A study of cadmium remediation and mechanisms: Improvements in the stability of walnut shell-derived biochar 机翻标题: 暂无翻译,请尝试点击翻译按钮。

来源
Science of the Total Environment
年/卷/期
2018 / 636 /
页码
80-84
ISSN号
0048-9697
作者单位
East China Normal Univ, Sch Ecol & Environm Sci, Shanghai Key Lab Urban Ecol Proc & Ecorestorat, Shanghai 200241, Peoples R China;East China Normal Univ, Sch Ecol & Environm Sci, Shanghai Key Lab Urban Ecol Proc & Ecorestorat, Shanghai 200241, Peoples R China;East China Normal Univ, Sch Ecol & Environm Sci, Shanghai Key Lab Urban Ecol Proc & Ecorestorat, Shanghai 200241, Peoples R China;East China Normal Univ, Sch Ecol & Environm Sci, Shanghai Key Lab Urban Ecol Proc & Ecorestorat, Shanghai 200241, Peoples R China;
作者
Qiu, Zhen;Chen, Jinhuan;Tang, Jiawen;Zhang, Qiuzhuo;
摘要
Biochar has been recognized as an efficient soil amendment for cadmium remediation in recent years. In the present study, biochar was prepared using walnut shell, and it was incubated in Cd(NO3)(2) and kaolin for 15 days. Different chemical forms of cadmium in kaolin and biochar were determined, and the stability of biochar was evaluated by R-50 using TGA analysis. It was found that walnut shell derived biochar could reduce the mobility of cadmium. After incubation, the R-50, biochar value increased from 61.31% to 69.57%-72.24%, indicating that the stability of biochar was improved. The mechanisms that initiated improvements in biochar stability were investigated by XPS, XRD and SEM-EDS analysis. The result showed that the enhanced biochar stability is likely due to physical isolation and the formation of precipitates and complexes, formed on the surface or interior of the biochar. The results suggested that walnut shell-derived biochar can be used as a cadmium sorbent for soil remediation. (C) 2018 Elsevier B.V. All rights reserved.
机翻摘要
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关键词/主题词
Biochar;Cadmium;Walnut shell;Kaolin;
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