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外文学位

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  • [学位] Synthesis, Monitoring, and Molechanical Action of Light-Driven Motorized Nanomachines

    This dissertation describes the design and synthesis of a series of unimolecular nanomachines bearing a fast light-driven rotary motor (3 MHz at 25 °C) as a power unit and fluorophores for their monitoring. A well-tailored structural design that unifies th

  • [学位] Carbon Nanotubides: An Alternative for Dispersion, Functionalization and Composites Fabrication

    Negatively charged single-walled carbon nanotube (SWCNT), also called SWCNT polyelectrolytes and single-walled carbon nanotubides (SWCNTDs), are formed by the reduction (either chemical or electrochemical) of the SWCNT wall by alkali metals (or an electrod

  • [学位] Ambient Mechanochemical Solid-State Reactions of Carbon Nanotubes and Their Reactions via Covalent Coordinate Bond in Solution

    In its first part, this thesis deals with ambient mechanochemical solid-state reactions of differently functionalized multiple walled carbon nanotubes (MWCNTs) while in its second part it investigates the cross-linking reactions of CNTs in solution via cov

  • [学位] Advanced Quantitative Analysis of Single-Walled Carbon Nanotube Samples

    Single-walled carbon nanotubes (SWCNTs) are a family of one-dimensional nanomaterials with remarkable physical properties promising wide range of potential applications. However, their usage is hindered by their structural heterogeneity. Thus, SWCNT sample

  • [学位] The Attempted Synthesis of Carba-Nicotinic Acid Mononucleotide Methyl Ester using the Zincke Reac

    According to the retrosynthetic analysis, the carba-nicotinic acid mononucleotide methyl ester can be synthesized from a nucleoside made using a primary amine and a Zincke salt by the Zincke reaction. The primary amine which was the cyclopentane analog of

  • [学位] A Biophysical Investigation of Calcineurin Binding to Calmodulin

    Calcineurin (CaN) plays an important role in T-cell activation, cardiac system development, and nervous system function. Previous studies have suggested that the regulatory domain (RD) of CaN binds Calmodulin (CaM) towards the N-terminal end of CaN. Calciu

  • [学位] Supramolecular Devices and Materials

    This thesis describes work towards the development of a range of supramolecular devices and materials based on cyclodextrin host-guest interactions, and/or short peptide structures. The first such device targeted was a photoswitchable molecular lariat com

  • [学位] Strategies for the detection of designer steroids in racehorses

    Anabolic androgenic steroids (AAS) are a class of compounds which include the parent compound testosterone, and are well-known for their misuse as performance enhancing substances in sport. Over the last decade there has a push towards the illicit use of s

  • [学位] Mechanistic Insights into Carbon-Carbon Bond Oxidative Reconstruction and Construction

    Chemical manipulation of carbon-carbon bond is an expansive subject and overarching theme in chemistry. By all accounts, it takes a broad and concerted experimental and theoretical effort in order to fully comprehend the nature of this chemical bond that i

  • [学位] Aqueous Photolysis of 6:2 Fluorotelomer Sulfonamide Alkylbetaine

    The aqueous photolytic fate of 6:2 fluorotelomer sulfonamide alkylbetaine (6:2 FTAB) was determined experimentally. The PhotoFate system was used to compare the kinetic and mechanistic differences between direct and indirect aqueous photolysis of 6:2 FTAB.

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