addition salt thereof, as an agricultural and horticultural insecticide.
法律状态
(EP1780202) LEGAL DETAILS FOR EP1780202  Actual or expected expiration date=2025-08-03    Legal state=ALIVE    Status=GRANTED     Event publication date=2005-08-03  Event code=EP/APP  Event indicator=Pos  Event type=Examination events  Application details  Application country=EP EP05768511  Application date=2005-08-03  Standardized application number=2005EP-0768511     Event publication date=2007-05-02  Event code=EP/A1  Event type=Examination events  Application published with search report  Publication country=EP  Publication number=EP1780202  Publication stage Code=A1  Publication date=2007-05-02  Standardized publication number=EP1780202     Event publication date=2007-05-02  Event code=EP/17P  Event indicator=Pos  Event type=Examination events  Request for examination filed Pruefungsantrag gestellt  Effective date of the event=2007-02-20     Event publication date=2007-05-02  Event code=EP/AK  Event indicator=Pos  Event type=Designated states  Designated contracting states: Benannte vertragsstaaten AT BE BG CH CY CZ DE DK EE ES FI FR GB GR HU IE IS IT LI LT LU LV MC NL PL PT RO SE SI SK TR    Event publication date=2007-08-15  Event code=EP/RIN1  Event type=Change of name or address  Event type=Administrative notifications  Inventor (correction) Inventor changed before grant    Event publication date=2007-08-15  Event code=EP/RIN1  Event type=Change of name or address  Event type=Administrative notifications  Inventor (correction) Inventor changed before grant    Event publication date=2007-08-15  Event code=EP/RIN1  Event type=Change of name or address  Event type=Administrative notifications  Inventor (correction) Inventor changed before grant    Event publication date=2007-08-15  Event code=EP/RIN1  Event type=Change of name or address  Event type=Administrative notifications  Inventor (correction) Inventor changed before grant    Event publication date=2007-08-15  Event code=EP/RIN1  Event type=Change of name or address  Event type=Administrative notifications  Inventor (correction) Inventor changed before grant    Event publication date=2007-08-15  Event code=EP/RIN1  Event type=Change of name or address  Event type=Administrative notifications  Inventor (correction) Inventor changed before grant    Event publication date=2007-08-15  Event code=EP/RIN1  Event type=Change of name or address  Event type=Administrative notifications  Inventor (correction) Inventor changed before grant    Event publication date=2007-08-15  Event code=EP/RIN1  Event type=Change of name or address  Event type=Administrative notifications  Inventor (correction) Inventor changed before grant    Event publication date=2007-11-07  Event code=EP/DAX  Event indicator=Neg  Event type=Designated states  Request for extension of the european patent (to any country) deleted    Event publication date=2009-06-17  Event code=EP/A4  Event indicator=Pos  Event type=Examination events  Supplementary search report Ergaenzender recherchenbericht  Publication country=EP  Publication number=EP1780202  Publication stage Code=A4  Publication date=2009-06-17  Standardized publication number=EP1780202     Event publication date=2009-06-17  Event code=EP/A4  Event indicator=Pos  Event type=Administrative notifications  Supplementary search report Despatch of supplementary search report  Effective date of the event=2009-05-20     Event publication date=2009-11-11  Event code=EP/17Q  Event indicator=Pos  Event type=Examination events  First examination report Erster pruefungsbescheid  Effective date of the event=2009-10-14     Event publication date=2009-11-11  Event code=EP/RIN1  Event type=Change of name or address  Event type=Administrative notifications  Inventor (correction) Inventor changed before grant    Event publication date=2009-11-11  Event code=EP/RIN1  Event type=Change of name or address  Event type=Administrative notifications  Inventor (correction) Inventor changed before grant    Event publication date=2009-11-11  Event code=EP/RIN1  Event type=Change of name or address  Event type=Administrative notifications  Inventor (correction) Inventor changed before grant    Event publication date=2009-11-11  Event code=EP/RIN1  Event type=Change of name or address  Event type=Administrative notifications  Inventor (correction) Inventor changed before grant    Event publication date=2009-11-11  Event code=EP/RIN1  Event type=Change of name or address  Event type=Administrative notifications  Inventor (correction) Inventor changed before grant    Event publication date=2009-11-11  Event code=EP/RIN1  Event type=Change of name or address  Event type=Administrative notifications  Inventor (correction) Inventor changed before grant    Event publication date=2009-11-11  Event code=EP/RIN1  Event type=Change of name or address  Event type=Administrative notifications  Inventor (correction) Inventor changed before grant    Event publication date=2009-11-11  Event code=EP/RIN1  Event type=Change of name or address  Event type=Administrative notifications  Inventor (correction) Inventor changed before grant    Event publication date=2012-02-22  Event code=EP/RAP1  Event type=Change of name or address  Event type=Reassignment  Transfer of rights of an application Anmelder uebertragung (korr.)    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Event publication date=2013-02-27  Event code=EP/B1  Event indicator=Pos  Event type=Event indicating In Force  Patent specification  Publication country=EP  Publication number=EP1780202  Publication stage Code=B1  Publication date=2013-02-27  Standardized publication number=EP1780202     Event publication date=2013-02-27  Event code=EP/AK  Event indicator=Pos  Event type=Designated states  Designated contracting states: Benannte vertragsstaaten AT BE BG CH CY CZ DE DK EE ES FI FR GB GR HU IE IS IT LI LT LU LV MC NL PL PT RO SE SI SK TR    Event publication date=2014-02-05  Event code=EP/26N  Event indicator=Pos  Event type=No opposition filed  Event type=Event indicating In Force  No opposition filed Kein einspruch eingelegt  Effective date of the event=2013-11-28  MEMBER STATE LEGAL DETAILS FOR AT  Actual or expected expiration date=2013-02-27    Legal state=DEAD    Status=LAPSED   Corresponding cc:  Designated or member state=AT Corresponding appl: AT598438    Event publication date=2013-03-15  Event code=EP/REG  Event code=AT/REF  Event indicator=Pos  Event type=Entry into national phase  Reference to a national code Reference to at number (ep patent enters austrian national phase) Nennung der e-nummer (ep patent tritt in at nationale phase ein) Corresponding cc:  Designated or member state=AT   Effective date of the event=2013-03-15     Event publication date=2013-07-15  Event code=EP/REG  Event code=AT/MK05  Event indicator=Neg  Event type=Event indicating Not In Force  Reference to a national code Revocation of the translation of the ep patent Loeschung gemaess par. 5 (zurueckziehung der uebersetzung des ep patents) Corresponding cc:  Designated or member state=AT   Effective date of the event=2013-02-27     Event publication date=2013-07-31  Event code=EP/PG25  Event indicator=Neg  Event type=Event indicating Not In Force  Event type=Payment or non-payment notifications  Lapsed in a contracting state announced via postgrant inform. from nat. office to EPO LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT  Corresponding cc:  Designated or member state=AT  MEMBER STATE LEGAL DETAILS FOR BE  Actual or expected expiration date=2013-08-30    Legal state=DEAD    Status=LAPSED   Corresponding cc:  Designated or member state=BE     Event publication date=2013-08-30  Event code=EP/PG25  Event indicator=Neg  Event type=Event indicating Not In Force  Event type=Payment or non-payment notifications  Lapsed in a contracting state announced via postgrant inform. from nat. office to EPO LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT  Corresponding cc:  Designated or member state=BE  MEMBER STATE LEGAL DETAILS FOR BG  Actual or expected expiration date=2013-07-31    Legal state=DEAD    Status=LAPSED   Corresponding cc:  Designated or member state=BG     Event publication date=2013-07-31  Event code=EP/PG25  Event indicator=Neg  Event type=Event indicating Not In Force  Event type=Payment or non-payment notifications  Lapsed in a contracting state announced via postgrant inform. from nat. office to EPO LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT  Corresponding cc:  Designated or member state=BG  MEMBER STATE LEGAL DETAILS FOR CH  Actual or expected expiration date=2025-08-03    Legal state=ALIVE    Status=GRANTED   Corresponding cc:  Designated or member state=CH     Event publication date=2013-02-28  Event code=EP/REG  Event code=CH/EP  Event indicator=Pos  Event type=Entry into national phase  Reference to a national code Entry in the national phase Eintritt in die nationale phase Corresponding cc:  Designated or member state=CH     Event publication date=2013-05-15  Event code=EP/REG  Event code=CH/NV  Event type=Change of name or address  Reference to a national code New agent Neuer vertreter/nouveaux mandataires/nuovi mandatari Corresponding cc:  Designated or member state=CH     Event publication date=2016-08-19  Event code=EP/PGFP  Event indicator=Pos  Event type=Event indicating In Force  Event type=Payment or non-payment notifications  Postgrant: annual fees paid to national office   Annual fees payment date=2016-08-19     Year of payment of annual fees=12  Corresponding cc:  Designated or member state=CH  MEMBER STATE LEGAL DETAILS FOR CY  Actual or expected expiration date=2013-11-29    Legal state=DEAD    Status=LAPSED   Corresponding cc:  Designated or member state=CY     Event publication date=2013-11-29  Event code=EP/PG25  Event indicator=Neg  Event type=Event indicating Not In Force  Event type=Payment or non-payment notifications  Lapsed in a contracting state announced via postgrant inform. from nat. office to EPO LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT  Corresponding cc:  Designated or member state=CY  MEMBER STATE LEGAL DETAILS FOR CZ  Actual or expected expiration date=2013-10-31    Legal state=DEAD    Status=LAPSED   Corresponding cc:  Designated or member state=CZ     Event publication date=2013-10-31  Event code=EP/PG25  Event indicator=Neg  Event type=Event indicating Not In Force  Event type=Payment or non-payment notifications  Lapsed in a contracting state announced via postgrant inform. from nat. office to EPO LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT  Corresponding cc:  Designated or member state=CZ  MEMBER STATE LEGAL DETAILS FOR DE  Actual or expected expiration date=2025-08-03    Legal state=ALIVE    Status=GRANTED   Corresponding cc:  Designated or member state=DE Corresponding appl: DE602005038344    Event publication date=2013-04-25  Event code=EP/REG  Event code=DE/R096  Event indicator=Pos  Event type=Examination events  Reference to a national code DPMA publication of mentioned EP patent grant Veroeffentlichung eines hinweises auf die ep-patenterteilung durch das dpma Corresponding cc:  Designated or member state=DE   Effective date of the event=2013-04-25     Event publication date=2014-03-13  Event code=EP/REG  Event code=DE/R097  Event indicator=Pos  Event type=No opposition filed  Reference to a national code No opposition filed against granted patent, or EPO opposition proceedings concluded without decision Gegen die patenterteilung wurde kein einspruch erhoben, bzw. einspruchsverfahren ist beim epa ohne entscheidung abgeschlossen Corresponding cc:  Designated or member state=DE   Effective date of the event=2013-11-28     Event publication date=2016-08-22  Event code=EP/PGFP  Event indicator=Pos  Event type=Event indicating In Force  Event type=Payment or non-payment notifications  Postgrant: annual fees paid to national office   Annual fees payment date=2016-08-22     Year of payment of annual fees=12  Corresponding cc:  Designated or member state=DE  MEMBER STATE LEGAL DETAILS FOR DK  Actual or expected expiration date=2013-10-31    Legal state=DEAD    Status=LAPSED   Corresponding cc:  Designated or member state=DK     Event publication date=2013-10-31  Event code=EP/PG25  Event indicator=Neg  Event type=Event indicating Not In Force  Event type=Payment or non-payment notifications  Lapsed in a contracting state announced via postgrant inform. from nat. office to EPO LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT  Corresponding cc:  Designated or member state=DK  MEMBER STATE LEGAL DETAILS FOR EE  Actual or expected expiration date=2013-10-31    Legal state=DEAD    Status=LAPSED   Corresponding cc:  Designated or member state=EE     Event publication date=2013-10-31  Event code=EP/PG25  Event indicator=Neg  Event type=Event indicating Not In Force  Event type=Payment or non-payment notifications  Lapsed in a contracting state announced via postgrant inform. from nat. office to EPO LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT  Corresponding cc:  Designated or member state=EE  MEMBER STATE LEGAL DETAILS FOR ES2407813  Actual or expected expiration date=2025-08-03    Legal state=ALIVE    Status=GRANTED   Corresponding cc:  Designated or member state=ES Corresponding appl: ES05768511  Application date in the designated or member state=2005-08-03   Application number in the designated or member state=2005ES-0768511T Corresponding cc:  Designated or member state=ES Corresponding pat: ES2407813  Publication stage code in the designated or member state=T3  Publication date in the designated or member state=2013-06-14   Publication number in the designated or member state=ES2407813    Event publication date=2013-06-14  Event code=EP/REG  Event code=ES/FG2A  Event indicator=Pos  Event type=Event indicating In Force  Reference to a national code Definitive protection Proteccion definitiva Corresponding cc:  Designated or member state=ES   Effective date of the event=2013-06-14     Event publication date=2016-08-10  Event code=EP/PGFP  Event indicator=Pos  Event type=Event indicating In Force  Event type=Payment or non-payment notifications  Postgrant: annual fees paid to national office   Annual fees payment date=2016-08-10     Year of payment of annual fees=12  Corresponding cc:  Designated or member state=ES  MEMBER STATE LEGAL DETAILS FOR FI  Actual or expected expiration date=2013-08-30    Legal state=DEAD    Status=LAPSED   Corresponding cc:  Designated or member state=FI     Event publication date=2013-08-30  Event code=EP/PG25  Event indicator=Neg  Event type=Event indicating Not In Force  Event type=Payment or non-payment notifications  Lapsed in a contracting state announced via postgrant inform. from nat. office to EPO LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT  Corresponding cc:  Designated or member state=FI  MEMBER STATE LEGAL DETAILS FOR FR  Actual or expected expiration date=2025-08-03    Legal state=ALIVE    Status=GRANTED   Corresponding cc:  Designated or member state=FR     Event publication date=2016-08-22  Event code=EP/REG  Event code=FR/PLFP  Event indicator=Pos  Event type=Payment or non-payment notifications  Event type=Restitution or restoration  Reference to a national code Fee payment Derniere annuite payee   Annual fees payment date=2016-08-22     Year of payment of annual fees=12  Corresponding cc:  Designated or member state=FR     Event publication date=2016-08-22  Event code=EP/PGFP  Event indicator=Pos  Event type=Event indicating In Force  Event type=Payment or non-payment notifications  Postgrant: annual fees paid to national office   Annual fees payment date=2016-08-22     Year of payment of annual fees=12  Corresponding cc:  Designated or member state=FR     Event publication date=2017-08-22  Event code=EP/REG  Event code=FR/PLFP  Event indicator=Pos  Event type=Payment or non-payment notifications  Event type=Restitution or restoration  Reference to a national code Fee payment Derniere annuite payee   Annual fees payment date=2017-08-22     Year of payment of annual fees=13  Corresponding cc:  Designated or member state=FR  MEMBER STATE LEGAL DETAILS FOR GB  Actual or expected expiration date=2025-08-03    Legal state=ALIVE    Status=GRANTED   Corresponding cc:  Designated or member state=GB     Event publication date=2013-02-27  Event code=EP/REG  Event code=GB/FG4D  Event indicator=Pos  Event type=Event indicating In Force  Reference to a national code European patent granted Corresponding cc:  Designated or member state=GB     Event publication date=2016-08-19  Event code=EP/PGFP  Event indicator=Pos  Event type=Event indicating In Force  Event type=Payment or non-payment notifications  Postgrant: annual fees paid to national office   Annual fees payment date=2016-08-19     Year of payment of annual fees=12  Corresponding cc:  Designated or member state=GB  MEMBER STATE LEGAL DETAILS FOR GR  Actual or expected expiration date=2013-08-30    Legal state=DEAD    Status=LAPSED   Corresponding cc:  Designated or member state=GR     Event publication date=2013-08-30  Event code=EP/PG25  Event indicator=Neg  Event type=Event indicating Not In Force  Event type=Payment or non-payment notifications  Lapsed in a contracting state announced via postgrant inform. from nat. office to EPO LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT  Corresponding cc:  Designated or member state=GR  MEMBER STATE LEGAL DETAILS FOR HU  Actual or expected expiration date=2015-07-31    Legal state=DEAD    Status=LAPSED   Corresponding cc:  Designated or member state=HU     Event publication date=2015-07-31  Event code=EP/PG25  Event indicator=Neg  Event type=Event indicating Not In Force  Event type=Payment or non-payment notifications  Lapsed in a contracting state announced via postgrant inform. from nat. office to EPO LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT  INVALID AB INITIO  Corresponding cc:  Designated or member state=HU  MEMBER STATE LEGAL DETAILS FOR IE  Actual or expected expiration date=2014-05-21    Legal state=DEAD    Status=LAPSED   Corresponding cc:  Designated or member state=IE     Event publication date=2013-03-27  Event code=EP/REG  Event code=IE/FG4D  Event indicator=Pos  Event type=Event indicating In Force  Reference to a national code European patents granted designating ireland Corresponding cc:  Designated or member state=IE     Event publication date=2014-05-21  Event code=EP/REG  Event code=IE/MM4A  Event indicator=Neg  Event type=Event indicating Not In Force  Reference to a national code Patent lapsed Corresponding cc:  Designated or member state=IE     Event publication date=2014-07-31  Event code=EP/PG25  Event indicator=Neg  Event type=Event indicating Not In Force  Event type=Payment or non-payment notifications  Lapsed in a contracting state announced via postgrant inform. from nat. office to EPO LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES  Corresponding cc:  Designated or member state=IE  MEMBER STATE LEGAL DETAILS FOR IS  Actual or expected expiration date=2013-07-31    Legal state=DEAD    Status=LAPSED   Corresponding cc:  Designated or member state=IS     Event publication date=2013-07-31  Event code=EP/PG25  Event indicator=Neg  Event type=Event indicating Not In Force  Event type=Payment or non-payment notifications  Lapsed in a contracting state announced via postgrant inform. from nat. office to EPO LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT  Corresponding cc:  Designated or member state=IS  MEMBER STATE LEGAL DETAILS FOR IT  Actual or expected expiration date=2025-08-03    Legal state=ALIVE    Status=GRANTED   Corresponding cc:  Designated or member state=IT     Event publication date=2016-08-25  Event code=EP/PGFP  Event indicator=Pos  Event type=Event indicating In Force  Event type=Payment or non-payment notifications  Postgrant: annual fees paid to national office   Annual fees payment date=2016-08-25     Year of payment of annual fees=12  Corresponding cc:  Designated or member state=IT  MEMBER STATE LEGAL DETAILS FOR LT  Actual or expected expiration date=2013-07-25    Legal state=DEAD    Status=LAPSED   Corresponding cc:  Designated or member state=LT     Event publication date=2013-07-25  Event code=EP/REG  Event code=LT/MG4D  Event indicator=Neg  Event type=Event indicating Not In Force  Reference to a national code Invalidated european patent Europos patentai, laikomi ab initio negaliojanciais Corresponding cc:  Designated or member state=LT     Event publication date=2013-07-31  Event code=EP/PG25  Event indicator=Neg  Event type=Event indicating Not In Force  Event type=Payment or non-payment notifications  Lapsed in a contracting state announced via postgrant inform. from nat. office to EPO LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT  Corresponding cc:  Designated or member state=LT  MEMBER STATE LEGAL DETAILS FOR LU  Actual or expected expiration date=2015-07-31    Legal state=DEAD    Status=LAPSED   Corresponding cc:  Designated or member state=LU     Event publication date=2015-07-31  Event code=EP/PG25  Event indicator=Neg  Event type=Event indicating Not In Force  Event type=Payment or non-payment notifications  Lapsed in a contracting state announced via postgrant inform. from nat. office to EPO LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES  Corresponding cc:  Designated or member state=LU  MEMBER STATE LEGAL DETAILS FOR LV  Actual or expected expiration date=2013-08-30    Legal state=DEAD    Status=LAPSED   Corresponding cc:  Designated or member state=LV     Event publication date=2013-08-30  Event code=EP/PG25  Event indicator=Neg  Event type=Event indicating Not In Force  Event type=Payment or non-payment notifications  Lapsed in a contracting state announced via postgrant inform. from nat. office to EPO LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT  Corresponding cc:  Designated or member state=LV  MEMBER STATE LEGAL DETAILS FOR MC  Actual or expected expiration date=2014-04-30    Legal state=DEAD    Status=LAPSED   Corresponding cc:  Designated or member state=MC     Event publication date=2014-04-30  Event code=EP/PG25  Event indicator=Neg  Event type=Event indicating Not In Force  Event type=Payment or non-payment notifications  Lapsed in a contracting state announced via postgrant inform. from nat. office to EPO LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT  Corresponding cc:  Designated or member state=MC  MEMBER STATE LEGAL DETAILS FOR NL  Actual or expected expiration date=2025-08-03    Legal state=ALIVE    Status=GRANTED   Corresponding cc:  Designated or member state=NL     Event publication date=2013-06-05  Event code=EP/REG  Event code=NL/T3  Event indicator=Pos  Event type=Event indicating In Force  Reference to a national code Translation files for an european patent granted for nl, confirming art. 52 par. 1 or 6 of the patents act 1995 Voor nederland verleende europese octrooien waarvoor een vertaling is ingediend conform artikel 52 lid 1 of 6 van de ocrooiwet 1995 Corresponding cc:  Designated or member state=NL     Event publication date=2017-08-21  Event code=EP/PGFP  Event indicator=Pos  Event type=Event indicating In Force  Event type=Payment or non-payment notifications  Postgrant: annual fees paid to national office   Annual fees payment date=2017-08-21     Year of payment of annual fees=13  Corresponding cc:  Designated or member state=NL  MEMBER STATE LEGAL DETAILS FOR PL  Actual or expected expiration date=2013-08-30    Legal state=DEAD    Status=LAPSED   Corresponding cc:  Designated or member state=PL     Event publication date=2013-08-30  Event code=EP/PG25  Event indicator=Neg  Event type=Event indicating Not In Force  Event type=Payment or non-payment notifications  Lapsed in a contracting state announced via postgrant inform. from nat. office to EPO LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT  Corresponding cc:  Designated or member state=PL  MEMBER STATE LEGAL DETAILS FOR PT  Actual or expected expiration date=2013-08-30    Legal state=DEAD    Status=LAPSED   Corresponding cc:  Designated or member state=PT     Event publication date=2013-08-30  Event code=EP/PG25  Event indicator=Neg  Event type=Event indicating Not In Force  Event type=Payment or non-payment notifications  Lapsed in a contracting state announced via postgrant inform. from nat. office to EPO LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT  Corresponding cc:  Designated or member state=PT  MEMBER STATE LEGAL DETAILS FOR RO  Actual or expected expiration date=2013-10-31    Legal state=DEAD    Status=LAPSED   Corresponding cc:  Designated or member state=RO     Event publication date=2013-10-31  Event code=EP/PG25  Event indicator=Neg  Event type=Event indicating Not In Force  Event type=Payment or non-payment notifications  Lapsed in a contracting state announced via postgrant inform. from nat. office to EPO LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT  Corresponding cc:  Designated or member state=RO  MEMBER STATE LEGAL DETAILS FOR SE  Actual or expected expiration date=2013-07-31    Legal state=DEAD    Status=LAPSED   Corresponding cc:  Designated or member state=SE     Event publication date=2013-07-31  Event code=EP/PG25  Event indicator=Neg  Event type=Event indicating Not In Force  Event type=Payment or non-payment notifications  Lapsed in a contracting state announced via postgrant inform. from nat. office to EPO LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT  Corresponding cc:  Designated or member state=SE  MEMBER STATE LEGAL DETAILS FOR SI  Actual or expected expiration date=2013-08-30    Legal state=DEAD    Status=LAPSED   Corresponding cc:  Designated or member state=SI     Event publication date=2013-08-30  Event code=EP/PG25  Event indicator=Neg  Event type=Event indicating Not In Force  Event type=Payment or non-payment notifications  Lapsed in a contracting state announced via postgrant inform. from nat. office to EPO LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT  Corresponding cc:  Designated or member state=SI  MEMBER STATE 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office to EPO LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT  Corresponding cc:  Designated or member state=TR
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