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外文学位

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  • [学位] Synthesis, Monitoring, and Molechanical Action of Light-Driven Motorized Nanomachines

    This dissertation describes the design and synthesis of a series of unimolecular nanomachines bearing a fast light-driven rotary motor (3 MHz at 25 °C) as a power unit and fluorophores for their monitoring. A well-tailored structural design that unifies th

  • [学位] A Biophysical Investigation of Calcineurin Binding to Calmodulin

    Calcineurin (CaN) plays an important role in T-cell activation, cardiac system development, and nervous system function. Previous studies have suggested that the regulatory domain (RD) of CaN binds Calmodulin (CaM) towards the N-terminal end of CaN. Calciu

  • [学位] Ambient Mechanochemical Solid-State Reactions of Carbon Nanotubes and Their Reactions via Covalent Coordinate Bond in Solution

    In its first part, this thesis deals with ambient mechanochemical solid-state reactions of differently functionalized multiple walled carbon nanotubes (MWCNTs) while in its second part it investigates the cross-linking reactions of CNTs in solution via cov

  • [学位] Carbon Nanotubides: An Alternative for Dispersion, Functionalization and Composites Fabrication

    Negatively charged single-walled carbon nanotube (SWCNT), also called SWCNT polyelectrolytes and single-walled carbon nanotubides (SWCNTDs), are formed by the reduction (either chemical or electrochemical) of the SWCNT wall by alkali metals (or an electrod

  • [学位] The Attempted Synthesis of Carba-Nicotinic Acid Mononucleotide Methyl Ester using the Zincke Reac

    According to the retrosynthetic analysis, the carba-nicotinic acid mononucleotide methyl ester can be synthesized from a nucleoside made using a primary amine and a Zincke salt by the Zincke reaction. The primary amine which was the cyclopentane analog of

  • [学位] Advanced Quantitative Analysis of Single-Walled Carbon Nanotube Samples

    Single-walled carbon nanotubes (SWCNTs) are a family of one-dimensional nanomaterials with remarkable physical properties promising wide range of potential applications. However, their usage is hindered by their structural heterogeneity. Thus, SWCNT sample

  • [学位] Direct Methods For Solving the Schrodinger Equation: Explicitly Correlated Wavefunctions

    The notions of electron correlation and correlation problem arising in the framework of approximate solutions to the Schrödinger equation are presented. Then, we briefly review the original ideas of explicit inclusion of the interelectronic distance, r12,

  • [学位] Mechanistic Insights into Carbon-Carbon Bond Oxidative Reconstruction and Construction

    Chemical manipulation of carbon-carbon bond is an expansive subject and overarching theme in chemistry. By all accounts, it takes a broad and concerted experimental and theoretical effort in order to fully comprehend the nature of this chemical bond that i

  • [学位] Functionalization of Linear Poly(ethylenimine) as DNA-Binding Polymer for Gene Therapy Application

    Gene therapy is a technique used to combat diseases by correcting the defective gene responsible for the disease to alleviate its symptoms and restore normal function to the defective gene. Gene therapy uses vectors to deliver a functional copy of the defe

  • [学位] Supramolecular Devices and Materials

    This thesis describes work towards the development of a range of supramolecular devices and materials based on cyclodextrin host-guest interactions, and/or short peptide structures. The first such device targeted was a photoswitchable molecular lariat com

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