[专利]
Method of polymethyl methacrylate producing
申请号:
2015RU-0132545
申请日:
2015-08-04
公开号:
RU2604538 C1 2016-12-10 [RU2604538]
公开日:
2016-12-10
申请人:
FEDERAL GOSUDARSTVENNOE AVTONOMNOE OBRAZOVATELNOE UCHREZHDENIE VYSSHEGO OBRAZOVANIJA NIZHEGORODSKIJ GOSU
专利权人:
FEDERAL GOSUDARSTVENNOE AVTONOMNOE OBRAZOVATELNOE UCHREZHDENIE VYSSHEGO OBRAZOVANIJA NIZHEGORODSKIJ GOSU
发明人:
VAGANOVA LJUDMILA BORISOVNA;LIZJAKINA OKSANA SERGEEVNA;CHEGEREV MAKSIM GENNADEVICH;PISKUNOV ALEKSANDR VLADIMIROVICH;GRISHIN DMITRIJ FEDOROVICH
国家:
IPC:
C08F-002/02;C08F-002/38;C08F-120/14
(RU2604538) FIELD: manufacturing technology.SUBSTANCE: invention relates to polymethacrylate producing method, which can be used in production of organic glass for aircraft industry, instrument making, for consumer goods production. Method of polymethyl methacrylate producing in methylmethacrylate mass in controlled mode is performed in presence of system consisting of radicals initiator, represented by azo-isooleic acid dinitrile, and additive while heating. Method is characterized by that additive used is 4,6-di-tert-butyl-N-(2,6-diethyl phenyl)-o-iminobenzoquinone with molar ratio radical initiator:additive of 1:4. Technical result is producing of polymethyl methacrylate without gel effect, with high outputs (up to 74 %), controlled molecular weight and low polydispersity (PDI=1.4).EFFECT: disclosed is polymethyl methacrylate producing method.1 cl, 1 tbl, 2 dwg